电化学改性对PAN基碳纤维表面状态的影响

郭云霞; 刘杰; 梁节英

电化学改性对PAN基碳纤维表面状态的影响

1.
中北大学化学工程系, 太原 030051;
2.
北京化工大学国家碳纤维工程与技术研究中心, 北京 100029

基金项目: 国家自然科学基金重点项目(50333070); 国家自然科学基金项目(50172004 和50273002)

详细信息

通讯作者:
刘杰,研究员,博士生导师,主要从事高性能碳纤维及功能碳纤维的应用挤出研究与开发 E-mail:liuj@mail.Buct.edu.cn

中图分类号: TB332;TQ342⁺.742
计量
- 文章访问数: 1700
- PDF下载量: 1253
- 被引次数: 0
出版历程
- 收稿日期: 2004-09-07
- 修回日期: 2004-12-20
- 刊出日期: 2005-06-15

EFFECT OF ELECTROCHEMICAL MODIFICATION ON THE SURFACESTATE OF PAN-BASED CARBON FIBERS

1.
Department of Chemical Engineering, North University of China, Taiyuan 030051, China;
2.
National Research Center of Carbon Fiber Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China

摘要

摘要: 采用电化学氧化法对聚丙烯腈(PAN) 基碳纤维进行表面改性, 利用扫描电子显微镜(SEM) 、原子力显微镜(AFM) 、X 射线光电子能谱(XPS) 和X 射线衍射(XRD) 对改性后的碳纤维表面状态进行了研究。同时探讨了碳纤维表面状态与其抗拉强度及其复合材料力学性能的关联。研究结果表明, 碳纤维经电化学氧化后, 表面的粗糙度提高了1.1 倍; 表面碳含量降低了9.7 %, 氧含量提高了53.8 %, 氮含量增加了7.5 倍, 羟基和羰基含量也有不同程度的提高; 表面取向指数减小了1.5 %, 表面微晶尺寸减小, 表面活性碳原子数增加了78 %。电化学氧化法的刻蚀作用致使碳纤维拉伸强度降低了8.1 %, 但同时也改善了碳纤维表面的物理性质和化学性质, 提高了碳纤维与树脂间的粘结性, 使复合材料的ILSS 提高26 %。
- 碳纤维 /
- 改性 /
- 电化学氧化 /
- 表面状态
Abstract: The surface of PAN-based carbon fibers was modified by elect rochemical oxidation. The surface state ofmodified carbon fibers was studied using SEM, AFM, XPS and XRD. The relationship s of surface state of carbonfibers and it s tensile st rength and mechanical performance of carbon fiber reinforced PAN (CFRP) were discussed.The result s show that surface roughness of modified carbon fibers was 1.1 times higher than that of the unt reatedone. Carbon content s decrease by 9.7 %, oxygen and nit rogen content s increase by 53.8 % and 7.5 times respectively, and the hydroxyl and carbonyl content s also increase. The surface orientation index reduces by 1.5 %, and themicrocrystalline dimension also decreases, and the active carbon atoms of carbon fiber surface increase by 78 %. Thetensile st rength of carbon fibers decreases by 8.1 % due to corrosion process of the elect rochemical oxidative method. The physical and chemical properties of carbon fiber, surface are modified during this process, the cohesivenessbetween the fibers and resin mat rix is improved and the ILSS of CFRP is increased by 26 %.
- carbon fiber /
- elect rochemical oxidation /
- surface state /