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热处理对含CSiCTaCC界面C/C复合材料力学性能的影响
引用本文:李斌,陈招科,熊翔.热处理对含CSiCTaCC界面C/C复合材料力学性能的影响[J].复合材料学报,2012,29(1):98-103.
作者姓名:李斌  陈招科  熊翔
作者单位:中南大学 粉末冶金国家重点实验室, 长沙 410083
基金项目:国家重点基础研究项目(2011CB605805); 国家自然科学基金创新群体研究项目(51021063); 湖南省自然科学基金联合基金项目(10JJ6083); 教授部博士点新教师基金项目(20100162120002)
摘    要:以准三维针刺炭纤维毡为预制体, 采用化学气相渗透工艺在预制体中炭纤维/基体炭之间制备C-SiC-TaC-C复合界面, 利用树脂浸渍-炭化工艺对材料进一步增密, 获得含C-SiC-TaC-C界面的C/C复合材料。研究了1400~2500℃不同温度热处理前后复合材料的微观结构和力学性能。结果表明: 热处理前, SiC-TaC界面为管状结构, 复合材料的抗弯强度为241.6 MPa, 以脆性断裂为主; 经1400~1800℃热处理后, TaC界面破坏呈颗粒状, 复合材料的平均抗弯强度下降到238.9~226.1 MPa, 其断裂方式不变, 但断裂位移由0.7 mm增至1.0 mm; 经2000~2500℃热处理后, SiC、 TaC界面均受到破坏, 复合材料平均抗弯强度急剧下降至158.7~131.8 MPa, 断裂方式由脆性断裂转变为假塑性断裂。 

关 键 词:C/C复合材料    C-SiC-TaC-C界面    热处理    界面微观结构    力学性能
收稿时间:2010-12-06
修稿时间:2011-05-24

Effect of heat treatment on mechanical properties of C/C composites with C SiC TaC C multi-interlayers
LI Bin,CHEN Zhaoke,XIONG Xiang.Effect of heat treatment on mechanical properties of C/C composites with C SiC TaC C multi-interlayers[J].Acta Materiae Compositae Sinica,2012,29(1):98-103.
Authors:LI Bin  CHEN Zhaoke  XIONG Xiang
Affiliation:State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China
Abstract:C-SiC-TaC-C multi-interlayers were introduced in the carbon fiber/carbon matrix interface in quasi 3D needled carbon felt by chemical vapor infiltration,the modified C/C porous performs were densified by impregnation-carbonization processes to obtain C/C composites with C-SiC-TaC-C multi-interlayers.The microstructure and mechanical properties were studied after heat treatment(HTT)at different temperatures of 1400℃~2500℃.The results show that the SiC-TaC interlayers have a tubular structure before HTT;while the average flexural strength of the as-prepared composites is 241.6MPa with a brittle fracture.After HTT at 1400~1800℃,TaC interlayer is damaged to granular structure;As a result,the flexural strength of the composites declines to 238.9~226.1MPa also with a brittle fracture,but an increasing of fracture displacement from 0.7mm to 1.0mm.After HTT at 2000~2500℃,both SiC and TaC interlayer are damaged.The flexural strength sharply declines to 158.7~131.8MPa with an obvious change of fracture behavior from brittleness to pseudo-ductility.
Keywords:C/C composites  C-SiC-TaC-C multi-interlayer  high temperature treatment  microstructure of interlayers  mechanical properties
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