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Polymer Self‐Etching for Superhydrophobicity through a Green Hot‐Pressing‐Exfoliation Process: Low and High Adhesion
Authors:Zhong Xiong  Chenglin Zheng  Yanzhi Xia
Affiliation:1. College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, China;2. State Key Laboratory Cultivating Base for New Fiber Materials and Modern Textiles, Collaborative Innovation Center for Marine Biomass Fibers, Materials and Textiles of Shandong Province, Qingdao University, Qingdao, China
Abstract:A green polymer self‐etching strategy for fabricating superhydrophobic surfaces exhibiting low and high adhesion is proposed by using hot‐pressing and exfoliation on a pair of low density polyethylene (LDPE) films. It is demonstrated that the hot‐pressing temperature has significant influence on the surface morphology of LDPE. Effective hot‐pressing temperature for low‐adhesive superhydrophobicity ranges from 109 to 161 °C. Bird's‐nest like micro‐/nanostructures are observed in the unzipped LDPE surfaces compressed at 109 °C, which shows excellent water repellency. LDPE surface compressed at 108 °C demonstrates superhydrophobicity with high adhesion, i.e., a water droplet cannot roll off even when the surface is turned upside down. Furthermore, superhydrophobic vessels are processed and applied to transport water and microdroplets of water losslessly.
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Keywords:high adhesion  hot‐pressing‐exfoliation  low density polyethylene  self‐etching  superhydrophobic
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