| 2-乙基-1，3-己二醇萃取硼酸的传质系数 |
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| 引用本文： | 吕建华,孙玉洁,李春利.2-乙基-1，3-己二醇萃取硼酸的传质系数[J].化工学报,2012,63(Z1):145-153. |
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| 作者姓名： | 吕建华 孙玉洁 李春利 |
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| 作者单位： | 河北工业大学化工学院，天津 300130 |
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| 基金项目： | 河北省教育厅2009年科学研究计划批准项目(2009426)~~ |
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| 摘 要： | 单液滴法因其测量结果精确与实验设备简单等优点广泛应用于萃取过程中的传质研究。应用此方法研究了硼酸在2-乙基-1，3-己二醇-甲苯/卤水体系中的传质系数。结果表明：传质系数随着有机相2-乙基-1，3-己二醇浓度、卤水相硼酸浓度及温度的增加而增大。通过双膜传质理论分析，并引入修正的传质系数关联式，将双膜传质模型应用到此萃取体系中，建立了新的针对此体系的传质系数模型。新模型的计算值与实验值的平均相对误差为7.59 %，两者吻合良好，因此，该模型可用于2-乙基-1，3-己二醇-甲苯体系萃取硼酸过程的设计与放大。
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| 关 键 词： | 2-乙基-1 3-己二醇 硼酸 传质系数 双膜理论 |
| 收稿时间： | 2012-05-02 |
| 修稿时间： | 2012-04-27 |
Mass transfer coefficient of extracting boric acid by 2-ethyl-1,3-hexanediol |
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| Lü Jianhua,SUN Yujie,LI Chunli.Mass transfer coefficient of extracting boric acid by 2-ethyl-1,3-hexanediol[J].Journal of Chemical Industry and Engineering(China),2012,63(Z1):145-153. |
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| Authors: | Lü Jianhua SUN Yujie LI Chunli |
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| Affiliation: | (School of Chemical Engineering,Hebei University of Technology,Tianjin 300130,China) |
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| Abstract: | Single drop technique is a good method for studying mass transfer in solvent extraction because of its accurate results and simple equipment.The mass transfer coefficient of forward extraction of boric acid from salt lake brine by 2-ethyl-1,3-hexanediol in toluene was investigated.The result shows that the mass transfer coefficient increases with the increasing of temperature and initial concentrations of 2-ethyl-1,3-hexanediol in the organic phase and boric acid in aqueous phase.The model of mass transfer coefficient was established with two-film theory model by considering the modified correlation of mass transfer coefficient.The average relative error of calculated and experimental value of the model was 7.59%,which showed that the results were in good agreement with experimental values.The model can be used to design and scale boric acid extraction process by 2-ethyl-1,3-hexanediol-toluene. |
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| Keywords: | 2-ethyl-1 3-hexanediol boric acid mass transfer coefficient two-film theory |
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