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Statistical Optimization for Production of Light Olefins in a Fluidized‐Bed Reactor
Authors:Hassan Sharifi Pajaie  Majid Taghizadeh
Affiliation:Babol University of Technology, Chemical Engineering Department, Babol, Iran.
Abstract:The methanol‐to‐olefins reaction (MTO) was studied in a small‐scale fluidized‐bed reactor over synthesized silicoaluminophosphate (SAPO‐34) catalysts. Mesoporous nanocrystalline SAPO‐34 molecular sieves were synthesized hydrothermally by ultrasonic and microwave‐assisted aging processes in the presence of hexadecyltrimethylammonium bromide (CTAB) and tetradecyldimethyl(3‐trimethoxysilylpropyl)ammonium chloride (TPOAC) as surfactant agents. The Box‐Behnken experimental design method was applied to determine the optimum operating parameters of this process conducted in the fluidized‐bed reactor. The optimum conditions in terms of reaction temperature, ratio of inlet gas velocity to minimum fluidizing velocity, and MeOH weight fraction were evaluated.
Keywords:Catalysis  Fluidized beds  Mesoporous materials  Molecular sieves
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