Homogeneous 2D MoTe2 p–n Junctions and CMOS Inverters formed by Atomic‐Layer‐Deposition‐Induced Doping |
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| Authors: | June Yeong Lim Atiye Pezeshki Sehoon Oh Jin Sung Kim Young Tack Lee Sanghyuck Yu Do Kyung Hwang Gwan‐Hyoung Lee Hyoung Joon Choi Seongil Im |
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| Affiliation: | 1. Institute of Physics and Applied Physics, Yonsei University, Seodaemun‐gu, Seoul, South Korea;2. Center for Optoelectronic Materials and Devices Post‐Silicon Semiconductor Institute, Korea Institute of Science and Technology (KIST), Seongbuk‐gu, Seoul, South Korea;3. Department of Materials Science and Engineering, Yonsei University, Seoul, South Korea |
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| Abstract: | Recently, α‐MoTe2, a 2D transition‐metal dichalcogenide (TMD), has shown outstanding properties, aiming at future electronic devices. Such TMD structures without surface dangling bonds make the 2D α‐MoTe2 a more favorable candidate than conventional 3D Si on the scale of a few nanometers. The bandgap of thin α‐MoTe2 appears close to that of Si and is quite smaller than those of other typical TMD semiconductors. Even though there have been a few attempts to control the charge‐carrier polarity of MoTe2, functional devices such as p–n junction or complementary metal–oxide–semiconductor (CMOS) inverters have not been reported. Here, we demonstrate a 2D CMOS inverter and p–n junction diode in a single α‐MoTe2 nanosheet by a straightforward selective doping technique. In a single α‐MoTe2 flake, an initially p‐doped channel is selectively converted to an n‐doped region with high electron mobility of 18 cm2 V?1 s?1 by atomic‐layer‐deposition‐induced H‐doping. The ultrathin CMOS inverter exhibits a high DC voltage gain of 29, an AC gain of 18 at 1 kHz, and a low static power consumption of a few nanowatts. The results show a great potential of α‐MoTe2 for future electronic devices based on 2D semiconducting materials. |
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| Keywords: | 2D semiconductors α ‐MoTe2 atomic‐layer‐deposition‐induced doping homogeneous complementary inverters p– n junction diodes |
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