|
|||||
|
|
Palm oil deodorizer distillate as toughening agent in polylactide packaging films |
|
| Authors: | Alexandre Ruellan Violette Ducruet Audrey Gratia Lidia Saelices Jimenez Alain Guinault Cyrille Sollogoub Guillaume Chollet Sandra Domenek |
| Affiliation: | 1. UMR Ingénierie Procédés Aliments, AgroParisTech, INRA, Université Paris Saclay, Massy, France;2. PIMM, Arts et Métiers ParisTech/CNRS/CNAM, Paris Cedex, France;3. Brodart Packaging, Département R&D, Arcis‐Sur‐Aube, France;4. LNE, Département Chimie et Physico‐Chimie des Matériaux, Trappes, France;5. ITERG, Lipochimie Hall Industriel, Pessac, France |
| Abstract: | Polylactide (PLA) is the most used biodegradable and biobased food packaging polymer for rigid containers and films. However, its low ductility is a hurdle for increasing its applications in flexible food packaging. A solution is the use of additives. Palm oil deodorizer distillate (PODC) is revealed to be an excellent additive promoting PLA ductility. PODC is a by‐product of vegetable oil refining, which is available in stable quality and in sufficient amounts. Amorphous PLA/PODC blends had an elongation at break of around 130% and that of semi‐crystalline blends was still around 55% compared to the initial 5% of neat PLA. At the same time the PLA rigidity and high glass transition temperatures were kept. PODC was also a very efficient processing aid, allowing for film blow extrusion. The blends were stable in properties during six months without exudation. They complied with legal norms of Food Contact Materials (EU 10/2011) and induced no sensorial alteration of packed food. Therefore PODC is a very interesting alternative to common plasticizers for the production of flexible PLA packaging films. © 2016 Society of Chemical Industry |
| Keywords: | poly(lactic acid) PLA ductility food packaging toughening agent processing aid biodegradation oil refinery by‐product deodorizer distillate |
