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基于微观机理的页岩气运移分析
作者姓名:张鹏伟  胡黎明  温庆博
作者单位:清华大学水利水电工程系,北京100084;清华大学水沙科学与水利水电工程国家重点实验室, 北京100084;清华大学水利水电工程系,北京100084;清华大学水沙科学与水利水电工程国家重点实验室, 北京100084;清华大学水利水电工程系,北京100084;清华大学水沙科学与水利水电工程国家重点实验室, 北京100084
基金项目:清华大学自主科研计划资助项目(THZ20161080101);国家自然科学基金资助项目(41372352)
摘    要:认识气体在页岩孔隙中的运移机理对页岩气开采具有重要的科学意义.页岩作为一种致密岩石,孔隙尺寸分布主要集中在几纳米到百纳米之间,小孔隙尺寸与气体的平均分子自由程在同一个数量级,气体与孔隙边壁的碰撞对流动起到控制作用.本文针对页岩气开采过程中孔隙中气体流动过程,建立了考虑气体滑移、Knudsen扩散、Langmuir等温吸附、孔隙压缩等过程的多场耦合控制方程.分析了流态变化对滑移效应的影响,得到了考虑滑移效应的临界孔径,并针对实际中不同页岩储层有机质含量的差异,分析了解吸机制对页岩气产气率、产气量的贡献.研究还表明孔隙压缩性对产气率影响显著,通过考虑开采过程中孔隙压缩,可以更真实地反映页岩气运移过程. 

关 键 词:滑移流动  孔隙压缩  Knudsen扩散  Langmuir等温吸附  页岩气
收稿时间:2017-05-06

Micro-mechanism analysis of shale gas migration
Affiliation:1) Department of Hydraulic Engineering, Tsinghua University, Beijing 100084, China2) State Key Laboratory of Hydroscience and Engineering, Tsinghua University, Beijing 100084, China
Abstract:For shale gas exploitation, it is scientifically essential to clarify the mechanism of gas flow in nanopore media. Shale is a kind of tight rock, whose pore size mainly ranges from several nanometers to dozens of nanometers. Since it is of the same magnitude as the gas molecular mean free path, the collision between the gas molecular and pore surface is not negligible for gas flow and results in the failure of Darcy's law when describing this low permeability reservoir gas flow mechanism. In order to clarify the micropore gas flow mechanism and the real extraction process of shale gas, a multiphysics governing equation was established, which combines slip flow, Knudsen diffusion, Langmuir isotherm adsorption, and pore compressibility. The effect of different flow regimes on slip flow was analyzed, and the threshold pore size was obtained with consideration of the slippage effect. Then, the contribution of desorption to gas production rate and gas output was clarified based on the organic content of disparate shale samples. The results indicate that the gas production rate is sensitive to pore compressibility, and it is more reasonable to simulate the gas flow process when considering pore compressibility. 
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