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A study based on the oxidation vaporization of LaCrO3
Authors:Xinglian Yin  Qing Zhao  Bo Zhang  Donglin He  Aimin Chang
Affiliation:1. Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry of CAS, Urumqi, China;2. University of Chinese Academy of Sciences, Beijing, China
Abstract:This is a study based on the assumption that the volatilization of Cr gives rise to the poor sinterability of LaCrO3. We have studied the effect of buried materials (none, Al2O3, La2O3, Cr2O3, LaCrO3) on the sinterability of LaCrO3 by conventional sintering in air. It was observed that the sinterability of LaCrO3 in air is largely enhanced by burying with La2O3 (with a linear shrinkage of 12.5% and a relative density of 86.90%). The energy dispersive spectroscopy (EDS) infers that there is a volatilization of Cr in sintering of LaCrO3 in air and the volatilization of Cr does affect the sinterability of LaCrO3.
Keywords:densification  microscopy  sinter/sintering  volatilization
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