| 烷基双胺和烷基单胺微波插层四钛酸材料的结构性能研究 |
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| 引用本文： | 张国辉,孔春梅,唐永明,杨文忠.烷基双胺和烷基单胺微波插层四钛酸材料的结构性能研究[J].硅酸盐通报,2011,30(4):850-853. |
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| 作者姓名： | 张国辉 孔春梅 唐永明 杨文忠 |
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| 作者单位： | 南京工业大学理学院,南京,210009 |
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| 摘 要： | 将K2CO3和TiO2高温固相法合成K2Ti4O9,酸化后得到H2 Ti4 O9,在微波辅助作用下进行烷基双胺H2N(CH2)nNH2(n=4,8,12)和烷基单胺n-CnH2n+1NH2(n=4,8,12)的插层反应,制得了烷基双胺和单胺柱撑的层状复合材料,采用IR、SEM、XRD和元素分析仪对材料进行了表征,并比较...
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| 关 键 词： | 微波辅助 烷基双胺和烷基单胺 层状化合物 插层反应 |
Study on Structural Performance of n-alkyldiamines and n-alkylamines Pillared Layerd Titanates by Microwave Irradiation |
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| ZHANG Guo-hui,KONG Chun-mei,TANG Yong-ming,YANG Wen-zhong.Study on Structural Performance of n-alkyldiamines and n-alkylamines Pillared Layerd Titanates by Microwave Irradiation[J].Bulletin of the Chinese Ceramic Society,2011,30(4):850-853. |
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| Authors: | ZHANG Guo-hui KONG Chun-mei TANG Yong-ming YANG Wen-zhong |
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| Affiliation: | ZHANG Guo-hui,KONG Chun-mei,TANG Yong-ming,YANG Wen-zhong (College of Science,Nanjing University of Technology,Nanjing 210009,China) |
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| Abstract: | The solid phase reaction between K2CO3 and TiO2 was used to prepare the precursor K2Ti4O9.H2Ti4O9 was obtained by ion-exchange of potassium ions with an acidic solution.The intercalation compounds was obtained by the intercalati on of H2N(CH2)nNH2(n=4,8,12)and n-CnH2nNH2(n=4,8,12)under microwave irradiation.The structure of the resultingmaterials was confirmed by X-ray diffraction(XRD),SEM and IR spectroscopy.The results indicate that the interlayer alkylchains are arranged in onelayer for the n-alkyldiamin... |
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| Keywords: | microwave irradiation n-alkyldiamines and n-alkylamines layred compounds intercalation reactions |
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