| 聚双胍/环氧树脂体系潜伏性固化过程 |
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| 引用本文： | 王权,史铁钧,张焱,虞伕,刘建华.聚双胍/环氧树脂体系潜伏性固化过程[J].化工学报,2015,66(1):464-470. |
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| 作者姓名： | 王权 史铁钧 张焱 虞伕 刘建华 |
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| 作者单位： | 合肥工业大学化工学院, 安徽 合肥 230009 |
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| 基金项目： | 国家自然科学基金项目(51273054)。@@@@supported by the National Natural Science Foundation of China |
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| 摘 要： | 用己二胺与双氰胺熔融缩聚,合成了一种新型潜伏性环氧树脂固化剂,并研究了其与环氧树脂的固化过程。用FTIR、XPS、1H NMR分析了固化剂的结构;用DSC分析得到了固化剂与环氧树脂的适宜配比、固化体系的适宜固化温度及固化动力学参数;通过XRD分析了固化物的相结构;通过TG分析了固化物的热稳定性。结果表明,与双氰胺环氧树脂固化体系相比,固化温度降低近70℃,同时潜伏性能良好,30 d内固化度少于10%,热稳定性能良好,热分解温度超过300℃。
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| 关 键 词： | 聚六亚甲基双胍 改性双氰胺 环氧树脂 潜伏性固化剂 合成 动力学 稳定性 |
| 收稿时间： | 2014-06-16 |
| 修稿时间： | 2014-10-14 |
Latent curing of polybiguanide/epoxy resin |
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| WANG Quan,SHI Tiejun,ZHANG Yan,YU Fu,LIU Jianhua.Latent curing of polybiguanide/epoxy resin[J].Journal of Chemical Industry and Engineering(China),2015,66(1):464-470. |
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| Authors: | WANG Quan SHI Tiejun ZHANG Yan YU Fu LIU Jianhua |
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| Affiliation: | School of Chemical Engineering, Hefei University of Technology, Hefei 230009, Anhui, China |
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| Abstract: | A new latent curing agent for epoxy resin was synthesized via melted polycondensation of dicyandiamide (DICY) and hexamethylenediamine. The structure of the curing agent was analyzed with FTIR, XPS, 1H NMR. The optimum ratio, suitable curing temperature and curing kinetic parameters of this epoxy resin curing system were studied with DSC. The phase structure of the cured epoxy resin was investigated with XRD. The thermostability of the cured epoxy resin was obtained by TG. Comparing with the DICY/EP curing system, curing temperature dropped by nearly 70℃. Latency performance was fine as curing degree was less than 10% within 30 days. Thermostability was nice as thermal decomposition temperature exceeded 300℃. |
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| Keywords: | polyhexamethylene biguanidine modified dicyandiamide epoxy resin latent curing agent synthesis kinetics stability |
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