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碳含量对Al0.5Co0.5NiCrFe高熵合金涂层组织与性能的影响
引用本文:时海芳,李强.碳含量对Al0.5Co0.5NiCrFe高熵合金涂层组织与性能的影响[J].金属热处理,2022,47(3):136-141.
作者姓名:时海芳  李强
作者单位:辽宁工程技术大学 材料科学与工程学院, 辽宁 阜新 123000
摘    要:使用氩弧熔覆制备不同碳含量Al0.5Co0.5NiCrFe高熵合金涂层,研究碳含量对Al0.5Co0.5NiCrFe高熵合金涂层组织与性能的影响。结果表明:碳加入后,高熵合金均由单一的FCC结构组成,并没有表征出其他物质,但根据高熵合金显微组织与能谱分析可以发现,高熵合金的枝晶间有碳铬化合物生成。高熵合金涂层的组织为典型的树枝晶结构,随着碳含量的增加,组织不断细化。随碳含量的增加,高熵合金涂层的硬度不断升高,当碳含量为4%时,硬度(383.2 HV0.5)和耐磨性均为最佳。随碳含量的不断增加,高熵合金的耐腐蚀性先增强后减弱,碳含量为2%时耐腐蚀性最佳。根据单位面积氧化增量,高熵合金的抗氧化性先增大后减小,当碳含量为2%时,抗氧化性最佳。

关 键 词:高熵合金涂层  耐磨性  耐腐蚀性  抗氧化性  
收稿时间:2021-12-30

Effect of carbon content on microstructure and properties of Al0. 5Co0. 5NiCrFe high-entropy alloy coating
Shi Haifang,Li Qiang.Effect of carbon content on microstructure and properties of Al0. 5Co0. 5NiCrFe high-entropy alloy coating[J].Heat Treatment of Metals,2022,47(3):136-141.
Authors:Shi Haifang  Li Qiang
Affiliation:School of Materials Science and Engineering, Liaoning Technical University, Fuxin Liaoning 123000, China
Abstract:Al0.5Co0.5NiCrFe high-entropy alloy coatings with different carbon contents were prepared by argon arc cladding, and effect of carbon content on the microstructure and properties of the Al0.5Co0.5NiCrFe high-entropy alloy coating was studied. The results show that after the addition of carbon, the high-entropy alloys are all composed of a single FCC structure, and no other structure are characterized. However, according to the microstructure and energy spectrum analysis of the high-entropy alloy, it can be found that there is carbon and chromium between the dendrites of the high-entropy alloy. The microstructure of the high-entropy alloy coating is a typical dendritic structure, and the microstructure is continuously refined with the increase of carbon content. With the increase of carbon content, the hardness of high-entropy alloy coating increases continuously. When the carbon content is 4%, the highest hardness is 383.2 HV0.5, and the wear resistance is also the best. With the continuous increase of carbon content, the corrosion resistance of high-entropy alloy first increases and then weakens, and when the carbon content is 2%, corrosion resistance is the best. According to the oxidation mass gain per unit area, the oxidation resistance of the high-entropy alloy first increases and then decreases. When the carbon content is 2%, the coating has the best oxidation resistance.
Keywords:high-entropy alloy coating  wear resistance  corrosion resistance  oxidation resistance  
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