Fabrication of Ni_3Al by hot pressing from element powders

Ni3Al intermetallic was synthesized by hot pressing from element powders of nickel, aluminum, and boron. The influences of parameters on the properties of Ni3Al were investigated. The parameters include the particle size of nickel powder, adding or without boron powder, hot pressing temperature, etc. The properties include the density of hot-pressed samples, resultant ratio of Ni3Al phase, and bending strength. The microstructures of hot-pressed samples were investigated by X-ray diffraction and scan electronic microscopy, and the properties, such as density and bending strength, were also measured. The results show that a higher bending strength was obtained under the same hot pressing conditions by the fine nickel powder than the coarse one, and there is little difference about density. Boron powder added in this process acceler- ates the formation of Ni3Al and markedly increases the hot pressed density. In the temperature range of this study, the den- sity increases along with the hot pressing temperature. Full dense Ni3Al samples were obtained under the condition of 860°C, 10 min, 45 MPa from Ni-22.89Al-0.5B powder.     

Diffusion behavior of Nb element in high Nb containing TiAl Alloys by reactive hot pressing

Diffusion behavior of Nb in elemental powder metallurgy high Nb containing TiAl alloys was investigated. The results show that Nb element dissolves into the matrix by diffusion. Pore nests are formed in situ after Nb diffusion. With the increase in hot pressing temperature, the diffusion of Nb will be more sufficient, and the microstructure is more homogeneous. Nb element diffuses completely at 1400℃. Meanwhile, compression deformation and agglomeration phenomena of pores are observed in some pore nests. Hot isostatic pressing （HIP） treatment can only efficiently decrease but not eliminate porosity completely.     

热等静压原位生成Al_2O_3颗粒强化Ti_4AlN_3复合材料

利用Al_3Ti/Ti N纳米复合粉体在1280℃/150 MPa/1 h热等静压条件下,制备出Al_2O_3/Ti_4Al N_3复合材料。利用XRD、SEM和TEM研究复合材料的形貌及成分。研究表明,复合材料主要由片层结构的Ti_4Al N_3基体和Al_2O_3颗粒增强相组成。Ti_4Al N_3基体的平均晶粒尺寸为7μm;Al_2O_3颗粒的弥散分布,形状不规则,粒度在1~3μm,体积分数约为27%。Al_2O_3/Ti_4Al N_3复合材料的强化机制为细晶强化和第二相粒子强化。Al_2O_3/Ti_4Al N_3复合材料与单相的Ti_4Al N_3材料相比,显微硬度从2.5GPa提高到6.7 GPa,室温下最大抗压缩强度从450 MPa提高到1 800 MPa,最大压缩应变由4%提高到6.2%。     

Fe3Al纳米粒子增强Al2O3陶瓷的制备及性能

用热压烧结法制备了纳米Fe3 Al粒子增强Al2 O3 基复合材料。研究了 14 5 0～ 16 0 0℃不同烧结温度下纳米Fe3 Al的加入量与材料的致密度、力学性能及显微结构的关系。结果表明 :纳米Fe3 Al的加入可使Al2 O3 晶粒的生长受到抑制 ,使复合材料的烧结温度提高。Fe3 Al/Al2 O3 纳米复合材料有良好的力学性能 ,其抗弯强度最高可达832MPa ,断裂韧性最高可达 7.96MPa·m1/ 2 。     

THE ALLOYING BEHAVIOR OF BORON AND CARBON INNi_3Al

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热轧薄板冲压性能研究

针对SPHC、SPHE热轧薄板冲压时部分板卷出现开裂、皱褶的问题 ,分析研究了相应钢卷的化学成分、力学性能、金相组织和织构 ,指出采用较高的终轧温度和卷取温度 ,并进行润滑轧制 ,可综合提高热轧薄板的深冲性能和冲压成材率     

MECHANICAL PROPERTIES OF DIRECTIONALLY-SOLIDIFIED Ni_3Al CONTAINING BORON AND CARBON

ＭＥＣＨＡＮＩＣＡＬＰＲＯＰＥＲＴＩＥＳＯＦＤＩＲＥＣＴＩＯＮＡＬＬＹＳＯＬＩＤＩＦＩＥＤＮｉ３ＡｌＣＯＮＴＡＩＮＩＮＧＢＯＲＯＮＡＮＤＣＡＲＢＯＮ①ＺｈａｎｇＹｕｎ，ＬｉｎＤｏｎｇｌｉａｎｇＩｎｓｔｉｔｕｔｅｏｆＭａｔｅｒｉａｌｓＳｃｉｅｎｃｅａ...     

含Zr多晶Ni3Al合金在不同热处理温度下的组织与性能

研究了冷轧多晶Ni3Al-(0．2％，0．6％，1．0％，1．5％)Zr(原子分数)合金在不同热处理温度(800-1100℃)下的显微组织和力学性能，结果表明，适当的热处理温度，可使无硼Ni3Al-Zr多晶合金获得优良的室温拉伸强度和塑性，随着热处理温度的升高，不同Zr含量Ni3Al合金的再结晶体积分数增加，再结晶晶粒尺寸增大，室温拉伸强度下降．随着合金中Zr含量的增加，再结晶温度降低，再结晶晶粒尺寸减小．不同Zr含量Ni3Al合金的拉伸塑性明显依赖于热处理温度，对于低Zr(0．2％)合金，在1000℃热处理后，拉伸塑性最佳；对于中Zr(0．6％)合金，在850℃热处理后，拉伸塑性达到最大值；对于高Zr(≥1．0％)合金，拉伸塑性峰值出现在900℃热处理下，当热处理温度超过900℃，拉伸塑性显著降低。     

大尺寸TiB2-Cu-Ni金属陶瓷块体的燃烧合成及准热等静压致密化

利用燃烧合成结合准热等静压 (PHIP)技术成功制备了直径为 2 40mm的大尺寸TiB2 Cu Ni金属陶瓷 ,对合成产物进行了X射线衍射 (XRD)、扫描电镜 (SEM)和力学性能等实验研究。XRD结果表明反应产物中只有TiB2 和 (Cu ,Ni)两相。SEM分析发现增强相TiB2 陶瓷颗粒已经形成骨架状 ,其间为 (Cu ,Ni)基体相 ,TiB2 颗粒形貌为近等轴状 ,尺寸细小且较均匀。合成产物的致密度为 94.2 % ,弯曲强度和断裂韧性分别达到 5 99.4MPa和12 .5 6MPa·m1/ 2 。     

不同压力下的热压加工对含Mn块体纳米晶Fe3Al组织和性能的影响

对铝热反应熔化制备的含10wt%Mn块体纳米晶Fe3Al材料在800℃和1000℃温度下,采用不同压力进行热压加工,利用XRD研究热压加工前后纳米晶粒尺寸的变化,并测试硬度变化和压缩率。结果显示,不同温度、压力下热压加工后,晶粒尺寸变化不大;热压加工后,材料的硬度有所上升,但温度和压力对硬度影响不大;热压加工中,材料表现出较好的塑性变形,并随着热压压力的增大,材料压缩率逐渐增大,但温度对材料的压缩率影响不明显。热压加工后,块体纳米晶Fe3Al材料几何尺寸得到了增大。     

Thermodynamic analysis of combusion synthesis and reaction hot pressing of Al2O3/B4C composite

１－ＩｎｔｒｏｄｕｃｔｉｏｎＢｏｒｏｎｃａｒｂｉｄｅｒｅｉｎｆｏｒｃｅｄａｌｕｍｉｎａｃｏｍｐｏｓｉｔｅｓ（Ａｌ２Ｏ３／Ｂ４Ｃ）ｈａｖｅｉｍｐｒｏｖｅｄｆｌｅｘｕｒａｌｓｔｒｅｎｇｔｈａｎｄｆｒａｃｔｕｒｅｔｏｕｇｈｎｅｓｓｏｖｅｒｔｈｅａｌｕｍｉｎａｃｅｒａｍｉｃ［１］．Ｍｏｒｅｏｖｅｒ,ｓｉｎｃｅｂｏｔｈｂｏｒｏｎｃａｒｂｉｄｅａｎｄａｌｕｍｉｎａｈａｖｅｌｏｗｄｅｎｓｉｔｉｅｓ（２．５１ａｎｄ３．９８ｇ／ｃｍ３,ｒｅｓｐｅｃｔｉｖｅｌｙ）,ｔｈｅｒｅｓｕｌｔｉｎｇｃｏｍｐｏｓｉｔｅ…     

Thermoelectric properties of p-type (Bi,Sb)2Te3 alloys fabricated by the hot pressing method

P-type (Bi_0.25Sb_0.75)₂Te₃ powders were fabricated by melting/grinding and mechanical alloying processes. Thermoelectric properties of the hot-pressed (Bi_0.25Sb_0.75)₂Te₃ were characterized with the powder processing method, powder size, hot pressing temperature, and the amount of excess-Te dopant. Specimens fabricated by melting/grinding exhibited lower Seebeck coefficient, lower electrical resistivity and higher thermal conductivity, compared to the specimens prepared by mechanical alloying. 3 wt.% excess Te-doped (Bi_0.25Sb_0.75)₂ Te₃, fabricated by melting/grinding and hot pressing at 550°C, exhibited a figure-merit of 3.2 x 10^-3/K. For 1 wt.% excess Te-doped specimen prepared by mechanical alloying and hot pressing at 550°C, a figure-merit of 3.05 x 10^-3/K was obtained.     

TC11钛合金粉末涡轮盘热等静压成形数值模拟研究

为了成形复杂结构的涡轮盘零件,采用粉末热等静压工艺(HIP),设计了粉末净成形和粉-固扩散连接成形两种方案,使用MSC.MARC软件,在Shima模型中嵌入TC11钛合金材料参数进行数值模拟研究。模拟结果显示:粉末净成形的模具变形是粉-固扩散连接成形的2倍左右;粉末净成形的粉末体在热等静压后,关键部位出现明显的密度梯度分布,相对密度较低,粉-固扩散连接成形的相对密度分布的均匀性优于粉末净成形,所以粉-固扩散连接成形方案优于粉末净成形方案。试验结果显示:热等静压工艺可以实现闭式涡轮盘的净成形。     

Bulk Al/SiC nanocomposite prepared by ball milling and hot pressing method

Nano-sized Al/SiC powders were prepared by mechanical alloying method. Two sorts of SiC particle, i.e., nano-sized and popular micron-sized SiC were utilized. The particle size and microstructure of the milled powder were characterised. Effects of the particle size and agglomerate state of SiC, as well as the microstructure of Al/SiC nanocomposite were studied by SEM and TEM. The results show that nano-sized SiC particles is dispersed in aluminium uniformly after ball milled for only 2 h, whereas the similar process need about 10 h for popular micron-sized SiC particle. The bulk Al/SiC nanocomposite can be fabricated by hot pressing the nano-sized Al/SiC powders at temperature about 723 K under pressure of 100 MPa.     

TiC/Ni3Al表面复合涂层及其耐磨性

采用铸造工艺结合SHS技术制备TiC/Ni3Al表面复合涂层,研究了涂层的显微组织及其耐磨性.结果表明表面复合涂层中直径为1 μm～2μm的TiC颗粒呈球形镶嵌在Ni3Al基体上,涂层致密.与钢基体为良好的冶金结合,界面随TiC含量的变化而呈现不同的形貌,在TiC含量＜45%时,涂层为一整体;在TiC含量≥45%时,涂层出现了分层.表面复合涂层的HV值最高达8970 MPa,沿界面呈梯度变化;涂层具有高的耐磨性,在室温下约是钢基体的3～5倍;在400℃下是钢基体的20倍左右.     

TiC/Ni3Al表面复合涂层及其耐磨性

采用铸造工艺结合SHS技术制备TiC/Ni3Al表面复合涂层,研究了涂层的显微组织及其耐磨性.结果表明:表面复合涂层中直径为1 μm～2μm的TiC颗粒呈球形镶嵌在Ni3Al基体上,涂层致密.与钢基体为良好的冶金结合,界面随TiC含量的变化而呈现不同的形貌,在TiC含量＜45%时,涂层为一整体;在TiC含量≥45%时,涂层出现了分层.表面复合涂层的HV值最高达8970 MPa,沿界面呈梯度变化;涂层具有高的耐磨性,在室温下约是钢基体的3～5倍;在400℃下是钢基体的20倍左右.     

钛/铝/钛层状复合材料的爆炸复合制备及后续热压处理研究

本文以纯钛板与纯铝板为原料,通过爆炸复合法制备钛/铝/钛层状复合材料,之后采用热处理以及热压工艺对钛/铝/钛层状复合材料进行进一步处理。研究结果表明：复合板界面主要由波状界面和平直状界面构成,铝元素与钛元素在界面上发生了互扩散,界面结合性能优良,可以承受后续较大的二次塑性变形;热处理后的复合板界面发生明显扩散,在热处理25 h后热压2.5 h后铝层完全反应,扩散反应层主要由TiAl₃相以及Ti₂Al₅相构成。     

反应热压法制备Al2O3/NiCrAl复合材料及功能梯度材料

采用NiO、Al和Cr粉末反应热压制备了Al2O3/NiCrAl复合材料,NiCrAl合金由NiO还原出来的Ni与添加的Cr和Al反应形成.制备了不同Al2O3含量的Al2O3/NiCrAl复合材料,并以Al2O3体积分数分别为25%、52.2%和75%的Al2O3/NiCrAl复合材料为过渡层制备了Y稳定氧化锆(YSZ)到NiCrAl合金的功能梯度材料.X射线衍射分析、金相观察、硬度测量和热循环冲击实验结果表明:用该方法制备的复合材料由Al2O3陶瓷相和(Ni,Cr,Al)固溶体组成,而Al2O3颗粒由NiO与Al原位反应形成,尺寸细小,呈弥散分布.该功能梯度材料经从室温到1 000℃空气中10次热循环后未发现有裂纹,表明该方法制备的材料陶瓷相与合金相有良好的相容性、较高的结合强度、良好的耐高温抗氧化及热循环冲击性能.     

连续式热压烧结金刚石制品的研究

烧结是决定金刚石制品性能的关键环节。通过对比分析普通电阻式热压烧结工艺和连续式热压烧结工艺所获得的锯片试样,阐述了连续式热压烧结工艺制备金刚石制品的优越性。结果表明:连续式热压烧结工艺能降低产品的气孔率,提高致密度和质量稳定性;改善金属胎体对金刚石的包镶状况;减少烧结过程中的能耗和烟尘,对金刚石制品行业节能减排具有积极推动作用。