Thermal performance of PCM thermal storage unit for a roof integrated solar heating system

The thermal performance of a phase change thermal storage unit is analysed and discussed. The storage unit is a component of a roof integrated solar heating system being developed for space heating of a home. The unit consists of several layers of phase change material (PCM) slabs with a melting temperature of 29 °C. Warm air delivered by a roof integrated collector is passed through the spaces between the PCM layers to charge the storage unit. The stored heat is utilised to heat ambient air before being admitted to a living space. The study is based on both experimental results and a theoretical two dimensional mathematical model of the PCM employed to analyse the transient thermal behaviour of the storage unit during the charge and discharge periods. The analysis takes into account the effects of sensible heat which exists when the initial temperature of the PCM is well below or above the melting point during melting or freezing. The significance of natural convection occurring inside the PCM on the heat transfer rate during melting which was previously suspected as the cause of faster melting process in one of the experiments is discussed. The results are compared with a previous analysis based on a one dimensional model which neglected the effect of sensible heat. A comparison with experimental results for a specific geometry is also made.     

Thermal performance simulations of a packed bed cool thermal energy storage system using n-tetradecane as phase change material

The objective of this paper is to study the thermal performance of latent cool thermal energy storage system using packed bed containing spherical capsules filled with phase change material during charging and discharging process. According to the energy balance of the phase change material (PCM) and heat transfer fluid (HTF), a mathematical model of packed bed is conducted. n-tetradecane is taken as PCM and aqueous ethylene glycol solution of 40% volumetric concentration is considered as HTF. The temperatures of the PCM and HTF, solid and melt fraction and cool stored and released rate with time are simulated. The effects of the inlet temperature and flow rate of HTF, porosity of packed bed and diameter of capsules on the melting time, solidification time, cool stored and released rate during charging and discharging process are also discussed.     

Experimental research on thermal characteristics of PCM thermal energy storage units

To explore thermal management integration in electric vehicles (EVs), a phase change materials (PCMs) thermal energy storage unit using flat tubes and corrugated fins is designed. The investigation focuses on the thermal characteristics of the PCM unit, such as the temperature variation, heat capacity, and heat transfer time, etc. Meanwhile, the heat storage and release process will be influenced by different inlet temperature, liquid flow rate, melting point of the PCM, and the combination order of the units. Under the same inlet temperature and flow rate condition, the PCM unit with higher melting point enters the latent heat storage stage slowly and enters the phase change melting release stage quickly. Furthermore, the heat storage and release rates increase with increasing liquid flow rates, but the effects are diminishing in the middle and later periods. The multiple PCM units with different melting temperatures are cascaded to help recycle low-grade heat energy with different temperature classes and exhibit well heat storage and release rates.     

Thermal Performance of a Phase Change Material‐Based Latent Heat Thermal Storage Unit

An experimental analysis is presented to establish the thermal performance of a latent heat thermal storage (LHTS) unit. Paraffin is used as the phase change material (PCM) on the shell side of the shell and tube‐type LHTS unit while water is used as the heat transfer fluid (HTF) flowing through the inner tube. The fluid inlet temperature and the mass flow rate of HTF are varied and the temperature distribution of paraffin in the shell side is measured along the radial and axial direction during melting and solidification process. The total melting time is established for different mass flow rates and fluid inlet temperature of HTF. The motion of the solid–liquid interface of the PCM with time along axial and radial direction of the test unit is critically evaluated. The experimental results indicate that the melting front moves from top to bottom along the axial direction while the solidification front moves only in the radial direction. The total melting time of PCM increases as the mass flow rate and inlet temperature of HTF decreases. A correlation is proposed for the dimensionless melting time in terms of Reynolds number and Stefan number of HTF. © 2013 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21120     

Melting of PCM in a thermal energy storage unit: Numerical investigation and effect of nanoparticle enhancement

The present paper describes the analysis of the melting process in a single vertical shell‐and‐tube latent heat thermal energy storage (LHTES), unit and it is directed at understanding the thermal performance of the system. The study is realized using a computational fluid‐dynamic (CFD) model that takes into account of the phase‐change phenomenon by means of the enthalpy method. Fluid flow is fully resolved in the liquid phase‐change material (PCM) in order to elucidate the role of natural convection. The unsteady evolution of the melting front and the velocity and temperature fields is detailed. Temperature profiles are analyzed and compared with experimental data available in the literature. Other relevant quantities are also monitored, including energy stored and heat flux exchanged between PCM and HTF. The results demonstrate that natural convection within PCM and inlet HTF temperature significantly affects the phase‐change process. Thermal enhancement through the dispersion of highly conductive nanoparticles in the base PCM is considered in the second part of the paper. Thermal behavior of the LHTES unit charged with nano‐enhanced PCM is numerically analyzed and compared with the original system configuration. Due to increase of thermal conductivity, augmented thermal performance is observed: melting time is reduced of 15% when nano‐enhanced PCM with particle volume fraction of 4% is adopted. Similar improvements of the heat transfer rate are also detected. Copyright © 2012 John Wiley & Sons, Ltd.     

Performance enhancement of a solar dynamic LHTS module having both fins and multiple PCMs

Latent heat thermal storage units span a wide and varied range of applications in the domestic, industrial and space based activities. Numerical investigations on the performance enhancement of a solar dynamic latent heat thermal storage (LHTS) unit employing multiple phase change materials (PCM) and fins are made. The LHTS unit has been studied for the charging mode alone. Enthalpy based formulation of the energy equations governing the behaviour of the LHTS system has been made and compared with the response of a single PCM unit. The governing conjugate equations have been solved employing finite difference techniques. The results show an appreciable enhancement in the rate of melting of PCM and nearly uniform exit temperature of heat transfer fluid (HTF) in the multiple PCM LHTS unit.     

Numerical and experimental investigation for heat transfer in triplex concentric tube with phase change material for thermal energy storage

This paper addresses a numerical and experimental investigation of a thermal energy storage unit involving phase change process dominated by heat conduction. The thermal energy storage unit involves a triplex concentric tube with phase change material (PCM) filling in the middle channel, with hot heat transfer fluid (HHTF) flowing outer channel during charging process and cold heat transfer fluid (CHTF) flowing inner channel during discharging process. A simple numerical method according to conversation of energy, called temperature & thermal resistance iteration method has been developed for the analysis of PCM solidification and melting in the triplex concentric tube. To test the physical validity of the numerical results, an experimental apparatus has been designed and built by which the effect of the inlet temperature and the flow rate of heat transfer fluid (HTF, including HHTF and CHTF) on the thermal energy storage has been studied. Comparison between the numerical predictions and the experimental data shows good agreement. Graphical results including fluid temperature and interface of solid and liquid phase of PCM versus time and axial position, time-wise variation of energy stored/released by the system were presented and discussed.     

Thermal and heat transfer characteristics in a latent heat storage system using lauric acid

The thermal and heat transfer characteristics of lauric acid during the melting and solidification processes were determined experimentally in a vertical double pipe energy storage system. In this study, three important subjects were addressed. The first one is temperature distributions and temporal temperature variations in the radial and axial distances in the phase change material (PCM) during phase change processes. The second one is the thermal characteristics of the lauric acid, which include total melting and total solidification times, the nature of heat transfer in melted and solidified PCM and the effect of Reynolds and Stefan numbers as inlet heat transfer fluid (HTF) conditions on the phase transition parameters. The final one is to calculate the heat transfer coefficient and the heat flow rate and also discuss the role of Reynolds and Stefan numbers on the heat transfer parameters. The experimental results proved that the PCM melts and solidifies congruently, and the melting and solidification front moved from the outer wall of the HTF pipe (HTFP) to the inner wall of the PCM container in radial distances as the melting front moved from the top to the bottom of the PCM container in axial distances. However, it was difficult to establish the solidification proceeding at the axial distances in the PCM. Though natural convection in the liquid phase played a dominant role during the melting process due to buoyancy effects, the solidification process was controlled by conduction heat transfer, and it was slowed by the conduction thermal resistance through the solidified layer. The results also indicated that the average heat transfer coefficient and the heat flow rate were affected by varying the Reynolds and Stefan numbers more during the melting process than during the solidification process due to the natural convection effect during the melting process.     

相变蓄热供热装置热性能试验研究与系统经济性分析

为分析相变蓄热装置在充热和放热过程中的热性能,设计并搭建一套相变蓄热供热装置中试实验系统,研究主要运行参数对相变蓄热装置热性能的影响;在此基础上,结合项目案例,对相变蓄热供热系统经济性进行分析。结果表明：相变材料(Phase Change Material, PCM)凝固过程中的传热主要受相变介质内部导热控制;而在其熔化过程中自然对流对传热起重要控制作用;蓄热装置充热速率快于放热速率。提高传热流体流量有助于增强PCM中的热传递,缩短充/放热时间,但蓄热装置内PCM温度分布均匀性有所降低;为降低系统能耗,提高储放热效率,优先选用小流量进行充/放热。该相变蓄热供热项目的动态投资回收期为3.55年,具有良好的经济性。研究结果可对相变蓄热供热系统的设计及应用推广提供参考依据。     

Performance evaluation of a solar thermal energy storage system using nanoparticle-enhanced phase change material

This paper presents a numerical investigation on the thermal performance of a solar latent heat storage unit composed of rectangular slabs combined with a flat-plate solar collector. The rectangular slabs of the storage unit are vertically arranged and filled with phase change material (PCM: RT50) dispersed with high conductive nanoparticles (Al₂O₃). A heat transfer fluid (HTF: water) goes flow in the solar collector and receives solar thermal energy form the absorber area, then circulates between the slabs to transfer heat by forced convection to nanoparticle-enhanced phase change material (NEPCM). A numerical model based on the finite volume method and the conservation equations was developed to model the heat transfer and flow processes in the storage unit. The developed model was validated by comparing the obtained results with the experimental, numerical and theoretical results published in the literature. The thermal performance of the investigated latent heat storage unit combined with the solar collector was evaluated under the meteorological data of a representative day of the month of July in Marrakesh city, Morocco. The effect of the dispersion of high conductive nanoparticles on the thermal behavior and storage performance was also evaluated and compared with the case of base PCM without additives.     

Numerical and experimental investigation of heat transfer in a shell and tube thermal energy storage system

A numerical and experimental investigation of phase change process dominated by heat conduction in a thermal storage unit is presented in this paper. The thermal energy storage involves a shell and tube arrangement where paraffin wax as phase change material (PCM) is filled in the shell. Water as heat transfer fluid (HTF) is passed inside the tube for both charging and discharging cycles. According to the conservation of energy, a simple numerical method called alternative iteration between thermal resistance and temperature has been developed for the analysis of heat transfer between the PCM and HTF during charging and discharging cycles. Experimental arrangement has been designed and built to examine the physical validity of the numerical results. Comparison between the numerical predictions and the experimental data shows a good agreement. A detailed parametric study is also carried out for various flow parameters and system dimensions such as different mass flow rates, inlet temperatures of HTF, tube thicknesses and radii. Numerical study reveals that the contribution of the inlet temperature of HTF has much influence than mass flow rate in terms of storage operating time and HTF outlet temperature. Tube radius is a more important parameter than thickness for better heat transfer between HTF and PCM.     

A numerical investigation into the charge behaviour of a spherical phase change material particle for high temperature thermal energy storage in packed beds

基于高温相变材料,对填充床储热系统中储热单元球体的储热性能进行了模拟研究.研究了不同传热流体温度和球体直径对球体储热性能的影响规律,对导热为主的相变储热过程与导热和自然对流共同作用的相变储热过程进行了比较分析,同时还探讨了高温辐射换热的影响.结果表明,相变时间随球体直径的增大而增大,随传热流体温度的增大而减小.当考虑相变区域自然对流时,总的相变时间显著减少,和单纯导热相比,完全相变时间缩短了近16%.在导热和自然对流的基础上加上辐射传热后可以看出,辐射换热强化了球体内的传热过程,加快了相变材料的熔化速度,强化了自然对流的作用.     

An experimental and numerical investigation of heat transfer during technical grade paraffin melting and solidification in a shell-and-tube latent thermal energy storage unit

The latent thermal energy storage system of the shell-and-tube type during charging and discharging has been analysed in this paper. An experimental and numerical investigation of transient forced convective heat transfer between the heat transfer fluid (HTF) with moderate Prandtl numbers and the tube wall, heat conduction through the wall and solid–liquid phase change of the phase change material (PCM), based on the enthalpy formulation, has been presented. A fully implicit two-dimensional control volume Fortran computer code, with algorithm for non-isothermal phase transition, has been developed for the solution of the corresponding mathematical model. The comparison between numerical predictions and experimental data shows good agreement for both paraffin non-isothermal melting and isothermal solidification. In order to provide guidelines for system performance and design optimisation, unsteady temperature distributions of the HTF, tube wall and the PCM have been obtained by a series of numerical calculations for various HTF working conditions and various geometric parameters, and the thermal behaviour of the latent thermal energy storage unit during charging and discharging has been simulated.     

A comparative study on the performances of different shell-and-tube type latent heat thermal energy storage units including the effects of natural convection

Numerical modeling was performed to simulate the melting process of a fixed volume/mass phase-change material (PCM) in different shell-and-tube type latent thermal energy storage units with identical heat transfer area. The effect of liquid PCM natural convection (NC) on the latent heat storage performance of the pipe and cylinder models was investigated using a 3D numerical model with FLUENT software. Result shows that NC can cause a non-uniform distribution of the solid–liquid interface, which accelerates PCM melting rate. The PCM melting rate and heat storage rate in the horizontal cylinder model are higher than those in the horizontal pipe model because of the combined effects of heat conduction and NC. A comparative study was conducted to determine the effects of horizontal and vertical shell-and-tube models with different heat transfer fluid (HTF) inlets including the effects of NC. The results indicate that the vertical model with an HTF inlet at the bottom exhibits the highest PCM melting rate and heat storage rate for the pipe models. For the cylinder models, the horizontal model and the vertical model with an HTF inlet at the bottom can achieve nearly the same completed melting time. In addition, NC has minimal effect on any model with an HTF inlet at the top.     

Thermal performance analysis of a phase change thermal storage unit for space heating

This paper presents the results of a comprehensive numerical study on the thermal performance of an air based phase change thermal storage unit (TSU) for space heating. The unit is designed for integration into space heating and cooling systems. The unit consists of a number of one dimensional phase change material (PCM) slabs contained in a rectangular duct where air passes between the slabs. The numerical analysis was based on an experimentally validated model. A parametric study has been carried out including the study on the effects of charge and discharge temperature differences, air mass flow rate, slab thicknesses, air gaps and slab dimensions on the air outlet temperatures and heat transfer rates of the thermal storage unit. The paper introduces and discusses quantities called charge and discharge temperature differences which play an important role in the melting and freezing processes.     

Heat transfer intensification in horizontal shell and tube latent heat storage unit

Employment of latent heat storage unit (LHSU) utilizing phase change material (PCM) in a substantial scale is constrained by the poor thermal conductivity of PCMs. Future utilization of LHSU will therefore to a great extent rely on the heat transfer intensification techniques. Present research is on enhancement techniques in which heat transfer mechanism is altered without altering the mass of PCM and heat transfer surface area. The intensification mechanisms considered in the present research include imparting eccentricity to heat transfer fluid (HTF) pipe, imparting rotation to the LHSU and providing multi HTF tube. Numerical investigations are reported here towards comparative evaluation of the thermal characteristics associated with such intensification mechanisms for horizontal LHSU. In the present study stearic acid (melting point 55.7–56.6?°C) is used as PCM and water is used as HTF. Results infer that all the three mechanisms offer quicker melting rate. For the geometric configuration of LHSU considered in the present research, a reduction in melting time of 47.75% is evaluated for rotating LHSU. The rate of energy storage is higher for both eccentric and rotating LHSU. Solidification process is however not accelerated by such techniques. On the contrary, eccentric and multi HTF tube LHSU takes more time for solidification.     

Numerical simulation of a multi-layer latent heat thermal energy storage system

A computational model for the prediction of the thermal behaviour of a compact multi-layer latent heat storage unit is presented. The model is based on the conservation equations of energy for the phase change material (PCM) and the heat transfer fluid (HTF). Electrical heat sources embedded inside the PCM are used for heat storage (melting) while the flow of an HTF is employed for heat recovery (solidification). Parametric studies are performed to assess the effect of various design parameters and operating conditions on the thermal behaviour of the unit. Results indicate that the average output heat load during the recovery period is strongly dependent on the minimum operating temperature, on the thermal diffusivity of the liquid phase, on the thickness of the PCM layer and on the HTF inlet mass flowrate and temperature. It is, on the other hand, nearly independent of the wall thermal diffusivity and thickness and of the maximum operating temperature. Correlations are proposed for the total energy stored and the output heat load as a function of the design parameters and the operating conditions. © 1998 John Wiley & Sons, Ltd.     

Numerical Study of a Shell-and-Tube Latent Thermal Energy Storage Unit Heated by Laminar Pulsed Fluid Flow

The present study aims to investigate the effect of the pulsed fluid flow on the thermal performance of a latent heat storage unit (LHSU). The storage unit consists of a shell-and-tube in which phase change material (PCM) occupied the shell space and the heat transfer fluid (HTF) flows in the inner tube. The present study is motivated by the need to intensify heat transfer and accelerate melting process in LHSU. A mathematical model based on the conservation equations of energy in both HTF and PCM has been developed. The finite volume approach was used for the discretization of equations. The developed model has been validated by comparing the obtained numerical results with experimental, analytical, and numerical data found in literature. The effects of the pulsation frequency and amplitude, the Reynolds and Stefan numbers on the thermal performance and behavior of the LHSU were investigated. The parametric study showed that the pulsating parameters (frequency and amplitude) affect the thermal performance of the LHSU. The results reveal reduction in the melting time for low pulsating frequency (less than 0.052) and high pulsating amplitude. For pulsating amplitude of 6 and pulsating frequency of 0.01, a reduction up to 13% (at Reynolds number of 500 and Stefan number of 0.16) was obtained. The results also showed that the Reynolds and Stefan numbers strongly affect the heat transfer rate, and the low melting time is obtained for high Reynolds and Stefan numbers.     

Numerical simulation of a shell-and-tube latent heat thermal energy storage unit

A theoretical model was developed to predict the transient behavior of a shell-and-tube storage unit with the phase change material (PCM) on the shell side and the heat transfer fluid (HTF) circulating inside the tubes. The multidimensional phase change problem is tackled with an enthalpy-based method coupled to the convective heat transfer from the HTF. The numerical predictions are validated with experimental data. A series of numerical experiments are then undertaken to assess the effects of various thermal and geometric parameters on the heat transfer process and on the behavior of the system. Results show that the shell radius, the mass flow rate, and the inlet temperature of the HTF must be chosen carefully in order to optimize the performance of the unit.     

Numerical Analysis on a Latent Thermal Energy Storage System with Phase Change Materials and Aluminum Foam

Abstract

A latent heat thermal energy storage system with phase change material (PCM) is numerically studied. To enhance the heat transfer inside the system, a highly conductive metal foam is employed with ceramic nanoparticles. The latter method of enhancement leads to a new class of material called Nano-PCM. The system under investigation is a 70-L tank filled up with pure PCM or Nano-PCM and several pipes are situated where the heat transfer fluid (HTF) flows. The pipe surfaces are assumed at constant temperature above the PCM melting temperature to simulate the heat transfer from the HTF. The enthalpy-porosity theory is applied to simulate the PCM phase change, while the porous media formulation is assumed to describe the metal foam behavior. The nano-PCM is modeled with single-phase model where the properties are the weighted-average between the fluid base and the nanoparticles. The simulations are accomplished for charging-discharging process at different porosities and nanoparticle concentration. The results are given in term of average melting fraction evolution, average temperature as function of time, average stored energy. The metal foam significantly improves the heat transfer between PCM and HTF respect to the addition of nanoparticles, reducing the charging and discharging time more than one order of magnitude.