Sliding Wear of Electrically Conductive ZrO<Subscript>2</Subscript>−WC Composites Against WC–Co Cemented Carbide

ZrO₂-based composites with WC addition can be successfully machined by electrical discharge machining (EDM) in demineralised water. ZrO₂ composites with 40 vol.% WC were produced from nanocrystalline and micrometre sized WC starting powders in order to compare their tribological behaviour. Friction and wear data are obtained on wire-EDM’ed ZrO₂–WC composite flats sliding against a WC–Co cemented carbide pin using a small-scale pin-on-plate testing rig. Correlations between wear volume, wear rate and friction coefficient on the one hand and material properties and test conditions on the other hand were elucidated. The experimental results revealed that the grain size of the electro-conductive WC-phase exhibits a strong influence on the friction and wear behaviour of the ZrO₂-based composite.     

Reciprocative sliding friction and wear properties of electrical discharge machined ZrO2‐based composites

Hot‐pressed, laboratory‐made, ZrO₂‐based composites with 40 vol. % WC, TiCN or TiN were surface finished by electrical discharge machining in order to compare their reciprocating sliding friction and wear response against WC–6wt%Co cemented carbide in unlubricated conditions. Sliding experiments were performed using a Plint TE77 pin‐on‐flat wear test rig, revealing a strong impact of the secondary phase on the tribological behaviour of the ZrO₂‐based composites. The worn surfaces and wear debris were characterised by scanning electron microscopy, energy dispersive X‐ray analysis and surface topography scanning, pointing out abrasion, polishing and adhesion as main wear mechanisms. The most favourable friction and wear characteristics were encountered with ZrO₂–WC composites compared to the other grades with equal amount of volumetric secondary phase. Copyright © 2009 John Wiley & Sons, Ltd.     

Optimisation of process parameters for multi-performance characteristics in EDM of Al2O3 ceramic composite

The advantages of electrical discharge machining (EDM) in machining of complex ceramic components have promoted research in the area of EDM of ceramic composites. The recent developments in ceramic composites are focused not only on the improvements of strength and toughness, but also on possibilities for difficult-to-machine shapes using EDM. One such EDM-machinable ceramic composite material (Al₂O₃–SiC_w–TiC) has been developed recently and has been selected in the present study to investigate its EDM machinability. Experiments were conducted using discharge current, pulse-on time, duty cycle and gap voltage as typical process parameters. The grey relational analysis was adopted to obtain grey relational grade for EDM process with multiple characteristics namely material removal rate and surface roughness. Analysis of variance was used to study the significance of process variables on grey relational grade which showed discharge current and duty cycle to be most significant parameters. Other than discharge current and duty cycle, pulse-on time and gap voltage have also been found to be significant. To validate the study, confirmation experiment has been carried out at optimum set of parameters and predicted results have been found to be in good agreement with experimental findings.     

WC–ZrO2 composites: processing and unlubricated tribological properties

In the present work, we report the processing and properties of WC–6 wt.% ZrO₂ composites, densified using the pressureless sintering route. The densification of the WC–ZrO₂ composites was carried out in the temperature range of 1500–1700 °C with varying time (1–3 h) in vacuum. The experimental results indicate that significantly high hardness of 22–23 GPa and moderate fracture toughness of ∼5 MPa m^1/2 can be obtained with 2 mol% Y-stabilized ZrO₂ sinter-additive, sintered at 1600 °C for 3 h. Furthermore, the friction and wear behavior of optimized WC–ZrO₂ composite is investigated on a fretting mode I wear tester. The tribological results reveal that a moderate coefficient of friction in the range from 0.15 to 0.5 can be achieved with the optimised composite. An important observation is that a transition in friction and wear with load is noted. The dominant mechanisms of material removal appear to be tribochemical wear and spalling of tribolayer.     

Influence of secondary phases on the tribological response of electro-discharge machined zirconia-based composites against WC-Co cemented carbide

Three ceramic composite grades, consisting of a ZrO₂ matrix and 40 vol.% WC, TiC_0.5N_0.5 or TiN phase, were completely self-developed by hot pressing powder mixtures of yttria-stabilised zirconia (Y-TZP) and distinctive WC, TiC_0.5N_0.5 or TiN powder sources. The friction and wear characteristics of the zirconia-based composites against WC-Co cemented carbide were investigated by performing dry reciprocating sliding experiments on a pin-on-plate tribometer under various normal contact forces. The generated wear was quantified using surface scanning topography. Post-mortem obtained wear volumes were correlated to real-time recorded wear depth. The ZrO₂-40 vol.% WC grade displayed more favorable tribological properties compared to the other grades with equal secondary phase content. The worn surfaces and the wear debris were analysed by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX), revealing several wear mechanisms such as polishing, abrasion and wear debris layer formation, mainly depending on the imposed contact load and the material composition.     

Research of micro EDM/ECM method in same electrolyte with running wire tool electrode

A micro rod machining method which can switch between electrical discharge machining (EDM) and electrochemical machining (ECM) by attaching/detaching a diode to/from a bipolar pulse generator in parallel to the working gap was newly developed using a wire electrode made of tungsten. The problem of the wire electrode wear was eliminated by the use of the wire electrochemical turning (WECT) method in which the tungsten wire electrode is continuously running. The ultra-short bipolar pulse current was generated by the electrostatic induction feeding method where a pulse voltage is coupled to the working gap through a feeding capacitance. The machining characteristics of three types of wire guide; disk-shaped WC guide, laminated wire guide and cylindrical acrylic guide, were studied. The experimental results showed that the cylindrical acrylic guide has the best machining characteristics without the influence of guide wear and with less stray current flowing through the working gap. Using the cylindrical acrylic guide, the influences of the feeding capacitance C₁, and the total amplitude of the pulse voltage on the machining characteristics were studied. Finally, a stainless steel SUS 304 micro-rod with a high aspect ratio of 14 was fabricated efficiently by using the EDM and ECM modes for rough and finish machining in sequence with the same setup, pulse generator, and neutral electrolyte.     

A NEW METHOD FOR MACHINING OF ELECTRICALLY NONCONDUCTIVE WORKPIECES USING ELECTRIC DISCHARGE MACHINING TECHNIQUE

In this study, a new method for machining of nonconductive ceramic workpieces in electric discharge machining (EDM) was developed. Machining surfaces of nonconductive workpieces were coated with a conductive layer (CL) and graphite powder was added to dielectric fluid for machining. Al₂O₃, ZrO₂, SiC, B₄C and glass workpiece samples were machined by using the method. Different machining conditions were tested for each sample and optimum machining parameters were determined. Effect of electrical conductivity, thermal conductivity and melting point of workpieces on material removal rate (MRR) was investigated. Optical microscope and SEM (Scanning Electron Microscope) surface photographs of workpieces taken after machining are presented and discussed.     

Surface Improvement Using a Combination of Electrical Discharge Machining with Ball Burnish Machining Based on the Taguchi Method

This study investigates the feasibility of improving surface integrity via a novel combined process of electrical discharge machining (EDM) with ball burnish machining (BBM) using the Taguchi method. To provide burnishing immediately after the EDM process, ZrO₂ balls were attached to the tool electrode in the experiments. To verify the optimal process, three observed values, i.e. material removal rate, surface roughness, and improvement ratio of surface roughness were chosen. In addition, six independent parameters were adopted for evalu-ation by the Taguchi method. From the ANOVA and S/N ratio response graph, the significant parameters and the optimal combination level of machining parameters were obtained. Experimental results indicate that the combined process effectively improves the surface roughness and eliminates the micro pores and cracks caused by EDM. Therefore, the combination of EDM and BBM is a feasible process by which to obtain a fine-finishing surface and achieve surface modification.     

Experimental research on electrical discharge machining characteristics of engineering ceramics with different electrical resistivities

Electrical discharge machining (EDM) is the extensively used nonconventional material removal process for machining engineering ceramics provided they are electrically conductive. However, the electrical resistivity of the popular engineering ceramics is higher, and there has been no research on the relationship between the EDM parameters and the electrical resistivity of the engineering ceramics that can be machined effectively by EDM. This paper investigates the effects of the electrical resistivity and the EDM parameters on the EDM performance of ZnO/Al₂O₃ ceramic in terms of the machining efficiency and the quality. The experimental results showed that the electrical resistivity and the EDM parameters such as pulse on-time, pulse off-time, and peak current had the great influence on the machining efficiency and the quality during electrical discharge machining of ZnO/Al₂O₃ ceramic. Moreover, the electrical resistivity of the ZnO/Al₂O₃ ceramic, which could be effectively machined by EDM, increased with increasing the pulse on-time and peak current and with decreasing the pulse off-time, respectively. Furthermore, the ZnO/Al₂O₃ ceramic with the electrical resistivity up to 3,410 Ω cm could be effectively machined by EDM with the appropriate machining condition.     

Performance Analysis of Wire Electrodes on Machining Ti-6Al-4V Alloy using Electrical Discharge Machining Process

High-strength materials with complex shapes can be easily machined by electrical discharge machining process. In the present study, an attempt has been made to analyze the influence of wire electrode on Kerf width and workpiece surface roughness in wire EDM process. Due to its importance in the aircrafts and automobiles, Ti-6Al-4V alloy has been chosen as the workpiece material. The various experiments have been conducted based on a Taguchi L₉ orthogonal array with various types of wire electrodes, such as conventional brass wire, zinc-coated wire and diffused coated brass wire. From the experimental results, it has been observed that diffused coated wire produced better surface finish with minimum kerf width compared to the other two wire electrodes. It has also been observed that the pulse off-time has more influent nature on machining characteristics such as surface roughness and kerf width.     

An experimental investigation of cylindrical wire electrical discharge turning process

The cylindrical wire electrical discharge turning (CWEDT) process was developed to generate precise cylindrical forms on hard, difficult to machine materials. A precise, flexible, and corrosion-resistant submerged rotary spindle was designed and added to a conventional five-axis CNC wire electrical discharge machine (EDM) to enable the generation of free-form cylindrical geometries. The hardness and strength of the work material are no longer the dominating factors that affect the tool wear and hinder the machining process. In this study, the effect of machining parameters on surface roughness (R _a) and roundness in cylindrical CWEDT of a AISI D3 tool steel is investigated. The selection of this material was made taking into account its wide range of applications in tools, dies, and molds and in industries such as punching, tapping, reaming, and so on in cylindrical forms. Surface roughness and roundness are chosen as two of the machining performances to verify the process. In addition, power, pulse off-time, voltage, and spindle rotational speed are adopted for evaluation by full factorial design of experiments. In this case, a 2²?×?3² mixed full factorial design has been selected considering the number of factors used in the present study. The main effects of factors and interactions were considered in this paper, and regression equations were derived using response surface methodology. Finally, the surfaces of the CWEDT parts were examined using scanning electron microscopy (SEM) to identify the macro-ridges and craters on the surface. Cross sections of the EDM parts were examined using the SEM and microhardness tests to quantify the sub-surface recast layers and heat-affected zones under specific process parameters.     

Development and application of new composite materials as EDM electrodes manufactured via selective laser sintering

The cost of a part manufactured by electrical dischargeEDM machining (EDM) is mainly determined by electrode cost. The production of electrodes by conventional machining processes is complex, time consuming, and can account for over 50 % of the total EDM process costs. The emerging additive manufacturing (AM) technologies provide the possibility of direct fabrication of EDM electrodes. Selective laser sintering (SLS) is an alternative AM technique because it has the possibility to directly produce functional components, reducing the tool-room lead time and total EDM costs. The main difficulty of manufacturing an EDM electrode using SLS is the selection of an appropriate material, once both processes require different material properties. The current work focused on the investigation of appropriate materials that fulfill EDM and SLS process demands. Three new metal-matrix materials composed of Mo–CuNi, TiB₂–CuNi, and ZrB₂–CuNi were developed and characterized. Electrodes under adequate SLS conditions were manufactured through a systematic methodology. EDM experiments using different discharge energies were carried out, and the performance evaluated in terms of material removal rate and volumetric relative wear. The results showed that the powder systems composed of Mo–CuNi, TiB₂–CuNi, and ZrB₂–CuNi revealed to be successfully processed by SLS, and the EDM experiments demonstrated that the new composite electrodes are promising materials. The work also suggests important topics for future research work on this field.     

A study of die helical thread cavity surface finish made by Cu-W electrodes with planetary EDM

An experimental research study intended for the application of a planetary electrical discharge machining (EDM) process with copper-tungsten (Cu-W) electrodes in the surface micro-finishing of die helical thread cavities made with AISI H13 tool steel full-hardened at 53 HRC is presented. To establish the EDM parameters’ effect on various surface finishing aspects and metallurgical transformations, three tool electrode Cu-W compositions are selected, and operating parameters such as the open-circuit voltage (U ₀), the discharge voltage (u _e), the peak discharge current (î _e), the pulse-on duration (t _i), the duty factor (τ) and the dielectric flushing pressure (p _in), are correlated. The researched machining characteristics are the material removal rate (MRR—V _w), the relative tool wear ratio (TWR—?), the workpiece surface roughness (SR—Ra), the average white layer thickness (WLT—e _wl) and the heat-affected zone (HAZ—Z _ha). An empirical relation between the surface roughness (SR—Ra) and the energy per discharge (W _e) has been determined. It is analysed that copper-tungsten electrodes with negative polarity are appropriate for planetary EDM die steel surface micro-finishing, allowing the attaining of good geometry accuracy and sharp details. For die steel precision EDM, the relative wear ratio optimum condition and minor surface roughness takes place at a gap voltage of 280 V, discharge current of 0.5–1.0 A, pulse-on duration of 0.8 μs, duty factor of 50%, dielectric flushing pressure of 40 kPa and copper tungsten (Cu20W80) as the tool electrode material with negative polarity. The copper-tungsten electrode’s low material removal rate and low tool-wear ratio allows the machining of EDM cavity surfaces with an accurate geometry and a “mirror-like” surface micro-finishing. A planetary EDM application to manufacture helical thread cavities in steel dies for polymer injection is presented. Conclusions are appointed for the planetary EDM of helical thread cavities with Cu-W electrodes validating the accomplishment as a novel technique for manufacturing processes.     

Development and application of copper–nickel zirconium diboride as EDM electrodes manufactured by selective laser sintering

The production of electrical discharge machining (EDM) electrodes by conventional machining processes can account for over 50 % of the total EDM process costs. The emerging additive manufacturing (AM) technologies provide the possibility of direct fabrication of EDM electrodes. Selective laser sintering (SLS) is an alternative AM technique because it has the possibility to reduce the tool-room lead time and total EDM costs. The main difficulty of manufacturing an EDM electrode using SLS is the selection of an appropriate material. This work investigated the direct production of EDM electrodes by means of the SLS using a newly developed non-conventional metal–matrix composite material composed of a metallic matrix (CuNi) and an advanced ceramic (ZrB₂). The influence of important SLS parameters and material content on the densification behavior and porosity of the electrodes was investigated. EDM experiments were conducted to observe the electrodes behavior and performance. It was found that the ZrB₂-CuNi electrodes could be successfully manufactured by SLS. Interlayer bonding and porosity are directly influenced by the layer thickness. Smaller layer thicknesses improved bonding between layers and decreased the porosity of the parts. The laser scan speed has a significant effect on the densification behavior. The scan line spacing affects the pore structure by means of overlapping. The surface morphology of the samples was not affected by varying the scan line spacing. The ZrB₂-CuNi electrodes presented a much superior performance than SLS copper powder electrodes, but inferior to solid copper electrodes.     

Effects of glass-to-rubber transition on the temperature,load and speed sensitivities of nano-ZrO2 reinforced polybenzoxazine

In the present work, nano ZrO₂ reinforced polybenzoxazine composites were produced. The friction behaviors of ZrO₂–polybenzoxazine nanocomposites were evaluated on a chase friction material test machine. An attempt was made to examine the variation of storage modulus, loss modulus and glass-to-rubber transition on the effect of the temperature, load and speed sensitivity of ZrO₂–polybenzoxazine nanocomposites. The results revealed that the temperature and load sensitivity of nanocomposites increased with the increasing of load and temperature. This behavior was speculated to be due to the effect of the temperature dependence of modulus in the surface topography and strength. But speed sensitivity varies with the temperature, due to the effect of temperature dependence of viscoelastic response in the energy dissipation.     

Effect of Mo and Ag on the friction and wear behavior of ZrO2 (Y2O3)–Ag–CaF2–Mo composites from 20 °C to 1000 °C

In this paper, a series of ZrO₂ matrix high-temperature self-lubricating composites were prepared by hot-press technique. The effect of Mo and Ag on the friction and wear behavior of the ZrO₂(Y₂O₃)–Ag–CaF₂–Mo composites in a wide temperature range was investigated. The XRD results showed that CaMoO₄ formed on the worn surface above 400 °C. The excellent lubrication performance of CaMoO₄ endowed the low coefficient of friction of the ZrO₂(Y₂O₃)–Ag–CaF₂–Mo composites at high temperatures. The ZrO₂(Y₂O₃)–10Ag–10CaF₂–10Mo composites showed favorable wear resistance at all the tested temperatures which was attributed to the combined action of hardness and phase transformation.     

Optimization of cryogenic cooled EDM process parameters using grey relational analysis

This paper presents an experimental investigation on cryogenic cooling of liquid nitrogen (LN₂) copper electrode in the electrical discharge machining (EDM) process. The optimization of the EDM process parameters, such as the electrode environment (conventional electrode and cryogenically cooled electrode in EDM), discharge current, pulse on time, gap voltage on material removal rate, electrode wear, and surface roughness on machining of AlSiCp metal matrix composite using multiple performance characteristics on grey relational analysis was investigated. The L₁₈ orthogonal array was utilized to examine the process parameters, and the optimal levels of the process parameters were identified through grey relational analysis. Experimental data were analyzed through analysis of variance. Scanning electron microscopy analysis was conducted to study the characteristics of the machined surface.     

Study on the nano-powder-mixed sinking and milling micro-EDM of WC-Co

Present study investigates the feasibility of improving surface characteristics in the micro-electric discharge machining (EDM) of cemented tungsten carbide (WC?CCo), a widely used die and mould material, using graphite nano-powder-mixed dielectric. In this context, a comparative analysis has been carried out on the performance of powder-mixed sinking and milling micro-EDM with view of obtaining smooth and defect-free surfaces. The surface characteristics of the machined carbide were studied in terms of surface topography, crater characteristics, average surface roughness (R _a) and peak-to-valley roughness (R _max). The effect of graphite powder concentration on the spark gap, material removal rate (MRR) and electrode wear ratio (EWR) were also discussed for both die-sinking and milling micro-EDM of WC?CCo. It has been observed that the presence of semi-conductive graphite nano-powders in the dielectric can significantly improve the surface finish, enhance the MRR and reduce the EWR. Both the surface topography and crater distribution were improved due to the increased spark gap and uniform discharging in powder-mixed micro-EDM. The added nano-powder can lower the breakdown strength and facilitate the ignition process thus improving the MRR. However, for a fixed powder material and particle size, all the performance parameters were found to vary significantly with powder concentration. Among the two processes, powder-mixed milling micro-EDM was found to provide smoother and defect-free surface compared to sinking micro-EDM. The lowest value of R _a (38?nm) and R _max (0.17???m) was achieved in powder-mixed milling micro-EDM at optimum concentration of 0.2?g/L and electrical setting of 60?V and stray capacitance.     

Micro electrical discharge machining using high electric resistance electrodes

In micro electrical discharge machining (EDM), because the material removal per single pulse discharge mainly determines the minimum machinable size of a micro EDM, decreasing the material removal per single pulse discharge is important. In this study, in order to decrease the material removal per single pulse discharge, high electric resistance materials such as single-crystal silicon are used for electrodes. Analytical results show that when the electrode resistance increases, the peak value of the discharge current decreases, whereas the pulse duration increases. In addition, the discharge energy decreases when increasing the resistance. Silicon is used as a tool electrode, and the effect of resistivity of the silicon tool electrode on the diameter of discharge craters generated on the stainless steel workpiece is examined. Experimental results reveal that with increasing silicon electrode resistivity, the diameter of discharge craters decreases. Because the diameter of discharge craters can be decreased to 0.5 μm, improved finished surfaces of R_z 0.03 μm are obtained.     

Study of high-efficiency electrical discharge machining-induced ablation machining of titanium alloy TC4 using a multi-function electrode

Aimed at overcoming the low efficiency of electrical discharge machining (EDM), and taking advantage of the characteristic that most metals can burn in oxygen, a new high-efficiency process is put forward: EDM-induced ablation machining (EDM-IAM) using multi-function electrode technology. EDM-IAM injects oxygen and dielectric fluid into the processing area through a dedicated channel of a multi-function electrode. The chemical energy caused by the reaction of metal and oxygen can much improve the material removal efficiency. To study the factors affecting the efficiency of the process, the ablation machining of a titanium alloy (TC4) using a multi-function electrode was carried out; analysis of the worked surface was done with scanning electron microscopy, X-ray diffraction, and discharge waveforms. The results show that the substances of the worked surface are mainly TiO, TiO_1.2, TiO₂, and smaller amounts of Ti₃O and other titanium oxides. Violent oxidation combustion reaction occurs during the ablation machining process. The processing efficiency of ablation machining can reach 347.7 mm³/min, which is 58.7 times that of normal EDM for the same processing conditions. The main reasons for the high material removal rate are the higher utilization rate of electric spark discharge energy, consumption of material by ablation, melting effect of combustion heat on the workpiece material, and forced chip removal effect by local explosion.