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对德国科兹490锌-铁合金电镀工艺进行了全面介绍,包括工艺的特点、镀液的配制、镀液成分的作用、操作条件的影响、镀液的维护及其故障的排除。在镀槽中采用不溶性阳极可获得均匀的电流分布;采用辅助槽时,能得到综合性能最好的锌-铁合金镀层。 相似文献
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本文研究了硫酸盐镀液中添加剂、pH值、电解液成份对锌铁合金镀层的影响.初步获得了镀取含铁0.6%左右的光亮锌铁镀层的镀液成份和工艺条件. 相似文献
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低铁锌铁合金电镀新工艺 总被引:1,自引:0,他引:1
研究了在碱性锌酸盐镀液中加入含铁补充剂后,得到镀层含铁量为0.4%~0.8%的锌铁合金电镀新工艺,讨论了影响镀层铁含量的各种因素,测试了镀层及镀液的性能.结果表明,锌铁合金镀层与锌镀层相比,更加光亮、细致,结晶致密,耐蚀性得到进一步提高. 相似文献
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采用硫氰酸盐分光光度法测定中温耐硫水解催化剂中三氧化钼含量,重点研究了试样处理方法、处理条件、酸度控制、抗坏血酸用量等测定条件对测定结果的影响.中温耐硫水解催化剂采用1#硫酸溶液溶解后,依次加入硫酸铁铵溶液、2#硫酸溶液、硫氰酸铵溶液及抗坏血酸溶液,用分光光度计测定其吸光度,从工作曲线查出或通过回归方程式计算出被测溶液中三氧化钼的质量.硫氰酸盐分光光度法测定结果与电感耦合等离子体发射光谱法基本一致,且成本低、操作快捷. 相似文献
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以L-抗坏血酸和棕榈酰氯为基本原料,以5,6-D-异亚丙基也-抗坏血酸为中间产物,在无水吡啶中进行酯化反应,经成盐和脱保护反应,制得最终产品。总收率为47%-51%。 相似文献
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Electrochemical impedance and cyclic voltammetric measurements of magnetite coating formed on carbon steel substrates were carried out in deaerated solutions of 1.0 × 10–2 M ascorbic acid and 3.5 × 10–2 M picolinic acid at 28 °C. Impedance data showed that the interaction between magnetite and ascorbic acid is associated with an incubation period, after which reductive dissolution takes place accompanied by oxidation of ascorbic acid. Once the magnetite film loses its thickness and protective properties on prolonged exposure to ascorbic acid, the charge transfer resistance and the capacitance is reduced. Initial dissolution of magnetite in picolinic acid is due to congruent chemical dissolution with little contribution from reduction by the electrons arising from the corrosive attack of acid on the carbon steel. With time the contribution of the latter process increases as more and more of the substrate opens up. Cyclic voltammetric studies showed that there is an adsorption phenomenon leading to the formation of a surface ferric complex that undergoes reduction to the ferrous species and transfers to the bulk solution. The accumulation of the ferrous ion accelerates the dissolution resulting in an increase in current. Dissolution of magnetite in picolinic acid is slow. The better complexing capability of picolinic acid compared to ascorbic acid does not permit the accumulation of the ferrous ion as indicated by the absence of a peak in the voltammogram. 相似文献
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Sung Ho Lee Kwang Rag Kim Jong Sik Shon Jae Hyung Yoo Hongsuk Chung 《Korean Journal of Chemical Engineering》1999,16(2):166-169
The precipitation characteristics of palladium (Pd) from a simulated radwaste solution by ascorbic acid was investigated.
Pd was selectively precipitated by the reduction reaction of Pd with ascorbic acid. When the nitric acid concentration in
the 8 component system was below 2.0 M, Pd over 99.5 % was selectively precipitated at an ascorbic acid concentration above
0.06 M, while other elements mainly remained in solution. The precipitation yield of Pd by ascorbic acid decreased with the
increase of the nitric acid concentration. 相似文献
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基于抗坏血酸将Fe3+还原为Fe2+,用邻二氮菲作Fe2+的显色剂,用pH 5.4的六亚甲基四胺-HCl缓冲溶液调节体系酸度,建立了测定抗坏血酸含量的新方法,即显色光度法测定药物中的抗坏血酸。讨论了最佳的反应条件,结果表明抗坏血酸浓度在0~10μg/mL范围内符合比尔定律。此方法可应用于药品、合成样品中抗坏血酸含量的测定。 相似文献
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Yan Zhang Lingling Lin Zengfang Feng Jianzhang Zhou Zhonghua Lin 《Electrochimica acta》2009,55(1):265-270
Polyaniline/Au nanocomposite modified nanoelectrodes based dopamine nanosensors have been developed. The polyaniline/Au nanocomposite film was deposited at the exposed end of the nanoelectrode tip by a surface-graft polymerization method to fabricate a desired modified nanoelectrode. With this modified method, the nanocomposites firmly adhered on the electrode surface and the modified nanoelectrode still had a sharp tip, which was proved by the scanning electron microscope. The electrochemical measurement shows the polyaniline/Au nanocomposite modified film has a good and stable redox activity in neutral solution. The modified nanoelectrode exhibits the excellent electrocatalytic activity towards the oxidations of ascorbic acid and dopamine in phosphate buffer solution. The separation of anodic peak potential of dopamine and ascorbic acid reaches 250 mV. Differential pulse voltammograms results illustrate that dopamine can be selectively determined in the presence of thousands times higher concentration of ascorbic acid with a wide linear range from 200 to 0.3 μM and the detection limit is 0.1 μM. This study provides a simple method for the construction of dopamine nanosensors that have a good sensitivity, wide linear range and stable response. The nanosensors are hopeful to be applied to the detection of dopamine in vivo. 相似文献
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Thickness of poly(malachite green) films electropolymerized on a glassy carbon electrode surface, the concentration of ascorbic acid, pH value of the solution, and accumulation time were found to affect the adsorption-controlled anodic peak current of ascorbic acid on this polymer film coated electrode. Adsorption efficiency, defined as the ratio of the active sites in polymer films to the amount of adsorbed ascorbic acid molecules, was then proposed and estimated from the comparison of mathematically simulated cyclic voltammograms with experimental ones. The concentration of ascorbic acid is the greatest parameter affected the adsorption efficiency. Poly(malachite green) film electropolymerized on the glassy carbon electrode was found to be not totally active towards oxidation of ascorbic acid when the concentration of ascorbic acid is too high or when the poly(malachite green) film is too thick. The potential shift of ascorbic acid on the modified electrodes was also discussed. 相似文献
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In this study, different concentrations of ascorbic acid (50, 100 and 200 µg/mL) were added to the liquid phase of a calcium phosphate cement (CPC). The cements were immersed in simulated body fluid (SBF) for different intervals and physical, physicochemical and mechanical properties of them were evaluated. The release of added ascorbic acid from CPCs into the SBF solution was also studied. From the results, both setting time and injectability of CPC decreased by adding ascorbic acid, however the compressive strength was sharply increased before soaking in SBF solution. But, the compressive strength values of all cements (with or without ascorbic acid) soaked in SBF solution for more than 7 d duration were comparable. The X-ray diffractometry results showed that in vitro apatite formation ability of cement reactants did not change by adding ascorbic acid. The scanning electron microscopy images indicated that morphology of the formed apatite crystals was nano-needlelike and needle diameter was less than 100 nm. The loaded ascorbic acid was slowly released from CPC into the SBF solution so that about 10% and 20% of the loaded drug was released after 504 h for the cements containing 100 and 200 µg/mL ascorbic acid, respectively. The release rate was increased when the amount of added ascorbic acid decreased by 50 µg/mL. 相似文献
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Controlled synthesis of copper nano/microstructures using ascorbic acid in aqueous CTAB solution 总被引:1,自引:0,他引:1
Mustafa Biçer 《Powder Technology》2010,198(2):279-949
This paper describes a low-temperature green chemical synthesis of various morphologies of copper nano/microstructures. These syntheses achieved high yields in aqueous solution using ascorbic acid as a reductant and the cationic surfactant cetyltrimethylammonium bromide (CTAB) as a capping agent. The resulting copper particles were characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and UV-Vis. absorption spectroscopy techniques. From the SEM analysis, it was found that different morphologies of copper particles, including submicron polyhedrons, micrometer rods, spherical nanoparticles, and nanowires were obtained by varying factors such as the molar ratio of reactants (ascorbic acid and CuSO4·5H2O), pH, reaction time, and temperature. Increasing the molar ratio of ascorbic acid to precursor salt and increasing the pH led to a decrease in the size of copper particles formed. At short reaction times, spherical copper nanoparticles with an average diameter of 90 nm are obtained. When the reaction time was prolonged, the nanoparticles transformed into nanowires with diameters in the range of 100-250 nm, and lengths of up to 6-8 μm. When the reaction temperature was decreased, Cu mixed with Cu2O particles were obtained instead of Cu particles. The resultant copper particles were confirmed by EDX and XRD to be pure Cu, with face-centred cubic (fcc) structures. 相似文献