Tensile properties and inhomogeneous deformation of ferrite-martensite dual-phase steels

The tensile properties and inhomogeneous deformation of coarse ferrite-martensite dual-phase steels containing 17–50% martensite were analysed. The stress of dual-phase steels at equal strain increased with increasing volume fraction of martensite, f, but the rate of increase was reduced after f=0.3. The strain hardening rate was dependent on f at small strains ( 0.03), however, it became independent of f at larger strains. It was found that the deformation of the dual-phase steels divided into three different stages when f was less than about 0.3. The concurrent in situ stress-strain states of ferrite, martensite and their composite, and the stress ratios and strain ratios between ferrite and martensite were evaluated by means of a new stress and strain partition theory. The martensite phase deformed plastically after the uniform strain for f < 0.25, while it was plastic before the uniform strain for f > 0.25. The theoretical analyses for inhomogeneous deformation implied that the volume-fraction dependence of the stress and the characteristics of the strain-hardening rate were influenced by the plastic deformation of martensite. Further, the in situ stress-strain curves of ferrite and martensite and the internal stresses at respective phases were calculated from the partitioned stresses and strains.     

Studies on the stress-strain relations of dual-phase steels

The correlations of the work-hardening exponent,n, with quenching temperature, martensite volume-fraction (MVF) and solute concentration in ferrite are discussed and derived for dual-phase steel. The flow stress of dual-phase steel at low strain is suggested to be expressed by the combination of the terms due to plastic deformation in ferrite and elastic deformation of martensite. Previous experimental results are compared with the behaviour suggested by this theoretical work. In addition, an expression for the work hardening exponents at moderate strains and at the onset of necking are also theoretically suggested.     

Effect of epitaxial ferrite on yielding and plastic flow in dual phase steel in tension and compression

Abstract

A low carbon, microalloyed steel was heat treated to obtain dual phase microstructures containing constant levels of 18 and 25 vol.-% martensite at two levels of microstructural refinement and with varying epitaxial ferrite content. Tensile and compression tests were conducted at a strain sensitivity of 2 × 10^-5. Elastic limits in tension and compression were indistinguishable and very low, suggesting that mobile dislocations were present in the ferrite as a consequence of stress relaxation processes. These mobile dislocations accommodated the volume increase accompanying the austenite to martensite transformation during heat treatment. Epitaxial ferrite had little effect on the 0·2% proof stress, but average proof stresses were generally higher in compression than in tension owing to residual stresses in the martensite and ferrite following heat treatment. The residual stresses calculated from this asymmetry in the proof stresses were small because of stress relaxation in the ferrite at the temperature at which the martensite formed. Epitaxial ferrite significantly increased uniform elongation in tension with a small decrease in tensile strength for both levels of martensite in the finer microstructure but only at the 18 vol.-% martensite level in the coarser microstructure. The cause of the increased ductility was the effect of epitaxial ferrite on the work hardening rate between approximately 0·5 and 3% strain; epitaxial ferrite reduced the work hardening rate in this range of strain.     

Deformation of sintered copper and 50Cu–50Fe mixture to large strains by cyclic extrusion and compression

Abstract

Sintered compacts of copper and a 50Cu–50Fe mixture have been plastically deformed to large strains (total strain ?_t=13·8) by cyclic extrusion and compression. The hardness changes after deformation indicate that no further work hardening occurs with either material when ?_t>4·6. With copper, strain accommodation at large strains would appear to occur solely by dynamic recovery and recrystallisation. With the Cu–Fe mixture, shear banding is still found at the highest strains used.

MST/1609     

Effects of microstructural variables on the deformation behaviour of dual-phase steel

An expression for the stress of martensite in dual-phase steel was developed, which shows the interdependence of the stress of martensite and strain hardening in the ferrite matrix and the contribution of microstructural variables (the volume fraction of martensite f_m, ferrite grain size d_f, and martensite particle size d_m). The onset of plastic deformation of martensite in dual-phase steel was predicted to depend on its yield strength and the microstructural variables, and this was verified by the modified Crussard-Jaoul analysis. It was found that for this dual-phase steel, refining the grain size and increasing f_m increase the flow stress and raise the strain hardening rate at low strains, but little affect the strain hardening rate at high strains. The effect of the ferrite grain size on the flow stress of this dual-phase steel was found to obey the Hall-Petch relation, i.e. σ = σ₀^e + K^ed_f^−1/2, where the Hall-Petch intersection σ₀^e and slope K^e are functions of strain, f_m and d_m. The effects of the plastic deformation of martensite and the microstructural variables on the strain hardening rate and the Hall-Petch behaviour were analysed in terms of the densities of statistically stored dislocations and geometrically necessary dislocations using the previously developed theoretical model.     

Formation of ultrafine grained ferrite during thermomechanical treatment in microalloyed steel

Abstract

In the present work, the formation of ultrafine grained ferrite has been studied by applying suitable thermomechanical treatment. A high amount of deformation (～80%) at varying strain rates (0·01–10 s^?1) was applied in the temperature range of Ar₃ to Ac₃ followed by water quenching. This treatment resulted in a two-phase ferrite–martensite microstructure as compared to fully martensite structure after quenching without deformation. The formation of ultrafine ferrite (?3 μm) during deformation was favourable at a lower temperature and a slower strain rate. A maximum ～50% ferrite formed during deformation at 780°C with a strain rate of 0·01 s^?1. Experimental rolling with a high strain (～1·3) with finish rolling temperature just above Ar₃ (～750°C) resulted in fine ferrite–pearlite of ?3 μm, and the properties showed a high value of strength as compared to steels rolled in a conventional way. Dual phase microstructure (ferrite and martensite) was produced after partial austenisation to 780°C followed by quenching in water, and this resulted in an excellent combination of properties (high ultimate tensile strength, low yield strength/ultimate tensile strength, high elongation and high n values).     

Effects of prestrain and strain rate on dynamic deformation characteristics of 304L stainless steel: Part 2—Microstructural study

Abstract

The morphologies and characteristics of microstructure, including dislocations, mechanical twins and α' martensite, in 304L stainless steel deformed under various strain, strain rate range from 10² to 5 × 10³ s^-1 for different prestrain levels at room temperature were examined by a split Hopkinson bar and TEM. The evolution of microstructure correlated with dynamic mechanical behaviour are presented and discussed in terms of prestrain and applied strain rate. The results show that characteristics of dislocations, mechanical twins and α' martensite varied with prestrains, strains and strain rates. They dominate the strengthening effects on the 304L stainless steel. Dislocation cell structures can be observed in all tested specimens. At larger prestrain under dynamic loading, the formation of elongated dislocation cells becomes evident. The presence of elongated dislocation cells leads to different work hardening behaviour. Twinning occurred at all testing conditions except for the 0·15 prestrain specimen deformed at 0·1 strain and 8 × 10² s^-1 strain rate. The formations of α' martensites were found to be confined to the microshear bands and were barriers of dislocation movement. As the heavy loading is imposed, irregular and blocky α' martensites were observed. Quantitative measurement revealed that dislocation and twin density, as well as the volume fraction of α' martensite increase with the prestrain, strain and applied strain rate, but a decay of twin density occurred as the prestrain of 0·5 is applied. These microstructrual changes can be related to the different work hardening stress (σσ_y and strengthening nature. The observed strengthening effect resulted from the dislocation multiplication, twin formation and α' martensite seems to reflect an enhancement of hardness. However, the increased hardness is less sensitive to the twin formation.     

Effects of morphology and strength of martensite on cyclic deformation behaviour in dual-phase steels

Abstract

Tension–compression cyclic deformation behaviour in dual-phase steels has been studied. Three different ferrite (α)–martensite (α′) microstructures, i.e. isolated α′-colonies dispersed in α-matrix (I), continuous α′ (C), and laminated α–α′ (L), were prepared by appropriate heat treatments, keeping the α′ volume fraction at ~0·3. The work hardening and the Bauschinger effect are found to be greater in microstructure C or L than in I when they are compared at an arbitrary forward (tension) prestrain level. An increase in the hardness of α′ enhances the Bauschinger effect and then narrows the stress–strain hysteresis loop. The stress evolved as a result of the Bauschinger stress (defined as the difference between forward prestress and backward (compression) 0·1% proof stress) is found to be almost independent of microstructure and hardness when it is compared at an arbitrarily fixed prestress level. The slip lines are very fine and relatively straight in microstructure C, but wavy in microstructure I. These findings are discussed from the standpoints of the accumulation of the average internal stress resulting from inhomogeneous plastic flow between two constituent phases and the plastic relaxation.

MST/382     

Effect of corrosive medium on fatigue crack growth behaviour and fracture in high martensite dual phase steel

Fatigue crack growth (FCG) behaviour in both near-threshold and higher stress intensity range (ΔK) in intercritically annealed dual-phase (DP) steel containing martensite between 32% and 76% in ferrite has been studied in 3·5% NaCl solution. It is shown that the amount of martensite content in dual phase steel has a significant effect on threshold (ΔK _th) values and FCG rates. Higher content of martensite in ferrite leads to higher threshold values and lower FCG rates. Further, ΔK _th is much higher in 3·5% NaCl solution as compared to that in laboratory air. Fractography studies reveal that in the near-threshold region, fracture surfaces are characterized mainly by intergranular cracking in corrosive (3·5% NaCl solution) environment. Higher threshold values in 3·5% NaCl solution is attributed to the higher crack closure induced by rougher fracture surface and by the strong wedge effects of corrosion products.     

Effects of ferrite grain size and martensite volume fraction on dynamic deformation behaviour of 0·15C–2·0Mn–0·2Si dual phase steels

Abstract

Effects of ferrite grain size and martensite volume fraction on quasistatic and dynamic deformation behaviour of 0·15C–2·0Mn–0·2Si dual phase steels were investigated in this study. Dynamic torsional tests were conducted on six steel specimens that had different ferrite grain sizes and martensite volume fractions, using a torsional Kolsky bar, and then the test data were compared in terms of microstructures, tensile properties, fracture mode, and adiabatic shear band formation. Under dynamic torsional loading, maximum shear stress and fracture shear strain increased with decreasing ferrite grain size and increasing martensite volume fraction. Observation of the deformed area beneath the fracture surface after the dynamic torsional test indicated that adiabatic shear bands of 5 to 15 μm in width were formed along the shear stress direction, and that voids or microcracks initiated at ferrites or martensite/ferrite interfaces below the shear band. The width of the shear band decreased as the ferrite grain size increased or the martensite volume fraction decreased. These phenomena were then analysed by introducing concepts of theoretical critical shear strain.     

Transition from upper to lower bainite in Fe–C–Cr steel

Abstract

An analytical evaluation of transition temperature from upper to lower bainite in Fe – 0·38C – 0·93Cr (wt-%) steel was carried out. Calculations were based on the model constructed by Takahashi and Bhadeshia, which involves a comparison between the time t_θ needed to precipitate cementite within the bainitic ferrite plates with the time t_θ required to decarburise supersaturated ferrite plates. It was found that the distribution of lath widths, shown by histograms, of the bainitic ferrite varies with isothermal transformation temperatures and holding times. The transition between upper and lower bainite is found to occur over a narrow range of temperatures (350 – 410°C) and depends on the thickness of bainitic ferrite laths and the volume fraction of precipitated cementite. On comparing t _d and t_θ it was found that a transition temperature from upper to lower bainite reaction L _S of about 350°C could be predicted if the thickness of bainitic ferrite laths is set as w _o = 0·1 μm and the volume fraction of cementite set as ξ = 0·01. Calculated differences in the relative behaviour of t _d and t_θ revealed the occurrence of upper and lower bainite in steel Fe – 0·38C – 0·93Cr consistent with the results of transmission electron microscopy investigation.     

A study on micro-mechanical deformation behaviour of heat-treated 20MnMoNi55 steel

Several heat treatment procedures are designed considering critical temperatures of phase transformation evaluated through dilatometric testing of 20MnMoNi55 steel to transform low carbon bainitic as-received material into ferrite-martensite dual-phase steels consisting of varied martensite fractions. A thorough metallographic study correlated with the micro-hardness of constituent phases ensures morphological characteristics along with its fractional variations in as-received and dual-phase steels. The impact of fractional variation in constituent phases on the uniaxial monotonic deformation characteristics of dual-phase steels has been observed with a correlation study between experimental tensile and finite element simulated results. Therefore, a physical-based model with a 2-dimensional representative volume element has been established, addressing actual morphological characteristics obtained from metallographic studies. Moreover, the constitutive flow behaviours of ferrite and martensite are also derived from the dislocation-based hardening model to address the actual deformation phenomenon. Finally, an inhomogeneous deformation behaviour among constituent phases and localization of plastic strain in ferrite matrix has been observed with von-Mises stress, and equivalent plastic strain distribution through finite element simulated results. This phenomenon is again confirmed with kernel average misorientation mapping and geometrically necessary dislocation density evaluation through electron backscattered diffraction of tensile samples subjected to different degrees of plastic strain.     

Influence of ferrite-martensite microstructural morphology on the low cycle fatigue of a dual-phase steel

A CMnSi dual-phase steel has been heat-treated to yield three different microstructures — a dispersion of martensite in fine-grained ferrite (Type I), a continuous network of martensite around ferrite grains (Type II) and martensite islands encapsulated in a ferrite matrix (Type III) — and low cycle fatigue tests have been conducted. All three conditions have been found to exhibit cyclic hardening. The lower hardening in the Type I microstructure and its cyclic softening at lower strains are attributed to a more uniform initial distribution of dislocations because of the dispersion of the martensite. The Type I microstructure displays the best fatigue performance and is shown to obey the Coffin-Manson law. The deviation of the other two microstructures from this law is shown to be due to a transition from a ductile mode of fracture at lower strains to a brittle type of fracture at higher strains.     

Importance of deformation induced ferrite and factors which control its formation

Abstract

The influence of strain, strain rate, temperature, and grain size on the formation of deformation induced ferrite has been examined. Deformation induced ferrite forms very readily in both fine and coarse grained steels and much more rapidly than the ferrite from strain free austenite. Very small strains are sufficient to induce the production of such ferrite and the temperature range over which it appears spans from just below the Ae₃ temperature down to the undeformed Ar₃ temperature. Although it forms readily in both coarse and fine grained steels, the volume fraction produced is sensitive to the austenite grain size. In coarse grained steels, deformation at low strain rates is concentrated along the grain faces; extensive dynamic recovery occurs, which is why the ferrite remains soft, so that only thin ferrite films are able to form. At higher strain rates, work hardening takes place so that the strength of the ferrite at high strains approaches that of the austenite. Under these conditions, the deformation is propagated towards the centres of the austenite grains and larger volume fractions of deformation induced ferrite are able to form. In fine grained steels, the flow stress in the austenite grain boundary region is increased, so that when ferrite first forms, a considerable amount of work hardening takes place, which strengthens the ferrite. When combined with the increased number of triple points present in the material, the increased work hardening promotes spreading of the deformation, with the result that larger volume fractions of ferrite are produced, even at low strains and strain rates.     

Fatigue performance of dual‐phase steels for automotive wheel application

Fatigue performance of ferrite–martensite (FM) and ferrite–bainite (FB) dual‐phase (DP) steels used in automotive wheels has been compared in terms of (i) high‐cycle fatigue performance and failure mechanisms and (b) low‐cycle fatigue performance (Δε_t/2 = 0.002 to 0.01) and associated deformation mechanisms. FBDP steel exhibits moderately better high‐cycle fatigue performance, owing to delay in microcrack initiation. In FBDP steel, microcracks initiate predominantly along ferrite grain boundaries, while that at FB interface is significantly delayed in comparison with FMDP steel, where few microcracks appear at FM interface even below the endurance limit. During low‐cycle fatigue, however, FMDP steel performs considerably better than FBDP steel till Δε_t/2 ≤ 0.005 attributed to initial cyclic hardening, followed by cyclically stable behaviour exhibited by FMDP steel. In sharp contrast, at all Δε_t/2 > 0.002, FBDP steel undergoes continuous cyclic softening. The latter may cause undesirable deformation of wheels in service.     

Improvement of mechanical properties in a dual-phase ferrite–martensite AISI4140 steel under tough-strong ferrite formation

This paper has been concerned to investigate in details the mechanical properties of AISI4140 heat treatable steel under ferrite–martensite dual-phase (DP) microstructures in conjunction with that of conventional quench-tempered (CQT) full martensitic condition. For this purpose, a wide variety of ferrite–martensite DP samples containing different volume fractions of ferrite and martensite microphases have been developed using step quenching heat treatment processes at 600 °C for 20–55 s holding times with the subsequent hot oil quenching after being austenitized at 860 °C for 60 min in the same situation as to the CQT condition. The finalized tempering heat treatment has been carried out at 600 °C for 30 min for both of direct quenched full martensitic and DP samples in order to optimize the strength–ductility combination. Light and electron microscopes have been used in conjunction with mechanical tests to assess the structure–property relationships in the DP and CQT heat treated samples. The experimental results indicate that the DP microstructures consisting about 7% volume fraction of fine grain boundary ferrite in the vicinity of martensite are associated with excellent mechanical properties in comparison to that of CQT condition. These observations are rationalized in terms of higher carbon concentration of the remaining metastable austenite leading to the harder martensite formation on the subsequent hot oil quenching, and so developing much harder ferrite grains as a consequence of more constraints induced in the ferrite grains during martensitic phase transformation in the remaining austenite adjacent to the ferrite area. The higher martensite volume fraction in the vicinity of thin continuous grain boundary ferrite network has been associated with the harder ferrite formation, causing higher work hardening behavior in the short time treated DP samples. Moreover, it has been found that in order to optimize the mechanical properties of ferrite–martensite DP samples, two independently parameters should be simultaneously controlled: one is the ferrite volume fraction and the other is ferrite morphology.     

Influence of deformation induced ferrite,grain boundary sliding,and dynamic recrystallisation on hot ductility of 0·1–0·75%C steels

Abstract

The influence of C on hot ductility in the temperature range 600–1000°C has been examined for three C contents (0·1, 0·4, and 0·75 wt-%). Using a strain rate of 3 × 10^?3 s^?1, tensile specimens were heated to 1330°C before cooling to the test temperature. For the 0·4%C steel, two further strain rates of 3 × 10^?2 and 3 × 10^?4 s^?1 were examined. At the strain rate of 3 × 10^?3 s^?1, increasing the C content shifted the low ductility trough to lower temperatures in accordance with the trough being controlled by the γ–α transformation. Thin films of the softer deformation induced ferrite formed around the γ grain boundaries and allowed strain concentration to occur. Recovery to higher ductility at high temperatures occurred when these films could no longer form (i.e. above Ae₃) and dynamic recrystallisation was possible. The thin films of deformation induced ferrite suppressed dynamic recrystallisation in these coarse grained steels when tested at low strain rates. Recovery of ductility at the low temperature side of the trough in the 0·1%C steel corresponded to the presence of a large volume fraction of ferrite, this being the more ductile phase. For the 0·4%C steel decreasing the strain rate to 3 × 10^?4 s^?1 resulted in a very wide trough – extended to both higher and lower temperatures compared with the other strain rates. The high temperature extension was due to grain boundary sliding in the γ. Recovery of the ductility only occurred when dynamic recrystallisation was possible and this occurred at high temperatures. At the low temperature end, thin films of deformation induced ferrite were present and recovery did not occur until the temperature was sufficiently low to prevent strain concentration from occurring at the boundaries. Of the two intergranular modes of failure grain boundary sliding produced superior ductility. At the higher strain rates there was less grain boundary sliding, which led to a lower temperature for dynamic recrystallisation. Higher strain rates also increased the rate of work hardening of deformation induced ferrite, reducing the strain concentration at the boundaries. Ductility started to recover immediately below Ae₃, resulting in very narrow troughs. Finally, it was shown that the 2% strain that occurs during the straightening operation in continuous casting is sufficient to form deformation induced ferrite in steel containing 0·1%C.

MST/1809     

Age hardening behaviour during reverse transformation from martensite to austenite in Fe–31·1wt-%Ni

Abstract

The effects of thermomechanical treatments on the reverse transformation behaviour from twinned plate martensite to austenite in Fe–31·1%Ni have been studied. The variation of both diffusion controlled and diffusionless reverse transformation with temperature and time was examined. Diffusional reversion was dominant at lower reheating temperatures and led to a fine martensite–austenite duplex microstructure with a grain size of 0·01–0·1 μm, which caused a remarkable hardening ?H_v of 170–230 HV during aging. Cold working of the martensite promoted diffusional reversion and enhanced age hardening. X-ray analysis indicates that the age hardening is caused mainly by elastic strain resulting from coherent precipitation of austenite in martensite.

MST/1414     

Influence of strain rate on production of deformation induced ferrite and hot ductility of steels

Abstract

Compression testing was used to explore the influence of strain rate on the formation of deformation induced ferrite. Samples of a 0·4%C–1·4%Mn plain C–Mn steel were heated to 1225°C, cooled to test temperatures in the range 1100–610°C, and then given a true strain of 0·6, at strain rates of3 × 10^?2, 3 × 10^?3, and 3 × 10^?4 S^?1. At the lowest strain rate it wasfound that the strain to peak stress decreased with decreasing temperature in the range 750–610°C. This behaviour is related to the formation of thin films of the softer deformation induced ferrite at the γ grain boundaries at the higher temperatures, and spheroidisation at the lower temperatures. More normal stress–strain curves were observed at the higher strain rates, as raising the strain rate prevents the formation of deformation induced ferrite and delays spheroidisation. The strain rate was also found to have an important influence on the extent of recovery in the deformation induced ferrite; the lowest strain rate enabling full recovery and or recrystallisation to occur, thus keeping the film soft. This behaviour is shown to account for the poor hot tensile ductility at the lowest strain rates. Raising the strain rate in this temperature range improves the ductility because work hardening takes place, raising the strength of the ferrite closer to that of the y, thus preventing strain concentration from occurring.

MST/1934     

Design of an effective heat treatment involving intercritical hardening for high-strength–high elongation of 0.2C–1.5Al–(6–8.5)Mn-Fe TRIP steels: microstructural evolution and deformation behaviour

ABSTRACT

We propose an effective heat treatment involving a combination of intercritical hardening and tempering to obtain high strength–high ductility in hot-rolled 0.2C–1.5Al–(6–8.5)Mn–Fe transformation-induced plasticity (TRIP) steels. An excellent combination of high ultimate tensile strength of 1045–1380?MPa and total elongation of 34–39% was obtained when the steels were subjected to intercritical hardening at 630–650?°C and tempered at 200?°C. Intercritical hardening impacted the co-existence of austenite, ferrite and martensite, such that the deformation behaviour varied with the Mn content. The excellent properties of the steels were attributed to cumulative contribution of enhanced TRIP effect of austenite and ferrite and martensite constituents. The discontinuous TRIP e?ect during tensile deformation involves stress relaxation and led to consequent enhancement of ductility.