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1.
Waste anchovy fish oils transesterification was studied with the purpose of achieving the conditions for biodiesel usage in a single cylinder, direct injection compression ignition. With this purpose, the pure biodiesel produced from anchovy fish oil, biodiesel-diesel fuel blends of 25%:75% biodiesel-diesel (B25), 50%:50% biodiesel-diesel (B50), 75%:25% biodiesel-diesel (B75) and petroleum diesel fuels were used in the engine to specify how the engine performance and exhaust emission parameters changed. The fuel properties of test fuels were analyzed. Tests were performed at full load engine operation with variable speeds of 1000, 1500, 2000 and 2500 rpm engine speeds. As results of investigations on comparison of fuels with each other, there has been a decrease with 4.14% in fish oil methyl ester (FOME) and its blends' engine torque, averagely 5.16% reduction in engine power, while 4.96% increase in specific fuel consumption have been observed. On one hand there has been average reduction as 4.576%, 21.3%, 33.42% in CO2, CO, HC, respectively; on the other hand, there has been increase as 9.63%, 29.37% and 7.54% in O2, NOx and exhaust gas temperature has been observed. It was also found that biodiesel from anchovy fish oil contains 37.93 wt.% saturated fatty acids which helps to improve cetane number and lower NOx emissions. Besides, for biodiesel and its blends, average smoke opacity was reduces about 16% in comparison to D2. It can be concluded that waste anchovy fish obtained from biodiesel can be used as a substitute for petroleum diesel in diesel engines.  相似文献   

2.
《Fuel》2007,86(10-11):1534-1544
This study presents analytical comparisons of atomization characteristics of 7 biodiesels and 17 binary and ternary blends with D1 and D2 at 80 °C, using a direct injection injector. The atomization of a genetically modified vegetable oil – Captex 355 – and its corresponding biodiesel were also studied. Results from statistical analysis showed that B100 coconut biodiesel had similar atomization characteristics to D2, because of its similar properties, i.e. density, surface tension and viscosity. No significant difference in drop size was observed for all B5 blends, and B20 blends and B100 biodiesels of palm, soybean, cottonseed, peanut and canola. It implies these stocks of biodiesels and their blends can be used in a DI engine with similar atomization characteristics. Ternary biodiesel blends, with ⩽10 wt.% petroleum diesel, can yield equal drop sizes as some binary blends with large quantities of D1 and D2. The ternary biodiesel blends are likely to reduce pollution from exhaust emissions better than the biodiesel blends with D1 or D2. Captex 355 biodiesel had the best atomization characteristics of all the fuels studied. The Sauter mean diameter (SMD) produced by this fuel was up to 13% and 25% smaller than that of D1 and D2, respectively. The Captex 355 biodiesel may be used as a base in binary or ternary biodiesel blends to achieve better atomization than D1 and D2 in diesel engines.  相似文献   

3.
《Fuel》2007,86(7-8):1139-1143
In this study, biodiesel fuel and fuel additives were produced from crude tall oil that is a by-product in the pulp manufacturing by craft or sulphate pulping process. Fatty acids and resinic acids were obtained from crude tall oil by distillation method. Tall oil methyl ester (biodiesel) was produced from fatty acids. Resinic acids were reacted with NiO and MnO2 stoichiometrically for production of metallic fuel additives. Each metallic fuel additive was added at the rate of 8 μmol/l and 12 μmol/l to make mixtures of 60% tall oil methyl ester/40% diesel fuel (TE60) for preparing test fuels. Metallic fuel additives improved properties of biodiesel fuels, such as pour point and viscosity values. Biodiesel fuels were tested in an unmodified direct injection diesel engine at full load condition. Specific fuel consumption of biodiesel fuels increased by 6.00%, however, in comparison with TE60, it showed trend of decreasing with adding of additives. Exhaust emission profile of biodiesel fuels improved. CO emissions and smoke opacity decreased up to 64.28% and 30.91% respectively. Low NOx emission was also observed in general for the biodiesel fuels.  相似文献   

4.
Non-edible jatropha (Jatropha curcas), karanja (Pongamia pinnata) and polanga (Calophyllum inophyllum) oil based methyl esters were produced and blended with conventional diesel having sulphur content less than 10 mg/kg. Ten fuel blends (Diesel, B20, B50 and B100) were tested for their use as substitute fuel for a water-cooled three cylinder tractor engine. Test data were generated under full/part throttle position for different engine speeds (1200, 1800 and 2200 rev/min). Change in exhaust emissions (Smoke, CO, HC, NOx, and PM) were also analyzed for determining the optimum test fuel at various operating conditions. The maximum increase in power is observed for 50% jatropha biodiesel and diesel blend at rated speed. Brake specific fuel consumptions for all the biodiesel blends with diesel increases with blends and decreases with speed. There is a reduction in smoke for all the biodiesel and their blends when compared with diesel. Smoke emission reduces with blends and speeds during full throttle performance test.  相似文献   

5.
Safflower seed oil was chemically treated by the transesterification reaction in methyl alcohol environment with sodium hydroxide (NaOH) to produce biodiesel. The produced biodiesel was blended with diesel fuel by 5% (B5), 20% (B20) and 50% (B50) volumetrically. Some of important physical and chemical fuel properties of blend fuels, pure biodiesel and diesel fuel were determined. Performance and emission tests were carried out on a single cylinder diesel engine to compare biodiesel blends with petroleum diesel fuel. Average performance reductions were found as 2.2%, 6.3% and 11.2% for B5, B20 and B50 fuels, respectively, in comparison to diesel fuel. These reductions are low and can be compensated by a slight increase in brake specific fuel consumption (Bsfc). For blends, Bsfcs were increased by 2.8%, 3.9% and 7.8% as average for B5, B20 and B50, respectively. Considerable reductions were recorded in PM and smoke emissions with the use of biodiesel. CO emissions also decreased for biodiesel blends while NOx and HC emissions increased. But the increases in HC emissions can be neglected as they have very low amounts for all test fuels. It can be concluded that the use of safflower oil biodiesel has beneficial effects both in terms of emission reductions and alternative petroleum diesel fuel.  相似文献   

6.
In the present paper, results of an experimental investigation carried out in a modern diesel engine running at different operative conditions and fuelled with blends of diesel and n-butanol, are reported. The exploration strategy was focused on the management of the timing and injection pressure to achieve a condition in which the whole amount of fuel was delivered before ignition. The aim of the paper was to evaluate the potential to employ fuel blends having low cetane number and high resistance to auto-ignition to reduce engine out emissions of NOx and smoke without significant penalty on engine performance. Fuel blends were mixed by the baseline diesel (BU00) with 20% and 40% of n-butanol by volume. The n-butanol was taken by commercial production that is largely produced through petrochemical pathways although the molecule is substantially unchanged for butanol produced through biological mechanisms.The experimental activity was performed on a turbocharged, water cooled, DI diesel engine, equipped with a common rail injection system. The engine equipment includes an exhaust gas recirculation system controlled by an external driver, a piezo-quartz pressure transducer to detect the in-cylinder pressure signal and a current probe to acquire the energizing current to the injectors. Engine tests were carried out at 2500 rpm and 0.8 MPa of BMEP exploring the effect of start of injection, O2 concentration at intake and injection pressure on combustion behavior and engine out emissions. The in-cylinder pressure and rate of heat release were investigated for the neat diesel and the two blends to evaluate engine performance and exhaust emissions both for the conventional diesel and the advanced premixed combustion processes.The management of injection pressure, O2 concentration at intake and injection timing allowed to realize a partial premixed combustion by extending the ignition delay, particularly for blends. The main results of the investigation made reach smoke and NOx emissions due to the longer ignition delay and a better mixing control before combustion. The joint effect of higher resistance to auto ignition and higher volatility of n-butanol blends improved emissions compared to the neat diesel fuel with a low penalty on fuel consumption.  相似文献   

7.
《Fuel》2007,86(1-2):143-151
The dynamic viscosities of biodiesel derived from ethyl esters of fish oil, no. 2 diesel fuel, and their blends were measured from 298 K down to their respective pour points. Blends of B80 (80 vol.% biodiesel–20 vol.% no. 2 diesel), B60, B40 and B20 were investigated. All the viscosity measurements were made with a Bohlin VOR Rheometer. Cloud point and pour point measurements were made according to ASTM standards. Arrhenius equations were used to predict the viscosities of the pure Biodiesel (B100), no. 2 diesel fuel (B0) and the biodiesel blends (B80, B60, B40, and B20) as a function of temperature. The predicted viscosities agreed well with measured values. An empirical equation for calculating the dynamic viscosity of these blends as a function of both temperature and blend has been developed. Furthermore, based on the kinematic viscosity and density measurements of B100 up to 573 K by Tate et al. [Tate RE, Watts KC, Allen CAW, Wilkie KI. The viscosities of three biodiesel fuels at temperatures up to 300 °C. Fuel 2006;85:1010–5; Tate RE, Watts KC, Allen CAW, Wilkie KI. The densties of three biodiesel fuels at temperatures up to 300 °C. Fuel 2006;85:1004–9] an empirical equation for predicting the dynamic viscosity of pure biodiesel for temperatures from 277 K to 573 K is given. Empirical equations for predicting the cloud and pour point for a given blend give values in good agreement with experiments. The dynamic viscosity of biodiesel and its blends increases as temperature decreases and show Newtonian behaviour down to the pour point. Dynamic viscosity, cloud point and pour point decreases with an increase in concentration of no. 2 diesel in the blend.  相似文献   

8.
This paper analyses the fuel injection characteristics of bioethanol-diesel fuel and bioethanol-biodiesel blends considered as fuel for diesel engines. Attention is focused on the injection characteristics which significantly influence the engine characteristics and subsequently the exhaust emissions. In this context the following injection characteristics have been investigated experimentally: fuelling, injection timing, injection delay, injection duration, mean injection rate, and injection pressure. The tested fuels were neat mineral diesel fuel, neat biodiesel made from rapeseed oil, bioethanol/diesel fuel and bioethanol/biodiesel blends up to 15% (v/v) bioethanol with an increment of 5%. The fuels blends were experimentally investigated in a fuel injection M system at rated condition (FL, 1100 rpm), peak torque (FL, 850 rpm), and maximum pump speed (1100 rpm) for different partial loads (PL 75% and PL 50%), at ambient temperature.It has been proven that for all operating regimens tested, the addition of bioethanol to biodiesel reduces fuelling, injection timing, injection duration, mean injection rate and maximum injection pressure and increases injection delay compared to pure biodiesel. Meanwhile, increasing bioethanol in diesel fuel shows no significant variations or a slightly increase in fuelling, injection timing, injection duration, and mean injection rate and a decrease in injection delay and maximum injection pressure, compared to pure diesel fuel.The influence of bioethanol in biodiesel is much more significant that in diesel fuel; it has a beneficial effect on biodiesel injection characteristics because bioethanol addition brings them nearer to the diesel fuel one and it is expected to decrease biodiesel NOx emissions.  相似文献   

9.
Yi Ren  Haiyan Miao  Yage Di  Deming Jiang  Ke Zeng  Bing Liu  Xibin Wang 《Fuel》2008,87(12):2691-2697
Combustion and emissions of a DI diesel engine fuelled with diesel-oxygenate blends were investigated. The results show that there exist the different behaviors in the combustion between the diesel-diglyme blends and the other five diesel-oxygenate blends as the diglyme has the higher cetane number than that of diesel fuel while the other five oxygenates have the lower cetane number than that of diesel fuel. The smoke concentration decreases regardless of the types of oxygenate additives, and the smoke decreases with the increase of the oxygen mass fraction in the blends without increasing the NOx and engine thermal efficiency. The reduction of smoke is strongly related to the oxygen-content of blends. CO and HC concentrations decrease with the increase of oxygen mass fraction in the blends. Unlike conventional diesel engines fueled with pure diesel fuel, engine operating on the diesel-oxygenate blends presents a flat NOx/Smoke tradeoff curve versus oxygen mass fraction.  相似文献   

10.
Engine performance and emission comparisons were made between the use of soy, Canola and yellow grease derived B100 biodiesel fuels and an ultra-low sulphur diesel fuel in the high load engine operating conditions. Compared to the diesel fuel engine-out emissions of nitrogen oxides (NOx), a high-cetane number (CN) biodiesel fuel produced comparable NOx while the biodiesel with a CN similar to the diesel fuel produced relatively higher NOx at a fixed start of injection. The soot, carbon monoxide and un-burnt hydrocarbon emissions were generally lower for the biodiesel-fuelled engine. Exhaust gas recirculation (EGR) was then extensively applied to initiate low temperature combustion (LTC) mode at medium and low load conditions. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. Simultaneous reduction of NOx and soot was achieved when the ignition delay was prolonged by more than 50% from the case with 0% EGR at low load conditions. Furthermore, a preliminary ignition delay correlation under the influence of EGR at steady-state conditions was developed. The correlation considered the fuel CN and oxygen concentrations in the intake air and fuel. The research intends to achieve simultaneous reductions of NOx and soot emissions in modern production diesel engines when biodiesel is applied.  相似文献   

11.
O?uzhan Do?an 《Fuel》2011,90(7):2467-9430
Nitrogen oxides and smoke emissions are the most significant emissions for the diesel engines. Especially, fuels containing high-level oxygen content can have potential to reduce smoke emissions significantly. The aim of the present study is to evaluate the influence of n-butanol/diesel fuel blends (as an oxygenation additive for the diesel fuel) on engine performance and exhaust emissions in a small diesel engine. For this aim five-test fuels, B5 (contains 5% n-butanol and 95% diesel fuel in volume basis), B10, B15, B20 and neat diesel fuel, were prepared to test in a diesel engine. Tests were performed in a single cylinder, four stroke, unmodified, and naturally aspirated DI high speed diesel engine at constant engine speed (2600 rpm) and four different engine loads by using five-test fuels. The experimental test results showed that smoke opacity, nitrogen oxides, and carbon monoxide emissions reduced while hydrocarbon emissions increased with the increasing n-butanol content in the fuel blends. In addition, there is an increase in the brake specific fuel consumption and in the brake thermal efficiency with increasing n-butanol content in fuel blends. Also, exhaust gas temperature decreased with increasing n-butanol content in the fuel blends.  相似文献   

12.
The need for diversification of energy sources and reducing various emissions including CO2 emission in diesel engine can be met with alternative diesel fuels such as gas to liquid (GTL) and GTL–biodiesel blends. But there should be a clear understanding of the combustion and engine-out emission characteristics for alternative fuels. In this respect, an experimental study was conducted on a 2.0 L 4 cylinders turbocharged diesel engine fuelled with those alternative diesel fuels to investigate the engine-out emission characteristics under various steady-state engine operating conditions. The results revealed that noticeable decreases in THC (22–56%) and CO (16–52%) emissions for GTL–biodiesel blends were observed, whereas NOx emissions for GTL–biodiesel blends increased by a maximum of 12% compared to diesel. With regard to particle size distributions (PSDs) for GTL–biodiesel blends, the particulate matter (PM) number concentration in accumulation mode decreased, as a result of the excess oxygen content in biodiesel. Contrary to the tendency in the accumulation mode, there was a slight increase in the PM number concentration in the nucleation mode under the operating conditions wherein the exhaust gas recirculation (EGR) strategy was applied. The total PM number concentration for G + BD40 decreased by a maximum of 46% compared to that for diesel. From these results of enhanced emission characteristics compared to diesel and GTL fuel, the potential for the use of GTL–biodiesel blends could be confirmed.  相似文献   

13.
《Fuel》2007,86(12-13):1831-1839
The effects of fuel characteristics and engine operating conditions on elemental composition of emissions from twelve heavy duty diesel buses have been investigated. Two types of diesel fuels – low sulfur diesel (LSD) and ultra low sulfur diesel (ULSD) fuels with 500 ppm and 50 ppm sulfur contents respectively and 3 driving modes corresponding to 25%, 50% and 100% power were used. Elements present in the tailpipe emissions were quantified by inductively coupled plasma mass spectrometry (ICPMS) and those found in measurable quantities included Mg, Ca, Cr, Fe, Cu, Zn, Ti, Ni, Pb, Be, P, Se, Ti and Ge. Multivariate analyses using multi-criteria decision making methods (MCDM), principal component analysis (PCA) and partial least squares (PLS) facilitated the extraction of information about the structure of the data. MCDM showed that the emissions of the elements were strongly influenced by the engine driving conditions while the PCA loadings plots showed that the emission factors of the elements were correlated with those of other pollutants such as particle number, total suspended particles, CO, CO2 and NOx. Partial least square analysis revealed that the emission factors of the elements were strongly dependent on the fuel parameters such as the fuel sulfur content, fuel density, distillation point and cetane index. Strong correlations were also observed between these pollutants and the engine power or exhaust temperature. The study provides insights into the possible role of fuel sulfur content in the emission of inorganic elements from heavy duty diesel vehicles.  相似文献   

14.
In this study, performance and exhaust emissions of biodiesel in a compression ignition engine was experimentally investigated. Therefore, biodiesel has been made by transesterification from cotton seed oil and then it was mixed with diesel fuel by 25% volumetrically, called here as B75 fuel. B75 fuel was tested, as alternative fuel, in a single cylinder, four strokes, and air-cooled diesel engine. The effect of B75 and diesel fuels on the engine power, engine torque and break specific fuel consumption were clarified by the performance tests. The influences of B75 fuel on CO, HC, NOx, Smoke opacity, CO2, and O2 emissions were investigated by emission tests. The engine torque and power, for B75 fuel, were lower than that of diesel fuel in range of 2-3%. However, for the B75, specific fuel consumption was higher than that of diesel fuel by approximately 3%. CO2, CO, HC, smoke opacity and NOx emissions of B75 fuel were lower than that of diesel fuel. The experimental results showed that B75 fuel can be substituted for the diesel fuel without any modifications in diesel engines.  相似文献   

15.
The paper presents the experimental results obtained concerning performances and pollution of a diesel engine fueled with diesel–biodiesel–ethanol blends compared with diesel fuel in laboratory tests. The main properties of the researched fuels are presented within this paper, in comparison with classical diesel fuel (chemical composition, density, kinematic viscosity, cold filter plugging point, flash point). Engines’ performances were evaluated by determining the brake specific fuel consumption and brake thermal efficiency. For pollution evaluation the emissions of CO, CO2, NOx, HC and smoke have been measured. An increasing of brake specific fuel consumption has been observed, especially at lower engines’ loads, with maximum 32.4%, reducing engine brake thermal efficiency with maximum 21.7%. CO emissions decrease, especially at high loads with maximum 59%, on the basis of CO2 increased emissions. NOx emissions slightly increase, especially at partial and high loads, meanwhile HC and smoke emissions decrease in all engines’ load cycles.  相似文献   

16.
Experiments were conducted on a 4-cylinder direct-injection diesel engine which has a compressing ratio of 19, using ultra low sulfur diesel blended with ethanol using 1–1.5% by volume of 1-dodecanol as the solvent to investigate the particulate emissions of the engine under five engine loads and at engine speeds of 1800 and 2400 rev/min. Blended fuels containing 6.1%, 12.2%, 18.2% and 24.2% by volume of ethanol, corresponding to 2%, 4%, 6% and 8% by mass of oxygen in the blended fuel, were used. At both engine speeds, with an increase in ethanol in the fuel, the smoke opacity, the particulate mass concentration and the total number of nano-size particles are all reduced. A diesel oxidation catalyst (Finnkat) was used and found to further reduce particulate emission. The smoke opacity, the particulate mass concentration and the total number concentration at 2400 rev/min are higher than those at 1800 rev/min.  相似文献   

17.
This work presents the physical-chemical properties of fuel blends of waste cooking oil biodiesel or castor oil biodiesel with diesel oil. The properties evaluated were fuel density, kinematic viscosity, cetane index, distillation temperatures, and sulfur content, measured according to standard test methods. The results were analyzed based on present specifications for biodiesel fuel in Brazil, Europe, and USA. Fuel density and viscosity were increased with increasing biodiesel concentration, while fuel sulfur content was reduced. Cetane index is decreased with high biodiesel content in diesel oil. The biodiesel blends distillation temperatures T10 and T50 are higher than those of diesel oil, while the distillation temperature T90 is lower. A brief discussion on the possible effects of fuel property variation with biodiesel concentration on engine performance and exhaust emissions is presented. The maximum biodiesel concentration in diesel oil that meets the required characteristics for internal combustion engine application is evaluated, based on the results obtained.  相似文献   

18.
K. Varatharajan  M. Cheralathan 《Fuel》2011,90(8):2721-2725
Biodiesel offers cleaner combustion over conventional diesel fuel including reduced particulate matter, carbon monoxide and unburned hydrocarbon emissions. However, several studies point to slight increase in NOx emissions (about 10%) for biodiesel fuel compared with conventional diesel fuel. Use of antioxidant additives is one of the most cost-effective ways to mitigate the formation of prompt NOx. In this study, the effect of antioxidant additives on NOx emissions in a jatropha methyl ester fuelled direct injection diesel engine have been investigated experimentally and compared. A survey of literature regarding the causes of biodiesel NOx effect and control strategies is presented. The antioxidant additives L-ascorbic acid, α tocopherol acetate, butylated hydroxytoluene, p-phenylenediamine and ethylenediamine were tested on computerised Kirloskar-make 4 stroke water cooled single cylinder diesel engine of 4.4 kW rated power. Results showed that antioxidants considered in the present study are effective in controlling the NOx emissions of biodiesel fuelled diesel engines. A 0.025%-m concentration of p-phenylenediamine additive was optimal as NOx levels were substantially reduced in the whole load range in comparison with neat biodiesel. However, hydrocarbon and CO emissions were found to have increased by the addition of antioxidants.  相似文献   

19.
A number of investigations have examined the impact of the use of biodiesel on the emissions of carbon dioxide and regulated emissions, but limited information exists on the chemical composition of particulate matter from diesel engines burning biodiesel blends. This study examines the composition of diesel particulate matter (DPM) emissions from a commercial agriculture tractor burning a range of biodiesel blends operating under a load that is controlled by a power take off (PTO) dynamometer. Ultra-low sulfur diesel (ULSD) fuel was blended with soybean and beef tallow based biodiesel to examine fuels containing 0% (B0), 25% (B25), 50% (B50), 75% (B75), and 100% (B100) biodiesel. Samples were then collected using a dilution source sampler to simulate atmospheric dilution. Diluted and aged exhaust was analyzed for particle mass and size distribution, PM2.5 particle mass, PM2.5 organic and elemental carbon, and speciated organic compounds. PM2.5 mass emissions rates for the B25, B50, and B75 soybean oil biodiesel mixtures had 20%–30% lower emissions than the petroleum diesel, but B100 emissions were about 40% higher than the petroleum diesel. The trends in mass emission rates with the increasing biodiesel content can be explained by a significant decrease in elemental carbon (EC) emissions across all blending ranges and increasing organic carbon (OC) emissions with pure biodiesel. Beef tallow biodiesel blends showed similar trends. Nevertheless, it is important to note that the study measurements are based on low dilution rates and the OC emissions changes may be affected by ambient temperature and different dilution conditions spanning micro-environments and atmospheric conditions. The results show that the use of biodiesel fuel for economic or climate change mitigation purposes can lead to reductions in PM emissions and a co-benefit of EC emission reductions. Detailed speciation of the OC emissions were also examined and are presented to understand the sensitivity of OC emissions with respect to biodiesel fuel blends.

Copyright 2012 American Association for Aerosol Research  相似文献   

20.
Lei Zhu  C.S. Cheung  W.G. Zhang 《Fuel》2011,90(5):1743-1750
In this study, Euro V diesel fuel, biodiesel, and ethanol-biodiesel blends (BE) were tested in a 4-cylinder direct-injection diesel engine to investigate the combustion, performance and emission characteristics of the engine under five engine loads at the maximum torque engine speed of 1800 rpm. The results indicate that when compared with biodiesel, the combustion characteristics of ethanol-biodiesel blends changed; the engine performance has improved slightly with 5% ethanol in biodiesel (BE5). In comparison with Euro V diesel fuel, the biodiesel and BE blends have higher brake thermal efficiency. On the whole, compared with Euro V diesel fuel, the BE blends could lead to reduction of both NOx and particulate emissions of the diesel engine. The effectiveness of NOx and particulate reductions increases with increasing ethanol in the blends. With high percentage of ethanol in the BE blends, the HC, CO emissions could increase. But the use of BE5 could reduce the HC and CO emissions as well.  相似文献   

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