共查询到18条相似文献,搜索用时 93 毫秒
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为了揭示硫化亚铁自燃引起油气储罐和炼油设备着火、爆炸机理,探索硫化亚铁自燃事故防治技术,分别以氧气、空气为反应气,通过同步热分析仪分别测定活性硫化亚铁样品及经钝化处理后的样品(简称钝化样品),在室温~800℃范围内的反应,采用等转化率法分别计算活性样品及钝化样品在氧气气氛下反应的表观活化能。结果表明,活性样品在氧气下的反应包括室温自燃和高温段分解两个阶段;在空气下的反应包括室温自燃、中温氧化及高温分解三个阶段,最终产物均为Fe_2O_3;钝化样品室温无法自燃,在氧气或空气气氛下,钝化样品加热至100℃左右发生氧化。经计算,在氧气气氛下,活性样品表观活化能为57.101 kJ/mol,钝化样品表观活化能为235.985 kJ/mol,钝化处理可抑制样品的活性。 相似文献
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硫化亚铁自燃防范措施浅析 总被引:2,自引:0,他引:2
硫化亚铁自燃事故经常发生,对炼油厂的安全生产造成直接严重威胁。文章阐述了硫化亚铁自燃的机理,分析了硫化亚铁自燃的案例并从硫化亚铁生成和清除以及其它方面提出了防范硫化亚铁自燃事故的对策措施。 相似文献
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硫化亚铁自燃事故在炼油装置中较为常见,且危害较大。本文分析了炼油装置中硫化亚铁产生原因及硫化亚铁自燃的机理,并从抑制硫化亚铁产生、已生产硫化亚铁的清除和降低自燃发生几率等方面给出了预防硫化亚铁自燃事故的相关措施。 相似文献
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针对能产生自燃内因火灾的典型硫化矿石类型,介绍了其堆积、氧化自热、着火及燃烧各阶段的特征,分析了氧化自燃发生的原因和发展过程,并探讨了影响硫化矿石自燃的各种因素及其作用机理.在此基础上,澄清了对硫化矿山火灾防治有重要指导意义的自燃发火初期的概念及其征兆识别方法,可为现场硫化矿山自燃火灾的早期识别与防治提供指导. 相似文献
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新桥硫铁矿矿石自燃特征及综合防治措施 总被引:2,自引:1,他引:1
通过新桥硫铁矿-230m中段6次自燃火灾事故调查和矿岩自燃倾向性以及现场堆矿实验研究,系统阐述了硫化矿石氧化自热到自燃整个过程的特征规律,并针对火灾提出了一系列防灭火技术措施,特别指出了硫化矿自燃初期征兆的识别方法,对硫化矿山火为预防和综合治理有重要指导意义。 相似文献
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为抑制褐煤堆放时发生自燃与煤粉爆炸,利用自燃装置试验台和煤粉爆炸试验台,对褐煤及其干燥到不同水分的干燥煤进行试验研究,分析其自燃特性和爆炸特性。结果表明,对于自燃特性而言,褐煤水分减少10%,耗氧速度增加约0.17%/min,粒径减小一个等级,耗氧速度增加约0.11%/min;对于爆炸特性而言,褐煤水分减少5%,平均煤粉爆炸下限质量浓度约降低0.015 kg/m~3,温度每升高10℃,平均煤粉爆炸下限质量浓度降低约0.03 kg/m~3;总体而言,随着干燥程度的加深,褐煤自燃、爆炸特性均增强,危险性增加。 相似文献
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《应用化工》2015,(11)
油品中的活性硫对设备具有腐蚀作用,探究有氧条件下硫化铁的生成及自燃性影响因素,对预防硫化铁自燃事故的发生具有重要意义。实验以三氧化二铁为主要原料,在氧气浓度为21%的条件下,与硫化氢气体反应来制备硫化铁。考察了环境温度、硫化产物的存放时间和储热条件对硫化铁自燃性的影响。结果表明,有氧条件下硫化铁的生成过程是一个硫化和氧化同时进行的过程,试样温度上升幅度大,单质硫生成量高;环境温度越高,所生成的硫化铁氧化升温越明显;存放时间对硫化铁的自燃性有重要影响,在存放过程中单质硫与Fe S反应生成自燃性更高的多硫化物;储热条件越好,越易造成热量的堆积,加剧硫化铁的氧化放热反应。 相似文献
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The ion-selectivity of ferrous sulfide film formed on a cellulose sheet was determined by measuring the film potentials in neutral chloride solution. The results show that ferrous sulfide film is a bipolar film consisting of an inner cation-selective layer and an outer anion-selective layer. This kind of film structure can accelerate the localized corrosion of steel. The influence of some anions, cations and imidazoline corrosion inhibitor on ion-selectivity of the film was also investigated. The ion-selectivity of the film is altered from bipolar to anion-selective with the adsorption of Ca2+, Mg2+ and Ba2+ ions, or to cation-selective with the adsorption of MoO42-, PO 43-and imidazoline inhibitor. Potentiodynamic polarization, AC impedance technology, and the weight-loss method were used to understand the relationship between the ion-selectivity and corrosion behaviors of steel in sulfide-containing solution. 相似文献
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The results of an experimental study aimed at evaluating the spontaneous combustion characteristics of two Turkish lignites moistured and air-dried at varying times are discussed. The spontaneous combustion characteristics of the coals were determined using Crossing Point Methods adapted to our laboratories conditions. The content of three predominant oxygen functional groups (carboxyl, hydroxyl, and carbonyl) of untreated, moisten and air-dried coal samples were also determined with wet chemical methods. The content of oxygen functional groups in moisten coal samples do not differ significantly that of untreated coal samples, for realized in vacuum desicator to moistured of coal samples. The liability of spontaneous combustion of the two coals was reduced when moisture content increased with increase in contacted time to water vapour. The moisten coal samples was dried in laboratory during 24 and 48 h time period. The concentration of oxygen contain functional groups of drying coal samples increased with increase of contact time with air and decrease of particle size. The liability of spontaneous combustion of the air-dried coal samples increased with increase of contacted time with air and with decrease of moisture content. 相似文献
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