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PVC/MBS共混物的形态及力学性能 总被引:2,自引:0,他引:2
褚明利;刘哲;李洪权;陈明;张会轩 《中国塑料》2010,24(3):25-28
采用种子乳液聚合方法,在聚丁二烯乳胶粒子上接枝甲基丙烯酸甲酯(MMA)和苯乙烯(St),制得MBS核壳接枝共聚物,并将其作为增韧剂与聚氯乙烯(PVC)共混制备PVC/MBS共混物。考察了接枝不同MMA和St含量的MBS在PVC中的分散状态及其对PVC/MBS共混物力学性能。结果表明,当MBS壳层中MMA含量增加时,MBS粒子在PVC基体中的分散状态被改善;PVC/MBS共混物的冲击强度随之增加,冲击强度最高时为1117.74 J/m;当MBS中接枝少量St时,PVC/MBS共混物呈现韧性断裂,冲击值最高时为1039.33 J/m;当MBS接枝大量St时,会产生内包容现象,不利于提高PVC共混物的冲击强度。 相似文献
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本文介绍了MBS与PVC共混改性的研究,找出了能制备综合性能较佳的MBS/PVC共混物的配方。用DSC法和扫描电镜分别研究上述两组分的相容性及所得共混物的相态结构。并就MBS中橡胶粒径,含胶量等对所制得的共混物冲击强度的影响进行了探讨。此外,用Brabender流变仪测定该共混物的流变曲线,预测其熔融加工情况。 相似文献
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苯乙烯在MBS中的结合方式对PVC/MBS性能的影响 总被引:4,自引:0,他引:4
以乳液聚合法合成了化学组成恒定的具有核-壳结构的(甲基丙烯酸甲酯/丁二烯/苯乙烯)共聚物(MBS),通过改变原料及其配比,使苯乙烯(St)在MBS中以共聚或接枝方式结合,用动态力学热分析仪研究了MBS内耗与温度的关系。将MBS与聚氯乙烯(PVC)共混,研究了St结合方式对共混物冲击韧性及增韧机理的影响,结果表明,随着MBS核中St含量的增加,PVC/MBS共混物的脆-韧转变向高温移动;当St仅以接枝的方式结合时,橡胶粒子的空洞化及剪切屈服是主要的增韧机理,当St仅以共聚方式结合时,剪切屈服是主要的增韧机理。 相似文献
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通过乳液聚合方法制备了不同橡胶粒径和橡胶相组成比的新型核-壳丙烯酸酯类抗冲改性剂(N-AIM),将其与聚甲基丙烯酸甲酯(PMMA)进行熔融共混,得到了PMMA/N-AIM共混物。对PMMA/N-AIM共混物的形态结构、冲击性能和光学性能分别进行了考察。通过透射电镜(TEM)分析表明,橡胶粒径为100 nm时改性剂在基体中发生聚集,大于100 nm时均可均匀分散在基体中;冲击测试结果表明,随着N-AIM橡胶粒径的增加,共混物的冲击强度先增大后减小;光学测试表明橡胶组成比影响共混物的光学性能。 相似文献
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MBS组成对PVC/MBS合金性能的影响 总被引:1,自引:0,他引:1
丁春黎 《现代塑料加工应用》2001,13(3):27-29
讨论了MBS的组成、粒径尺寸以及粒子结构等因素对PVC/MBS合金综合性能的影响,结果表明,当MBS组成为25/60/42时,与PVC树脂的相容性好,所得合金为折光指数匹配的透明材料,具有好的光学及力学性能。 相似文献
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Chao Zhou Hua Liu Ming Chen Guangfeng Wu Huixuan Zhang 《Polymer Engineering and Science》2012,52(12):2523-2529
An analysis was made on the effects of rubber particle size on the mechanical properties and deformation mechanisms of transparent polyvinyl chloride (PVC) blends containing core–shell methyl methacrylate–butadiene–styrene (MBS) impact modifiers. The critical interparticle distance was found not to be the criterion for the brittle‐ductile transition in the blends. In tensile tests, the blends with larger (100–280 nm) rubber particles exhibited intense stress‐whitening, while one blend with small (83 nm) rubber particles showed only slight stress‐whitening. These differences were due to an increase in resistance to cavitation with decreasing rubber particle size. Transmission electron microscopy studies on blends with a bimodal distribution of particle sizes showed that in the whitened zone of Izod specimens the larger rubber particles cavitated and expanded on yielding, while the smaller particles remained intact. However, Izod test results showed that small MBS rubber particles can toughen the PVC matrix very effectively, especially at low temperatures and at low rubber concentrations. The deformation mechanisms responsible for these effects were discussed. POLYM. ENG. SCI., 2012. © 2012 Society of Plastics Engineers 相似文献
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Summary An analysis was made on the effects of particle morphology on the mechanical and optical properties of polyvinyl chloride/methyl
methacrylate-butadiene-styrene (PVC/MBS) blends. Special care was taken to make comparisons of blends with different structural
MBS under same conditions. The blend with a three-layer structure MBS had a lowest brittle-ductile transition (BDT) temperature,
while the blend with a two-layer structure MBS had a relatively higher BDT temperature due to its higher Tg of rubber particles
enhanced by combination of St. Furthermore, the transparency of blend with two-layer structure MBS was higher than that with
three-layer structure MBS. In addition, SEM investigations showed the cavitation of rubber particles took place to remove
the plastic constraint and promote a large volume of deformation in the blend with three-layer structure MBS. 相似文献
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为了考察MBS微观结构与其合成工艺、产品性能之间的关系,利用电子显微镜技术对丁苯胶乳、MBS接枝胶乳、MBS粉末颗粒、PVC/MBS共混物的微观形态进行了系统的研究分析;对PVC/MBS共混物经过拉伸后内部微观结构和冲击后的断面进行分析研究,初步探讨了MBS的抗冲改性机理。 相似文献
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Effects of core‐shell particle growth manners on morphologies and properties of poly(vinyl chloride)/(methyl methacrylate–butadiene–styrene) blends 下载免费PDF全文
A series of methyl methacrylate‐butadiene‐styrene (MBS) core‐shell particles were synthesized by seeded emulsion polymerization. All the MBS particles are designed with the same defined chemical composition, which is a prerequisite for producing transparent blends with poly(vinyl chloride) (PVC). Three different growth manners of core‐shell particles: agglomeration of small styrene‐butadiene rubbers (SBRs) followed by styrene (ST) and methyl methacrylate (MMA) monomers grafting, agglomeration of small MBS particles and traditional MBS with single SBR rubber core, and ST/MMA shells are used. The effects of growth manners of MBS on the properties and deformation mechanism of PVC/MBS blends are studied. It is found that all the MBS particles can toughen the PVC matrix effectively, but different deformation modes are observed: cavitation in large particles, debonding at the PVC/MBS interface, rubber cavitation, and clusters of voids, respectively. In addition, it is found that the stress‐whitening extent is associated with the deformation modes. J. VINYL ADDIT. TECHNOL., 22:37–42, 2016. © 2014 Society of Plastics Engineers 相似文献
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