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This paper reports a study of the effects of molybdenum on tempered martensite embrittlement (TME) of medium carbon Si-Mn steels. The study employed standard U-notch impact tests, scanning electron fractography, transmission electron microscopy, Auger electron spectroscopy, and dilatometric measurements. It is shown that the addition of molybdenum to Si-Mn steels does not eliminate TME, but molybdenum acts to decrease the ductile-brittle transition temperature (DBTT), thus making the impact test temperature for revealing TME lowered. Furthermore, the deferring role of molybdenum on TME is observed. In the molybdenum doped steels the TME embrittlement trough is displaced to a higher tempering temperature. The embrittlement is found to be concurrent with the replacement of ?-carbide by cementite during tempering. In the molybdenum doped steels the displacement of TME to a higher tempering temperature is seen to be associated with the role of molybdenum retarding cementite precipitation. 相似文献
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The general corrosion behaviour of low residual steels alloyed with chromium or cobalt or molybdenum in seawater solutions was studied. The carbon content of low residual steels ranged from 0.1 to 0.4%, chromium content between 1.0 and 4.0%, cobalt content between 1.0 and 3.0%, and molybdenum content between 0.3 and 1.0%. Repeated laboratory tests demonstrated that low levels of chromium reduce the dissolution rate of low residual steels in seawater solutions. The results of this study suggest that cobalt alloying plays a neutral role, whereas molybdenum plays a major role in reducing the corrosion rates, particularly in higher carbon steels. 相似文献
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本研究用钨钼氧化物间接加入法生产高速钢的工艺。通过增加吨钢钨钼氧化物用量和降低对钨钼氧化物中硫,磷等有害元素的要求,扩大了钢种范围,并保证了钢的质量。 相似文献
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The fractures of three model alloys, imitating by their chemical composition the matrixes of the quenched high-speed steels of various Mo: W relations were analyzed. According to the measurements of the stress intensity factor KIc and the differences in the precipitation processes of carbides it was found out that the higher fracture toughness of the matrix of the molybdenum high-speed steels than on the tungsten ones is the results of the differences in the kinetics of precipitation from the martensite matrix of these steels during tempering. After tempering at 250 and 650°C the percentage of the intergranular fracture increases with the increase of the relation of Mo to W in the model alloys of the high-speed steel matrix. This is probably the result of higher precipitation rate of the M3C carbide (at 250°C) and the MC and M6C carbides (at 650°C) in the privileged regions along the grain boundaries. The change of the character of the model alloy fractures after tempering at 450°C from the completely transgranular one in the tungsten alloy to the nearly completely intergranular one in the molybdenum alloy indicates that the coherent precipitation processes responsible for the secondary hardness effect in the tungsten matrix begin at a lower temperature than in the molybdenum matrix. After tempering for the maximum secondary hardness the matrix fractures of the high-speed steels reveal a transgranular character regardless the relation of Mo to W. The higher fracture toughness of the Mo matrix can be the result of the start of the coherent precipitation processes at a higher temperature and their intensity which can, respectively, influence the size of these precipitations, their shape and the degree of dispersion. The transgranular character of the fractures of the S 6-5-2 type high-speed steel in the whole range tempering temperatures results from the presence of the undissolved carbides which while cracking in the region of stress concentration can constitute flaws of critical size which form the path of easy cracking through the grains. The transgranular cracking of the matrix of the real high-speed steels does not change the adventageous influence of molybdenum upon their fracture toughness. On the other hand, the carbides, undissolved during austenitizing, whose size distribution in the molybdenum steels from the point of view of cracking mechanics seems to be unsatisfactory, influence significantly the fracture toughness of these steels. 相似文献