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1.
Web of Science (wos) and scopus have often been compared with regard to user interface, countries, institutions, author sets, etc., but rarely employing a more systematic assessment of major research fields and national production. The aim of this study was to appraise the differences among major research fields in scopus and wos based on a standardized classification of fields and assessed for the case of an entire country (Slovenia). We analyzed all documents and citations received by authors who were actively engaged in research in Slovenia between 1996 and 2011 (50,000 unique documents by 10,000 researchers). Documents were tracked and linked to scopus and wos using complex algorithms in the Slovenian cobiss bibliographic system and sicris research system where the subject areas or research fields of all documents are harmonized by the Frascati/oecd classification, thus offsetting some major differences between wos and scopus in database-specific subject schemes as well as limitations of deriving data directly from databases. scopus leads over wos in indexed documents as well as citations in all research fields. This is especially evident in social sciences, humanities, and engineering & technology. The least citations per document were received in humanities and most citations in medical and natural sciences, which exhibit similar counts. Engineering & technology reveals only half the citations per document compared to the previous two fields. Agriculture is found in the middle. The established differences between databases and research fields provide the Slovenian research funding agency with additional criteria for a more balanced evaluation of research.  相似文献   

2.
New exact solutions for isotropic Kirchhoff plates, with no kinematic boundary constraints, are inferred by an analogy with the cross-section warping of orthotropic, homogeneous Saint-Venant beams bent and twisted by a shear force. The procedure is based on a formal equivalence between the elastic equilibrium conditions, respectively, for the tangential stresses in terms of a warping function in a Saint-Venant beam and for the bending–twisting moment in a Kirchhoff plate. The analysis refers to simply or multiply connected plates with an isotropic elastic stiffness proportional to the beams warping function. The result extends the one provided by the author for the special case of simple torsion (Barretta, Acta Mech 224(12):2955–2964, 2013). An example for a circular plate is developed, thus providing a new benchmark for computational mechanics.  相似文献   

3.
The theory of plasticity operates with different yield criteria of incompressible behavior for isotropic materials. Mostly known are the criteria of Tresca, Schmidt-Ishlinsky and von Mises. The first two criteria have a hexagonal symmetry, and the criterion of von Mises has a rotational symmetry in the π-plane. All these criteria do not distinguish between tension and compression (no strength differential effect), but numerous problems are treated in the engineering practice using these criteria. Within this paper, the yield criteria with hexagonal symmetry for isotropic incompressible materials are compared. For this purpose, their geometries in the π-plane will be presented in polar coordinates. The radii at the angles of 15? and 30? will be related to the radius at 0?. Based on these two relations, well-known criteria will be shown in one diagram. The extreme shapes of the yield surfaces are restricted by two criteria: the unified yield criterion (UYC) and the multiplicative ansatz criterion (MAC). The examinations of the UYC and MAC depict a linear combination of these extreme yield surfaces. The resulting criterion with two parameters describes all possible convex forms of hexagonal symmetry. On the other hand, this criterion has one disadvantage: It is not possible to solve explicitly the equation for the equivalent stress. Other known criteria (Sokolovsky, Ishlinsky-Ivlev, Dodd-Naruse, Drucker) are depicted in the proposed diagram and compared with the above mentioned criteria. Further criteria are derived from the consideration of solids with orthogonal symmetry planes in the shear stress space. New criteria are introduced for practical applications. The constraints of convexity are established for them. The proposed consideration of the yield criteria simplifies the selection of a proper criterion. The extreme solutions for the analysis of construction parts can be found using these criteria.  相似文献   

4.
5.
K R Padiyar  H S Y Sastry 《Sadhana》1993,18(5):787-799
Direct stability analysis ofAC/DC power systems using a structure-preserving energy function (SPEF) is proposed in this paper. The system model considered retains the load buses thereby enabling the representation of nonlinear voltage dependent loads. TheHVDC system is represented with the same degree of detail as is normally done in transient stability simulation. The converter controllers can be represented by simplified or detailed models. Two or multi-terminalDC systems can be considered. The stability analysis is illustrated with a 3-machine system example and encouraging results have been obtained.  相似文献   

6.
In this work, the functionalization of ZnS quantum dots using the thiol group of l-cysteine for different concentrations has been reported. Chemical precipitation method was used for the synthesis of nascent as well as l-cysteine functionalized ZnS quantum dots for optimized values of pH and molar concentrations of the precursors. Morphological studies were done by X-ray diffraction (XRD) and TEM. Optical measurements were done by UV–visible, Fourier transform infrared (FTIR) and energy resolved photoluminescence studies. Particle size was calculated by using Brus equation. Appreciable changes in morphological and optical properties of ZnS quantum dots were observed in few cases. XRD results shows that, the primary crystallite size decreases with increasing the capping concentration, however, the crystal structure remain same for all the used concentrations of l-cysteine. UV–visible analysis shows that band gap and particle size is also tunable with l-cysteine capping. FTIR studies confirmed l-cysteine capping on the surface of quantum dots. As l-cysteine is non toxic and stable compound, the surface modification of ZnS quantum dots with l-cysteine not only prevents the aggregation of quantum dots but also make them available for the interaction with the target materials and make them suitable for specific biomedical applications.  相似文献   

7.
Qualitative and quantitative analysis of molecular interaction prevailing in glycine, l-alanine, l-valine, and aqueous solution of ionic liquid (IL) [1-ethylpyridinium tetrafluoroborate ( \(\mathrm{EPyBF}_{4})\) ] have been investigated by thermophysical properties. The apparent molar volume ( \(\phi _{V}\) ), viscosity \(B\) -coefficient, molal refraction ( \(R_{\mathrm{M}}\) ), and adiabatic compressibility ( \(\phi _{ K} )\) of glycine, l-alanine, and l-valine have been studied in 0.001 mol \({\cdot }\, \mathrm{dm}^{-3}\) , 0.003 mol \({\cdot }\, \mathrm{dm}^{-3}\) , and 0.005 mol  \({\cdot } \,\mathrm{dm}^{-3}\) aqueous 1-ethylpyridinium tetrafluoroborate [ \(\mathrm{EPyBF}_{4}\) ] solutions at 298.15 K from the values of densities \((\rho )\) , viscosities ( \(\eta \) ), refractive index ( \(n_{\mathrm{D}})\) , and speed of sound \((u)\) , respectively. The extent of interaction, i.e., the solute–solvent interaction is expressed in terms of the limiting apparent molar volume ( \(\phi _{V}^0 )\) , viscosity \(B\) -coefficient, and limiting apparent molar adiabatic compressibility ( \(\phi _{K}^0)\) . The limiting apparent molar volumes ( \(\phi _{V}^0 )\) , experimental slopes ( \(S_{V}^*)\) derived from the Masson equation, and viscosity \(A\) - and \(B\) -coefficients using the Jones–Dole equation have been interpreted in terms of ion–ion and ion–solvent interactions, respectively. Molal refractions ( \(R_{\mathrm{M}})\) have been calculated with the help of the Lorentz–Lorenz equation. The role of the solvent (aqueous IL solution) and the contribution of solute–solute and solute–solvent interactions to the solution complexes have also been analyzed through the derived properties.  相似文献   

8.
9.
lpcvd polycrystalline silicon films were deposited on thermally oxidized silicon as well as onlpcvd silicon nitride deposited on silicon. Acw argon ion laser was used to recrystallize the polysilicon film into large grains (grain size from 5μm to 40μm). Boron was then implanted and standard N-channel silicon gate process and N-channel metal gate process were carried out to realisemosfets on this material. Channel mobilities upto 450 cm2/V-sec for electrons have been measured. This thin filmmosfet has a four-terminal structure with a top and a bottom gate and the influence of one gate on the drain current due to the other gate has been investigated. Comparison of theI D v-V D curves of the devices with physical models was found in good agreement.  相似文献   

10.
This paper reports a facile l-cysteine-assisted solvothermal synthesis of TiO2 nanomaterials using ethylenediamine (En) and distilled water as solvent. The influence of reaction time, temperature, l-cysteine and solvent was initially investigated. Results demonstrated the reaction temperature, l-cysteine and En significantly imposed impact on the phase and morphology of the particles. Amorphous nanosheets, mixed-crystal nanorods and pure anatase nanoparticles were controllably synthesized by varying reaction temperature. The formation of the amorphous nanosheets and mixed-crystal nanorods were directly affected by the presence of l-cysteine and En. And the presence of En distinctly affected the crystal phase of the products, which was rarely mentioned in other studies. Moreover, the photocatalytic activities of three typical samples were excellent. The possible formation mechanism of the sample was also discussed.  相似文献   

11.
12.
Polyurethanes are very often used in the cardiovascular field due to their tunable physicochemical properties and acceptable hemocompatibility although they suffer from poor endothelialization. With this in mind, we proposed the synthesis of a family of degradable segmented poly(urea)urethanes (SPUUs) using amino acids (l-arginine, glycine and l-aspartic acid) as chain extenders. These polymers degraded slowly in PBS (pH 7.4) after 24 weeks via a gradual decrease in molecular weight. In contrast, accelerated degradation showed higher mass loss under acidic, alkaline and oxidative media. MTT tests on polyurethanes with l-arginine as chain extenders showed no adverse effect on the metabolism of human umbilical vein endothelial cells (HUVECs) indicating the leachables did not provoke any toxic responses. In addition, SPUUs containing l-arginine promoted higher levels of HUVECs adhesion, spreading and viability after 7 days compared to the commonly used Tecoflex® polyurethane. The biodegradability and HUVEC proliferation on l-arginine-based SPUUs suggests that they can be used in the design of vascular grafts for tissue engineering.  相似文献   

13.
The Optimization Test Environment is an interface to efficiently test different optimization solvers. It is designed as a tool for both developers of solver software and practitioners who just look for the best solver for their specific problem class. It enables users to:
  • Choose and compare diverse solver routines;
  • Organize and solve large test problem sets;
  • Select interactively subsets of test problem sets;
  • Perform a statistical analysis of the results, automatically produced as , PDF, and JPG output.
  • The Optimization Test Environment is free to use for research purposes.  相似文献   

    14.
    At the moment scanning transmission electron microscopy (stem) instruments are not competetive with conventionaltem instruments for high resolution bright field imaging. For studies of the structure and defects of crystalline materials, their special virtues lie in the application of dark field imaging modes combined with observations of microdiffraction patterns from regions of diameter comparable with the microscope resolution limit (currently about 5 Å). They also offer capabilities for microanalysis by use of energy dispersive x-ray spectroscopy (eds) or electron energy loss spectroscopy (els). In principle the spatial resolution of these microanalysis methods is comparable to that of the imaging modes but in practice it is limited by poor signal-to-noise ratios or by the nonlocalized nature of the inelastic scattering process. The capabilities for microdiffraction are illustrated by sequences of diffraction patterns obtained as the incident beam is moved within the unit cell of a crystal of large (20 Å) periodicity. Applications of more immediate practical significance include diffraction studies of small crystallites of gold 20 to 50 Å in diameter and of the near-amorphous, thin oxide layers formed on chromium and iron films at room temperature. Microdiffraction, combined with reflection electron microscopy andels analysis, provides a powerful new approach to the study of the surface structure of crystals, including bulk samples, and the investigation of surface reactions. In particular, if a beam of small diameter (10–20 Å) is made to run along the face of a small crystal, the diffraction pattern andels curves are very sensitive to the form of the potential distribution at the surface and the excitations of the surface states of the crystal.  相似文献   

    15.
    Developments in dynamical systems theory provide new support for the macroscale modelling of pdes and other microscale systems such as lattice Boltzmann, Monte Carlo or molecular dynamics simulators. By systematically resolving subgrid microscale dynamics the dynamical systems approach constructs accurate closures of macroscale discretisations of the microscale system. Here we specifically explore reaction–diffusion problems in two spatial dimensions as a prototype of generic systems in multiple dimensions. Our approach unifies into one the discrete modelling of systems governed by known pdes and the ‘equation-free’ macroscale modelling of microscale simulators efficiently executing only on small patches of the spatial domain. Centre manifold theory ensures that a closed model exists on the macroscale grid, is emergent, and is systematically approximated. Dividing space into either overlapping finite elements or spatially separated small patches, the specially crafted inter-element/patch coupling also ensures that the constructed discretisations are consistent with the microscale system/pde to as high an order as desired. Computer algebra handles the considerable algebraic details, as seen in the specific application to the Ginzburg–Landau pde. However, higher-order models in multiple dimensions require a mixed numerical and algebraic approach that is also developed. The modelling here may be straightforwardly adapted to a wide class of reaction–diffusion pdes and lattice equations in multiple space dimensions. When applied to patches of microscopic simulations our coupling conditions promise efficient macroscale simulation.  相似文献   

    16.
    Chitosan/poly(dl-lactide-co-glycolide) (Ch/dl PLG) composite scaffolds were fabricated by freeze-drying lyophilization, and were evaluated and compared for use as a bone regeneration scaffold through measurements of the compression mechanical properties of the porous scaffolds. Also, In vitro cell culture of Sprague?CDawley rat??s osteoblasts were used to evaluate the phenotype expression of cells in the scaffolds, characterizing the cellular adhesion, proliferation and alkaline phosphatase activity. The gene expression of osteocalcin, sialoprotein, alkaline phosphatase, Type I collagen and TGF??1 were confirmed in the samples; moreover, it was confirmed, the mineralization by IR spectra and EDS analysis. Our results thus show that Ch/dl PLG scaffolds are suitable for biological applications.  相似文献   

    17.
    P. R. Pisharoty 《Sadhana》1983,6(2):97-107
    Remote sensing consists of gathering information about objects and features without placing instruments in contact with them. The sensors are placed on aircraft or spacecraft platforms and the earth’s surface surveyed for its natural resources. Electromagnetic radiation (emr) in the visible, infrared and microwave bands are employed, mostly solar radiation or natural emissions. The interactions ofemr with the objects are impressed as “signatures” on the reflected, scattered, transmitted or emittedemr. The sensors employed are (i) cameras with normal or special films sensitive to infrared, (ii) electro-optical systems in the scanning mode using solid state detectors, (iii) imaging tubes and devices and (iv) microwave systems which can gather data even when clouds intervene. The data gathered with the sophisticated systems are converted into imagery or directly processed on electronic computers. The processed data are then interpreted in terms of known ground truths or ‘emr signatures’ of the objects. Remote sensing has wide applications in agriculture, forestry, geology, hydrology cartography and oceanography.  相似文献   

    18.
    Biodegradable polymer networks were prepared by photo-initiated radical polymerization of methacrylate functionalized poly(d,l-lactide) oligomers. The kinetic chains formed in this radical polymerization are the multifunctional crosslinks of the networks. These chains are carbon–carbon chains that remain after degradation. If their molecular weight is too high these poly(methacrylic acid) chains can not be excreted by the kidneys. The effect of the photo-initiator concentration and the addition of 2-mercaptoethanol as a chain transfer agent on the molecular weight of the kinetic chains was investigated. It was found that both increasing the initiator concentration and adding 2-mercaptoethanol decrease the kinetic chain length. However, the effect of adding 2-mercaptoethanol was much larger. Some network properties such as the glass transition temperature and the swelling ratio in acetone are affected when the kinetic chain length is decreased.  相似文献   

    19.
    Assembly line balancing problems (ALBP) consist of distributing the total workload for manufacturing any unit of the products to be assembled among the work stations along a manufacturing line as used in the automotive or the electronics industries. Usually, theory assumes that, within each station, tasks can be executed in an arbitrary precedence-feasible sequence without changing station times. In practice, however, the task sequence may influence the station time considerably as sequence-dependent setups (e.g., walking distances, tool changes) have to be considered. Including this aspect leads to a joint balancing and scheduling problem, which we call SUALBSP (setup assembly line balancing and scheduling problem). In this paper, we modify the problem by modeling setups more realistically, give a new, more compact mathematical model formulation and develop effective heuristic solution procedures. Computational experiments based on existing and new data sets indicate that the new procedures outperform formerly proposed heuristics. They are able to solve problem instances of real-world size with small deviations from optimality in computation times short enough to be accepted in real-world decision support systems.  相似文献   

    20.
    This investigation addresses the morphological, mechanical, and antibacterial evaluation of nanocomposite mats based on poly(d,l-lactide) nanofibers with different zinc oxide nanoparticles (nano-ZnO) concentration, that were elaborated by two techniques, i.e., electrospinning of polymer/ZnO solutions and the combination of electrospinning of polymer solutions with electrospraying of nano-ZnO dispersions. The analysis of the precursory solutions was carried out in order to understand the achieved morphology of nanofibers. The obtained poly(d,l-lactide)/ZnO fibrous mats showed a uniform morphology with an average porosity ca. 55 % and average pore size around 45 μm. The presence of ZnO nanoparticles increased the toughness of the mats, and an optimal nano-ZnO concentration (i.e., 3 wt%) was observed at which the tensile strength and Young’s modulus could be improved. Concerning to the antibacterial properties, a relatively low concentration of nanoparticles provoked a growth inhibition of the Gram-negative Escherichia coli and the Gram-positive Staphylococcus aureus bacteria. The mats have potential features for use as antimicrobial wound dressings.  相似文献   

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