固溶处理对Mg-8Al-1Zn-1Si-0.6Sb合金组织与力学性能的影响

采用重力铸造法制备Mg-8Al-1Zn-1Si-0.6Sb合金,研究了固溶处理对该合金组织及力学性能的影响。结果表明,铸态合金主要由α-Mg、β-Mg_(17)Al_(12)、Mg_2Si、Mg Zn和Mg_3Sb_2相组成。对合金进行430℃×(8～32) h固溶处理,随保温的时间延长,Mg Zn相和β-Mg_(17)Al_(12)相固溶于α-Mg基体;粗大汉字状Mg_2Si相发生球状化;与此同时,合金的室温及高温(150℃)抗拉强度、屈服强度和伸长率逐步提高,硬度逐渐下降。铸态与固溶处理态合金的拉伸断裂形式均呈准解理脆性断裂。     

固溶处理对铸态Mg-4Al-2Si合金组织和性能的影响

研究了固溶处理对铸态Mg-4Al-2Si(AS42)合金组织和性能的影响.结果表明,铸态与热处理态合金均由α-Mg基体、β-Mg17Al12相和Mg2Si相3部分组成.固溶处理使合金中的β-Mg17Al12相发生部分溶解,汉字状Mg2Si相颗粒出现球状化,合金的力学性能有较大幅度的提高.铸态与热处理态合金的断裂形式均为准解理脆性断裂.     

热处理对Mg-7Al-1Si-1Gd合金组织及硬度的影响

在不同的T4和T6热处理条件下,对Mg-7Al-1Si-1Gd合金的组织和硬度进行了研究。结果表明,T4(400℃×12h)固溶处理后β-Mg17Al12相几乎全部溶入α-Mg基体中,但Al2Gd相和汉字状Mg2Si相形貌几乎没有发生变化,因而合金的硬度变化很小。经400℃×12h+200℃×10h的T6处理后,β-Mg17Al12相沿晶界沉淀析出,呈层片状不连续分布,Mg2Si相由粗大汉字状变为细小的块状或棒状,合金硬度达到峰值,较铸态提高了12.45%。     

Al含量对Mg-xAl-1Zn-1Si合金组织与力学性能的影响

研究了Al含量对Mg-x Al-1Zn-1Si(x=4,6,8,wt%)合金显微组织和力学性能的影响。结果表明,合金主要由α-Mg、β-Mg17Al12和Mg2Si相组成。随着Al含量的增加,α-Mg基体晶粒尺寸先减小后增大;呈网状分布于晶界上的Mg17Al12相的体积分数逐渐增大;Mg2Si相由原来粗大的汉字状逐渐转变为相对细小的杆状。Al含量从4%增加到6%和8%时,α-Mg基体晶粒的平均尺寸分别为30、20和40μm,合金硬度逐渐提高;其室温与150℃抗拉强度、屈服强度和伸长率先升高后下降;合金拉伸断裂形式为准解理脆性断裂。     

流变压铸AM60镁合金在固溶处理过程中的组织演变

采用光学显微镜(0M)、扫描电镜(SEM),研究了固溶处理对流变压铸AM60镁合金组织及硬度的影响.结果表明,流变压铸成形的AM60镁合金在430 ℃固溶处理24 h后,AM60镁合金晶界及枝晶间的粗大网状β-Mg17Al12相几乎全部消除,只剩少量、不连续状的β-Mg17Al12相残留在晶界,α-Mg基体中出现少量细小颗粒状β-Mg17Al12相,α-Mg基体中的A1含量显著增加.而且,随着固溶时间的延长,流变压铸成形AM60镁合金组织中的初生颗粒与二次凝固区颗粒出现合并长大现象,它们的长大速率都随固溶时间的延长而降低,随固溶温度的升高而增大.     

固溶处理对AZ81-xSr合金组织及力学性能的影响

研究了固溶处理对AZ81-xSr(x=0.9、1.8、2.7)镁合金铸态组织及力学性能的影响。结果表明,该合金被固溶处理后,合金组织中的β-Mg17Al12相几乎全部溶于α-Mg基体中,而Sr5Al9相未见溶解。固溶处理使热稳定的Sr5Al9相由骨骼状向层片状和颗粒状转变。并且,固溶处理后,该合金的高温力学性能和硬度得到明显提高。     

Sr对Sb变质Mg-5Sn-1.5Al-1Zn-1Si合金组织的影响

用重力铸造法制备Sb及Sr+Sb联合变质Mg-5Sn-1.5Al-1Zn-1Si合金,再进行不同的固溶处理,研究Sr对Sb变质Mg-5Sn-1.5Al-1Zn-1Si合金组织的影响。结果表明:Sb和Sr+Sb联合变质均可以使初生Mg_2Si和Mg_2(Si,Sn)颗粒发生不同程度的球化,而Sr+Sb联合变质比Sb单变质具有更好的细化和球化效果;Sr+Sb联合变质后,共晶Mg_2Si和Mg_2(Si,Sn)相由汉字状变为细小近似球形或多边形颗粒状;Sb变质Mg-5Sn-1.5Al-1Zn-1Si合金在较低固溶温度和较短保温时间下即可使大部分Mg17Al12相和部分Mg_2Sn相固溶到基体中,而Sr+Sb联合变质合金组织中,Mg_(17)Al_(12)和Mg_2Sn依然清晰可见,未完全溶解的Mg_(17)Al_(12)相发生球化,均匀的分散在基体中;Sr+Sb联合变质Mg-5Sn-1.5Al-1Zn-1Si合金固溶温度要比Sb单变质时略高一些,但对固溶时间的影响并不明显。     

纳米SiC颗粒对Mg9Al-1Si合金组织及力学性能的影响

研究了纳米Si C颗粒对Mg9Al-1%Si(以下记作Mg9Al-1Si)合金显微组织和力学性能的影响。研究结果表明:Mg9Al-1Si合金组织由α-Mg基体、网状β-Mg17Al12相及粗大汉字状或细长鱼骨状两种形态的Mg2Si相组成。加入质量分数为1%的纳米Si C颗粒,Mg9Al-1Si合金的α-Mg基体晶粒明显细化;β-Mg17Al12相变细变小,网状分布改善不大;粗大汉字状Mg2Si相消失,鱼骨状的Mg2Si相变得更加细小。合金的力学性能得到显著提高,屈服强度提高了13.5%;抗拉强度提高了54%;伸长率由0.48%提高到1.56%,提高了225%.     

铸态Mg-Li-Al-xSi合金微观组织和力学性能（英文）

实验铸造了Mg-9Li-3Al-x Si(x=0,0.1,0.5,1.0,质量分数,%)合金并通过OM,SEM,XRD和力学性能测试对其进行了研究。结果表明:铸态Mg-9Li-3Al合金组织中主要由α-Mg、β-Li、Mg_(17)Al_(12)相组成。加入Si后,合金中出现了新相Mg2Si,晶粒得到了明显细化,且Si能够抑制Mg_(17)Al_(12)的形成;当合金中的Si含量过高时,α-Mg相粗化,且会在相界处出现块状和汉字状的Mg_2Si相。合金的强度随着Si含量的增加呈现先增加后降低的趋势,合金的延伸率随着Si含量的增加呈现逐渐降低的趋势。当合金中Si含量为0.1%时,抗拉强度达到最大值182.5 MPa,延伸率为12.1%。     

Mg-6Al-1Zn-xSi合金的显微组织与高温力学性能

采用重力铸造法制备了不同Si含量的Mg-6Al-1Zn-x Si合金,分析了合金的显微组织,测试了合金在150℃下的拉伸力学性能。结果表明,合金均由α-Mg基体、β-Mg17Al12和Mg2Si相组成。随着Si含量的增加,α-Mg基体晶粒的平均尺寸逐渐减小,Mg2Si颗粒的平均尺寸逐渐增大;β-Mg17Al12由分布于晶界及晶内的点状转变为网状分布于晶界上;合金的高温抗拉强度、屈服强度和伸长率逐渐提高。此外,高温拉伸断裂形式为准解理脆性断裂。     

Electrical conductivity of 1 : 1 and 2 : 1 clay minerals

The A.C. impedance plots were used as tools to analyze the electrical response of two varieties of Tunisian halloysite 1: 1 and illitic samples 2: 1 as a function of frequency at different temperatures (80–800°C). The real and imaginary parts of the complex impedance trace semicircles in the complex plane. Except for the illite, It-1, the second sample analyzed in this study, these plots give evidence for the presence of both bulk and grain boundary effect, above 600°C onwards. The bulk resistance of the materials decreases with the rise in temperature. Impedance Spectroscopy data reveal a non-Debye type of dielectric relaxation. The Nyquist plots show the negative temperature coefficient of resistance of both pure Tunisian illite and halloysite samples. The results of bulk electrical conductivity and its activation energy are presented for the two mineral clay samples. For illite It-1, the activation energy values estimated from the AC conductivity pattern and modulus pattern are very similar and suggest a possibility of a long-range mobility of charge carriers (ions) via hopping mechanism of electrical transport processes at higher temperature. On the other hand, for the halloysite sample provided from kasserine, (Ha-Kass), the modulus analysis admit that the electrical transport processes of the material are very likely of electronic nature. Relaxation frequencies follow an Arrhenius behavior with the activation energy values not comparable to those found for the electrical conductivity.     

20Cr1Mo1V1钢的分级时效工艺研究

研究了 2 0Cr1Mo1V1钢的强韧化工艺。所优化出的分级时效工艺能使其强度和韧性达到质保书的要求。     

Stabilization of extended stacking faults by {1 1 1}/{1 1 2} twin junction interactions

Extended stacking faults, with lengths of up to 10 nm, that join {1 1 1}/{1 1 2} twin-boundary junctions were observed by high-resolution transmission electron microscopy (HRTEM) in gold thin films. Circuit analysis shows that these defects possess a Burgers vector of 1/3〈1 1 1〉. In order to explain the generation of these extended defects, we consider the behavior of 1/3〈1 1 1〉 dislocations at {1 1 1}- and {1 1 2}-type twin boundaries and near {1 1 1}/{1 1 2} twin-boundary junctions using HRTEM observations and theoretical modeling. By establishing the interaction forces that lead to this defect configuration, our analysis shows that the relief of intrinsic strain at the junction corners, which results from the incompatibility of the translation states at the intersecting boundaries, is sufficient to stabilize the stacking fault extension. Because grain–boundary junctions possess intrinsic strain fields whenever they join boundaries with incompatible translation states, similar mechanisms for stacking fault emission may arise between other closely spaced grain–boundary junctions.     

A contribution to the crystallochemistry of ternary 1:1:1 and 1:1:2 rare earth intermetallic phases with Pb and Pd

The ternary alloys of the rare earths with lead and palladium were studied for the stoichiometric ratios 1:1:1 and 1:1:2 with respect to the structure of these alloys and their existence field. RPbPd (R = La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Y, Ho, Er, Tm, Yb) compounds have a hexagonal structure, hP9 Fe₂P type, while RPbPd₂ (R = Pr, Sm, Gd, Tb, Dy, Ho, Er, Yb) alloys have the cubic AlCu₂Mn-type structure (cF16, BiF₃ superstructure).     

Variability in Co2 Oxidation Resistance of 2 1/4 Cr 1 Mo and 1 Cr 1/2 Mo Steels

Abstract

Oxidation tests in CO₂ atmospheres on nominally identical casts of low alloy steels have revealed wide variation in oxidation resistance. A study has been made of the influence of chemical composition, mechanical and thermal treatment, and remelting on the CO₂ oxidation behaviour of steels of the 21/4 Cr 1 Mo and 1 Cr 1/2 Mo type.

Statistical analyses of CO₂ oxidation results have shown a strong positive correlation of oxidation rate with sulphur content in certain instances, but a number of anomalies have been found. A similar relationship has been obtained between ‘MnS’ content and oxidation rate by area count studies of the inclusions in a range of 2 1/4 Cr 1 Mo steels. These have also indicated a possible effect of ‘MnS’ particle size and particle size distribution which could account for some of the anomalous results obtained in the statistical work. Conventional solid state heat treatments appear to have no significant effect on the oxidation behaviour of 2 1/2 Cr 1 Mo and while remelting in argon did not generally improve oxidation behaviour, remelting in vacuo followed by forging and rolling resulted in a material of high oxidation resistance.     

有机阴离子转运多肽1B1的遗传药理学进展

人体存在多种类型的药物转运体,对于药物的吸收、分布和排泄起重要作用。参与药物跨膜转运的转运体功能受影响,将可能导致诸多临床药物的疗效、毒副作用甚至药物相互作用的发生。在各种影响因素中,遗传多态性所起的作用最为重要,可导致基因表达和蛋白功能发生改变。目前,阐明转运体基因的多态性以及基因型与表型之间的相互关系已成为应用遗传信息指导临床个体化用药的必要步骤。本文就肝脏有机阴离子转运多肽1B1(OATP1B1[OATP-C],编码基因SLCO1B1)基因多态性对药代动力学和药效动力学的影响及其临床意义等方面的进展作一综述。     

1Cr12Ni2W1Mo1V钢等离子淬火后的疲劳行为

采用模拟点蚀坑试样,研究了等离子淬火不同温度回火1Cr12Ni2W1Mo1V钢疲劳裂纹萌生和扩展行为.结果表明,由于等离子淬火的晶粒细化作用和在试样表面引入的残余压应力,提高了末级叶片用钢裂纹萌生抗力.比较两种回火温度试样试验结果,250 ℃回火试样裂纹萌生和扩展抗力均优于540 ℃回火试样.本研究结果为选择合适的热处理工艺提供了理论依据.