频率对VHB4910介电弹性体材料介电性能的影响

介电弹性材料是一种新型的电活性聚合物,在电激励下能产生较大的机械变形,可被广泛的用作致动器和传感器.其中3M公司的VHB4910系列丙烯酸薄膜是研究最广泛的介电弹性材料,其关键的电学参数,特别是介电常数,将影响整体的机电耦合性能.然而到目前为止,人们对于VHB4910介电材料介电常数取值的认识尚不统一,特别是频率对介电...     

电场活化丙烯酸弹性体的失效特性研究

研究介电场活化丙烯酸弹性体材料的失效特性,分析其失效机理.以实验为主要手段,分析失效形式与其主要影响因素之间的关系.实验表明:起皱、放电和击穿崩溃是电场活化丙烯酸弹性体材料的主要失效形式.预拉伸量、激活区与窗口半径比以及电极材料对起皱和击穿崩溃有明显的影响,其中电极材料对电场活化丙烯酸弹性体材料起皱失效的影响最为明显....     

磁流变弹性体剪切式动态力学性能测试

磁流变弹性体（MRE）是磁流变材料中新的一员,研究磁流变弹性体材料,其动态力学性能的探究是研究的重要组成部分,建立一套磁流变弹性体动态力学性能测试系统是需亟待解决的问题。设计了一种磁流变弹性体剪切式动态力学性能测试装置,由电磁振动台提供稳定的正弦激励,通过可调间距的钕铁硼永磁体产生可变的磁场,利用安装在测试系统中的力与加速度传感器,获取磁流变弹性体在往复剪切运动中的剪切力与加速度信号,其中加速度信号经两次数值积分获得位移数据,通过力与位移数据建立磁流变弹性体在动态剪切模式下的应力-应变关系,结合粘弹性材料理论模型,得到磁流变弹性体在剪切模式下的磁控动态力学性能参数。为研制高性能的磁流变弹性体提供了评价体系。     

磁流变弹性体压缩模式动态力学性能测试

磁流变弹性体是一种新型的磁流变材料,已被成功地应用于变刚度器件设计中。为了评价磁流变弹性体材料性能,迫切需要建立一套磁流变弹性体性能测试系统。利用电磁振动台的线性扫频功能,采用激光位移传感器同步获取测试系统在不同磁感应强度下测试系统的激励与响应信号,通过系统的运动力学模型和相关理论计算,实现压缩模式下的磁流变弹性体刚度与阻尼性能的测试。该测试系统的建立为研制高性能的磁流变弹性体提供了动态压缩模式下的评价手段。     

Applicability of elastomer time-dependent behavior in dynamic mechanical damping systems

Dynamic thermomechanical analysis (DTMA) of unfilled as well as particle-filled poly(dimethylsiloxane) and poly(norbornene) was performed to compare their behavior as dampers. PDMS and PNB were filled with varying contents of spherical iron particles (aspect ratio of 1) and also different hardness formulations of the materials were characterized. The wicket-plot (tanδ vs. storage modulus) was considered therefore and all frequency- and temperature-dependent results were presented. Linear dependencies were observed for PDMS, even though the material did not reveal thermorheologically simple behavior. However, tanδ of PNB was a unique function of its storage modulus and so the material exhibited thermorheologically simple behavior. A linear shift factor over frequency–temperature and frequency–internal pressure (Fe-content) was found for PDMS. Master curves of PNB were constructed and reasonable results were achieved, which were due to their thermorheologically simple material behavior.     

聚烯烃弹性体在CPP薄膜上的应用研究简

选用具有代表性的聚烯烃弹性体牌号,研究不同类型、不同型号聚烯烃弹性体对CPP薄膜透明度、韧性及热封性能的影响,结果表明不管是何种聚烯烃弹性体,都可以降低CPP薄膜的雾度,乙烯基弹性体DF740及丙烯基弹性体868适合于CPP薄膜增韧改性,丙烯基弹性体3980FL则适合热封改性。     

淀粉/明胶/甘油含水电流变胶体的电场响应行为

将天然高分子淀粉颗粒分散到明胶／甘油含水体系中．在无、有电场作用的条件下分别胶凝得到了两种含水电流变弹性胶体．从分散介质和分散相两方面对含水电流变胶体进行了改善．使胶体的弹性和柔韧性以及颗粒的分散程度都明显提高。通过对弹性胶体压缩模量的测试和胶凝过程中电阻的动态监测,研究了胶体体系对电场的响应行为。结果表明两种电流变胶体对电场的响应程度有明显不同．它们的力学性能可受电场调控。而且体系在两种务件下胶凝时电阻变化也有较大的差异。分析认为由于电场作用使颗粒有序分布于母体的胶联网络中。并形成链状结构．导致胶体对电场作用的响应程度增大．压缩模量增强,以及胶体体系的电阻值增大。     

聚酰胺类热塑性弹性体的合成与发展现状

聚酰胺类热塑性弹性体 (TPAE)是一种新型热塑性弹性体 ,具有突出的性能优势 ,其合成方法主要有二元酸法和异氰酸酯法 ,应用领域广泛 ,有着良好的发展前景。     

热塑性弹性体材料的研究进展与市场前景

本文综述了热塑性弹性体 (TPE)材料的发展 ,共混型TPE的动态硫化技术及制备TPE的技术条件 ,评述并展望了其发展态势与方向     

八氨苯基POSS交联改性聚氨酯弹性体的制备与性能

以八氨苯基多面体低聚倍半硅氧烷(OapPOSS)为交链剂,原位合成了含有POSS结构的聚氨酯弹性体纳米复合材料,分别采用FT-IR、光学显微镜,动态热机械(DMA)分析以及热重分析(TGA)等对所合成的复合材料进行了表征。结果表明:随着OapPOSS用量的增加,所制POSS/PUE复合材料的拉伸强度增加,扯断伸长率下降,储能模量增加,阻尼因子下降,玻璃化转变温度升高,热分解速率降低。     

微孔聚氨酯弹性体耐候性的研究

考察了各种紫外光吸收剂和抗氧剂对微孔聚氨酯弹性体材料抗强日光照射后性能的影响,实验结果表明,紫外光吸收剂和抗氧剂的合理使用能有效提高微孔聚氨酯弹性体材料对光的稳定性,并使其物理机械性能具有较好的保持率.     

Rate-dependent mechanical properties of cured conductive adhesives and drop impact behavior of adhesive bonding points in electronic interconnection

Journal of Materials Science: Materials in Electronics - Given the boom of portable electronic products and the increasing risk of drop impact load in electronic interconnection points, the...     

Strain-rate effects on the mechanical behavior of the AISI 300 series of austenitic stainless steel under cryogenic environments

A series of uni-axial tensile tests were carried out under various low temperatures and strain-rate ranges for AISI 300 austenitic stainless steel. The strain-rate dependencies of the materials under investigation were evaluated at temperatures ranging from ambient to cryogenic. Non-linear mechanical behavior such as phase transformation, discontinuous yielding and micro-damage of four kinds of commercial stainless steel-based material were quantitatively investigated by measuring transformation induced plasticity (TRIP) and threshold strain for 2nd hardening. In this study, the main properties of each material were analyzed and compared based on the conditions of strain-rates and temperature. Test results showed that all the test materials were strongly dependent on temperature and strain rate. It is expected that the findings in this study could be used for the cryogenic design and further research of structure materials under cryogenic environments.     

聚氨酯/环氧树脂弹性体声学性能仿真

基于声学边界条件,建立了聚氨酯/环氧树脂(PU/EP)弹性体的水声模型,探讨了弹性体弹性模量、损耗因子及泊松比对其声学性能的影响;在水声脉冲声管中测试了PU/EP的水声性能并进行了算例验证。仿真结果表明,较大的模量、合适的阻尼因子和较高的泊松比是PU/EP弹性体获得低反射、高吸声性能的关键。水声测试结果表明,PU/EP(70/30)弹性体的平均吸声系数为0.39,最大吸声系数为0.42,且反射系数在整个频段范围内小于0.4,可作为水声吸声材料的基材。算例验证表明,计算结果与实验测量结果吻合的较好。     

基于链化分析的磁流变弹性体剪切模量模型

磁流变弹性体是一种磁流变材料,由高分子橡胶基体掺杂微米级的铁磁性颗粒固化而成.基于磁性物理学理论,从磁流变弹性体在磁场作用下铁磁性固体颗粒极化成链的微观结构出发,探讨磁流变流体中固体颗粒间的相互作用机理,分析研究颗粒间的相互作用力,建立了一种微观力学模型,可用于分析磁流变流体在外加磁场作用下剪切模量及其影响因素的作用效果,揭示磁流变效应的微结构机理,为磁流变弹性体的性能优化、工程开发及应用提供理论依据.     

基于链化模型的磁流变弹性体磁致效应影响因素分析

磁流变弹性体是磁流变材料中新的一员,它是由可磁化的铁磁性颗粒和橡胶基在外加磁场下固化而成的,固化后铁磁性颗粒在基体中形成链状等有序结构,因此其力学、电学、磁学等性质可由外加磁场控制.目前限制磁流变弹性体的大规模应用的一个重要因素是其磁致效应还不能够满足工程需要,制备出具有更大磁致效应的磁流变弹性体材料是当前的紧迫任务之一.在磁流变弹性体链化模型的基础上,引入斜链夹角的正态分布,采用偶极子法从理论上分析了诸多因素对磁流变弹性体磁致效应的影响,包括颗粒链的初始倾斜角、外加磁场强度、剪应变大小等,为材料的制备和性能的优化提供理论上的帮助.     

丙烯基弹性体在CPP薄膜中的改性应用研究

介绍了CPP薄膜应用丙烯基弹性体改性的研究,并对照了传统塑料薄膜与改性后的薄膜在主要物理机械性能上的差别,以确认新材料应用的可行性与可靠性。     

Morphology, mechanical and thermal behavior of acrylate rubber/fluorocarbon elastomer/polyacrylate blends

Novel thermoplastic elastomers derived from binary and ternary blends of polyfunctional acrylates, acrylic rubber (ACM) and fluorocarbon rubber (FKM) were analyzed by using Transmission Electron Microscopy (TEM), Differential Scanning Calorimetry (DSC), Dynamic Mechanical Thermal Analysis (DMTA) and mechanical tests. TEM revealed the presence of a single-phase structure for both acrylate rubber/fluorocarbon elastomer (ACM/FKM) and ACM/polyacrylate binary blends. Increase of FKM concentration in the ACM/FKM/polyacrylate ternary blend resulted in phase separation of FKM from the ternary blend. The FKM formed a dispersed phase with polynodal particle distribution and irregular shape ranging from ellipsoidal to highly elongated form with inclusion of ACM. The FKM/polyacrylate binary blend showed complete phase separation. Ageing of the blend increased the domain size of the dispersed phase. Differential scanning calorimetric (DSC) and DMTA studies showed no major changes in the T _gs of individual polymers in the blend, although the peak tan values were affected on changing the composition of the blends. Vulcanization of the thermoplastic elastomer (TPE) changed the phase morphology with increase in particle size. There is a distinct difference in morphology of statically and dynamically vulcanized blends.     

Dynamics of a thick-walled dielectric elastomer spherical shell

The nonlinear vibration response of a thick-walled spherical shell subjected to the mechanical pressure and electric field is studied in this paper. When subject to an electric field through the thickness of the spherical shell, the material expands in plane and contracts in thickness. The dielectric elastomer is assumed to be isotropic and neo-Hookean. Based on simple geometrical and spherical capacitor assumptions, we deduce an explicit analytical equation of motion of the dielectric elastomer spherical shell. The dynamic behaviors of the spherical shell under a constant electric loading and periodic electric loading are analyzed. In addition, the critical voltage is calculated in terms of various loading.     

磁场对磁流变弹性体表面特性的影响

为探究磁流变弹性体在磁场作用下的表面特性,制备体积分数为5%,10%,15%,20%,25%和30%的磁流变弹性体(MRE)样本,分别在施加磁场前后进行金相显微镜、白光干涉仪表面观察实验以及滑动摩擦验证实验。表面观察实验表明:样本的表面磁性颗粒随组分体积分数的增加而增加,并且各组分样本表面在磁场下粗糙度均降低,5%MRE的样本降低最多,约20%;摩擦实验结果表明:摩擦因数随着体积分数增加和在磁场作用下均出现降低趋势,30%MRE的摩擦因数相比于5%的摩擦因数约减小了38%, MRE表面铁磁颗粒含量是影响其摩擦特性的主要因素。