Light concentrators for the Sudbury Neutrino Observatory

There is an important and growing class of elementary particle detectors which are characterized by a large sensitive volume (thousands of tonnes), very low radioactive backgrounds, and rely on the emission of light for particle detection. Water Cherenkov detectors come into this category; they have a large mass of water as the sensitive medium. Particles are detected when they interact with the water and produce Cherenkov light, so detection efficiency relies on having a huge light sensitive area at the periphery of the detector. The most cost-effective way of achieving this is by placing light concentrators on large photomultiplier tubes (PMTs). This paper describes the work carried out on light concentrators for the PMTs in the Sudbury Neutrino Observatory, a 1000 tonne heavy water Cherenkov detector. We discuss the advantages of using light concentrators, summarize the optical theory of non-imaging light concentration, and describe in detail the development and manufacture of the concentrators themselves.     

Study of TOF PET using Cherenkov light

This work investigates the possibilities of improving the measurements of arrival time difference of the two 511 keV photons arising from annihilation of a positron in positron emission tomography (PET). The new technique of detecting the prompt Cherenkov light, produced by absorption of the annihilation photon in a suitable crystal, could considerably improve the image quality. A simple apparatus with PbF₂ crystals and microchannel plate photomultipliers (MCP PMTs) has been constructed and coincidence resolutions of 71 ps FWHM and 95 ps FWHM have been achieved with 5 and 15 mm thick crystals, respectively. Simulation calculations are in agreement with the experimental findings.     

Evaluation of 400 low background 10-in. photo-multiplier tubes for the Double Chooz experiment

The Double Chooz is a reactor neutrino experiment which measures the last unknown neutrino mixing angle θ₁₃. The Double Chooz experiment uses two identical detectors placed at sites far and near from Chooz reactor cores. The detector uses 390 low-background and high performance 10-in. Photo-Multiplier Tubes (PMTs) to detect scintillation light from gadolinium loaded liquid scintillator. In order to test and characterize the PMTs and to tune operation parameter, we developed two types of PMT test system and evaluated 400 PMTs before installation. Those PMTs fulfilled our requirements and half of them were installed in the far detector in 2009 and physics data have been successfully taken since 2011.     

Observations on dual-ended readout of 100 mm long LYSO crystals

We are investigating using dual-ended readout of axially oriented long thin scintillator crystals in detectors for a compact geometry, small ring diameter animal PET system. The axial position of interaction is determined from the light sharing between two photodetectors at opposite ends of the crystal. We examine the light output, energy resolution and axial spatial resolution of 1.5-5×2×100 mm³ polished LYSO crystals by irradiating with an electronically collimated beam of 511 keV photons oriented perpendicular to the long axis and read out at either end by position sensitive photomultiplier tubes (PSPMTs). Three reflector materials, namely Teflon, 3 M enhanced specular reflector (ESR) and black paint are examined for the 2×2×100 mm³ crystal size. The light output increases and energy resolution improves with the crystal cross-section. Generally, the spatial resolution worsens with increase in crystal cross-section. For the 2×2×100 mm³ crystal size, the mean energy resolutions of the photopeak over the nine irradiation positions were 14.4±0.4%, 16.0±1.2% and 28.3±2.1% with mean spatial resolutions of 7.0±1.0, 9.4±3.3 and 26.0±5.0 mm using ESR, Teflon and black paint, respectively. ESR reflector gave the best light output, energy and axial spatial resolutions. These characterization results of PSPMT-based dual-ended long LYSO crystals will be useful in the design of detector modules for a highly compact geometry preclinical PET system using this detector technology.     

Large-scale gadolinium-doped water Cherenkov detector for nonproliferation

Fission events from Special Nuclear Material (SNM), such as highly enriched uranium or plutonium, can produce simultaneous emission of multiple neutrons and high-energy gamma-rays. The observation of time correlations between any of these particles is a significant indicator of the presence of fissionable material. Cosmogenic processes can also mimic these types of correlated signals. However, if the background is sufficiently low and fully characterized, significant changes in the correlated event rate in the presence of a target of interest constitutes a robust signature of the presence of SNM. Since fission emissions are isotropic, adequate sensitivity to these multiplicities requires a high efficiency detector with a large solid angle with respect to the target. Water Cherenkov detectors are a cost-effective choice when large solid angle coverage is required. In order to characterize the neutron detection performance of large-scale water Cherenkov detectors, we have designed and built a 3.5 kL water Cherenkov-based gamma-ray and neutron detector, and modeled the detector response in Geant4 [1]. We report the position-dependent neutron detection efficiency and energy response of the detector, as well as the basic characteristics of the simulation.     

Low temperature growth and properties of Cu-In-Te based thin films for narrow bandgap solar cells

Cu-In-Te based thin films were grown onto soda-lime glass (SLG) substrates at 200 °C by co-evaporation using a molecular beam epitaxy system. The microstructural properties were examined by means of scanning electron microscopy, X-ray diffraction and Raman scattering. The crystalline quality of Cu-In-Te based thin films with high Cu/In ratios is superior to that of films with low Cu/In ratios. The films with Cu/In ratios of 0.69 ± 0.04 exhibited a single chalcopyrite phase with random orientation, whereas a defect chalcopyrite phase with a preferred (112) orientation was obtained for thin films with Cu/In ratios of 0.26 ± 0.02. However, the films with high Cu/In ratios of 0.69 ± 0.04 showed nearly constant low resistivity (∼ 10^− 2 Ω cm) at temperatures from 80 to 400 K due to high hole concentration (> 10¹⁹ cm^− 3), resulting in semi-metallic behavior. The hole conduction mechanism of the film (Cu/In atomic ratios = 0.26 ± 0.02) with semi-conductive properties was found to be variable-range-hopping of the Mott type in the wide range of 80-300 K. The optical bandgaps of Cu-In-Te based thin films are determined to be 0.93-1.02 eV at 300 K from transmission and reflection measurements. A solar cell with a ZnO/CdS/CuIn₃Te₅/Mo/SLG structure showed a total area (0.50 cm²) efficiency of 5.1% under AM1.5 illumination (100 mW/cm²) after light soaking. The conduction band offset at the CdS/CuIn₃Te₅ interface was estimated to be − 0.14 eV from X-ray photoelectron spectroscopy analysis.     

The track imaging Cherenkov experiment

We describe a dedicated cosmic-ray telescope that explores a new method for detecting Cherenkov radiation from high-energy primary cosmic rays and the large particle air shower they induce upon entering the atmosphere. Using a camera comprising 16 multi-anode photomultiplier tubes for a total of 256 pixels, the Track Imaging Cherenkov Experiment (TrICE) resolves substructures in particle air showers with 0.086° resolution. Cherenkov radiation is imaged using a novel two-part optical system in which a Fresnel lens provides a wide-field optical trigger and a mirror system collects delayed light with four times the magnification. TrICE records well-resolved cosmic-ray air showers at rates ranging between 0.01 Hz and 0.1 Hz.     

A study of reactor neutrino monitoring at the experimental fast reactor JOYO

We carried out a study of neutrino detection at the experimental fast reactor JOYO using a 0.76 tons gadolinium loaded liquid scintillator detector. The detector was set up on the ground level at 24.3 m from the JOYO reactor core of 140 MW thermal power. The measured neutrino event rate from reactor on-off comparison was 1.11±1.24(stat.)±0.46(syst.) events/day. Although the statistical significance of the measurement was not enough, backgrounds in such a compact detector at the ground level were studied in detail and MC simulations were found to describe the data well. A study for improvement of the detector for future such experiments is also shown.     

A neutron Albedo system with time rejection for landmine and IED detection

A neutron Albedo system has been developed for imaging of buried landmines and improvised explosive devices (IEDs). It involves irradiating the ground with fast neutrons and subsequently detecting the thermalized neutrons that return. A scintillating ⁶Li loaded ZnS(Ag) screen with a sensitive area of 40 cm×40 cm is used as a thermal neutron detector. Scintillation light is captured by orthogonal arrays of wavelength-shifting fibers placed on either side of the scintillator surface and then transferred to X and Y multi-pixel PMTs. A timing circuit, used with pulsed neutron sources, records the time when a neutron detection takes place relative to an external synchronization pulse from the pulsed source. Experimental tests of the Albedo system performance have been done in a sand box with a ²⁵²Cf neutron source (no time gating) and with pulsed D-D (2.6 MeV) neutrons from the Defense R&D Ottawa Van de Graaff accelerator (with time gating). Information contained in the time evolution of the thermal neutron field provided improved detection capability and image reconstruction. The detector design is described and experimental results are discussed.     

Highly sensitive ultraviolet detector using a ZnO/Si layered SAW oscillator

This study elucidates a highly sensitive ultraviolet light detector using the combination of an oscillator circuit with a high-frequency amplifier, a matching network and a layered surface acoustic wave (SAW) device. In this structure, a ZnO thin film is simultaneously used as an active layer for UV detection and a piezoelectric layer for exciting a high-order surface acoustic wave. The microstructure and crystallization of ZnO films were investigated using the scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. The SAW oscillator shows a good performance with output power of − 1.14 dBm and phase noise of −94.7 dBc at 100 kHz. Firstly, the frequency shifts of the oscillator exhibit rapid increase with the intensity of the UV light. Then the increased shifts decayed at certain UV intensity due to the saturated photogenerated carriers. An extreme frequency shift of 1017 kHz was obtained as the UV intensity reached 551 μW/cm². The maximum sensitivity of 8.12 ppm/(μW/cm²) can be obtained in this detector.     

Etching process optimization using NH4Cl aqueous solution to texture ZnO:Al films for efficient light trapping in flexible thin film solar cells

0.5 μm-thick aluminum-doped zinc oxide (ZnO:Al) films were deposited at 100 °C on polyethylene terephthalate substrates by Radio Frequency magnetron sputtering. The as-deposited films were compact and dense, showing grain sizes of 32.0 ± 6.4 nm and resistivities of (8.5 ± 0.7) × 10^− 4 Ω cm. The average transmittance in the visible wavelength range of the structure ZnO:Al/PET was around 77%. The capability of a novel two-step chemical etching using diluted NH₄Cl aqueous solution to achieve efficient textured surfaces for light trapping was analyzed. The results indicated that both the aqueous solution and the etching method resulted appropriated to obtain etched surfaces with a surface roughness of 32 ± 5 nm, haze factors at 500 nm of 9% and light scattering at angles up to 50°. To validate all these results, a commercially ITO coated PET substrate was used for comparison.     

4π FOV compact Compton camera for nuclear material investigations

A compact Compton camera with a 4π field of view (FOV) was manufactured using the design parameters optimized with the effective choice of gamma-ray interaction order determined from a Monte Carlo simulation. The camera consisted of six CsI(Na) planar scintillators with a pixelized structure that was coupled to position sensitive photomultiplier tubes (H8500) consisting of multiple anodes connected to custom-made circuits. The size of the scintillator and each pixel was 4.4×4.4×0.5 and 0.2×0.2×0.5 cm, respectively. The total size of each detection module was only 5×5×6 cm and the distance between the detector modules was approximately 10 cm to maximize the camera performance, as calculated by the simulation. Therefore, the camera is quite portable for examining nuclear materials in areas, such as harbors or nuclear power plants. The non-uniformity of the multi-anode PMTs was corrected using a novel readout circuit. Amplitude information of the signals from the electronics attached to the scintillator-coupled multi-anode PMTs was collected using a data acquisition board (cDAQ-9178), and the timing information was sent to a FPGA (SPARTAN3E). The FPGA picked the rising edges of the timing signals, and compared the edges of the signals from six detection modules to select the coincident signal from a Compton pair only. The output of the FPGA triggered the DAQ board to send the effective Compton events to a computer. The Compton image was reconstructed, and the performance of the 4π FOV Compact camera was examined.     

Artificial petal surface based on hierarchical micro- and nanostructures

In this paper, we present an artificial rose petal composed of hierarchical micro- and nanostructures on a polymethyl methacrylate surface. The petal effect implies that the surface has a high adhesion force in spite of being in a super-hydrophobic state, while the lotus effect implies that the surface has a low adhesion force when it is in a super-hydrophobic state. We have fabricated four different types of surfaces, namely, smooth, nanostructured, microstructured, and hierarchically micro-nanostructured surfaces. Microstructures and nanostructures have a quadrangular pyramid shape (one-side length: 15 ± 2 μm, height: 10.6 ± 1 μm) and a circular bump shape (diameter: 130 ± 10 nm, height: 100 ± 10 nm), respectively. The four types of surfaces are also chemically treated with trichlorosilane in order to reduce the surface energy. The contact angles of the smooth, nanostructured, microstructured, and hierarchically micro-nanostructured surfaces are measured to be 104° ± 2°, 112° ± 2°, 138° ± 4°, and 159° ± 2° after the chemical treatment. In the case of the super-hydrophobic micro-nanostructured surfaces, water droplets remain attached to the surface, even when the surface is turned upside down.     

The extended-track event reconstruction for MiniBooNE

The Booster Neutrino Experiment (MiniBooNE) searches for ν_μ→ν_e oscillations using the neutrino beam produced by the FNAL Booster synchrotron. The array of photomultiplier tubes (PMTs) lining the MiniBooNE detector records Cherenkov and scintillation photons from the charged particles produced in neutrino interactions. We describe a maximum likelihood fitting algorithm used to reconstruct the basic properties (position, direction, energy) of these particles from the charges and times measured by the PMTs. The likelihoods returned from fitting an event to different particle hypotheses are used to categorize it as a signal ν_e event or as one of the background ν_μ processes, in particular charged current quasi-elastic scattering and neutral current π⁰ production. The reconstruction and event selection techniques described here can be applied to current and future neutrino experiments using similar Cherenkov-based detection.     

Growth and in-situ electrical characterization of ultrathin epitaxial TiN films on MgO

We examine the properties of ultrathin TiN films grown by reactive dc magnetron sputtering on single-crystalline MgO(100) substrates at growth temperatures ranging from 30 to 650 °C. The resistance of the films is measured in-situ, during growth, to study the thickness at which the films coalesce and become structurally continuous. Both the in-situ resistance measurements and X-ray diffraction measurements show a clear transition from polycrystalline growth to epitaxial (100) growth well below typical TiN growth temperatures, or between 100 and 200 °C. The coalescence and continuity thicknesses are 1.09 ± 0.06 nm and 5.5 ± 0.5 nm, respectively, at room temperature but reach a minimum of 0.08 ± 0.02 nm and 0.7 ± 0.1 nm, respectively, at 600 °C. A large drop in resistivity is seen with increasing growth temperature and the resistivity reaches 16.6 μΩ cm at 600 °C. Achieving epitaxy at such a low temperature and a low continuity thickness is important in a variety of applications such as device interconnects and metal-oxide-semiconductor devices.     

Radiological hazards of TENORM in precipitated calcium carbonate generated as waste at nitrophosphate fertilizer plant in Pakistan

The NORM (naturally occurring radioactive material) in phosphate rock is transferred as TENORM (technologically enhanced naturally occurring radioactive material) to phosphatic fertilizers and to the waste generated by the chemical processes. The waste generated at the NP (nitrophosphate) fertilizer plant at Multan in Pakistan is PCC (precipitated calcium carbonate). Thirty samples of the PCC were collected from the heaps of the waste near the fertilizer plant. Activity concentrations of radionuclides in the waste samples were measured by using the technique of gamma ray spectrometry consisting of coaxial type HPGe (high purity germanium) detector coupled with a PC (personal computer) based MCA (multichannel analyzer) through a spectroscopy amplifier. Activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in the waste samples were determined to be 273 ± 23 (173-398), 32 ± 4 (26-39) and 56 ± 5 (46-66) Bq kg⁻¹ respectively. The activity concentration of ²²⁶Ra in the PCC waste was found to be higher than that in naturally occurring calcium carbonate (limestone and marble) and in worldwide soil. Radiological hazard was estimated from indoor and outdoor exposure to gamma rays from the PCC. Indoor annual effective dose was higher than 1 m Sv. Potential radiological pollution in the environment from TENORM in the PCC has also been addressed.     

Characterization of LFS-3 scintillator in comparison with LSO

Performance of Lutetium Fine Silicate (LFS-3) scintillator in gamma-ray spectrometry has been investigated in comparison with the well known LSO crystal. The tests covered measurements of light output in terms of number of photoelectrons, energy resolution and non-proportionality. Time resolution was measured in coincidence experiments with 511 keV annihilation quanta from a ²²Na gamma source. Decay time constants of the light pulse were calculated on the basis of timing spectra obtained using Thomas-Bollinger single photon method. Afterglow was measured about 30 ms after the crystal was irradiated by a strong 13.9 GBq ²⁴¹Am source. Improvement in the energy resolution for 662 keV γ-rays from ¹³⁷Cs, shorter decay time constants and better time resolution were observed in case of LFS-3, when compared with LSO. For LFS-3 energy resolution for 662 keV from ¹³⁷Cs, decay time and time resolution were equal to about 7.66±0.23%, 40.5±1.2 ns and 161±5 ps, respectively, whereas for LSO the same parameters were equal to 8.13±0.23%, 43.9±1.3 ns and 173±5 ps, respectively. The study showed that LFS-3 crystal is an excellent substitute for LSO crystal.     

Cr(VI) adsorption on functionalized amorphous and mesoporous silica from aqueous and non-aqueous media

A mesoporous silica (SBA-15) and amorphous silica (SG) have been chemically modified with 2-mercaptopyridine using the homogeneous route. This synthetic route involved the reaction of 2-mercaptopyridine with 3-chloropropyltriethoxysilane prior to immobilization on the support. The resulting material has been characterized by powder X-ray diffraction, nitrogen gas sorption, FT-IR and MAS NMR spectroscopy, thermogravimetry and elemental analysis. The solid was employed as a Cr(VI) adsorbent from aqueous and non-aqueous solutions at room temperature. The effect of several variables (stirring time, pH, metal concentration and solvent polarity) has been studied using the batch technique. The results indicate that under the optimum conditions, the maximum adsorption value for Cr(VI) was 1.83 ± 0.03 mmol/g for MP-SBA-15, whereas the adsorption capacity of the MP-SG was 0.86 ± 0.02 mmol/g. On the basis of these results, it can be concluded that it is possible to modify chemically SBA-15 and SG with 2-mercaptopyridine and to use the resulting modified silicas as effective adsorbents for Cr(VI).     

Thermal annealing behaviour of Pd Schottky contacts on melt-grown single crystal ZnO studied by IV and CV measurements

Current-voltage (IV) and capacitance-voltage (CV) measurement techniques have successfully been employed to study the effects of annealing highly rectifying Pd/ZnO Schottky contacts. IV results reveal a decrease in the contact quality with increasing annealing temperature as confirmed by a decrease in the zero bias barrier height and an increase in the reverse current measured at −1.5 V. An average barrier height of (0.77 ± 0.02) eV has been calculated by assuming pure thermionic emission for the as-deposited material and as (0.56 ± 0.03) eV after annealing at 550 °C. The reverse current has been measured as (2.10 ± 0.01) × 10⁻¹⁰ A for the as-deposited and increases by 5 orders of magnitude after annealing at 550 °C to (1.56 ± 0.01) × 10⁻⁵ A. The depletion layer width measured at −2.0 V has shown a strong dependence on thermal annealing as it decreases from 1.09 μm after annealing at 200 °C to 0.24 μm after annealing at 500 °C, resulting in the modification of the dopant concentration within the depletion region and hence the current flowing through the interface from pure thermionic emission to thermionic field emission with the donor concentrations increasing from 6.90 × 10¹⁵ cm⁻³ at 200 °C to 6.06 × 10¹⁶ cm⁻³ after annealing at 550 °C. This increase in the volume concentration has been explained as an effect of a conductive channel that shifts closer to the surface after sample annealing. The series resistance has been observed to decrease with increase in annealing temperature. The Pd contacts have shown high stability up to an annealing temperature of 250 °C as revealed by the IV and CV characteristics after which the quality of the contacts deteriorates with increase in annealing temperature.