Performance Improvement of N-Type $hbox{TiO}_{x}$ Active-Channel TFTs Grown by Low-Temperature Plasma-Enhanced ALD

We report on performance improvement of $n$-type oxide–semiconductor thin-film transistors (TFTs) based on $hbox{TiO}_{x}$ active channels grown at 250 $^{circ}hbox{C}$ by plasma-enhanced atomic layer deposition. TFTs with as-grown $hbox{TiO}_{x}$ films exhibited the saturation mobility $(mu_{rm sat})$ as high as 3.2 $hbox{cm}^{2}/hbox{V}cdothbox{s}$ but suffered from the low on–off ratio $(I_{rm ON}/I_{rm OFF})$ of $hbox{2.0} times hbox{10}^{2}$. $hbox{N}_{2}hbox{O}$ plasma treatment was then attempted to improve $I_{rm ON}/I_{rm OFF}$. Upon treatment, the $hbox{TiO}_{x}$ TFTs exhibited $I_{rm ON}/I_{rm OFF}$ of $hbox{4.7} times hbox{10}^{5}$ and $mu_{rm sat}$ of 1.64 $hbox{cm}^{2}/hbox{V}cdothbox{s}$, showing a much improved performance balance and, thus, demonstrating their potentials for a wide variety of applications such as backplane technology in active-matrix displays and radio-frequency identification tags.      

Electrical Properties of $hbox{Bi}_{5}hbox{Nb}_{3} hbox{O}_{15}$ Thin Film Grown on $hbox{TiN}/hbox{SiO}_{2}/ hbox{Si}$ at Room Temperature for Metal–Insulator–Metal Capacitors

Buckling was observed in $hbox{Bi}_{5}hbox{Nb}_{3}hbox{O}_{15}$ (BiNbO) films grown on $hbox{TiN}/hbox{SiO}_{2}/hbox{Si}$ at 300 $^{circ}hbox{C}$ but not in films grown at room temperature and annealed at 350 $^{circ}hbox{C}$. The 45-nm-thick films showed a high capacitance density and a low dissipation factor of 8.81 $hbox{fF}/muhbox{m}^{2}$ and 0.97% at 100 kHz, respectively, with a low leakage current density of 3.46 $hbox{nA}/hbox{cm}^{2}$ at 2 V. The quadratic and linear voltage coefficients of capacitance of this film were 846 $hbox{ppm}/hbox{V}^{2}$ and 137 ppm/V, respectively, with a low temperature coefficient of capacitance of 226 $hbox{ppm}/^{circ}hbox{C}$ at 100 kHz. This suggests that a BiNbO film grown on a $hbox{TiN}/ hbox{SiO}_{2}/hbox{Si}$ substrate is a good candidate material for high-performance metal–insulator–metal capacitors.      

High-Density and Low-Leakage-Current MIM Capacitor Using Stacked $hbox{TiO}_{2}/hbox{ZrO}_{2}$ Insulators

We have fabricated high-$kappa hbox{Ni}/hbox{TiO}_{2}/hbox{ZrO}_{2}/ hbox{TiN}$ metal–insulator–metal (MIM) capacitors. A low leakage current of $hbox{8} times hbox{10}^{-8} hbox{A/cm}^{2}$ at 125 $^{circ}hbox{C}$ was obtained with a high 38- $hbox{fF}/muhbox{m}^{2}$ capacitance density and better than the $hbox{ZrO}_{2}$ MIM capacitors. The excellent device performance is due to the lower electric field in 9.5-nm-thick $hbox{TiO}_{2}/ hbox{ZrO}_{2}$ devices to decrease the leakage current and to a higher $kappa$ value of 58 for $ hbox{TiO}_{2}$ as compared with that of $hbox{ZrO}_{2}$ to preserve the high capacitance density.      

Cooperative Quantum Cutting in Yb $^{3+}$–Tb $^{3+}$ Codoped Borosilicate Glasses

Quantum cutting down-conversion (DC) with the emission of two near-infrared photons for each blue photon absorbed is realized in $hbox{Yb}^{3+}hbox{–}hbox{Tb}^{3+}$ codoped borosilicate glasses. With the excitation of $hbox{Tb}^{3+}$ ion by a 484-nm monochromatic light, emission from the $^{2} hbox{F} _{5/2}rightarrow ^{2} hbox{F} _{7/2}$ transition of $hbox{Yb}^{3+}$ ions is observed and this emission is proved to originate from the DC between $hbox{Tb}^{3+}$ ions and $hbox{Yb}^{3+}$ ions. Results shows that maximum quantum efficiency reach as high as 153%, which is comparable with that in oxyfluoride glass ceramics in this system. With the advantages of excellent transparence, easy shaping, good stability, and low cost, $hbox{Yb}^{3+}hbox{–}hbox{Tb}^{3+}$ codoped borosilicate glasses are potentially used as down-converter layer in silicon-based solar cells.      

Fully Depleted Polysilicon TFTs for Capacitorless 1T-DRAM

A capacitorless 1T-DRAM is fabricated on a fully depleted poly-Si thin-film transistor (TFT) template. A heavily doped back gate with a thin back-gate dielectric is employed to facilitate the formation of a deep potential well that retains excess holes. An asymmetric double gate ($hbox{n}^{+}$ front gate and $hbox{p}^{+}$ back gate) shows a wider sensing current window than a symmetric double gate ($hbox{n}^{+}$ front gate and $hbox{n}^{+}$ back gate). This is attributed to the inherent flatband voltage between the $hbox{p}^{+}$ back gate and the channel inducing a deeper potential well, which allows capacitorless 1T-DRAM operation at a low back-gate voltage. The TFT capacitorless 1T-DRAM can be applied for future stackable memory for the ultrahigh density era.      

$hbox{TiN/ZrO}_{2}$/Ti/Al Metal–Insulator–Metal Capacitors With Subnanometer CET Using ALD-Deposited $hbox{ZrO}_{2}$ for DRAM Applications

We provide the first report of the structural and electrical properties of $hbox{TiN/ZrO}_{2}$/Ti/Al metal–insulator–metal capacitor structures, where the $hbox{ZrO}_{2}$ thin film (7–8 nm) is deposited by ALD using the new zirconium precursor ZrD-04, also known as Bis(methylcyclopentadienyl) methoxymethyl. Measured capacitance–voltage ($C$– $V$) and current–voltage ( $I$–$V$) characteristics are reported for premetallization rapid thermal annealing (RTP) in $hbox{N}_{2}$ for 60 s at 400 $^{circ}hbox{C}$, 500 $^{circ}hbox{C}$, or 600 $^{ circ}hbox{C}$. For the RTP at 400 $^{circ}hbox{C}$ , we find very low leakage current densities on the order of nanoamperes per square centimeter at a gate voltage of 1 V and low capacitance equivalent thickness values of $sim$ 0.9 nm at a gate voltage of 0 V. The dielectric constant of $ hbox{ZrO}_{2}$ is 31 $pm$ 2 after RTP treatment at 400 $^{circ}hbox{C}$.      

Electrical Properties of Amorphous $hbox{Bi}_{5} hbox{Nb}_{3}hbox{O}_{15}$ Thin Film for RF MIM Capacitors

Amorphous $hbox{Bi}_{5}hbox{Nb}_{3}hbox{O}_{15}(hbox{B}_{5} hbox{N}_{3})$ film grown at 300 $^{circ}hbox{C}$ showed a high-$k$ value of 71 at 100 kHz, and similar $k$ value was observed at 0.5–5.0 GHz. The 80-nm-thick film exhibited a high capacitance density of 7.8 fF/$muhbox{m}^{2}$ and a low dissipation factor of 0.95% at 100 kHz with a low leakage-current density of 1.23 nA/ $hbox{cm}^{2}$ at 1 V. The quadratic and linear voltage coefficient of capacitances of the $hbox{B}_{5}hbox{N}_{3}$ film were 438 ppm/$hbox{V}^{2}$ and 456 ppm/V, respectively, with a low temperature coefficient of capacitance of 309 ppm/$^{circ}hbox{C}$ at 100 kHz. These results confirmed the potential of the amorphous $hbox{B}_{5}hbox{N}_{3}$ film as a good candidate material for a high-performance metal–insulator–metal capacitors.      

Schottky Barrier Height Modulation of Nickel–Dysprosium-Alloy Germanosilicide Contacts for Strained P-FinFETs

This letter reports on the fabrication and hole Schottky barrier $(Phi_{ rm B}^{rm p})$ modulation of a novel nickel (Ni)–dysprosium (Dy)-alloy germanosilicide (NiDySiGe) on silicon–germanium (SiGe). Aluminum (Al) implant is utilized to lower the $Phi_{rm B}^{rm p}$ of NiDySiGe from $sim$0.5 to $sim$ 0.12 eV, with a correspondingly increasing Al dose in the range of $ hbox{0}$–$hbox{2}timeshbox{10}^{15} hbox{atoms}/ hbox{cm}^{2}$. When integrated as the contact silicide in p-FinFETs (with SiGe source/drain), NiDySiGe with an Al implant dose of $hbox{2}timeshbox{10}^{14} hbox{atoms}/ hbox{cm}^{2}$ leads to 32% enhancement in $I_{rm DSAT}$ over p-FinFETs with conventional NiSiGe contacts. Ni–Dy-alloy silicide is a promising single silicide solution for series-resistance reduction in CMOS FinFETs.      

Effective Modulation of Quadratic Voltage Coefficient of Capacitance in MIM Capacitors Using $hbox{Sm}_{2}hbox{O}_{3}/hbox{SiO}_{2}$ Dielectric Stack

We report the first demonstration of metal–insulator–metal (MIM) capacitors with $hbox{Sm}_{2}hbox{O}_{3}/hbox{SiO}_{2}$ stacked dielectrics for precision analog circuit applications. By using the “canceling effect” of the positive quadratic voltage coefficient of capacitance (VCC) of $hbox{Sm}_{2}hbox{O}_{3}$ and the negative quadratic VCC of $hbox{SiO}_{2}$, MIM capacitors with capacitance density exceeding 7.3 $hbox{fF}/muhbox{m}^{2}$ , quadratic VCC of around $-hbox{50} hbox{ppm/V}^{2}$ , and leakage current density of $hbox{1} times hbox{10}^{-7} hbox{A/cm}^{2}$ at $+$3.3 V are successfully demonstrated. The obtained capacitance density and quadratic VCC satisfy the technical requirements specified in the International Technology Roadmap for Semiconductors through the year 2013 for MIM capacitors to be used in precision analog circuit applications.      

Extraction of the Effective Mobility of $ hbox{In}_{0.53}hbox{Ga}_{0.47}hbox{As}$ MOSFETs

The extraction of the effective mobility on $hbox{In}_{0.53} hbox{Ga}_{0.47}hbox{As}$ metal–oxide–semiconductor field-effect transistors (MOSFETs) is studied and shown to be greater than 3600 $hbox{cm}^{2}/hbox{V} cdot hbox{s}$. The removal of $C_{rm it}$ response in the split $C$–$V$ measurement of these devices is crucial to the accurate analysis of these devices. Low-temperature split $C$–$V$ can be used to freeze out the $D_{rm it}$ response to the ac signal but maintain its effect on the free carrier density through the substrate potential. Simulations that match this low-temperature data can then be “warmed up” to room temperature and an accurate measure of $Q_{rm inv}$ is achieved. These results confirm the fundamental performance advantages of $hbox{In}_{0.53}hbox{Ga}_{0.47}hbox{As}$ MOSFETs.      

The Electrical and Interfacial Properties of Metal-High-$kappa$ Oxide-Semiconductor Field-Effect Transistors With $hbox{LaAlO}_{3}$ Gate Dielectric

$hbox{LaAlO}_{3}$ is a promising candidate for gate dielectric of future VLSI devices. In this letter, n-channel metal–oxide–semiconductor field-effect transistors with $hbox{LaAlO}_{3}$ gate dielectric were fabricated, and the electron mobility degradation mechanisms were studied. The leakage current density is $hbox{7.6} times hbox{10}^{-5} hbox{A/cm}^{2}$ at $-!$ 1 V. The dielectric constant is 17.5. The surface-recombination velocity, the minority-carrier lifetime, and the effective capture cross section of surface states were extracted from gated-diode measurement. The rate of threshold voltage change with temperature $(Delta V_{T} / Delta T)$ from 11 K to 400 K is $-!$ 1.51 mV/K, and the electron mobility limited by surface roughness is proportional to $E_{rm eff}^{-0.66}$.      

180$^{circ}$ and 90$^{circ}$ Phase Shifting Networks With an Octave Bandwidth and Small Phase Errors

A new phase shifting network for both 180 $^{circ}$ and 90 $^{circ}$ phase shift with small phase errors over an octave bandwidth is presented. The theoretical bandwidth is 67% for the 180$^{circ}$ phase bit and 86% for the 90$^{circ}$ phase bit when phase errors are $pm 2^{circ}$. The proposed topology consists of a bandpass filter (BPF) branch, consisting of a LC resonator and two shunt quarter-wavelength transmission lines (TLs), and a reference TL. A theoretical analysis is provided and scalable parameters are listed for both phase bits. To test the theory, phase shifting networks from 1 GHz to 3 GHz were designed. The measured phase errors of the 180$^{circ}$ and the 90$^{circ}$ phase bit are $pm 3.5^{circ}$ and $pm 2.5^{circ}$ over a bandwidth of 73% and 102% while the return losses are better than 18 dB and 12 dB, respectively.      

Electrical Properties of $hbox{Ga}_{2}hbox{O}_{3}/ hbox{GaAs}$ Interfaces and GdGaO Dielectrics in GaAs-Based MOSFETs

Electrical properties of $hbox{Ga}_{2}hbox{O}_{3}/hbox{GaAs}$ interfaces with GdGaO cap dielectrics used in recent enhancement-mode GaAs-based NMOSFETs which perform in line with theoretical model predictions are presented. Capacitors with GdGaO thickness ranging from 3.0 to 18 nm ($hbox{0.9} leq hbox{EOT} leq hbox{3.9} hbox{nm}$) have been characterized by capacitance–voltage measurements. Midgap interface state density $D_{rm it}$, effective workfunction $phi_{m}$, fixed charge $Q_{f}$, dielectric constant $kappa$, and low field leakage current density are $hbox{2} times hbox{10}^{11} hbox{cm}^{-2} cdot hbox{eV}^{-1}$, 4.93 eV, $-hbox{8.9} times hbox{10}^{11} hbox{cm}^{-2}$, 19.5, and $hbox{10}^{-9}{-} hbox{10}^{-8} hbox{A/cm}^{2}$, respectively. The presence of interfacial Gd was confirmed to dramatically degrade electrical interface properties. The data illuminate the intimate interplay between heterostructure and interface engineering to achieve optimum MOSFET operation.      

Bending and Strain Sensitivities in a Helicoidal Long-Period Fiber Gratings

In this letter, we report bending and strain sensitivities of helicoidal long-period fiber gratings fabricated by twisting single-mode fibers during $hbox{CO}_{2}$ laser irradiation. Linear spectral shifts of the resonant wavelengths under the bending and tensile strain were observed with the sensitivities of $-$11.7 nm/m$^{-1}$ and $-$1.1 $hbox{pm}/muvarepsilon$, respectively. The corresponding transmission power variations at the resonance wavelength were 4.1 $hbox{dB/m}^{-1}$ and $2.2times 10^{-4} hbox{dB}/muvarepsilon$, respectively. Detailed measurement techniques and sensor applications are discussed.      

Cubic-Structured $hbox{HfO}_{2}$ With Optimized Doping of Lanthanum for Higher Dielectric Constant

It is demonstrated that $hbox{HfO}_{2}$ films can have much higher dielectric-constant values than the usual reported value of 20–24 by optimized incorporation of lanthanum element and crystallization to cubic structure. When $hbox{HfO}_{2}$ with 8% La is crystallized into cubic structure, the film exhibits the $kappa$ value of $sim$ 38 which is the highest among ever reported $hbox{HfO}_{2}$ -based high-$kappa$ dielectrics. The increased $kappa$ value of $ hbox{HfO}_{2}$ with 8% La enables the leakage current to be reduced more than one order of magnitude lower, compared to amorphous-phase $hbox{HfO}_{2}$ under the same electric field. The dependence of film thickness and annealing temperature on the cubic crystallization is also reported.      

High-Performance Poly-Silicon TFTs Using a High-$k$ $hbox{PrTiO}_{3}$ Gate Dielectric

In this letter, a polycrystalline-silicon thin-film transistor (poly-Si TFT) with a high- $k$ $hbox{PrTiO}_{3}$ gate dielectric is proposed for the first time. Compared to TFTs with a $hbox{Pr}_{2}hbox{O}_{3}$ gate dielectric, the electrical characteristics of poly-Si TFTs with a $hbox{PrTiO}_{3}$ gate dielectric can be significantly improved, such as lower threshold voltage, smaller subthreshold swing, higher $I_{rm on}/I_{rm off}$ current ratio, and larger field-effect mobility, even without any hydrogenation treatment. These improvements can be attributed to the high gate capacitance density and low grain-boundary trap state. All of these results suggest that the poly-Si TFT with a high- $k$ $hbox{PrTiO}_{3}$ gate dielectric is a good candidate for high-speed and low-power display driving circuit applications in flat-panel displays.      

Distributed-Feedback Quantum-Cascade Lasers at 9 $mu$m Operating in Continuous Wave Up to 423 K

Single-mode lasers operating at $lambdaapprox 9 muhbox{m}$ in continuous wave up to 423 K (150 $^{circ}hbox{C}$) were achieved by the combination of strong distributed-feedback coupling, a narrow gain active region design, low intersubband, and free-carrier losses as well as a good thermal management. Tuning of 10 $hbox{cm}^{-1}$ or 0.9% of the center frequency was achieved by heating the device. The threshold current density varies from 1.1 $hbox{kA/cm}^{2}$ at 303 K to 2.4 $hbox{kA/cm}^{2}$ at 423 K. Other devices with low electrical power consumption of 1.6 and 3.8 W for an optical output power of 16 and 100 mW have been demonstrated at 263 K.      

High Conversion Efficiency InP/InGaAs Strained Quantum Well Infrared Photodetector Focal Plane Array With 9.7 $mu$m Cut-Off for High-Speed Thermal Imaging

InP/InGaAs material system is an alternative to AlGaAs/GaAs for long wavelength quantum well infrared photodetectors (QWIPs). We demonstrate a large format (640 $times$ 512) QWIP focal plane array (FPA) constructed with the strained InP/InGaAs material system. The strain introduced to the structure through utilization of $hbox{In}_{0.48}hbox{Ga}_{0.52}hbox{As}$ (instead of $hbox{In}_{0.53}hbox{Ga}_{0.47}hbox{As}$ ) as the quantum well material shifts the cut-off wavelength from $sim$8.5 to 9.7 $muhbox{m}$. The FPA fabricated with the 40-well epilayer structure yields a peak quantum efficiency as high as 12% with a broad spectral response $(Deltalambda/lambda_{rm p}=17%)$. The peak responsivity of the FPA pixels is 1.4 A/W corresponding to 20% conversion efficiency in the bias region where the detectivity is reasonably high ($2.6times 10^{10} hbox{cmHz}^{1/2}/hbox{W}$ , f/1.5, 65 K). The FPA providing a background limited performance temperature higher than 65 K (f/1.5) satisfies the requirements of most low integration time/low background applications where AlGaAs/GaAs QWIPs suffer from read-out circuit noise limited sensitivity due to lower conversion efficiencies. Noise equivalent temperature differences of the FPA are as low as 19 and 40 mK with integration times as short as 1.8 ms and 430 $muhbox{s}$ (f/1.5, 65 K).      

Demonstration of Tunneling FETs Based on Highly Scalable Vertical Silicon Nanowires

This letter demonstrates a vertical silicon-nanowire (SiNW)-based tunneling field-effect transistor (TFET) using CMOS-compatible technology. With a $hbox{Si} hbox{p}^{+}{-}hbox{i}{-} hbox{n}^{+}$ tunneling junction, the TFET with a gate length of $sim$200 nm exhibits good subthreshold swing of $sim$ 70 mV/dec, superior drain-induced-barrier-lowering of $sim$ 17 mV/V, and excellent $I_{rm on} {-} I_{rm off}$ ratio of $sim!!hbox{10}^{7}$ with a low $I_{rm off} (sim!!hbox{7} hbox{pA}/muhbox{m})$. The obtained 53 $muhbox{A}/muhbox{m} I_{rm on}$ can be further enhanced with heterostructures at the tunneling interface. The vertical SiNW-based TFET is proposed to be an excellent candidate for ultralow power and high-density applications.      

Impacts of $hbox{N}_{2}$ and $hbox{NH}_{3}$ Plasma Surface Treatments on High-Performance LTPS-TFT With High-$kappa$ Gate Dielectric

Low-temperature polycrystalline-silicon thin-film transistors (LTPS-TFTs) with high- $kappa$ gate dielectrics and plasma surface treatments are demonstrated for the first time. Significant field-effect mobility $mu_{rm FE}$ improvements of $sim$86.0% and 112.5% are observed for LTPS-TFTs with $hbox{HfO}_{2}$ gate dielectric after $hbox{N}_{2}$ and $ hbox{NH}_{3}$ plasma surface treatments, respectively. In addition, the $hbox{N}_{2}$ and $ hbox{NH}_{3}$ plasma surface treatments can also reduce surface roughness scattering to enhance the field-effect mobility $mu_{rm FE}$ at high gate bias voltage $V_{G}$, resulting in 217.0% and 219.6% improvements in driving current, respectively. As a result, high-performance LTPS-TFT with low threshold voltage $V_{rm TH} sim hbox{0.33} hbox{V}$, excellent subthreshold swing S.S. $sim$0.156 V/decade, and high field-effect mobility $mu_{rm FE} sim hbox{62.02} hbox{cm}^{2}/hbox{V} cdot hbox{s}$ would be suitable for the application of system-on-panel.