共查询到19条相似文献,搜索用时 453 毫秒
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镁合金因其具有优良的性能而日益受到重视,但是镁合金耐腐蚀性较差限制了它的应用。综述了镁合金环保型防护处理技术,包括化学氧化处理、阳极氧化、微弧氧化、金属镀层等技术,分析了镁合金表面防腐处理技术的发展趋势。 相似文献
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在医用镁合金功能化表面改性技术中,仿生钝化具有其他方法无可比拟的优越性。利用仿生钝化技术,可在镁合金表面原位制备兼具优异生物相容性、生物活性和降解控制功能的生物磷灰石膜层,全面满足镁合金生物医用对表面质量的苛刻要求。本文分别从前处理、钝化工艺、钝化后处理等方面,综述了医用镁合金仿生钝化技术的研究进展,并展望了医用镁合金仿生钝化技术的发展趋势。 相似文献
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A super-hydrophobic film was successfully deposited on magnesium alloy AZ31 by the microwave plasma-enhanced chemical vapor deposition (MPECVD) process. The film surface showed a static water contact angle of more than 150°. The hydrophobicity and root mean square roughness of the film surface increased with an increase in deposition time. The anticorrosion resistance of the deposited film was estimated by electrochemical impedance spectroscopy (EIS) measurements. The EIS measurements and appropriate equivalent circuit models revealed that the super-hydrophobic film considerably improved the anticorrosion resistant performance of magnesium alloy AZ31. The anticorrosion mechanism of the super-hydrophobic film was also considered. Moreover, the chemical stability of the super-hydrophobic film in acidic, neutral, and alkaline aqueous solutions was investigated. The super-hydrophobic film showed high chemical stability in acidic and neutral aqueous solutions. 相似文献
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为了改善AM60镁合金的抗腐蚀性能,通过电化学阻抗、极化曲线和浸泡等方法研究了苯甲酸钠(SB)对AM60镁合金在3.5%氯化钠溶液中的缓蚀作用,并考察了温度对缓蚀率的作用规律,借助扫描电镜观察了不同温度和不同SB浓度下镁合金腐蚀后的表面形貌,分析了SB的缓蚀机制。结果表明:SB明显减缓了AM60镁合金的腐蚀速率,当其浓度为0.5 mol·L-1时,缓蚀率达到75%以上,这主要是因为SB在AM60镁合金表面发生了物理吸附,这种吸附为放热、熵增的自发过程,形成的多分子吸附层隔离了镁合金和腐蚀介质的直接接触。随着SB浓度增加,镁合金腐蚀反应活化能增大,缓蚀率随之而增大。当SB浓度增大到0.7 mol·L-1以后,由于分子间排斥作用占主导作用,导致缓蚀率没有明显增加,且随着温度从25℃升高到70℃,SB的缓蚀率略有下降。 相似文献
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A novel composite films technology was developed to improve the anticorrosion performance of AZ91D magnesium alloy. The composite films were prepared via sol–gel method which is a simple application procedure within industry. The structure of xerogels and films, morphology of films were analyzed using thermo-gravimetric (TG) and differential thermal analysis (DTA), Fourier transformed infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and scan electron microscopy (SEM). The anticorrosion performance of the sol–gel coated and uncoated samples in 3.5 wt.% NaCl neutral solution had been evaluated by electrochemical tests. The results demonstrated that the composite films “Ce inner film/Mg outer film” exhibited better corrosion resistance. 相似文献
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Ruonan Ji Minyu Ma Yuntao He Chenxu Liu Tao Fang Zhan Zhang Yi Wang Yedong He Junsheng Wu 《Ceramics International》2018,44(13):15192-15199
In this study, we explored the phase compositions and morphologies of the ceramic coatings from different aluminum sources (aluminum isopropoxide, aluminum nitrate, or a mixture of the two) prepared using cathode plasma electrolytic deposition (CPED) onto AZ31 magnesium alloys. Scanning electron microscopy and X-ray diffraction analyses of these coatings indicate that the deposited ceramic made from aluminum isopropoxide was composed of γ-Al2O3 whereas the one made from aluminum nitrate was composed of MgA12O4, and that the former was more compact and uniform than the latter. A composite coating was prepared using epoxy resin as a protective layer that sealed the micropores on the CPED coating, thereby further improving its anticorrosion property. The elemental distribution of the cross-section of the composite coating was examined via energy dispersive spectroscopy. Corrosion resistance was investigated using potentiodynamic polarization curves and electrochemical impedance spectroscopy in a 3.5?wt% NaCl medium, and a salt spray test. The results indicate that the corrosion protection property of the Al2O3/epoxy resin coating of the magnesium alloy was better than that of the single Al2O3 coating. A cross-cut test revealed that the adhesion of the Al2O3/epoxy resin composite coating to the magnesium alloy surface was better than that of the single epoxy resin coating. The approach presented herein provides an attractive way to modify the surface of magnesium alloys to improve anticorrosion. 相似文献
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This work aims to develop and study new anticorrosion films for AZ31B magnesium alloy based on the sol-gel coating approach.Hybrid organic-inorganic sols were synthesized by copolymerization of epoxy-siloxane and titanium or zirconium alkoxides. Tris(trimethylsilyl) phosphate was also used as additive to confer additional corrosion protection to magnesium-based alloy. A sol-gel coating, about 5-μm thick, shows good adhesion to the metal substrate and prevents corrosion attack in 0.005 M NaCl solution for 2 weeks. The sol-gel coating system doped with tris(trimethylsilyl)-phosphate revealed improved corrosion protection of the magnesium alloy due to formation of hydrolytically stable Mg-O-P chemical bonds.The structure and the thickness of the sol-gel film were characterized by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The corrosion behaviour of AZ31B substrates pre-treated with the sol-gel derived hybrid coatings was tested by electrochemical impedance spectroscopy (EIS). The chemical composition of the silylphosphate-containing sol-gel film at different depths was investigated by X-ray photoelectron spectroscopy (XPS) with depth profiling. 相似文献