An experimental investigation of pool boiling characteristics of alumina-water nanofluid over micro-/nanostructured surfaces

Abstract

Experiments were conducted to investigate the nucleate pool boiling heat transfer of pure water and alumina/water nanofluids on different micro- and nanostructured surfaces prepared via the thermal spray coating method. Results indicate that nanofluids boiling on all the test surfaces led to critical heat flux (CHF) values greater than that obtained for the base fluid (i.e., water). Higher roughness value, however, led to higher CHF values in boiling over the surfaces. Another finding of this study indicated that CHF values obtained with boiling on Cu-coated micro- and nanosurfaces were identical although the heat transfer coefficient (HTC) values obtained for boiling on the micro-structure surface were higher than those obtained for a nanostructured surface with almost the same roughness. A series of consecutive nanofluid boiling cycles were also performed on the aluminum-coated nanostructured surface. The CHF value obtained for water boiling on the surface undergoing repeated nanofluid boiling cycles was by 27% higher than that obtained for a clean surface although the relevant HTC values were nearly identical.     

Nucleate pool boiling heat transfer characteristics of dilute Al2O3–ethyleneglycol nanofluids

Pool boiling heat transfer coefficients of dilute stabilized Al₂O₃–ethyleneglycol nanofluids as possible coolant fluid are experimentally quantified. The influence of different parameters such as heat flux, heating surface nano-roughness, concentration of nanofluids and fouling resistance on the pool boiling heat transfer coefficient of alumina nanofluids has experimentally been investigated and briefly discussed. Results demonstrated that there are two heat transfer regions with different mechanisms namely free convection and nucleate boiling heat transfer. Studies on the influence of parameter demonstrated that with increasing the heat flux, the pool boiling heat transfer coefficient of nanofluids significantly increases. In contrast, with increasing the concentration of nanofluid, due to the deposition of nanoparticles on the surface, the average roughness of the surface and the heat transfer coefficient dramatically deteriorate, while a significant increase in fouling resistance is reported. Also, studies reveal asymptotic and rectilinear behaviors of fouling resistance parameter in nucleate boiling and free convective domains.     

Boiling enhancement by TiO2 nanoparticle deposition

TiO₂ nanoparticle-coated nickel wires were produced by electrical heating in various nanofluid concentrations ranging from 0.01 to 1 wt.% with various processing heat fluxes from 0 to 1000 kW/m². The experimental results demonstrated up to 82.7% enhancement on critical heat flux (CHF) in condition of coated nickel wire (processed in 1 wt.% with 1000 kW/m²) boiling in pure water. The contact angle measurement revealed that the hydrophilic porous coating formed by vigorous vaporization of TiO₂ nanofluid in nucleate boiling regime enormously modified the wettability of heating surface consequently improving the CHF. Besides, it is evident that the coverage of nanoparticle deposition tended to become more complete as concentration and processing heat flux increased based on SEM and EDS analysis. The nanoparticles dispersed in base fluid exhibited little effect on CHF enhancement and could even hinder the percentage of CHF augmentation from boosting, which demonstrated that one could enhance CHF by using only small amount of nanoparticles just adequate to form surface coatings instead of preparing working fluid with great bulk. However, according to the boiling curves in all cases of coated nickel wires, it is supposed that the nucleate boiling heat transfer coefficient deteriorates as a result of thermal resistance resulted from the occurrence of nanoparticle deposition. In summary, the coated porous structure of nanoparticles leads to enhance CHF and to decrease boiling heat transfer coefficient.     

Pool boiling characteristics of nanofluid on flat plate based on heater surface analysis

Nucleate pool boiling of Al₂O₃ based aqueous nanofluid on flat plate heater has been studied experimentally. For boiling of nanofluid (< 0.1 vol.%) on heating surface with ratio of average surface roughness to average diameter of particles much less than unity when boiling continue to CHF, the heat transfer coefficient of nanofluid boiling reduces while critical heat flux (CHF) increases. CHF enhancement increased with volume fraction of nanoparticles. Atomic force microscope (AFM) images from boiling surface showed that after boiling of nanofluid the surface roughness increases or decreases depending on initial condition of heater surface. Changes in boiling surface topology during different regions of boiling, wettability and thermal resistance of heater surface owing to nanoparticles deposition cause to variations in nanofluids boiling performance.     

Sorption and agglutination phenomenon of nanofluids on a plain heating surface during pool boiling

The pool nucleate boiling heat transfer experiments of water (H₂O) based and alcohol (C₂H₅OH) based nanofluids and nanoparticles-suspensions on the plain heated copper surface were carried out. The study was focused on the sorption and agglutination phenomenon of nanofluids on a heated surface. The nanofluids consisted of the base liquid, the nanoparticles and the surfactant. The nanoparticles-suspensions consisted of the base liquid and nanoparticles. The both liquids of water and alcohol and both nanoparticles of CuO and SiO₂ were used. The surfactant was sodium dodecyl benzene sulphate (SDBS). The experimental results show that for nanofluids, the agglutination phenomenon occurred on the heated surface when the wall temperature was over 112 °C and steady nucleated boiling experiment could not be carried out. The reason was that an unsteady porous agglutination layer was formed on the heated surface. However, for nanoparticles-suspensions, no agglutination phenomenon occurred on the heating surface and the steady boiling could be carried out in the whole nucleate boiling region. For the both of alcohol based nanofluids and nano-suspensions, no agglutination phenomenon occurred on the heating surface and steady nucleate boiling experiment could be carried out in the whole nucleate boiling region whose wall temperature did not exceed 112 °C. The boiling heat transfer characteristics of the nanofluids and nanoparticles-suspensions are somewhat poor compared with that of the base fluids, since the decrease of the active nucleate cavities on the heating surface with a very thin nanoparticles sorption layer. The very thin nanoparticles sorption layer also caused a decrease in the solid–liquid contact angle on the heating surface which leaded to an increase of the critical heat flux (CHF).     

Boiling characteristics of carbon nanotube suspensions under sub-atmospheric pressures

An experimental study was performed to understand the pool boiling heat transfer of deionized water-based carbon nanotube (CNT) suspensions on a flat copper surface under atmospheric and sub-atmospheric pressures. Experimental results indicate that the addition of CNT in the base liquid can apparently enhance both the heat transfer coefficient (HTC) and the critical heat flux (CHF). The pressure has great impacts on both the HTC and the CHF enhancement of CNT suspensions and the both increase significantly with the decrease of the pressure. The CNT mass concentration of CNT suspensions also has strong influences on both the HTC and the CHF of CNT suspensions and there exists an optimal CNT mass concentration corresponding to the maximum heat transfer enhancement. Besides, the effects of the surface characteristics of the heated surface on both the HTC and the CHF of CNT suspensions were also investigated.     

Effects of Al2O3/R-123 nanofluids containing C19H40 core–shell phase change materials on critical heat flux

In this paper, the curiosity is coming from how to bring out the fluidic capability of nanofluids (fluid itself) for critical heat flux (CHF) enhancement away from surface deposition effects such as improved wettability. The pool boiling characteristics of dilute dispersions of alumina and the microencapsulated C₁₉H₄₀ phase change material (MPCM) in R-123 were studied. Whereas other nanofluid studies only reported that a significant enhancement of CHF was achieved by buildup of a porous layer of nanoparticles on the heater surface during nucleate boiling, it was found that the additional CHF enhancement of 24% occurred with the MPCM compared to alumina nanomaterials. With solid–liquid phase changes, PCMs in suspension delay the occurrence of CHF by absorbing heat around from the heater, nucleate bubbles and merged bubbles while PCM shells prevent leakage of molten cores and allows the return to solid with exchanges of heat at some distances. The present study found that PCMs could make fluidic effects of nanofluid not relying on the surface depositions.     

Boiling time effect on CHF enhancement in pool boiling of nanofluids

Using TiO₂–water nanofluids as the test liquid, pool boiling experiments were carried out to investigate the dependence of the nucleate boiling heat transfer, surface wettability and critical heat flux (CHF) on the boiling time in nanofluids. In the experiments performed at sufficiently high nanoparticle concentrations, the boiling heat transfer first degraded, then improved, and finally reached an equilibrium state. It was hence supposed that the present nanofluids had competing effects to deteriorate and enhance the nucleate boiling heat transfer. As for the surface wettability and CHF, the static contact angle asymptotically decreased whilst the CHF asymptotically increased with an increase in the boiling time. The maximum CHF enhancement measured in the present experiments was 91%, and strong correlation was found between the contact angle and the CHF. Although the boiling time needed to achieve the maximum CHF enhancement was less than a minute at high particle concentrations, a longer time of the order of 1 h was necessary at the lowest particle concentration tested in this work. This experimental result indicated that sufficient attention should be paid to the boiling time effect particularly in industrial applications of nanofluids to emergency cooling.     

Nucleate boiling on the superhydrophilic surface with a small water impingement jet

In this study, the coating process on the copper surface with titanium dioxide (TiO₂) has been introduced. The coated surface exhibits extremely high affinity for water and the solid–liquid contact angle decreases nearly to zero by exposing the surface to ultra-violet light. This superhydrophilic characteristic was applied to nucleate boiling heat transfer of water jet impingement on a flat heated plate. By making use of this special heat transfer surface, the nucleate boiling heat transfer and the critical heat flux (CHF) of a bar water jet impingement on a large flat superhydrophilic surface was experimentally investigated. The experimental data were measured in a steady state. The purified water was employed as the working liquid. Three main influencing factors, i.e., subcooling, impact velocity and the surface coating condition, were changed and their effects on the nucleate boiling heat transfer and the CHF were investigated. The empirical correlations were obtained for predicting the CHF of steady boiling for a small round water jet impingement on a large flat superhydrophilic surface. The experimental results show that the CHF on the superhydrophilic surface is about 30% higher than that on conventional copper surface by decreasing the solid–liquid contact angle.     

A nucleate boiling limitation model for the prediction of pool boiling CHF

A nucleate boiling limitation model which is applicable to the heat transfer prediction in the nucleate boiling region and the CHF was proposed for a pool boiling. The present model was developed based on the direct observations of the physical boiling phenomena. The predicted boiling curves for the nucleate boiling region agree well with both the vertical and the horizontal surface data for all the contact angles. The predicted CHF for the vertical surface also agrees well with the experimental data, but the present model underpredicts the CHF by about 30% for the horizontal surface data.     

Behavioral study of alumina nanoparticles in pool boiling heat transfer on a vertical surface

Experiments were carried out to investigate the pool boiling of alumina‐water nanofluid at 0.1 g/l to 0.5 g/l of distilled water, and the nucleate pool boiling heat transfer of pure water and nanofluid at different mass concentrations were compared at and above the atmospheric pressure. At atmospheric pressure, different concentrations of nanofluids display different degrees of deterioration in boiling heat transfer. The effect of pressure and concentration of nanoparticles revealed significant enhancement in heat flux and deterioration in pool boiling. The heat transfer coefficient of 0.5 g/l alumina‐water nanofluid was compared with pure water and clearly indicates deterioration. At all pressures the heat transfer coefficients of the nanofluid were lower than those of pure water. Experimental observation revealed particles coating over the heater surface and subsequent SEM inspection of the heater surface showed nanoparticles coating on the surface forming a porous layer. To substantiate the nanoparticle deposition and its effect on heat flux, investigation was done by measuring the surface roughness of the heater surface before and after the experiment. While SEM images of the heater surface revealed nanoparticle deposition, surface roughness of the heater surface confirmed it. Based on the experimental investigations it can be concluded that an optimum thickness of nanoparticles coating favors an increase in heat flux. Higher surface temperature due to the presence of nanoparticles coating results in the deterioration of boiling heat transfer. © 2011 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.20365     

Direct numerical simulations of pool boiling curves including heater's thermal responses and the effect of vapor phase's thermal conductivity

Effects of heater's thermal properties and vapor phase's thermal conductivity on saturated pool boiling above a large horizontal heater are simulated numerically based on an improved pseudo-potential liquid-vapor phase change lattice Boltzmann model. A transient conjugate heat transfer problem is under consideration, where the conjugate thermal boundary condition is imposed and heater's thermal responses during boiling processes are investigated. Saturated pool boiling curves from onset of nucleate boiling to critical heat flux (CHF), to transition boiling regime to stable film boiling regime are obtained numerically. It is found that the simulated critical heat flux (CHF) agrees reasonably well with existing analytical models. Also, the simulated boiling heat fluxes in stable film boiling regime are shown to be in good agreement with the existing analytical solution. Thus, this improved pseudo-potential liquid-vapor phase change lattice Boltzmann model is quantitatively validated. Simulation results demonstrate that there is significant maldistribution in temperature distribution near the top of heater surface in nucleate boiling regime, CHF point and transition boiling regime. As a result, two-dimensional heat conduction can not be ignored when evaluating heat flux closely beneath the heater's top surface. It is also shown that both heater's thermal conductivity and thermal mass (the product of density and specific heat at constant pressure) have no effect on CHF value as well as the boiling curve in nucleate boiling regime and film boiling regime for a thick heater. However, the transition boiling regime of the boiling curve moves to the left with the increasing heater thermal conductivity and heater thermal mass for a thick heater. Increasing the vapor theraml conductivity has no effect on CHF but would increase boiling heat flux in film boiling regime, and hence shortening the transition boiling regime.     

Pool boiling heat transfer of water and nanofluid outside the surface with higher roughness and different wettability

In order to investigate the effect of surface wettability on the pool boiling heat transfer, nucleate pool boiling experiments were conducted with deionized water and silica based nanofluid. A higher surface roughness value in the range of 3.9 ~ 6.0μm was tested. The contact angle was from 4.7° to 153°, and heat flux was from 30kW/m² to 300kW/m². Experimental results showed that hydrophilicity diminish the boiling heat transfer of silica nanofluid on the surfaces with higher roughness. As the increment of nanofluid mass concentration from 0.025% to 0.1%, a further reduction of heat transfer coefficient was observed. For the super hydrophobic surface with higher roughness (contact angle 153.0°), boiling heat transfer was enhanced at heat flux less than 93 kW/m², and then the heat transfer degraded at higher heat flux.     

Measurement of surface dryout near heating surface at high heat fluxes in subcooled pool boiling

The authors have conducted measurements of liquid–vapor behavior in the vicinity of a heating surface for saturated and subcooled pool boiling on an upward-facing copper surface by using a conductance probe method. A previous paper [A. Ono, H. Sakashita, Liquid–vapor structure near heating surface at high heat flux in subcooled pool boiling, Int. J. Heat Mass Transfer 50 (2007) 3481–3489] reported that thicknesses of a liquid rich layer (a so-called macrolayer) forming in subcooled boiling are comparable to or thicker than those formed near the critical heat flux (CHF) in saturated boiling. This paper examines the dryout behavior of the heating surface by utilizing the feature that a thin conductance probe placed very close to the heating surface can detect the formation and dryout of the macrolayer. It was found that the dryout of the macrolayer formed beneath a vapor mass occurs in the latter half of the hovering period of the vapor mass. Two-dimensional measurements conducted at 121 grid points in a 1-mm × 1-mm area at the center of the heating surface showed that the dryout commences at specific areas and spreads over the heating surface as the heat flux approaches the CHF. Furthermore, transient measurements of wall void fractions from nucleate boiling to transition boiling were conducted under the transient heating mode, showing that the wall void fraction has small values (<10%) in the nucleate boiling region, and then steeply increases in the transition boiling region. These findings strongly suggest that the macrolayer dryout model is the most appropriate model of the CHF for saturated and subcooled pool boiling of water on upward facing copper surfaces.     

Nucleate pool boiling heat transfer of TiO2–R141b nanofluids

Nucleate pool boiling heat transfer of a refrigerant-based-nanofluid was investigated at different nanoparticle concentrations and pressures. TiO₂ nanoparticles were mixed with the refrigerant HCFC 141b at 0.01, 0.03 and 0.05 vol%. The experiment was performed using a cylindrical copper tube as a boiling surface. Pool boiling experiments of nanofluid were conducted and compared with that of the base refrigerant. The results indicate that the nucleate pool boiling heat transfer deteriorated with increasing particle concentrations, especially at high heat fluxes. At 0.05 vol%, the boiling heat transfer curves were suppressed. At high pressures of 400 and 500 kPa, the boiling heat transfer coefficient at a specific excess temperature was almost the same.     

Effect of pressure, subcooling, and dissolved gas on pool boiling heat transfer from microporous, square pin-finned surfaces in FC-72

The present research is an experimental study of the effects of pressure, subcooling, and non-condensable gas (air) on the pool nucleate boiling heat transfer performance of microporous enhanced finned surfaces. The test surfaces, solid copper blocks with 1-cm² bases and 5×5 square pin-fin arrays of 2, 4 and 8 mm fin lengths, were immersed in FC-72. The test conditions included an absolute pressure range of 30-150 kPa and a subcooling range of 0 (saturation) to 50 K. Effects of these parameters on nucleate boiling and critical heat flux (CHF) were investigated. In addition, differences between pure subcooled and gas-saturated conditions as well as horizontal and vertical base orientations were also investigated. Results showed that, in general, the effects of pressure and subcooling on both nucleate boiling and CHF were consistent with previously tested flat surface results, however, subcooling was found to significantly affect the high heat flux region of the microporous finned surfaces nucleate boiling curves. The relative enhancement of CHF from increased subcooling was greater for the microporous surface than the plain surface but less than a microporous flat surface. The horizontal orientation (horizontal base/vertical fins) was found to be slightly better than the vertical orientation (vertical base/horizontal fins). Correlations for both nucleate boiling and CHF for the microporous surfaces were also developed.     

Pool boiling heat transfer of functionalized nanofluid under sub-atmospheric pressures

A water-based functionalized nanofluid was made by surface functionalizing the ordinary silica nanoparticles. The functionalized nanoparticles were water-soluble and could still keep dispersing well even at the mass concentration of 10% and no sedimentation was observed. An experimental study was carried out to investigate the pool boiling heat transfer characteristics of functionalized nanofluid at atmospheric and sub-atmospheric pressures. The same work was also performed for DI water and traditional nanofluid consisted of water and ordinary silica nanoparticles for the comparison. Experimental results show that there exist great differences between pool boiling heat transfer characteristics of functionalized and traditional nanofluid. The differences mainly result from the changes of surface characteristics of the heated surface during the boiling. A porous deposition layer exists on the heated surface during the boiling of traditional nanofluid; however, no layer exists for functionalized nanofluid. Functionalized nanofluid can slightly increase the heat transfer coefficient comparing with the water case, but has nearly no effects on the critical heat flux. It is mainly due to the changes of the thermoproperties of nanofluids. Traditional nanofluid can significantly enhance the critical heat flux, but conversely deteriorates the heat transfer coefficient. It is mainly due to effect of surface characteristics of the heated surface during the boiling. Therefore, the pool boiling heat transfer of nanofluids is governed by both the thermoproperties of nanofluids and the surface characteristics of the heated surface.     

Surface wettability change during pool boiling of nanofluids and its effect on critical heat flux

The pool boiling characteristics of dilute dispersions of alumina, zirconia and silica nanoparticles in water were studied. Consistently with other nanofluid studies, it was found that a significant enhancement in critical heat flux (CHF) can be achieved at modest nanoparticle concentrations (<0.1% by volume). Buildup of a porous layer of nanoparticles on the heater surface occurred during nucleate boiling. This layer significantly improves the surface wettability, as shown by a reduction of the static contact angle on the nanofluid-boiled surfaces compared with the pure-water-boiled surfaces. A review of the prevalent CHF theories has established the nexus between CHF enhancement and surface wettability changes caused by nanoparticle deposition. This represents a first important step towards identification of a plausible mechanism for boiling CHF enhancement in nanofluids.     

Investigation of pool boiling of nanofluids using artificial neural networks and correlation development techniques

The nucleate pool boiling heat transfer characteristics of TiO₂ nanofluids are investigated to determine the important parameters' effects on the heat transfer coefficient and also to have reliable empirical correlations based on the neural network analysis. Nanofluids with various concentrations of 0.0001, 0.0005, 0.005, and 0.01 vol.% are employed. The horizontal circular test plate, made from copper with different roughness values of 0.2, 2.5 and 4 μm, is used as a heating surface. The artificial neural network (ANN) training sets have the experimental data of nucleate pool boiling tests, including temperature differences between the temperatures of the average heater surface and the liquid saturation from 5.8 to 25.21 K, heat fluxes from 28.14 to 948.03 kW m^− 2. The pool boiling heat transfer coefficient is calculated using the measured results such as current, voltage, and temperatures from the experiments. Input of the ANNs are the 8 numbers of dimensional and dimensionless values of the test section, such as thermal conductivity, particle size, physical properties of the fluid, surface roughness, concentration rate of nanoparticles and wall superheating, while the outputs of the ANNs are the heat flux and experimental pool boiling heat transfer coefficient from the analysis. The nucleate pool boiling heat transfer characteristics of TiO₂ nanofluids are modeled to decide the best approach, using several ANN methods such as multi-layer perceptron (MLP), generalized regression neural network (GRNN) and radial basis networks (RBF). Elimination process of the ANN methods is performed together with the copper and aluminum test sections by means of a 4-fold cross validation algorithm. The ANNs performances are measured by mean relative error criteria with the use of unknown test sets. The performance of the method of MLP with 10-20-1 architecture, GRNN with the spread coefficient 0.7 and RBFs with the spread coefficient of 1000 and a hidden layer neuron number of 80 are found to be in good agreement, predicting the experimental pool boiling heat transfer coefficient with deviations within the range of ± 5% for all tested conditions. Dependency of output of the ANNs from input values is investigated and new ANN based heat transfer coefficient correlations are developed, taking into account the input parameters of ANNs in the paper.     

CaCO3垢的形成对池核沸腾传热的影响

在一水平圆形加热表面上通过实验考察了饱和池核沸腾和过冷池核沸腾时CaCO3垢的生成对传热的影响。结果表明，在饱和池核沸腾和过冷池核沸腾的初始阶段沸腾传热系数均呈先降低后升高、达到一个最大值后稳定降低的趋势，而且在初始阶段出现了负污垢热阻现象。在相同操作条件下，过冷池核沸腾传热系数明显低于饱和池核沸腾传热系数。在分析污垢的生成和生长影响表面活化中心的基础上，对污垢的形成对沸腾传热的影响进行了机理分析。