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锂铝硅系微晶玻璃是一种具有优异的光学、力学性能的微晶玻璃材料。本文制备了以透锂长石和二硅酸锂为主晶相的锂铝硅系透明微晶玻璃,并通过DSC、XRD与SEM研究了MgO含量对该微晶玻璃析晶行为及结构的影响,利用维氏硬度、抗弯强度等测试方法研究了MgO含量对该微晶玻璃力学性能的影响。结果表明,当MgO含量(质量分数)从0%增加至3%,基础玻璃的析晶温度从771 ℃降低至729 ℃,析晶能力增强,微晶玻璃的结晶度从62%增加至72%,晶粒尺寸从29 nm增大至33 nm。随着MgO含量的增加,微晶玻璃中会析出β-石英固溶体,抗弯强度增大。 相似文献
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人工神经网络在锂铝硅超低膨胀透明微晶玻璃热处理研究中的应用 总被引:3,自引:0,他引:3
人工神经网络在锂铝硅超低膨胀透明微晶玻璃热处理研究中的应用陈建华,孙方明(盐城工业专科学校224003)(华东理工大学200237)ArtificialNeuralNetworksAppliedtoStudyofHeatTreatmentofLith... 相似文献
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与传统的钠钙硅玻璃和高铝玻璃相比,锂铝硅玻璃具有网络结构致密、弹性模量较高和适宜两步法化学钢化等特点,被视为第三代高强玻璃基板,可用作电子信息产品盖板、航空透明器件以及舰船、特种车辆的观察窗口等。目前,锂铝硅玻璃的研究主要涉及:(1)探究锂铝硅玻璃的“组成-结构-性能”本构关系,为设计优化高性能锂铝硅玻璃提供理论指导和性能预测;(2)改进现有溢流和浮法成型方法和装备,满足大尺寸、多厚度和高尺寸精度锂铝硅玻璃成型需要;(3)研究锂铝硅玻璃的两步法化学增强方法,解决表面压应力和应力层深度同步提升难题,显著提高玻璃强度、硬度和抗跌落性能。本文基于上述三个方面综述了锂铝硅玻璃的国内外研究进展。 相似文献
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环境温度的变化,会引起材料的膨胀与收缩,在材料中产生热应力,会影响材料使用。零膨胀锂铝硅透明微晶玻璃卓越的热学性能,优良的光学和机械性能使之成为不可或缺的综合材料。本文主要介绍了零膨胀LAS系透明微晶玻璃的主要形态和结构特征,热学、光学性能以及应用现状,并提出了研究中存在的问题及今后发展的方向。 相似文献
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锂铝硅透明微晶玻璃的发朦现象研究陈建华,孙方明(盐城工业专科学校224003)(华东理工大学200237)StudyonHazedSamplesofTransparentLithiumAluminosilicateGlass-Ceramics¥Che... 相似文献
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锂铝硅透明微晶玻璃着色研究 总被引:3,自引:0,他引:3
引入Cr2O3、CoO、NiO、MnO2等过渡金属氧化物对低膨胀锂铝硅透明微晶玻璃进行着色研究,结果表明,微晶玻璃与其母体玻璃相比,颜色有明显的不同,主波长向长波方向移动。研究还发现,在从核化阶段到晶化阶段的过程中颜色变化最为明显,而在核化阶段和晶化阶段颜色没有发生明显的变化。同时运用配位场理论和光散射原理来解释这种颜色变化的原因。 相似文献
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Maria Laczka Karolina Laczka Katarzyna Cholewa‐Kowalska Christoph Appert 《Journal of the American Ceramic Society》2014,97(2):361-364
A glass composition in the Li2O–Al2O3–SiO2 (LAS)‐ternary phase diagram is presented, which enables the crystallization of Li2Si2O5 as well as LiAlSi2O6 upon a well‐defined heat treatment. Li2Si2O5 is the minor crystalline phase in the glass‐ceramic and generates through the bulk strengthening of the LAS glass‐ceramic. A flexural strength as higher as 400 MPa is measured in the proposed glass‐ceramic formulation, thus outperforming conventional LAS‐glass‐ceramics. A combination of the presence of those two crystalline phases of very different mechanical properties and coefficient of thermal expansion as well as the microstructure are believed to contribute largely to the enhancement of the measured properties. 相似文献
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短切SiC纤维含量对SiC_(sf)/LAS复合材料性能的影响 总被引:1,自引:0,他引:1
用热压烧结法制备了不同纤维含量的SiCsf/LAS玻璃陶瓷复合材料,研究了该复合材料的微观结构、力学性能和微波介电性能。结果表明:随着SiC纤维含量的增加,SiCsf/LAS材料的抗弯强度先增加后降低,最大值为104MPa。由于碳界面层的形成,SiCsf/LAS比LAS具有更高的介电常数。当SiC短切纤维的质量分数为1.5%时,SiCsf/LAS复合材料介电常数具有最大值,其实部ε′和虚部ε″均值分别为48和66,并具有明显的频散效应。 相似文献
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《Journal of the European Ceramic Society》2006,26(15):3301-3306
Dense nanocrystalline glass ceramics of the Li2O–Al2O3–SiO2 (LAS) system were obtained by spark plasma sintering (SPS) of powders prepared by sol–gel method. The low thermal expansion LAS glass ceramic was chosen as host matrix for erbium ions. ZrO2 was added both as a nucleating agent and as a possible good environment for the rare earth. The developed crystalline phases were analysed by X-ray diffraction (XRD) and the amorphous phase was quantified. Scanning and transmission electron microscopy (SEM, TEM) was used to investigate the microstructure. A different behaviour during the crystallisation process was observed between the sample prepared through the sintering of powders and the glass produced by the melting technique. A photoluminescence characterisation was also performed. 相似文献
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《应用陶瓷进展》2013,112(4):227-231
AbstractGlass ceramics in the Li2O–Al2O3–SiO2 system have been synthesised to produce bulk materials grown in a glass phase via quenching followed by controlled crystallisation. The crystallisation and microstructure of Li2O–Al2O3–SiO2 (LAS) glass–ceramic with nucleating agents (B2O3 and/or P2O5) are investigated by differential thermal analysis, X-ray diffraction and scanning electron microscopy and the effects of B2O3 and P2O5 on the crystallisation of LAS glass are also analysed. The introduction of both B2O3 and P2O5 promotes the crystallisation of LAS glass by decreasing the crystallisation temperature and adjusting the crystallisation kinetic parameters, allows a direct formation of β spodumene phase and as a result, increases the crystallinity of the LAS glass ceramic. Microstructural observations show that the randomly oriented, nanometre sized crystalline is found with residual glass concentrated at crystallite boundaries. Furthermore, it is interesting that codoping of B2O3 and P2O5 creates not much effect on the crystallisation temperature. The dielectric properties of the glass–ceramics formed through controlled crystallisation have a strong dependence on the phases that are developed during heat treatment. The dielectric constant is continuously increased and the dielectric loss is decreased with addition of additives where mobile alkali metal ions (e.g. Li+) are incorporated in a crystal phase and minimise the residual glass phase. 相似文献
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Franck Doreau Hlne Maupas Dominique Kervadec Pierre Ruterana Jean Vicens Jean-Louis Chermant 《Journal of the European Ceramic Society》1995,15(12):1235-1247
In this paper a critical examination of the diagrams of different silicate systems is presented: LAS, MAS YAS, MLAS and YMAS (A: alumina; L: lithia; M: magnesia; S: silica; Y: yttria). These systems have been developed to fabricate ceramic matrix composites based on a glass ceramic matrix, because of their low thermal expansion coefficient and good mechanical properties up to 1000 °C. The observations and microanalyses, by transmission electron microscopy, of different batches of MLAS and YMAS confirm the complexity of the systems investigated. 相似文献
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密封连接石英玻璃被广泛应用于航空航天、半导体加工以及微机电系统真空连接等领域。改进的低膨胀Li2O-Al2O3-SiO2(LAS)系微晶玻璃可以用于封接石英玻璃,但存在流动性不佳的难题。本文通过掺入WO3对LAS系微晶玻璃进行改性,利用线膨胀系数分析仪、差示扫描量热仪、X射线衍射仪、高温烧结影像仪、扫描电镜,研究了掺入WO3后LAS玻璃封接石英玻璃的机理。结果表明:WO3对LAS玻璃的析晶产生先增强后削弱的影响; WO3掺量越大,热膨胀系数越大,当掺量达到5.0%(质量分数)时,热膨胀系数提升至5.69×10-7 ℃-1;流动性与润湿性随着掺量增加而提升,铺展面积随掺量增加而增大,润湿角随掺量增加而减小,有效改善了LAS玻璃本身流动性不足的问题;LAS玻璃与石英玻璃之间主要是通过化学元素迁移实现封接。 相似文献
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低熔封接微晶玻璃是一种先进的焊接材料,由于其具有低的熔化温度和封接温度,优良的机械强度和化学稳定性,而在很多领域中得到广泛的应用,实现了玻璃、陶瓷、金属、半导体间的相互封接。综述了无铅低熔封接微晶玻璃的研究现状,展望了无铅低熔封接微晶玻璃今后的研究发展方向。 相似文献
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The sintering and crystallization of spodumene-cordierite glass-ceramics that are made from mixtures of Li2 O-Al2 O3 -SiO2 (LAS) and MgO-Al2 O3 -SiO2 (MAS) glass powders were investigated. Pure LAS and MAS powders have good sinterability. However, the densification of LAS was drastically reduced when small amounts of MAS were added. When larger amounts of MAS were added, the amount of densification further increased. The decrease in the Li2 O content in the LAS glass promoted the densification of the mixed glass samples. The above-mentioned results can be explained by examining the crystallization temperature, which is influenced by the interactions between the LAS and MAS glass particles. The lower the temperature of crystallization, the less sintering occurred. For the sintered samples, the phase that crystallized from the MAS glass was alpha-cordierite, and that which crystallized from the LAS glass was ß-spodumene or high-quartz solid solution, depending on the Li2 O content in the LAS glass. 相似文献