A critical review on the current technologies for the generation,storage, and transportation of hydrogen

Hydrogen production, storage, and transportation are the key issues to be addressed to realize a so-called clean and sustainable hydrogen economy. Various production methods, storage methods, and hydrogen transportations have been listed in the literature, along with their limitations. Therefore, to summarize the state of the art of these proposed technologies, a detailed discussion on hydrogen production, storage, and transportation is presented in this review. Also, to discuss the recent advancements of these methods including, hydrogen production, storage, and transportation on their kinetics, cyclic behavior, toxicity, pressure, thermal response, and cost-effectiveness. Moreover, new techniques such as ball milling, ultrasonic irradiation, ultrasonication, alloying, additives, cold rolling, alloying, and plasma metal reaction have been highlighted to address those drawbacks.Furthermore, the development of modern hydrogen infrastructure (reliability, safety, and low cost) is needed to scale up hydrogen delivery. This review summarizes promising techniques to enhance kinetic hydrogen production, storage, and transportation. Nevertheless, the search for the materials is still far from meeting the aimed target for production, storage, and transportation application. Therefore, more investigations are needed to identify promising areas for future H₂ production, storage, and transportation developments.     

Hydrogen supply chain and challenges in large-scale LH2 storage and transportation

Hydrogen is considered to be one of the fuels of future and liquid hydrogen (LH2) technology has great potential to become energy commodity beyond LNG. However, for commercial widespread use and feasibility of hydrogen technology, it is of utmost importance to develop cost-effective and safe technologies for storage and transportation of LH2 for use in stationary applications as well as offshore transportation. This paper reviews various aspects of global hydrogen supply chain starting from several ways of production to storage and delivery to utilization. While each these aspects contribute to the overall success and efficiency of the global supply chain, storage and delivery/transport are the key enablers for establishing global hydrogen technology, especially while current infrastructure and technology are being under development. In addition, while all storage options have their own advantages/disadvantages, the LH2 storage has unique advantages due to the familiarity with well-established LNG technology and existing hydrogen technology in space programs. However, because of extremely low temperature constraints, commercialization of LH2 technology for large-scale storage and transportation faces many challenges, which are discussed in this paper along with the current status and key gaps in the existing technology.     

氢——未来的绿色燃料

石油燃料在几十年内逐渐耗尽,而燃料电池以其高效、清洁的特点将会成为未来交通的推动力.本文对可再生绿色能源载体--氢的研制方法进行了研究,详细阐述了两种制氢的工艺过程--热化学工艺和电解水工艺过程.给出了氢气的四种储存方法,其中金属氢化物和碳质吸附储氢两种方法,由于安全可靠,储存效率较高,是目前广泛研究的储氢方式.本文综述了氢能系统的各项技术,并对未来的发展趋势作了展望.     

Hydrogen strategy as an energy transition and economic transformation avenue for natural gas exporting countries: Qatar as a case study

In the wake of the apparent impacts of climate change, the world is searching for clean energy transformations and a consequent transition to a carbon-neutral economy and life. The intermittent nature of renewable energy sources introduces several risks, and efficient energy storage technologies are developed to circumvent such issues. However, these storage methods also come with additional costs and uncertainties. Hydrogen is considered a viable option as an energy carrier and storage medium, offering versatility to the energy mix. This study reviews hydrogen production, storage, transmission, and applications avenues, describes the current global hydrogen market and compares national hydrogen strategies. A framework for evaluating the relative competitiveness of natural gas-exporting countries as hydrogen exporters is developed. Qatar's national hydrogen strategy should focus on blue and turquoise hydrogen production in the short/medium term with a mix of green hydrogen in the future term and investment in technological research and development to compete with other gas exporters that have abundant renewable energy potential.     

The future of hydrogen energy: Bio-hydrogen production technology

The widespread use of non-renewable energy has caused serious environmental problems such as global warming and the depletion of fossil fuels. Hydrogen, as a well-known carbon-free gaseous fuel, has become the most promising energy carrier for future energy. Hydrogen has an excellent mass-basis calorific value and no carbon atom contained, which makes it to be an attractive fuel for various power devices (like the internal combustion engine, gas turbine, and fuel cell). Nowadays, the production of hydrogen is still predominated by fossil-based techniques, which is considered undesirable due to low conversion efficiency and release of greenhouse gases. It is necessary to find green and sustainable hydrogen production routes with low energy consumption and cost. In this paper, the different hydrogen production technologies via fossil routes or non-fossil routes are reviewed in general, and it is found that bio-hydrogen production has certain environmental advantages and broad prospects compared with other hydrogen production technologies. Then, the characteristics and research status of different bio-hydrogen production technologies are discussed in depth. It is found that each bio-hydrogen production technique has its own advantages, challenges, and applicability. The economic analysis of bio-hydrogen energy is also performed from the aspects of production, storage, and transportation. The results show that bio-hydrogen production technology could be a good possibility way for producing renewable hydrogen, which is of high efficiency and thus competitive over other hydrogen production methods both in economics and environmental benefits.     

Recent advancements in the hydrogen value chain: Opportunities,challenges, and the way Forward–Middle East perspectives

This work highlights the recent advancements in the hydrogen value chain for the Middle East region by evaluating the feedstock, production technologies, storage options, delivery routes, and end-user applications. It discusses the national strategies for implementing the hydrogen value chain in the Middle East from 2020 to 2050. The challenges in the hydrogen value chain from techno-economic, safety, and social perspectives are also discussed in this study. Hydrogen production technologies are analyzed and compared. Steam-methane reforming has a high efficiency of 74% and a low hydrogen cost of $2.27/kg-H₂, making it the most dominant technology for hydrogen production. Electrolysis has a lower efficiency of 60% and a higher hydrogen cost of $10.30/kg-H_2, with more potential for further improvments.Furthermore, hydrogen storage options are compared. Compressed gas and cryogenic liquid options have the highest storage capacities of 39.2 and 70.9 kg/m³, respectively. However, they are not entirely safe due to the high flammability of hydrogen. Two hydrogen explosion incidents are also reported, the first explosion at the Fukushima nuclear power plant in 2011 and the second in the Hindenburg fire in 1937. Metal hydrides propose a safer and more effective option, but they are still under research and development. For H₂ transportation options, pipelines and cryogenic tankers are the most conventional and efficient options (above 99%). Ships have the largest capacity of 10,000 tons per shipment and the maximum investment costs of 465M - 620M$ per barge, but they are not feasible. This review paper will help researchers and practitioners analyze the hydrogen value chain in a more systematic way for further improvements toward more practical applications.     

Safety assessment of envisaged systems for automotive hydrogen supply and utilization

A novel consequence-based approach was applied to the inherent safety assessment of the envisaged hydrogen production, distribution and utilization systems, in the perspective of the widespread hydrogen utilization as a vehicle fuel. Alternative scenarios were assessed for the hydrogen system chain from large scale production to final utilization. Hydrogen transportation and delivery was included in the analysis. The inherent safety fingerprint of each system was quantified by a set of Key Performance Indicators (KPIs). Rules for KPIs aggregation were considered for the overall assessment of the system chains. The final utilization stage resulted by large the more important for the overall expected safety performance of the system. Thus, comparison was carried out with technologies proposed for the use of other low emission fuels, as LPG and natural gas. The hazards of compressed hydrogen-fueled vehicles resulted comparable, while reference innovative hydrogen technologies evidenced a potentially higher safety performance. Thus, switching to the inherently safer technologies currently under development may play an important role in the safety enhancement of hydrogen vehicles, resulting in a relevant improvement of the overall safety performance of the entire hydrogen system.     

Hydrogen energy demonstration plant in Patagonia: Description and safety issues

Hydrogen safety issues and especially hydrogen hazard's address are key points to remove any safety-related barrier in the implementation process of hydrogen energy systems. Demonstrative systems based on hydrogen technologies represent a clear contribution to the task of showing the feasibility of the new technologies and their beneficial capabilities among the public. In this paper, the safety features of the first hydrogen energy demonstrative plant conceived in Latin America are analyzed. The facilities, located in the village of Pico Truncado, Patagonia, Argentina, serve to gain day-to-day experience in the production, storage, distribution, conversion and use of hydrogen in several applications. The plant uses electrolysis to generate pure hydrogen from renewable primary sources, taking advantage of the installed wind power capacity that is continually growing in the region. The installations were designed to accomplish with two primary objectives: total safety assurance and minimization of human errors. Some details of the plant, including a general layout, are presented here, in addition with design criteria, hydrogen hazards, structural precautions, gas monitoring system, existing regulations and safety requirements.     

Hydrogen supply chain architecture for bottom-up energy systems models. Part 2: Techno-economic inputs for hydrogen production pathways

This article is the second paper of a serial study on hydrogen energy system modelling. In the first study, we proposed a stylized hydrogen supply chain architecture and its pathways for the representation of hydrogen systems in bottom-up energy system models. In this current paper, we aim to present and assess techno-economic inputs and bandwidths for a hydrogen production module in bottom-up energy system models. After briefly summarizing the current technological status for each production method, we introduce the parameters and associated input data that are required for the representation of hydrogen production technologies in energy system modelling activities. This input data is described both as numeric values and trend line modes that can be employed in large or small energy system models. Hydrogen production technologies should be complemented with hydrogen storage and delivery pathways to fully understand the system integration. In this context, we will propose techno-economic inputs and technological background information for hydrogen delivery pathways in later work, as the final paper of this serial study.     

Bibliometric analysis of the research on hydrogen economy: An analysis of current findings and roadmap ahead

Based on literature research, this comprehensive analysis of 1275 articles published in the past five decades provides quantitative and objective insight into research trends in the hydrogen economy. Scholars and experts agree that by 2030, hydrogen will play a critical role in energy transition by complementing other renewable energy technologies. We applied indicators such as the Field-Weighted Citation Impact index, cited by and usage count (180 days) to evaluate countries, authors, documents, journals and so on. We also used VOS viewer to visualize the evolving trend using keyword analysis and cluster analysis of documents. Results show that the literature on the hydrogen economy has been recently increasing, particularly from 2016 to 2020. Scopus database was employed to acquire the required data for the study. From preliminary analysis, it was established that from 218 journals, 1275 documents related to hydrogen economy had been published so far. The average publication per year since introducing the term “hydrogen economy” is 6.62 and increasing. The average citation per document is 47.21. There have been 3760 authors so far who have been associated with publications related to a hydrogen economy. Of which 139 authors have written 156 documents individually, and 3621 authors have collaborated to publish 1119 documents, thus forming a collaborative index of 3.24. The International Journal of Hydrogen Energy contributes 40% of the overall publications. In terms of countries, China and United States are the leaders, with 126 papers each. Our analysis shows that the study on hydrogen economy mostly deals with multidisciplinary aspects like hydrogen production, storage, transportation, application, and public policy formulation. We adopted the 180 days usage count offered by the Web of Science database to better understand the research hotspot and evolving trends. It helped us view the existing gaps and potential scope of study that future researchers working on the hydrogen economy can explore. Aspects like pipeline transportation, risk assessment studies, blending, public safety and hazard mitigation can play a vital role in the hydrogen economy research in the future. Cooperation between nations and research institutes should be fostered with cross-disciplinary interchange to boost the hydrogen economy's multidisciplinary growth.     

Perspective on hydrogen energy carrier and its automotive applications

The paper outlines the concept of energy carrier with a particular reference to hydrogen, in view of a more disseminated employment in the field of automotive applications. In particular hydrogen production is analyzed considering the actual state of the art and recent technologies applied in production from the primary sources (fossil fuels, renewable energies, and water electrolysis). Then the problem of hydrogen storage is considered both from technical and economical point of views. In particular, differences between physical and chemical storage are here considered with a particular glance to the most innovative technologies including carbon nanostructures. A review on the main problems in storage and transportation is then shown with a particular attention given to infrastructures costs that perhaps will address particular choices for the technologies of the next future. Automotive applications are called out, accounting the main current technologies and notes on fueling station for hydrogen fed vehicle. The discussion of hydrogen safety in automotive put in evidence the needs for sophisticated sensors, but a comparison with the safety of gasoline and fire risks, evidences that some common incertitudes on hydrogen usage should be overcome. Some other safety issues are introduced in the section of hydrogen transportation. An overview of costs related hydrogen production, storage and transportation is finally given. This aspect is of a capital importance for the future dissemination of the hydrogen energy carrier.     

Large-scale compressed hydrogen storage as part of renewable electricity storage systems

Storing energy in the form of hydrogen is a promising green alternative. Thus, there is a high interest to analyze the status quo of the different storage options. This paper focuses on the large-scale compressed hydrogen storage options with respect to three categories: storage vessels, geological storage, and other underground storage alternatives. In this study, we investigated a wide variety of compressed hydrogen storage technologies, discussing in fair detail their theory of operation, potential, and challenges. The analysis confirms that a techno-economic chain analysis is required to evaluate the viability of one storage option over another for a case by case. Some of the discussed technologies are immature; however, this does not rule out these technologies; rather, it portrays the research opportunities in the field and the foreseen potential of these technologies. Furthermore, we see that hydrogen would have a significant role in balancing intermittent renewable electricity production.     

中国规模化氢能供应链的经济性分析

    目的   文章研究规模化氢能供应链的经济性,未来十年,氢能作为战略能源将会重构社会的能源结构,并影响未来社会能源总成本。预测大规模氢能时代的制氢、储氢、输氢、分销、应用的成本,和市场化的趋势有着重要的意义。氢气由于高储运成本,用途、品质的多样性,氢气市场存在分层结构。分析氢能与常规能源的可比价格,提出原油当量价格(POE)的概念,预测未来氢能价格的合理区间。解决供应链问题是获得低成本氢能的关键,由此提出干线门站模式,解决绿氢的资源分布与长距离输送氢能的问题。    方法   利用平准化氢气成本(LCOH)分析模型,测算大型光伏制氢管道输氢LCOH,分析大规模可再生能源制氢输氢的经济性。利用氢能供应链的储、输、卸六个象限成本公式,分析气氢、液氢、固氢、有机氢、管道氢等不同储运技术,短距离氢储运成本,分析门站后输氢的场景和成本,预测短距离输氢的成本趋势。    结果   研究表明:我国有丰富的绿氢资源,随着投资下降,预计大规模绿氢管道输送的城市门站LCOH将低于2.0 RMB/Nm3,将成为未来主要的氢源。当前,氢储运技术气氢、液氢、甲醇、合成氨、有机氢、固氢、管道氢,随着规模的增加实现远距离输送。在现有的技术下,城市门站到终端的输送,氢短距输送（<100 km）测算成本都在1.2 RMB/Nm3以下,由此评估的氢能供应链的总成本,干线门站模式下氢能最终到达终端的价格约为3.2 RMB/Nm3,当量价格POE与汽油价格接近,考虑燃料电池的能效因素,氢能汽车在4.0 RMB/Nm3的氢价下,具有比汽油车更低的百公里燃料费用。    结论   因此,氢能作为战略能源,在无补贴的情况下实现中国氢能源的绿氢替代,在技术经济上是可行的。     

Wind energy and the hydrogen economy—review of the technology

The hydrogen economy is an inevitable energy system of the future where the available energy sources (preferably the renewable ones) will be used to generate hydrogen and electricity as energy carriers, which are capable of satisfying all the energy needs of human civilization. The transition to a hydrogen economy may have already begun. This paper presents a review of hydrogen energy technologies, namely technologies for hydrogen production, storage, distribution, and utilization. Possibilities for utilization of wind energy to generate hydrogen are discussed in parallel with possibilities to use hydrogen to enhance wind power competitiveness.     

Hydrogen in energy transition: A review

The energy transition is not something that awaits us in the next decade. On the contrary, it is a process in which we are already deeply enrolled. The main step towards the creation of a carbon-neutral society is the implementation of renewable energy sources (RES) as replacements for fossil fuels. Given the intermittency of RES, energy storage has an essential role to play in this transition. Hydrogen technology with its many advances was recognized to be the most promising choice. As multiple hydrogen applications were researched relatively recently, the current development of its technology is not yet on the large-scale implementation level. With the increasing number of studies and initiated projects, the utilization of hydrogen's immense ecological potential is to be expected in the next few decades. New innovative solutions of hydrogen technology that includes hydrogen production, storage, distribution, and usage, are permeating all industry sectors. In a rapidly changing world, technological advances bring forth public discussions, that are a deciding factor whether society will be able to adapt and accept those new contributions or reject them. Currently, hydrogen is the best associated with fuel cell electric vehicles which emit only water vapour and warm air, producing no harmful tailpipe emissions. As various scientists are stressing the gravity of climate change effects that are reaching the physical environment, ecosystems, and humanity in general, concern for the future is becoming the main global topic. Consequently, governments are implementing new sustainable policies that promote RES as a substitute for fossil fuels. Increasing progress in hydrogen technology instigated nations worldwide to incorporate hydrogen in their energy legislations and national development plans, which resulted in numerous national hydrogen strategies. This work shows the progress of hydrogen taking its place as a key factor of the future green energy society. It reviews recent developments of hydrogen technologies, their social, industrial, and environmental standing, as well as the stage of transitioning economies of both advanced and beginner countries. An example of the ongoing energy transition is Croatia, which is in the process of implementing a hydrogen strategy with the ambition to be able to one day equally participates in the rapidly emerging hydrogen market.     

Hydrogen storage technology options for fuel cell vehicles: Well-to-wheel costs, energy efficiencies, and greenhouse gas emissions

Five different hydrogen vehicle storage technologies are examined on a Well-to-Wheel basis by evaluating cost, energy efficiency, greenhouse gas (GHG) emissions, and performance. The storage systems are gaseous 350 bar hydrogen, gaseous 700 bar hydrogen, Cold Gas at 500 bar and 200 K, Cryo-Compressed Liquid Hydrogen (CcH2) at 275 bar and 30 K, and an experimental adsorbent material (MOF 177) -based storage system at 250 bar and 100 K. Each storage technology is examined with several hydrogen production options and a variety of possible hydrogen delivery methods. Other variables, including hydrogen vehicle market penetration, are also examined. The 350 bar approach is relatively cost-effective and energy-efficient, but its volumetric efficiency is too low for it to be a practical vehicle storage system for the long term. The MOF 177 system requires liquid hydrogen refueling, which adds considerable cost, energy use, and GHG emissions while having lower volumetric efficiency than the CcH2 system. The other three storage technologies represent a set of trade-offs relative to their attractiveness. Only the CcH2 system meets the critical Department of Energy (DOE) 2015 volumetric efficiency target, and none meet the DOE’s ultimate volumetric efficiency target. For these three systems to achieve a 480-km (300-mi) range, they would require a volume of at least 105-175 L in a mid-size FCV.     

Sustainable hydrogen roadmap: A holistic review and decision-making methodology for production,utilisation and exportation using Qatar as a case study

Hydrogen is seen as a promising and inevitable energy carrier in the transition towards a carbon-free energy era. This study reviews the potential for carbon-free hydrogen production, utilisation and exportation from the State of Qatar. The study aims to introduce a roadmap for current and future exploration of carbon-free hydrogen production and exportation from Qatar, for which an assessment of several available alternatives for the production of hydrogen in Qatar is performed. These alternatives include the use of natural gas as a feedstock for hydrogen production through steam methane reforming (SMR), solar integrated steam methane reforming with carbon capture, as well as the possibilities for hydrogen production from electrolysis using renewables and ammonia as another intermediate. The potential of each alternative is reviewed based on selected technical, economic and environmental criteria. The findings of this review study indicate that the production and exportation of blue ammonia currently present the best pathway for Qatar, while green hydrogen is expected to become as competitive as blue ammonia in the mid-future. It is widely accepted that as the technologies associated with clean hydrogen production improve, and the cost of renewable energy falls, green hydrogen will become quite competitive in the region.     

Safety strategy for the first deployment of a hydrogen-based green public building in France

HELION, a subsidiary of AREVA in charge of the business unit Hydrogen and energy storage, is deploying for the first time in a French public building, a hydrogen-based energy storage system, the Greenergy Box™. The 50 kWe system is coupled with a photovoltaic farm to ensure up to 45% electrical autonomy and power backup to the building. The safety system and siting measures of the complete hydrogen chain are described. The paper also highlights the work accomplished with Fire Authorities and Public to gain the acceptance of the project and allow the deployment of four other hydrogen-based green buildings.     

A green hydrogen credit framework for international green hydrogen trading towards a carbon neutral future

Hydrogen as a low-carbon clean energy source is experiencing a global resurgence and has been recognized as an alternative energy carrier that can help bring the world to a carbon neutral future. However, getting to scale is one of the main challenges limiting the growth of the hydrogen economy. In particular, the high cost of transporting green hydrogen is bottlenecking the international trading and wider adoption of hydrogen for global carbon natural objectives. In order to explore incentives for the global hydrogen economy and develop new pathways towards the carbon neutral future, the concept of hydrogen credit is proposed by this research and a framework of trading hydrogen credits similar to carbon credits in the international market is established. This research aims to contribute to the overall uptake of green hydrogen financially rather than relying on the physical production, transportation, and storage of hydrogen. Case studies are presented to demonstrate the feasibility and efficiency of the proposed hydrogen credit framework, as well as the great potential of a global hydrogen credit market.     

Analysis of Ontario's hydrogen economy demands from hydrogen fuel cell vehicles

The ‘Hydrogen Economy’ is a proposed system where hydrogen is produced from carbon dioxide free energy sources and is used as an alternative fuel for transportation. The utilization of hydrogen to power fuel cell vehicles (FCVs) can significantly decrease air pollutants and greenhouse gases emission from the transportation sector. In order to build the future hydrogen economy, there must be a significant development in the hydrogen infrastructure, and huge investments will be needed for the development of hydrogen production, storage, and distribution technologies. This paper focuses on the analysis of hydrogen demand from hydrogen FCVs in Ontario, Canada, and the related cost of hydrogen. Three potential hydrogen demand scenarios over a long period of time were projected to estimate hydrogen FCVs market penetration, and the costs associated with the hydrogen production, storage and distribution were also calculated. A sensitivity analysis was implemented to investigate the uncertainties of some parameters on the design of the future hydrogen infrastructure. It was found that the cost of hydrogen is very sensitive to electricity price, but other factors such as water price, energy efficiency of electrolysis, and plant life have insignificant impact on the total cost of hydrogen produced.