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Thesynthesesandcharacterizationofnew typeheteropolycomplexescontainingrareearthelementshavebeenreportedinthepast.Nowmuchattentionhasbeendirectedtowardstheresearchonacidic ,redoxordifunctionalcatalysts[1~ 3] .Vacantheteropolycomplexisanactiveinorganicligan… 相似文献
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The complexes of 3-methoxy-2-nitrobenzoates of Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Tb(III), Er(III) and Tm(III) with the formula: Ln(C8H6NO5)3·2H2O, where Ln=lanthanides(III), were synthesized and characterized by elemental analysis, Forier transform irtrared (FTIR) spectroscopy, magnetic and thermogravimetric studies and also by X-ray diffraction (XRD) measurements. The complexes had col- ours typical for Ln(III) ions. The carboxylate groups bound as bidentate chelating. On heating to 1173 K in air they decomposed in the same way, at first, dehydrated in one step to anhydrous salts, and then decomposed to the oxides of respective metals with intermediate formation of the oxycarbonates. The enthalpy values of the dehydration process changed from 133.72 to 44.50 kJ/mol. Their solubility in water at 293 K was of the order of 10-4 mol/dm3. The magnetic moments of analysed complexes were determined by Gouy’s method in the range of 76-303 K. 相似文献
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Themetalcomplexesofhydrazideshaveattractedconsiderableinterestowingtotheirantifungalandantibacterialactivities[1 ,2 ] .Theycanalsobeusedasanalyticalreagents[3 ]andextractingagentsformetalsalts[4 ] .Manycomplexesofhydrazideshavebeensynthesizedandcharacterized[5]… 相似文献
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Theharmfulnessofheavymetalelementsonplantsisoneoftheseriousenvironmentalproblemsofthemodernworld .Inrecentyears ,thestudyonthemisalsooneofveryac tiveresearchprojectsinplantpollutionecologyfields[1~ 6 ] .LanthanidecomplexeswiththeSchiffbaseareaclassofcompou… 相似文献
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Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2’-biphenyldicarboxylic acid and tpy= 2,2’:6’,2’’-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2-ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature. 相似文献
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Nd(Ⅲ)、Sm(Ⅲ)、Eu(Ⅲ)与邻香兰素缩邻苯二胺配合物的合成与性质 总被引:1,自引:0,他引:1
合成了稀土硝酸盐与双希夫碱邻香兰素缩邻苯二胺(以L表示)的3种新固体配合物。通过元素分析、红外光谱、紫外光谱、差热一热重、摩尔电导及X射线粉末衍射分析等手段,确定配合物的组成为(LnL(NO3)2)NO3(Ln=Nd、Sm、Eu)。并对其结构和某些物理化学性质进行了研究。 相似文献
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Coordination chemistry of rare earth with Schiffbase has developed rapidly in the last fewyears ,butthe majority of the complexes studied are derivedfromaromatic Schiff base .So far less papers of rare earthcomplex with aliphatic Schiff base have been rep… 相似文献
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SynthesisandCharacterizationofLn(NO3)3PhenFuTernaryComplexesLinJiyun(林纪筠),MaDejian(马德建)(DepartmentofChemistry,EastChinaNorm... 相似文献
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Synthesis, structures,thermal and magnetic properties of a series of lanthanide [Ln=Sm, Gd, Er, Yb] complexes with 4-quinolineacarboxylate 总被引:2,自引:1,他引:1
A series of lanthanide binuclear complexes, [Ln2(L)6(H2O)4]·2H2O (Ln=Sm(III), Gd(III), Er(III), Yb(III), HL=4-quinolineacarboxylic acid, were synthesized by reactions of corresponding rare earth salts with 4-quinolineacarboxylic acid at room temperature and were characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. X-ray diffraction analyses showed that they exhibited the same binuclear architecture and crystallized in monoclinic system and P21/c space group. In four complexes, each metal center adopted nine-coordinated mode coordinated by nine O atoms from two H2O molecules and three carboxyls of three ligands, and HL showed three different coordination modes. The variable-temperature magnetic susceptibility showed that complex [Gd2(L)6(H2O)4]·2H2O performed very weak antiferromagnetic property at low temperature and exchange was almost paramagnetic at high temperature. Complexes [Er2(L)6(H2O)4]·2H2O and [Yb2(L)6(H2O)4]·2H2O performed dominating antiferromagnetic coupling. 相似文献
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Reaction of (MeC5H4)3Ln with HOCH2CH2NMe2 in tetrahydrofuran (THF) gives the new complexes [ (MeC5H4)2Ln(μ-OCH2CH2NMe2)]2(Ln = Sm, Y, Nd) with nitrogen functionalized μ-alkoxide ligand. The complexes were characterized by elemental analysis and IR, and [ (MeC5H4)2Sm(μ-OCH2CH2NMe2)]2 was structurally characterized by the X-ray diffraction to be a dimer formed by two unsymmetric oxygen bridges. The complex has a tricyclic skeleton with the additional two Sm- N bonds via intmmoleeular coordination of OCH2CH2NMe2. The coordination number of the central metal Sm is nine. The tide complexes show good catalytic activity for ring-opening polymerization of ε-capmlactone. 相似文献
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Rare earth (RE) ternary complexes of Eu0.5Ln0.5(NPPD)3·(DPQ) (HNPPD=1-(naphthalen-2-yl)-3-phenylpropane-1,3-dione; DPQ= dipyridobenzoquinone) and Eu1-xLax(NPPD)3·(DPQ) (Ln3+=La3+, Gd3+, Sm3+, Pr3+; x=0.0, 0.1, 0.3, 0.5, 0.7, 0.9) were synthesized by the reaction of RECl3·6H2O with HNPPD and DPQ in stoichiometry. The complexes were characterized with IR, elemental analysis, TGA-DSC and wide-angle X-ray diffraction. The UV-Vis absorption spectra and fluorescence properties of the complexes were also investigated. The experimental results showed that the luminescence efficiency of Eu3+ complexes was enhanced by doping some other lanthanide ions. Eu0.7La0.3(NPPD)3·(DPQ) showed the highest luminescence efficiency. 相似文献
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Synthesis and Characterization of Gadolinium Doping M-type Hexagonal Barium Ferrite Ultrafine Powders 总被引:2,自引:1,他引:1
Becausepermanentbariumferritematerialpos sessesrelativelyhighsaturationmagnetization ,greatcoerciveforceandhighmagneticanisotropyfieldaswellasexcellentchemicalstabilityandcorrosionresis tance ,ithasbeenwidelyusedastraditionalperma nentmagnets ,high densitymagneticandmagneto op ticrecordingmedia ,microwavefilters[1,2 ] .Thusthestudyonthesynthesisofmagnetoplumbite typebariumferriteisconsiderablyimportanttotheelectronicandmagneticmaterialsindustry .Duringthelastfewdecades ,peoplehavemadegreateffo… 相似文献
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PreparationandCharacterizationofHeteropolytungstoarsenateComplexesContainingLanthanideElements¥WangWeiqing(DepartmentofChemic... 相似文献
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Therapidlygrowinginterestinpolynuclearcomplexesarisesfromthesignificantrolewhichhasplayedintheextensiveareasofcatalysts,magne... 相似文献
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Naphthalene-1-acetic acid (HNAA), dichlorophenoxy acetic acid (HDAA), and indole-3-acetic acid (HIAA) are auxinhormones that can affect the growth of plants. The lanthanide complexes of the above auxinhormone LnA3 x 3H2O (Ln = La3+, Ce3+, Sm3+, Er3+, Yb3+; HA = HNAA, HDAA, HIAA; A = NAA-, DAA-, IAA-) were synthesized and are characterized in this paper. The solubility and IR spectra of these complexes were also studied. Experiments of the effects of LnCl3 x nH2O, HA, and LnA3 x 3H2O on the growth rate of wheat coleoptile sections show, that LnCl3 x nH2O promotes the growth of wheat coleoptile when this compounds concentration is lower than 2 x 10(-5) M and the promotion is very significant when the concentration of Ln3+ is lower than 8 x 10(-6) M. It was also found that the effect of LnA3 x 3H2O on the growth of wheat coleoptile is stronger than that of LnCl3 x nH2O and HA, which indicates that the combination of Ln3+ with HA act synergistically. 相似文献