共查询到20条相似文献,搜索用时 218 毫秒
1.
Coordination chemistry of rare earth with Schiffbase has developed rapidly in the last fewyears ,butthe majority of the complexes studied are derivedfromaromatic Schiff base .So far less papers of rare earthcomplex with aliphatic Schiff base have been rep… 相似文献
2.
Themetalcomplexesofhydrazideshaveattractedconsiderableinterestowingtotheirantifungalandantibacterialactivities[1 ,2 ] .Theycanalsobeusedasanalyticalreagents[3 ]andextractingagentsformetalsalts[4 ] .Manycomplexesofhydrazideshavebeensynthesizedandcharacterized[5]… 相似文献
3.
Themagneticresonanceimaging (MRI)tech niqueforthemedicineisveryusefultodiagnosepre tumorandbloodvesseldiseaseinheartandbrainandothermalignantpre diseases .Therefore ,specialatten tionhasbeenalsopaidtoMRIcontrastagents ,whichareindispensablediagnosingdrugsforthemagneticresonanceimagingtechnique[1,2 ] .Gadolinium (Ⅲ)complexwithsomepolycarboxylicandpolyaminelig ands ,suchasGd(DTPA)·nH2 O ,waswidelyusedincliniclongago .OurpreviousworkshowsthatsomepolycarboxylicSchiffbasecomplexeswithrareea… 相似文献
4.
Naphthalene-1-acetic acid (HNAA), dichlorophenoxy acetic acid (HDAA), and indole-3-acetic acid (HIAA) are auxinhormones that can affect the growth of plants. The lanthanide complexes of the above auxinhormone LnA3 x 3H2O (Ln = La3+, Ce3+, Sm3+, Er3+, Yb3+; HA = HNAA, HDAA, HIAA; A = NAA-, DAA-, IAA-) were synthesized and are characterized in this paper. The solubility and IR spectra of these complexes were also studied. Experiments of the effects of LnCl3 x nH2O, HA, and LnA3 x 3H2O on the growth rate of wheat coleoptile sections show, that LnCl3 x nH2O promotes the growth of wheat coleoptile when this compounds concentration is lower than 2 x 10(-5) M and the promotion is very significant when the concentration of Ln3+ is lower than 8 x 10(-6) M. It was also found that the effect of LnA3 x 3H2O on the growth of wheat coleoptile is stronger than that of LnCl3 x nH2O and HA, which indicates that the combination of Ln3+ with HA act synergistically. 相似文献
5.
Rare earth (RE) ternary complexes of Eu0.5Ln0.5(NPPD)3·(DPQ) (HNPPD=1-(naphthalen-2-yl)-3-phenylpropane-1,3-dione; DPQ= dipyridobenzoquinone) and Eu1-xLax(NPPD)3·(DPQ) (Ln3+=La3+, Gd3+, Sm3+, Pr3+; x=0.0, 0.1, 0.3, 0.5, 0.7, 0.9) were synthesized by the reaction of RECl3·6H2O with HNPPD and DPQ in stoichiometry. The complexes were characterized with IR, elemental analysis, TGA-DSC and wide-angle X-ray diffraction. The UV-Vis absorption spectra and fluorescence properties of the complexes were also investigated. The experimental results showed that the luminescence efficiency of Eu3+ complexes was enhanced by doping some other lanthanide ions. Eu0.7La0.3(NPPD)3·(DPQ) showed the highest luminescence efficiency. 相似文献
6.
YU Qiongyan ZHOU Xiuxia LIU Maosheng CHEN Jianqiao ZHOU Zhengyuan YIN Xia CAI Yuepeng 《中国稀土学报(英文版)》2008,26(2)
Two dinuclear compounds [Ln2(acetate)6(H2O)4]·4H2O (Ln=Tb(1), Sm(2)) were obtained by the hydrothermal reaction of Ln2O3 with malonic acid at 150 ℃. Both compounds were characterized by elemental analyses, infrared spectra, and single crystal X-ray diffraction. The results showed that complexes 1 and 2 were isomorphous and crystallize in triclinic space group P(-1). The coordination geometry around Ln(III) ions in the complexes 1 and 2 was a distorted tricapped trigonal prism with a nine coordination. In the crystal, the molecular organization was further stabilized by well-defined weak hydrogen bonding interactions between the neutral dinuclear molecular units that led to the formation of a three-dimensional network. The fluorescence properties of the two complexes 1 and 2 in organic solvents were also studied. The results show that the ligand acetate favored energy transfer to the emitting energy level of Tb(III) in complex 1. Some factors that influence the fluorescent intensity were also discussed in the article. 相似文献
7.
8.
Two three-dimensional complexes Ln(DMPA)3phen2(HDMPA=3,4-dimet hoxyphenylacetic acid,homoveratric acid;Ln=La,Y;phen=1,10-phenanthroline) were synthesized under hydrothermal conditions and characterized with IR and emission spectra.The crystal structures were determined with single crystal X-ray diffraction method.The two compounds were isostructural,and 3D supramolecule architectures were formed by hydrogen bonds and π-π stacking interactions.They strongly emitted upon excitation due to π→π transition of the ligands. 相似文献
9.
Therapidlygrowinginterestinpolynuclearcomplexesarisesfromthesignificantrolewhichhasplayedintheextensiveareasofcatalysts,magne... 相似文献
10.
Three coordination polymers, Ln2(bpdc)3(phen)2(H2O)2 (Ln=Nd(1), Eu(2), and Tb (3); bpdc=2,2'-bipyridine-3,3'-dicarboxylate; phen=1,10-phenanthroline), were obtained by hydrothermal reaction of Ln2O3 with 2,2'-bipyridine-3,3'-dicarboxylate acid, and 1,10-phe- nanthroline. They were characterized by single-crystal X-ray diffraction, IR spectra, and photoluminescent spectra. The crystallographic data of 1-3 indicated that they were isostructural. Both complexes contained paddle-wheel building blocks, formed by bpdc and phen ligands. These paddle-wheel secondary building units (SBUs) were further connected to form two-dimensional (2-D) metal organic framework (MOF) networks by 2,2'-bipyridine-3, and 3'-dicarboxylate tinkers. A three-dimensional (3-D) supramolecular structure was formed by π-π aromatic interactions between adjacent 2-D infinite networks. Photoluminescent measurements indicated that europium compound 2 and terbium compound 3 were strong, red and green emitters, respectively. 相似文献
11.
Thesynthesesandcharacterizationofnew typeheteropolycomplexescontainingrareearthelementshavebeenreportedinthepast.Nowmuchattentionhasbeendirectedtowardstheresearchonacidic ,redoxordifunctionalcatalysts[1~ 3] .Vacantheteropolycomplexisanactiveinorganicligan… 相似文献
12.
Synthesis, Characterization and Fluorescence of Phenylcarboxymethyl Sulfoxide Complexes with Lanthanide Nitrates 总被引:4,自引:0,他引:4
Rareearthcomplexeswithsulfoxideandaromaticcarboxylacidhavebeenwidelystud ied[1~ 3 ] .Itisprovedthattheybothhavebet terfluorescencecharacter .Howeverthearo maticcarboxylofrareearthcomplexeshaveveryhighfluorescenceemissionintensityandstability ,butsolubilityi… 相似文献
13.
SynthesisandCharacterizationofLn(NO3)3PhenFuTernaryComplexesLinJiyun(林纪筠),MaDejian(马德建)(DepartmentofChemistry,EastChinaNorm... 相似文献
14.
Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2’-biphenyldicarboxylic acid and tpy= 2,2’:6’,2’’-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2-ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature. 相似文献
15.
16.
PreparationandCharacterizationofHeteropolytungstoarsenateComplexesContainingLanthanideElements¥WangWeiqing(DepartmentofChemic... 相似文献
17.
Two rare earth substituted Keggin-type phosphotungstates containing 5-fluorouracil,K10C4H4FN2O2Y(PW11O39)2·10H2O(FYPW) and K9(C4H4FN2O2)2La(PW11O39)2·18H2O(FLaPW)were synthesized in aqueous solution,and the structures were characterized by Fourier transform infrared spectroscopy(FT-IR),element analysis,inductively coupled plasma spectrometry(ICP),X-ray powder diffraction(XRD) and 1 H nuclear magnetic resonance(NMR).Thermal analysis showed that the decomposition processes of the two compounds could be divided into three steps,the loss of crystal water,the decomposition of 5-fluorouracil unit and the decomposition of Keggin-type polyanions. The in vitro cytotoxicities against HEK 293,HeLa and HepG-2 cells were studied by methyl thiazolyl tetrazolium(MTT)assay.The results showed that FYPW and FLaPW had higher antitumor activities than 5-fluorouracil,C4H4FN2O2H2PW12O40·8H2O and rare earth substituted polyoxometalates K11Ln(PW11O39)2·nH2O(Ln=Y,La).It was concluded that introducing 5-fluorouracil and rare earth(Y or La)into its structure was a considerable way to enhance antitumor activities of polyoxometalates. 相似文献
18.
Two three-dimensional complexes [Ln(DMPA)3phen]2 (HDMPA=3,4-dimet hoxyphenylacetic acid, homoveratric acid; Ln=La, Y; phen=1,10-phenanthroline) were synthesized under hydrothermal conditions and characterized with IR and emission spectra. The crystal structures were determined with single crystal X-ray diffraction method. The two compounds were isostructural, and 3D supramolecule architectures were formed by hydrogen bonds and π–π stacking interactions. They strongly emitted upon excitation due to π*→π transition of the ligands. 相似文献
19.
Heteropolycompoundisanewcatalystwithmanyfunctionsinchemistryindustry .Itsexcellentcatalyticperformanceisdeterminedbyitscompositionandstructure .Ithassimplecompositionandfixedstructure ,althoughitmayconsistofmanyelements .Itsstructureandpropertycanbechang… 相似文献
20.
The new lanthanum (Ⅲ) and praseodymium (Ⅲ) complexes of the general formula [Ln(L)3] (Ln=La(Ⅲ) or Pr(Ⅲ); LK=potassium salt of dithiocarbazinates) were prepared by both, conventional thermal and by the use of microwave technology. Elemental analyses, elec-trical conductance, magnetic moment and electronic, infrared, far-infrared, 1H and 13C NMR spectral studies were used to characterize the complexes. The molecular weights of few complexes were determined by FAB-mass spectra. Nephelauxetic ratio, covalency parameter and bonding parameter for these complexes were also calculated. The probable structures of the complexes were proposed. The antifungal and antibacterial activities of the complexes were evaluated. The activities were correlated with the structures of the compounds. 相似文献