共查询到20条相似文献,搜索用时 78 毫秒
1.
新型混凝剂聚硅氯化铁的制备及性能研究 总被引:5,自引:0,他引:5
在制备聚合氯化铁( P F C) 的过程中,加入一定量的硅酸钠( Na O·3 .2 Si O2) ,制得新型混凝剂聚硅氯化铁( P F S C) ,试验了其混凝性能及影响因素。实验结果表明: Si 的含量,p H 值和碱化度都会影响 P F S C 的混凝效果。在铁硅摩尔比n( Fe)/n( Si) = 10 ~15 ,碱化度为25 % ~35 % ,水样的p H 值为4 ~9 范围内, P F S C 具有优良的混凝性能,其除浊能力和对工业废水的处理效果明显优于 P F C 。 相似文献
2.
氯化铁催化合成苯乙酸异丁酯 总被引:7,自引:0,他引:7
作者在研究羧酸酯化法中曾发现氯化铁是良好的催化剂[1]。氯化铁易得,无毒性污染。本文探讨了氯化铁对苯乙酸和异丁醇直接酯化的催化作用,效果良好。C6H5CH2COOH+(CH3)2CHCH2OHFeCl3→C6H5CH2COOCH2CH(CH3)2+H... 相似文献
3.
喹禾灵含酚废水混凝效果的试验研究 总被引:1,自引:0,他引:1
喹禾灵生产过程中产生的废水是一种深棕色(色度为10000)的高浓度有机含酚废水(CODcr=2672mg/L。对苯二酚=2330mg/L。选用三氯化铁混凝剂,就混凝剂最佳用量及pH值对混凝效果的影响进行了试验研究。 相似文献
4.
5.
铝铁共聚复合絮凝剂的研制及应用 总被引:42,自引:2,他引:40
研究了铝铁共聚复合絮凝剂的实验室制备方法及其中Fe(Ⅲ)形态组分分布规律和pH变化特征,混凝实验结果表明其混凝效果优于PAC和FeCl3。 相似文献
6.
氯化铁催化合成马来酸二丁酯 总被引:2,自引:0,他引:2
在氯化铁(FeCl3·6H2O)催化剂存在下从马来酸酐和正丁醇制备了马来酸二丁酯,当马来酸酐、正丁醇和氯化铁的摩尔比为1∶6∶0074,反应温度115℃~124℃,反应时间120~140分钟时,该酯收率达90% 相似文献
7.
8.
PP/CPE复合阻燃体系增容剂的研制 总被引:1,自引:1,他引:0
以聚丙烯(PP)、氯化聚乙烯(CPE)和架桥剂为反应物料,过氧化苯甲酰(BPO)为引发剂,制备PP/CPE复合阻燃体系增容剂。通过观察测MI时压出样条的表面状况及样条180℃弯折的现象研究了制备工艺条件对增容剂中各组分间相容性的影响,并通过IR谱图研究了增容剂的结构。结果表明,在较佳工艺条件〔CPE/(PP+CPE)=0.25,架桥剂/(PP+CPE)=0.11,BPO/架桥剂=0.10,T=125~130℃〕下制得的增容剂中,架桥剂的接枝、架桥效率为47%,CPE的转化率为22.6%,起增容作用的有效成分含量较大。架桥剂的应用对增容剂中有效成分的形成有重要意义。 相似文献
9.
钢管酸洗液制作聚氯化铁的方法与应用 总被引:1,自引:0,他引:1
利用钢管酸洗液制备了一种高效无机絮凝剂一聚合氯化铁,对制作工艺进行了研究并对实际效果进行了验证。研究结果表明:根据盐酸洗管废液中游离酸与铁的含量,采用铁屑等含铁原料调整铁的含量,加入聚合稳定剂与原料充分反应后,加入聚合氧化剂进行氧化聚合,最后用盐酸来调整盐基度。制备的高浓度聚合氯化铁具有比聚合硫酸铁更好的混凝除浊的能力,并便于贮存,适用于给水及污水处理。 相似文献
10.
《高校化学工程学报》1994,(Z1)
LARGESCALEPURIFICATIONOFPHOSPHOGLYCERATEKINASE(PGK)ANDGLYCERALDEHYDE3-PHOSPHATEDEHYDROGENASE(GAPDH)FROMYELLOWPEASBYPEG/REPPAL... 相似文献
11.
Controlled-release phosphate fertilizers include phosphate rocks (PRs) for direct application, partially acidulated phosphate
rocks (PAPRs) and thermal phosphates. Phosphate rocks contain apatite as the main P containing mineral, the composition and
the chemical nature of which vary between PRs. Based on the solubility in chemical extractants PRs are broadly grouped into
‘reactive’ and ‘unreactive’. The ‘reactivity’ of PRs is influenced strongly by the extent of carbonate substitution for phosphate
in the apatite minerals. Under certain soil and climatic conditions reactive PRs (RPRs) can be used as a source of P for direct
application.
Partially acidulated phosphate rocks (PAPRs) are produced either by direct partial acidulation of PRs with mineral acids or
by mixing PRs with fully acidulated superphosphate reaction mixtures. Partial acidulation of PRs with H3PO4 generally results in higher water soluble P contents than those acidulated with H2SO4. Mixing of RPRs with superphosphate reaction mixtures sometimes results in the preferential consumption of free acid and
thereby increases the amounts of residual unreacted PRs.
Thermal phosphates are produced by either heating PRs below melting point both in the presence and the absence of silica (calcined
phosphates) or heating PRs with silica above melting point (fused phosphate). These phosphates are alkaline in nature and
hence suitable for acidic soils. 相似文献
12.
14.
15.
评述了世界饲料磷酸盐产品的品种,包括磷酸氢钙、磷酸二氢钙、脱氟磷酸钙等,市场需求量变化情况,主要生产工艺的比较,生产能力与产量变化及现状等。介绍了影响饲料磷酸盐市场需求变化的因素并对饲料磷酸盐所面对的生物技术、生物效价、生产环保等问题进行分析,预测了饲料磷酸盐的发展方向。 相似文献
16.
J. Hagin S. S. S. Rajan M. K. Boyes M. Upsdell 《Nutrient Cycling in Agroecosystems》1990,22(2):109-117
Five phosphate rocks varying in formic acid P solubility from 18.9 to 52.7%, expressed as percentage of total P, were acidulated with phosphoric or sulphuric acids to 0, 20%, 33% and 50% of full acidulation and granulated. In an incubation experiment fertilizer granules of diameter 1–2 mm were mixed with two acid soils and after 1 week incubation soil samples were extracted with a 0.5 M NaOH solution. In a dissipation experiment single fertilizer granules of 4 mm diameter were implanted into soil, incubated for 1 and 4 weeks and inorganic P fractionation in the residual granules and the surrounding soil was performed. Dissipated P was greater than the water soluble P content of the partly acidulated phosphate rock fertilizers indicating the dissolution of the non-acidulated phosphate rocks. The amount of P dissipated was related to the initial water soluble P content and to the formic acid solubility of phosphate rocks used for manufacturing the fertilizers. The P dissipated increased with an increase in soil acidity. 相似文献
17.
在介绍国内外饲料磷酸盐发展概况的基础上,重点论述了饲料级磷酸氢钙和脱氟磷酸钙的生产方法和技术进步,并对加快我国饲料磷酸盐生产的发展提出了一些看法。 相似文献
18.
Water insoluble residues (WIR) of unreactive phosphate rocks in single superphosphate-reactive phosphate rock (SSP-RPR) mixtures are considered to reduce the agronomic value of these mixtures. A technique using concentration ratios of elements to identify the quantities of WIR of ground North Carolina (NC), ground Nauru and as received NC phosphate rocks in a SSP-RPR was developed. Of 22 elements tested P/Sr ratios were found to be the only element ratios that could be used to distinguish between WIR's derived from Nauru and NC. P/Sr ratios in Nauru and NC were markedly different and provided a useful index for differentiating between the two rocks. During acidulation the P/Sr concentration ratio remained essentially constant in the WIR's from both rocks.Using the element ratio technique the percentage of total P in the SSP-RPR sample was determined to be 60-61% water soluble, 5% water insoluble Nauru, 2% water insoluble ground NC and 32-33% water insoluble as received NC.The element ratio technique developed in this study can be applied to partially acidulated P fertilizers made with rocks other than NC and Nauru provided elements which satisfy the same conditions as Sr in this study can be found. 相似文献
19.
20.
针对磷化渣产生的机理及危害,分析了磷化液中磷化渣的沉降特性,并在此基础上,结合本公司涂装车间,提出了一种新的除磷化渣装置系统及其管理技术。 相似文献