Energy,exergy and economic analyses and multiobjective optimization of a novel solar multi-generation system for production of green hydrogen and other utilities

Renewable energy based multi-generation systems can help solving energy-related environmental problems. For this purpose, a novel solar tower-based multi-generation system is proposed for the green hydrogen production as the main product. A solar-driven open Brayton cycle with intercooling, regeneration and reheat is coupled with a regenerative Rankine cycle and a Kalina cycle-11 as a unique series of power cycles. Significant portion of the produced electricity is utilized to produce green hydrogen in an electrolyzer. A thermal energy storage, a single-effect absorption refrigeration cycle and two domestic hot water heaters are also integrated. Energy, exergy and economic analyses are performed to examine the performance of the proposed system, and a detailed parametric analysis is conducted. Multiobjective optimization is carried out to determine the optimum performance. Optimum energy and exergy efficiencies, unit exergy product cost and total cost rate are calculated as 39.81%, 34.44%, 0.0798 $/kWh and 182.16 $/h, respectively. Products are 22.48 kg/h hydrogen, 1478 kW power, 225.5 kW cooling and 7.63 kg/s domestic hot water. Electrolyzer power size is found as one of the most critical decision variables. Solar subsystem has the largest exergy destruction. Regenerative Rankine cycle operates at the highest energy and exergy efficiencies among power cycles.     

Multi-objective technoeconomic optimization of an off-grid solar-ground-source driven cycle with hydrogen storage for power and fresh water production

Utilizing renewable sources integrated with thermodynamic cycles has been gaining attention in recent years due to being economical and environment-friendly, among which, renewable-energy driven water and power generation systems have shown promising outcomes. In the field of renewable-energy based multi-generation systems (MGS), many recent works have focused on energy analysis or simple optimization. Therefore, in this study, an off-grid solar-geothermal cogeneration system which is able to produce power by Kalina cycle, hydrogen by proton exchange membrane electrolyzer (PEMEC), and freshwater by a multi-effect desalination (MED) unit, was investigated and optimized in terms of economic and energy viewpoints. Unlike previous studies, in this work, a comprehensive multi-objective optimization (MOO) was employed on the system in order to find the optimal working condition. The decision variables of the optimization include flat plate collector area, water mass flow, and ammonia concentration of the Kalina cycle, and the objective functions were levelized cost of electricity (LCOE), payback period (PBP), the overall energy efficiency of the system, and freshwater production of MED unit. Final results show that the system, in its optimum condition, is able to produce 182.09 m³.day⁻¹ fresh water, with energy efficiency, PBP, and LCOE equal to 6.23%, 5.19 years and 0.238 $.kWh⁻¹, respectively.     

Development and exergoeconomic evaluation of a SOFC-GT driven multi-generation system to supply residential demands: Electricity,fresh water and hydrogen

In this study, a novel multi-generation system is proposed by integrating a solid oxide fuel cell (SOFC)-gas turbine (GT) with multi-effect desalination (MED), organic flash cycle (OFC) and polymer electrolyte membrane electrolyzer (PEME) for simultaneous production of electricity, fresh water and hydrogen. A comprehensive exergoeconomic analysis and optimization are conducted to find the best design parameters considering exergy efficiency and total unit cost of products as objective functions. The results show that the exergy efficiency and the total unit cost of products in the optimal condition are 59.4% and 23.6 $/GJ, respectively, which offers an increase of 2% compared to exergy efficiency of SOFC-GT system. Moreover, the system is capable of producing 2.5 MW of electricity by the SOFC-GT system, 5.6 m³/h of fresh water by MED unit, and 1.8 kg/h of hydrogen by the PEME. The associated cost for producing electricity, fresh water and hydrogen are 3.4 cent/kWh, 37.8 cent/m³, and 1.7 $/kg, respectively. A comparison between the results of the proposed system and those reported in other related papers are presented. The diagram of the exergy flow is also plotted for the exact determination of the exergy flow rate in each component, and also, location and value of exergy destruction. Finally, the capability of the proposed system for a case study of Iran is examined.     

Thermodynamic analysis and optimization of an integrated solar thermochemical hydrogen production system

In this study, thermodynamic analysis of solar-based hydrogen production via copper-chlorine (Cu–Cl) thermochemical water splitting cycle is presented. The integrated system utilizes air as the heat transfer fluid of a cavity-pressurized solar power tower to supply heat to the Cu–Cl cycle reactors and heat exchangers. To achieve continuous operation of the system, phase change material based on eutectic fluoride salt is used as the thermal energy storage medium. A heat recovery system is also proposed to use the potential waste heat of the Cu–Cl cycle to produce electricity and steam. The system components are investigated thoroughly and system hotspots, exergy destructions and overall system performance are evaluated. The effects of varying major input parameters on the overall system performance are also investigated. For the baseline, the integrated system produces 343.01 kg/h of hydrogen, 41.68 MW of electricity and 11.39 kg/s of steam. Overall system energy and exergy efficiencies are 45.07% and 49.04%, respectively. Using Genetic Algorithm (GA), an optimization is performed to evaluate the maximum amount of produced hydrogen. The optimization results show that by selecting appropriate input parameters, hydrogen production rate of 491.26 kg/h is achieved.     

Energy,exergy, and exergoeconomics (3E) analysis and multi-objective optimization of a multi-generation energy system for day and night time power generation - Case study: Dezful city

The present study aimed to investigate a multi-generation energy system for the production of hydrogen, freshwater, electricity, cooling, heating, and hot water. Steam Rankine cycle (SRC), organic Rankine cycle (ORC), absorption chiller, Parabolic trough collectors (PTCs), geothermal well, proton exchange membrane (PEM) electrolyzer, and reverse osmosis (RO) desalination are the main subsystems of the cycle. The amount of exergy destruction is calculated for each component after modeling and thermodynamic analysis. The PTCs, absorption chiller, and PEM electrolyzer had the highest exergy destruction, respectively. According to meteorological data, the system was annually and hourly tested for Dezful City. For instance, it had a production capacity of 13.25 kg/day of hydrogen and 147.42 m³/day of freshwater on 17th September. Five design parameters are considered for multi-objective optimization after investigating objective functions, including cost rate and exergy efficiency. Using a Group method of data handling (GMDH), a mathematical relation is obtained between the input and output of the system. Next, a multi-objective optimization algorithm, a non-dominated sorting genetic algorithm (NSGA-II), was used to optimize the relations. A Pareto frontier with a set of optimal points is obtained after the optimization. In the Pareto frontier, the best point is selected by the decision criterion of TOPSIS. At the TOPSIS point, the exergy efficiency is 31.66%, and the total unit cost rate is 21.9 $/GJ.     

Design and thermodynamic assessment of a biomass gasification plant integrated with Brayton cycle and solid oxide steam electrolyzer for compressed hydrogen production

In this paper, a comprehensive thermodynamic evaluation of an integrated plant with biomass is investigated, according to thermodynamic laws. The modeled multi-generation plant works with biogas produced from demolition wood biomass. The plant mainly consists of a biomass gasifier cycle, clean water production system, hydrogen production, hydrogen compression, gas turbine sub-plant, and Rankine cycle. The useful outputs of this plant are hydrogen, electricity, heating and clean water. The hydrogen generation is obtained from high-temperature steam electrolyzer sub-plant. Moreover, the membrane distillation unit is used for freshwater production, and also, the hydrogen compression unit with two compressors is used for compressed hydrogen storage. On the other hand, energy and exergy analyses, as well as irreversibilities, are examined according to various factors for examining the efficiency of the examined integrated plant and sub-plants. The results demonstrate that the total energy and exergy efficiencies of the designed plant are determined as 52.84% and 46.59%. Furthermore, the whole irreversibility rate of the designed cycle is to be 37,743 kW, and the highest irreversibility rate is determined in the biomass gasification unit with 12,685 kW.     

Development of a sustainable multi-generation system with re-compression sCO2 Brayton cycle for hydrogen generation

Current research aims to develop, design, and analyze a novel solar-assisted multi-purpose energy generation system for hydrogen production, electricity generation, refrigeration, and hot water preparation. The suggested system comprises a solar dish for supplying the necessary heat demand, a re-compression carbon dioxide-based Brayton cycle, a PEM electrolyzer for hydrogen generation, an ejector refrigeration system working with ammonia, and a hot water preparation system. The first law and exergy analyses are implemented to determine the performance of the multi-generation plant with various outputs. Besides, the exergo-environmental evaluation of the plant is conducted for the environmental impacts of the plant. Furthermore, parametric analyses are executed for investigating the system outputs, exergy destruction rate, and system efficiencies. According to the results, the rate of hydrogen generated by means of the multi-generation power plant is determined to be 0.062 g/s which corresponds to an hourly production of 0.223 kg. Besides, with the utilization of the supercritical closed Brayton cycle, a power generation rate of 74.86 kW is achieved. Furthermore, the irreversibility of the overall plant is estimated as 535.7 kW in which the primary contributor of this amount is the solar system with a destruction rate of 365.5 kW.     

Energy,exergy and economic analysis of industrial boilers

In this paper, the useful concept of energy and exergy utilization is analyzed, and applied to the boiler system. Energy and exergy flows in a boiler have been shown in this paper. The energy and exergy efficiencies have been determined as well. In a boiler, the energy and exergy efficiencies are found to be 72.46% and 24.89%, respectively. A boiler energy and exergy efficiencies are compared with others work as well. It has been found that the combustion chamber is the major contributor for exergy destruction followed by heat exchanger of a boiler system. Furthermore, several energy saving measures such as use of variable speed drive in boiler's fan energy savings and heat recovery from flue gas are applied in reducing a boiler energy use. It has been found that the payback period is about 1 yr for heat recovery from a boiler flue gas. The payback period for using VSD with 19 kW motor found to be economically viable for energy savings in a boiler fan.     

Thermal management of metal hydride hydrogen storage using phase change materials for standalone solar hydrogen systems: An energy/exergy investigation

This paper reports on an energy/exergy analysis of a standalone solar-hydrogen system with a metal hydride (MH) system thermally managed using a phase change material (PCM). This is a self-contained thermal management arrangement that stores the heat released from the MH unit, when it is being charged and transfers it back to the MH while discharging hydrogen. The first and second laws of thermodynamics were used to develop a mathematical model in MATLAB to simulate this system and quality its performance from the energy and exergy viewpoints. The model was then applied on a passive standalone house, with ～3.8 MWh/year electricity demand, located in southeast Australia. The exergy efficiencies of the solar PV, electrolyser, fuel cell and the whole solar hydrogen system were found to be 6.5%, 88%, 50.6%, and 3.74%, respectively. The paper also provides the detailed entropy generation and exergy analysis on the MH hydrogen storage unit together with its PCM-based thermal management arrangement. The results show that the annual entropy generation, exergy destruction and exergy efficiency of the MH hydrogen storage unit were 173 Wh/K, 51.5 kWh, and 98.8%, respectively.     

Evaluation of a new geothermal based multigenerational plant with primary outputs of hydrogen and ammonia

Increasing environmental concerns and decreasing fossil fuel sources compel engineers and scientists to find resilient, clean, and inexpensive alternative energy options Recently, the usage of renewable power resources has risen, while the efficiency improvement studies have continued. To improve the efficiency of the plants, it is of great significance to recover and use the waste heat to generate other useful products. In this paper, a novel integrated energy plant utilizing a geothermal resource to produce hydrogen, ammonia, power, fresh water, hot water, heated air for drying, heating, and cooling is designed. Hydrogen, as an energy carrier, has become an attractive choice for energy systems in recent years due to its features like high energy content, clean, bountiful supply, non-toxic and high efficiency. Furthermore in this study, hydrogen beside electricity is selected to produce and stored in a hydrogen storage tank, and some amount of hydrogen is mixed with nitrogen to compound ammonia. In order to determine the irreversibilities occurring within the system and plant performance, energy and exergy analyses are then performed accordingly. In the design of the plant, each sub-system is integrated in a sensible manner, and the streams connecting sub-systems are enumerated. Then thermodynamic balance equations, in terms of mass, energy, entropy and exergy, are introduced for each unit of the plant. Based on the system inputs and outputs, the energy and exergy efficiencies of the entire integrated plant is found to be 58.68% and 54.73% with the base parameters. The second part of the analysis contains some parametric studies to reveal how some system parameters, which are the reference temperature, geothermal resource temperature and mass flow rate, and separator inlet pressure in the geothermal cycle, affect both energy and exergy efficiencies and hence the useful outputs.     

Development and analysis of a novel biomass-based integrated system for multigeneration with hydrogen production

Energy and exergy analyses of an integrated system based on anaerobic digestion (AD) of sewage sludge from wastewater treatment plant (WWTP) for multi-generation are investigated in this study. The multigeneration system is operated by the biogas produced from digestion process. The useful outputs of this system are power, freshwater, heat, and hydrogen while there are some heat recoveries within the system for improving efficiency. An open-air Brayton cycle, as well as organic Rankine cycle (ORC) with R-245fa as working fluid, are employed for power generation. Also, desalination is performed using the waste heat of power generation unit through a parallel/cross multi-effect desalination (MED) system for water purification. Moreover, a proton exchange membrane (PEM) electrolyzer is used for electrochemical hydrogen production option in the case of excess electricity generation. The heating process is performed via the rejected heat of the ORC's working fluid. The production rates for products including the power, freshwater, hydrogen, and hot water are obtained as 1102 kW, 0.94 kg/s, 0.347 kg/h, and 1.82 kg/s, respectively, in the base case conditions. Besides, the overall energy and exergy efficiencies of 63.6% and 40% are obtained for the developed system, respectively.     

Multi-objective optimization and exergoeconomic analysis of a multi-generation system based on biogas-steam reforming

In the current work, a new design of a multi-generation integrated energy system powered by biogas energy is proposed, assessed, and optimized. To scrutinize the workability of the offered system, energy, exergy, exergo-economic, and economic investigations have been applied as robust tools to the evaluation of the system. Moreover, to boost the rate of hydrogen production rate, the steam reforming method and purification process are integrated into the systems. It is found that the designed multi-generation integrated energy system is able to generate 108.7 kW, 888.7 kW, and 703.3 kg/h, power, cooling load, and hydrogen, sequentially. Besides, it is determined that the energy and exergy efficiencies of the system are about 31.51% and 31.14%, sequentially. Furthermore, a comprehensive parametric evaluation is employed to appraise the influences of key variables on the operation of the system and relying on its achieved outcomes, two different optimization styles are established. From the optimization outcomes, it is remarked that in the multi-objective optimization mode, a TCOP of 16.23 S/GJ and a net power of 158.21 KW, are achievable.     

Entropy production and exergy destruction: Part II—illustrative technologies

In a previous companion article, we pointed out that inter-technology synergies will become a generic feature of coming hydrogen age systems. These synergies will develop between sources, currencies and technologies. Unfortunately, today's optimization methodologies, based on energy rather than exergy optics, are often a misleading basis for optimization. To illustrate how the energy and exergy optics give quite startlingly different perceptions, this article uses both approaches to examine a range of technologies from civilization's energy systems, including hydroelectric generating stations at Niagara Falls, a coal-fired electricity generating station and home heating systems. Some observations are provided on how the results apply to fuel cells, which can be used for electricity generation or to cogenerate electricity and heat. The main objectives of this work are to understand better the nature of thermodynamic efficiencies and losses, to see clearly where losses should be attributed, and to more accurately identify how to improve efficiencies.     

Thermo-environmental investigation of solar parabolic dish-assisted multi-generation plant using different working fluids

The present study investigates the performance of a multi-generation plant by integrating a parabolic dish solar collector to a steam turbine and absorption chiller producing electricity and process heat and cooling. Thermodynamic modeling of the proposed solar dish integrated multi-generation plant is conducted using engineering equation solver to investigate the effect of certain operating parameters on the performance of the integrated system. The performance of the solar integrated plant is evaluated and compared using three different heat transfer fluids, namely, supercritical carbon dioxide, pressurized water, and Therminol-VPI. The useful heat gain by collector is utilized to drive a Rankine cycle to evaluate the network output, rate of process heat, cooling capacity, overall energetic, and exergetic efficiencies as well as coefficient of performance. The results show that water is an efficient working fluid up to a temperature of 550 K, while Therminol-VPI performs better at elevated temperatures (630 K and above). Higher integrated efficiencies are linked with the lower inlet temperature and higher mass flow rates. The integrated system using pressurized water as a heat transfer fluid is capable of producing 1278 and 832 kW of power output and process heat, respectively, from input source of almost 6121 kW indicating overall energy and exergy efficiencies of 34.5% and 37.10%, respectively. Furthermore, multi-generation plant is evaluated to assess the exergy destruction rate and steam boiler is witnessed to have the major contribution of this loss followed by the turbine. The exergo-environmental analysis is carried out to evaluate the impact of the system on its surroundings. Exergo-environmental impact index, impact factor, impact coefficient, and impact improvement are evaluated against increase in the inlet temperature of the collector. The single-effect absorption cycle is observed to have the energetic and exergetic coefficient of performances of 0.86 and 0.422, for sCO₂ operating system, respectively, with a cooling load of 228 kW.     

Development and multi-criteria optimization of a solar thermal power plant integrated with PEM electrolyzer and thermoelectric generator

This study investigates a novel solar-driven energy system for co-generating power, hydrogen, oxygen, and hot water. In the proposed system, parabolic trough collectors (PTCs) are used as the heat source of cascaded power cycles, i.e., steam and organic Rankine cycles (SRC and ORC). While the electricity produced by the SRC is supplied to the grid, the energy output of the ORC is used to drive an electrolyzer for hydrogen production. In addition, the use of a thermoelectric generator (TEG) using heat rejected from the ORC condenser for supplying additional electricity to the electrolyzer is investigated. A multi-objective optimization based on the genetic algorithm approach is carried out to estimate the optimal results for the proposed system. The specific cost of the system product and exergy efficiency are the chosen objective parameters to be minimized and maximized, respectively. The results show that, for the optimal system with the TEG, the specific cost of the system product and the exergy efficiency are 30.2$/GJ and 21.9%, respectively, and the produced hydrogen rate is 2.906 kg/h. The results also show that using a TEG increases efficiency and reduces the specific cost of system product. For having the most realistic interpretation of the investigations, the performance of the proposed system is investigated for four cities in Khuzestan province in Iran.     

Thermodynamic and thermoeconomic optimization of a cooling tower-assisted ground source heat pump

Thermodynamic and thermoeconomic optimization of a cooling tower-assisted ground source heat pump (GSHP) in a multi-objective optimization process is performed. A thermodynamic model based on energy and exergy analyses is presented, and an economic model of the hybrid GSHP (HGSHP) system is developed according to the total revenue requirement (TRR) method. The proposed hybrid cooling tower-assisted GSHP system, including 12 decision variables, is considered for optimization. Three optimization scenarios, including thermodynamic single objective, thermoeconomic single objective, and multi-objective optimizations, are performed. In multi-objective optimization, both thermodynamic and thermoeconomic objectives are simultaneously considered. An optimization process is performed using the genetic algorithm (GA). In the case of multi-objective optimization, an example of a decision-making process for selection of the final solution from the Pareto optimal frontier is presented. The results obtained using the various optimization approaches are compared and discussed. Further, the sensitivity of optimized systems to the interest rate, the annual number of operating hours in cooling mode, the electricity price, and the water price are studied in detail. It is shown that the thermodynamic optimization is focused on provision for the limited source of energy, whereas the thermoeconomic optimization only focuses on monetary resources. In contrast, the multi-objective optimization considers both energy and monetary. Further, it is found that thermodynamic optimization is economical when the operating time in cooling mode is long and/or the electricity price is high, and water prices variations have no marked impact on the total product cost.     

Performance analysis of a novel solar PTC integrated system for multi-generation with hydrogen production

The performance analysis of a novel multi-generation (MG) system that is developed for electricity, cooling, hot water and hydrogen production is presented in this study. MG systems in literature are predominantly built on a gas cycle, integrated with other thermodynamic cycles. The aim of this study is to achieve better thermodynamic (energy and exergy) performance using a MG system (without a gas cycle) that produces hydrogen. A proton exchange membrane (PEM) utilizes some of the electricity generated by the MG system to produce hydrogen. Two Rankine cycles with regeneration and reheat principles are used in the MG configuration. Double effect and single effect absorption cycles are also used to produce cooling. The electricity, hot water, cooling effect, and hydrogen production from the multi-generation are 1027 kW, 188.5 kW, 11.23 kg/s and 0.9785 kg/h respectively. An overall energy and exergy efficiency of 71.6% and 24.5% respectively is achieved considering the solar parabolic trough collector (PTC) input and this can increase to 93.3% and 31.9% if the input source is 100% efficient. The greenhouse gas emission reduction of this MG system is also analyzed.     

Thermodynamic analysis of a combined PV/T–fuel cell system for power,heat, fresh water and hydrogen production

A hybrid renewable energy system is proposed and analyzed for electricity, heated air, purified water and hydrogen production. Energy, exergy and economic analyses are performed to analyze and determine the performance of the system under different operating conditions. The photovoltaic/thermal (PV/T) system produces heat and electricity for residential applications. Excess power is used to operate electrolyser which produces hydrogen to be fed directly to a fuel cell. Fuel cell is operated during high power demand, and it produces electricity, heat and water for residential applications. The water produced as a by-product by the fuel cell is used for drinking water supply. The parametric studies are conducted to determine the efficiencies of the system with and without fuel cell network for hot air, power and purified water. When fuel cell heat is used, the overall system efficiency increases to 5.65% for energy and 19.8% for exergy. Up to 80 L of drinkable water can be collected from the fuel cell when operated for extended periods. The present study confirms a significant economic gain when fuel cell heat and water are utilized as useful outputs.     

Performance investigation of an integrated wind energy system for co-generation of power and hydrogen

In this paper, a wind turbine energy system is integrated with a hydrogen fuel cell and proton exchange membrane electrolyzer to provide electricity and heat to a community of households. Different cases for varying wind speeds are taken into consideration. Wind turbines meet the electricity demand when there is sufficient wind speed available. During high wind speeds, the excess electricity generated is supplied to the electrolyzer to produce hydrogen which is stored in a storage tank. It is later utilized in the fuel cell to provide electricity during periods of low wind speeds to overcome the shortage of electricity supply. The fuel cell operates during high demand conditions and provides electricity and heat for the residential application. The overall efficiency of the system is calculated at different wind speeds. The overall energy and exergy efficiencies at a wind speed 5 m/s are then found to be 20.2% and 21.2% respectively.     

基于压缩空气储能的CCHP系统特性研究

以先进绝热压缩空气储能（AA-CAES）为基础,构建冷热电联产（CCHP）系统,对比4种不同储气室和运行方式方案下的系统特性,并针对关键参数进行敏感性分析。结果表明,采用恒温储气室且滑压运行时系统储能效率和效率最高;采用恒温储气室且恒压运行时系统能量密度最高。第二级换热器损最大,是提高系统性能时的首要优化目标。当换热器效能提高时,储能效率、效率均出现折点。储气室最大压比越大,系统储能效率和效率越低,能量密度越高。采用恒温储气室时,系统不受压缩/膨胀影响;采用恒壁温储气室时,较高的压缩/膨胀功率有利于提高储能效率和效率,但压缩功率升高会降低能量密度。