A highly threshold Voltage-controllable 4T FinFET with an 8.5-nm-thick Si-fin channel

Highly threshold voltage (V/sub th/)-controllable four-terminal (4T) FinFETs with an aggressively thinned Si-fin thickness down to 8.5-nm have successfully been fabricated by using an orientation-dependent wet-etching technique, and the V/sub th/ controllability by gate biasing has systematically been confirmed. The V/sub th/ shift rate (/spl gamma/=-/spl delta/V/sub th///spl delta/V/sub g2/) dramatically increases with reducing Si-fin thickness (T/sub Si/), and the extremely high /spl gamma/=0.79 V/V is obtained at the static control gate bias mode for the 8.5-nm-thick Si-fin channel device with the 1.7-nm-thick gate oxide. By the synchronized control gate driving mode, /spl gamma/=0.46 V/V and almost ideal S-slope are achieved for the same device. These experimental results indicate that the optimum V/sub th/ tuning for the high performance and low-power consumption very large-scale integrations can be realized by a small gate bias voltage in the ultrathin Si-fin channel device and the orientation-dependent wet etching is the promising fabrication technique for the 4T FinFETs.     

Ultra-thin decoupled plasma nitridation (DPN) oxynitride gate dielectric for 80-nm advanced technology

Balancing gate leakage reduction, device performance, and gate dielectric reliability is a major challenge for oxynitride used as a gate dielectric for advanced technology. As compared to RTONO oxynitride, pMOSFET threshold voltage shift and transconductance degradation have been problematic for devices using remote plasma nitridation (RPN) or decoupled plasma nitridation (DPN) process due to non-optimal nitrogen profile in the film. In this paper, we report that the nitrogen profile of DPN gate dielectric can be engineered primarily by tuning the plasma pressure after optimizing other DPN process parameters to solve these problems. An EOT of 15 /spl Aring/ (23-/spl Aring/ NMOS CETinv) DPN oxynitride is demonstrated to have an acceptable pMOS Vt, comparable transconductance, significantly (/spl sim/30/spl times/) longer pMOS time-to-breakdown reliability for packaged devices, and 5/spl times/ gate leakage reduction relative to a high quality RTONO used in industry. The high quality ultrathin DPN film is fabricated in a commercially available system, which is compatible with standard CMOS processing technology. These encouraging results make high-pressure DPN oxynitride an attractive gate dielectric candidate for 80-nm advanced technology and beyond.     

Charge trapping in ultrathin hafnium silicate/metal gate stacks

Charge trapping characteristics of MOCVD HfSi/sub x/O/sub y/ (20% SiO/sub 2/) gate stack of n-MOSFETs during substrate injection have been investigated. Positive constant voltage stress (CVS) and constant current stress (CCS) were applied at the gate of TiN-HfSi/sub x/O/sub y/-SiO/sub 2//p-Si n-MOSFETs having EOT of 2 nm. Significant electron trapping is observed from the positive shift of threshold voltage (/spl Delta/V/sub t/) after stress. Curve fitting of the threshold voltage shift data confirms power law dependence for Hf-silicate gate stacks. Charge pumping measurements for both cases showed significant electron trapping at bulk Hf-silicate while interface trap generation was comparatively insignificant. A turn-around effect is noticed for /spl Delta/V/sub t/ as the stress current and voltage increases under CCS and CVS. Dependence of spatial distribution of charge trapping at shallow traps on stress level in the Hf-silicate film and redistribution of trapped charges during and after removal of stress is possibly responsible for the turn-around effect.     

High-energy tail electrons as the mechanism for the worst-case hot-carrier stress degradation of the deep submicrometer N-MOSFET

Experimental evidence, based on sensitively modulating the concentration of the high-energy tail of the electron energy distribution, reveals an important trend in the mid-to-high gate stress voltage (V/sub g/) regime, where device degradation is seen to continuously increase with the applied V/sub g/, for a given drain stress voltage V/sub d/. The shift in the worst-case degradation point from V/sub g//spl ap/V/sub d//2 to V/sub g/=V/sub d/, depicting an uncorrelated behavior with the substrate current, is caused by the injection of the high-energy tail electrons into the gate oxide, when the oxide field near the drain region becomes increasingly favorable as V/sub g/ approaches V/sub d/. This letter offers an improved framework for understanding the worst-case hot-carrier stress degradation of deep submicrometer N-MOSFETs under low bias condition.     

Mobility enhancement in TaN metal-gate MOSFETs using tantalum incorporated HfO/sub 2/ gate dielectric

TaN metal-gate nMOSFETs using HfTaO gate dielectrics have been investigated for the first time. Compared to pure HfO/sub 2/, a reduction of one order of magnitude in interface state density (D/sub it/) was observed in HfTaO film. This may be attributed to a high atomic percentage of Si-O bonds in the interfacial layer between HfTaO and Si. It also suggests a chemical similarity of the HfTaO-Si interface to the high-quality SiO/sub 2/-Si interface. In addition, a charge trapping-induced threshold voltage (V/sub th/) shift in HfTaO film with constant voltage stress was 20 times lower than that of HfO/sub 2/. This indicates that the HfTaO film has fewer charged traps compared to HfO/sub 2/ film. The electron mobility in nMOSFETs with HfO/sub 2/ gate dielectric was significantly enhanced by incorporating Ta.     

Improved device performance and reliability in high /spl kappa/ HfTaTiO gate dielectric with TaN gate electrode

The device performance and reliability of higher-/spl kappa/ HfTaTiO gate dielectrics have been investigated in this letter. HfTaTiO dielectrics have been reported to have a high-/spl kappa/ value of 56 and acceptable barrier height relative to Si (1.0 eV). Through process optimization, an ultrathin equivalent oxide thickness (EOT) (/spl sim/9 /spl Aring/) has been achieved. HfTaTiO nMOSFET characteristics have been studied as well. The peak mobility of HfTaTiO is 50% higher than that of HfO/sub 2/ and its high field mobility is comparable to that of HfSiON with an intentionally grown SiO/sub 2/ interface, indicative of superior quality of the interface and bulk dielectric. In addition, HfTaTiO dielectric has a reduced stress-induced leakage current (SILC) and improved breakdown voltage compared to HfO/sub 2/ dielectric.     

Enhancement of BTI degradation in pMOSFETs under high-frequency bipolar gate bias

Negative bias temperature (NBT) instability of p-MOSFETs with ultrathin SiON gate dielectric has been investigated under various gate bias configurations. The NBT-induced interface trap density (/spl Delta/N/sub it/) under unipolar bias is essentially lower than that under static bias, and is almost independent of the stress frequency up to 10 MHz. On the contrary, /spl Delta/N/sub it/ under bipolar pulsed bias of frequency larger than about 10 kHz is significantly enhanced and exhibits a strong frequency dependence, which has faster generation rate and smaller activation energy as compared to other stress configurations. The degradation enhancement is attributed to the energy to be contributed by the recombination of trapped electrons and free holes upon the silicon surface potential reversal from accumulation to inversion.     

Ge n-MOSFETs on lightly doped substrates with high-/spl kappa/ dielectric and TaN gate

In this letter, we report successful fabrication of germanium n-MOSFETs on lightly doped Ge substrates with a thin HfO/sub 2/ dielectric (equivalent oxide thickness /spl sim/10.8 /spl Aring/) and TaN gate electrode. The highest peak mobility (330 cm/sup 2//V/spl middot/s) and saturated drive current (130 /spl mu/A/sq at V/sub g/--V/sub t/=1.5 V) have been demonstrated for n-channel bulk Ge MOSFETs with an ultrathin dielectric. As compared to Si control devices, 2.5/spl times/ enhancement of peak mobility has been achieved. The poor performance of Ge n-MOSFET devices reported recently and its mechanism have been investigated. Impurity induced structural defects are believed to be responsible for the severe degradation.     

Positive bias temperature instability effects of Hf-based nMOSFETs with various nitrogen and silicon profiles

Positive bias temperature instability (PBTI) effects of HfO/sub 2/-based nMOSFETs with various nitrogen profiles in HfO/sub 2/ were investigated. The nitrogen profile was modulated by an inserting Si layer (/spl sim/6/spl Aring/) into hafnium oxynitride gate dielectrics. The Si layer is used to trap nitrogen and to suppress nitrogen out-diffusion during subsequent anneals. Compared to control HfO/sub x/N/sub y/ without Si insertion, the Si-inserted HfO/sub x/N/sub y/ samples exhibited reduced PBTI degradation, especially if the Si layer was placed further from the Si interface. The improvement can be attributed to the reduction of oxide bulk trapped as well as reduced interface trapped charge generation resulting from compensation effect of inserted Si layer.     

Drain-bias dependence of threshold voltage stability of amorphous silicon TFTs

Amorphous silicon (a-Si:H) thin-film transistors (TFTs) used in emerging, nonswitch applications such as analog amplifiers or active loads, often have a bias at the drain terminal in addition to the gate that can alter their threshold voltage (V/sub T/) stability performance. At small gate stress voltages (0/spl les/V/sub ST//spl les/15 V) where the defect state creation instability mechanism is dominant, the presence of a bias at the TFT drain decreases the overall shift in V/sub T/(/spl Delta/V/sub T/) compared to the /spl Delta/V/sub T/ in the absence of a drain bias. The measured shift in V/sub T/ appears to agree with the defect pool model that the /spl Delta/V/sub T/ is proportional to the number of induced carriers in the a-Si:H channel.     

Hafnium Titanate bilayer structure multimetal dielectric nMOSCAPs

A novel approach of fabricating laminated TiO/sub 2//HfO/sub 2/ bilayer multimetal oxide dielectric has been developed for high-performance CMOS applications. Ultrathin equivalent oxide thickness (/spl sim/8 /spl Aring/) has been achieved with increased effective permittivity (k/spl sim/36). Hysteresis was significantly reduced using the bilayer dielectric. Top TiO/sub 2/ layer was found to induce effective negative charge from the flatband voltage shift. Leakage current characteristic was slightly higher than control HfO/sub 2/, and this is believed to be due to the lower band offset of TiO/sub 2/. However, the interface state density of this bilayer structure was found to be similar to that of HfO/sub 2/ MOSCAP because the bottom layer is HfO/sub 2/. These results demonstrate the feasibility of new multimetal dielectric application for future CMOS technology.     

Modeling study of the impact of surface roughness on silicon and Germanium UTB MOSFETs

We outlined a simple model to account for the surface roughness (SR)-induced enhanced threshold voltage (V/sub TH/) shifts that were recently observed in ultrathin-body MOSFETs fabricated on <100> Si surface. The phenomena of enhanced V/sub TH/ shifts can be modeled by accounting for the fluctuation of quantization energy in the ultrathin body (UTB) MOSFETs due to SR up to a second-order approximation. Our model is then used to examine the enhanced V/sub TH/ shift phenomena in other novel surface orientations for Si and Ge and its impact on gate workfunction design. We also performed a calculation of the SR-limited hole mobility (/spl mu//sub H,SR/) of p-MOSFETs with an ultrathin Si and Ge active layer thickness, T/sub Body/<10 nm. Calculation of the electronic band structures is done within the effective mass framework via the Luttinger Kohn Hamiltonian, and the mobility is calculated using an isotropic approximation for the relaxation time calculation, while retaining the full anisotropy of the valence subband structure. For both Si and Ge, the dependence of /spl mu//sub H,SR/ on the surface orientation, channel orientation, and T/sub Body/ are explored. It was found that a <110> surface yields the highest /spl mu//sub H,SR/. The increasing quantization mass m/sub z/ for <110> surface renders its /spl mu//sub H,SR/ less susceptible with the decrease of T/sub Body/. In contrast, <100> surface exhibits smallest /spl mu//sub H,SR/ due to its smallest m/sub z/. The SR parameters, i.e. autocorrelation length (L) and root-mean-square (/spl Delta//sub rms/) used in this paper is obtained from the available experimental result of Si<100> UTB MOSFETs, by adjusting these SR parameters to obtain a theoretical fit with experimental data on SR-limited mobility and V/sub TH/ shifts. This set of SR parameters is then employed for all orientations of both Si and Ge devices.     

Electrical characterization and material evaluation of zirconium oxynitride gate dielectric in TaN-gated NMOSFETs with high-temperature forming gas annealing

The electrical, material, and reliability characteristics of zirconium oxynitride (Zr-oxynitride) gate dielectrics were evaluated. The nitrogen (/spl sim/1.7%) in Zr-oxynitride was primarily located at the Zr-oxynitride/Si interface and helped to preserve the composition of the nitrogen-doped Zr-silicate interfacial layer (IL) during annealing as compared to the ZrO/sub 2/ IL - resulting in improved thermal stability of the Zr-oxynitride. In addition, the Zr-oxynitride demonstrated a higher crystallization temperature (/spl sim/600/spl deg/C) as compared to ZrO/sub 2/ (/spl sim/400/spl deg/C). Reliability characterization was performed after TaN-gated nMOSFET fabrication of Zr-oxynitride and ZrO/sub 2/ devices with equivalent oxide thickness (EOTs) of 10.3 /spl Aring/ and 13.8 /spl Aring/, respectively. Time-zero dielectric breakdown and time-dependent dielectric breakdown (TDDB) characteristics revealed higher dielectric strength and effective breakdown field for the Zr-oxynitride. High-temperature forming gas (HTFG) annealing on TaN/Zr-oxynitride nMOSFETs with an EOT of 11.6 /spl Aring/ demonstrated reduced D/sub it/, which resulted in reduced swing (69 mV/decade), reduced off-state leakage current, higher transconductance, and higher mobility. The peak mobility was increased by almost fourfold from 97 cm/sup 2//V/spl middot/s to 383 cm/sup 2//V/spl middot/s after 600/spl deg/C HTFG annealing.     

Ultrathin aluminum oxide gate dielectric on N-type 4H-SiC prepared by low thermal budget nitric acid oxidation

MOS capacitors with an ultrathin aluminum oxide (Al/sub 2/O/sub 3/) gate dielectric were fabricated on n-type 4H-SiC. Al/sub 2/O/sub 3/ was prepared by room-temperature nitric acid (HNO/sub 3/) oxidation of ultrathin Al film followed by furnace annealing. The effective dielectric constant of k/spl sim/9.4 and equivalent oxide thickness of 26 /spl Aring/ are produced, and the interfacial layer and carbon clusters are not observed in this paper. The electrical responses of MOS capacitor under heating and illumination are used to identify the conduction mechanisms. For the positively biased case, the conduction mechanism is shown to be dominated by Schottky emission with an effective barrier height of 1.12/spl plusmn/0.13 eV. For the negatively biased case, the gate current is shown to be due to the generation-recombination process in depletion region and limited by the minority carrier generation rate. The feasibility of integrating alternative gate dielectric on SiC by a low thermal budget process is demonstrated.     

SOI technology for radio-frequency integrated-circuit applications

This paper presents a silicon-on-insulator (SOI) integration technology, including structures and processes of OFF-gate power nMOSFETs, conventional lightly doped drain (LDD) nMOSFETs, and spiral inductors for radio frequency integrated circuit (RFIC) applications. In order to improve the performance of these integrated devices, body contact under the source (to suppress floating-body effects) and salicide (to reduce series resistance) techniques were developed for transistors; additionally, locally thickened oxide (to suppress substrate coupling) and ultra-thick aluminum up to 6 /spl mu/m (to reduce spiral resistance) were also implemented for spiral inductors on high-resistivity SOI substrate. All these approaches are fully compatible with the conventional CMOS processes, demonstrating devices with excellent performance in this paper: 0.25-/spl mu/m gate-length offset-gate power nMOSFET with breakdown voltage (BV/sub DS/) /spl sim/ 22.0 V, cutoff frequency (f/sub T/)/spl sim/15.2 GHz, and maximal oscillation frequency (f/sub max/)/spl sim/8.7 GHz; 0.25-/spl mu/m gate-length LDD nMOSFET with saturation current (I/sub DS/)/spl sim/390 /spl mu/A//spl mu/m, saturation transconductance (g/sub m/)/spl sim/197 /spl mu/S//spl mu/m, cutoff frequency /spl sim/ 25.6 GHz, and maximal oscillation frequency /spl sim/ 31.4 GHz; 2/5/9/10-nH inductors with maximal quality factors (Q/sub max/) 16.3/13.1/8.95/8.59 and self-resonance frequencies (f/sub sr/) 17.2/17.7/6.5/5.8 GHz, respectively. These devices are potentially feasible for RFIC applications.     

High-performance fully depleted silicon nanowire (diameter /spl les/ 5 nm) gate-all-around CMOS devices

This paper demonstrates gate-all-around (GAA) n- and p-FETs on a silicon-on-insulator with /spl les/ 5-nm-diameter laterally formed Si nanowire channel. Alternating phase shift mask lithography and self-limiting oxidation techniques were utilized to form 140- to 1000-nm-long nanowires, followed by FET fabrication. The devices exhibit excellent electrostatic control, e.g., near ideal subthreshold slope (/spl sim/ 63 mV/dec), low drain-induced barrier lowering (/spl sim/ 10 mV/V), and with I/sub ON//I/sub OFF/ ratio of /spl sim/10/sup 6/. High drive currents of /spl sim/ 1.5 and /spl sim/1.0 mA//spl mu/m were achieved for 180-nm-long nand p-FETs, respectively. It is verified that the threshold voltage of GAA FETs is independent of substrate bias due to the complete electrostatic shielding of the channel body.     

An experimental study on transport issues and electrostatics of ultrathin body SOI pMOSFETs

We present an experimental study of the transport properties (low field hole mobility /spl mu//sub h/) and electrostatics (threshold voltage V/sub th/, and gate-to-channel capacitance C/sub gc/) of ultrathin body (UTB) SOI pMOSFETs using a large RingFet structure. Body thicknesses were /spl sim/4.3 nm to 50 nm. We find that 1) hole mobility decreases significantly as T/sub Si/<10 nm, and tends to show negligible dependence on the transverse electric field for extremely thin T/sub Si/ (<6 nm) and 2) a V/sub th/ shift of /spl sim/150 mV occurs over the studied T/sub Si/ range, accompanied by enhancement of weak inversion capacitance in thin body devices. Simulations were performed to provide insight into the experimental observations.     

Characterization of 1.9- and 1.4-nm ultrathin gate oxynitride by oxidation of nitrogen-implanted silicon substrate

For gate oxide thinned down to 1.9 and 1.4 nm, conventional methods of incorporating nitrogen (N) in the gate oxide might become insufficient in stopping boron penetration and obtaining lower tunneling leakage. In this paper, oxynitride gate dielectric grown by oxidation of N-implanted silicon substrate has been studied. The characteristics of ultrathin gate oxynitride with equivalent oxide thickness (EOT) of 1.9 and 1.4 nm grown by this method were analyzed with MOS capacitors under the accumulation conditions and compared with pure gate oxide and gate oxide nitrided by N/sub 2/O annealing. EOT of 1.9- and 1.4-nm oxynitride gate dielectrics grown by this method have strong boron penetration resistance, and reduce gate tunneling leakage current remarkably. High-performance 36-nm gate length CMOS devices and CMOS 32 frequency dividers embedded with 57-stage/201-stage CMOS ring oscillator, respectively, have been fabricated successfully, where the EOT of gate oxynitride grown by this method is 1.4 nm. At power supply voltage V/sub DD/ of 1.5 V drive current Ion of 802 /spl mu/A//spl mu/m for NMOS and -487 /spl mu/A//spl mu/m for PMOS are achieved at off-state leakage I/sub off/ of 3.5 nA//spl mu/m for NMOS and -3.0 nA//spl mu/m for PMOS.     

Charge trapping and detrapping characteristics in hafnium silicate gate stack under static and dynamic stress

The V/sub th/ instability of nMOSFET with HfSiON gate dielectric under various stress conditions has been evaluated. It is shown that after constant voltage stress, the threshold voltage (V/sub th/) relaxes to its initial prestress value. The relaxation rate is strongly affected by the stress duration and magnitude rather than injected charge flux or magnitude of the V/sub th/ shift. It is proposed that spatial distribution of trapped charges, which is strongly affected by the stress conditions, determines the relaxation rate. The implications of the electron trapping/detrapping processes on electrical evaluation of the high-/spl kappa/ gate dielectrics are discussed.     

Physically based quantum-mechanical compact model of MOS devices substrate-injected tunneling current through ultrathin (EOT /spl sim/ 1 nm) SiO/sub 2/ and high-/spl kappa/ gate stacks

Building on a previously presented compact gate capacitance (C/sub g/-V/sub g/) model, a computationally efficient and accurate physically based compact model of gate substrate-injected tunneling current (I/sub g/-V/sub g/) is provided for both ultrathin SiO/sub 2/ and high-dielectric constant (high-/spl kappa/) gate stacks of equivalent oxide thickness (EOT) down to /spl sim/ 1 nm. Direct and Fowler-Nordheim tunneling from multiple discrete subbands in the strong inversion layer are addressed. Subband energies in the presence of wave function penetration into the gate dielectric, charge distributions among the subbands subject to Fermi-Dirac statistics, and the barrier potential are provided from the compact C/sub g/-V/sub g/ model. A modified version of the conventional Wentzel-Kramer-Brillouin approximation allows for the effects of the abrupt material interfaces and nonparabolicities in complex band structures of the individual dielectrics on the tunneling current. This compact model produces simulation results comparable to those obtained via computationally intense self-consistent Poisson-Schro/spl uml/dinger simulators with the same MOS devices structures and material parameters for 1-nm EOTs of SiO/sub 2/ and high-/spl kappa//SiO/sub 2/ gate stacks on (100) Si, respectively. Comparisons to experimental data for MOS devices with metal and polysilicon gates, ultrathin dielectrics of SiO/sub 2/, Si/sub 3/N/sub 4/, and high-/spl kappa/ (e.g., HfO/sub 2/) gate stacks on (100) Si with EOTs down to /spl sim/ 1-nm show excellent agreement.