Effects of CuO、MoO3 and WO3 dopping on magnetic properties of NiZn ferrites

研究了CuO、MoO3和WO3掺杂对NiZn铁氧体电磁性能的影响.研究表明,适量的CuO掺杂能提高材料烧结密度并降低磁晶各向异性常数,从而提高材料的起始磁导率,但居里温度也有一定程度的下降.当主配方中CuO含量(摩尔分数)为4%时能最好的兼顾材料高磁导率和高居里温度的要求.而MoO3和WO3掺杂则均能引起晶界附近阳离子空位增多,从而加速晶界移动,促进晶粒尺寸增大,进而提高材料的起始磁导率.同时,由于W离子具有较强的占据铁氧体A位替代Fe3 的趋势,需要更大的掺杂量才能达到磁导率的峰值,其居里温度和饱和磁感应强度也低于相应MoO3掺杂的材料.     

高磁导率MnZn铁氧体材料中ZnO量对磁性能的影响研究

研究了MnZn高磁导率铁氧体材料在Fe2O3含量不变的前提下,增加ZnO量,起始磁导率、品质因数、饱和磁感应强度及其与温度、频率的关系.结果表明,加入ZnO可以提高起始磁导率,饱和磁感应强度Bs和居里温度降低;当ZnO含量不超过25%mol时,高磁导率MnZn铁氧体材料有着良好的频率特性,但ZnO含量超过25mol%时,由于Zn2+是非磁性离子,且ZnO挥发严重,相反会使得起始磁导率μi下降.     

贫铁MnZn铁氧体材料

介绍了贫铁MnZn铁氧体材料配方、工艺及磁特性.通过优化配方、掺杂及工艺,可以获得高的磁导率、高电阻率特性的材料,贫铁MnZn铁氧体材料的电阻率与富铁的相比,可高达1000倍以上,其优良的高频特性与NiZn铁氧体相近.提出了贫铁MnZn铁氧体居里温度的经验公式.     

准低烧结温度条件下制备的高磁导率NiZn铁氧体

通过减小原材料粒度和在主配方中添加适量CuO,显著降低了NiZn铁氧体样品的烧结温度,在930℃低烧结温度条件下制备的NiZn铁氧体样品的晶粒更完整,组织更致密,使得材料的初始磁导率>1500。与传统工艺条件下制备的磁导率相当的NiZn铁氧体相比,本文中使用较低的NiO含量、预烧温度和烧结温度,制备的NiZn铁氧体具有更好的性能和较低的生产成本。     

MoO3掺杂对高磁导率NiCuZn铁氧体性能的影响

为获得具有高磁导率、高居里温度的NiCuZn铁氧体材料,研究了MoO3掺杂对NiCuZn铁氧体微观结构及电磁性能的影响.少量MoO3掺杂可使铁氧体晶粒尺寸增大,均匀性改善,起始磁导率提高,而居里温度仅有较小幅值的下降.但掺杂过量时,晶粒中气孔率增加,起始磁导率下降,损耗也大为增加.在配方(Ni0.28Cu0.1Zn0.62)Fe2.04O4中,当MoO3掺杂为0.12wt%时,可获得起始磁导率为2650,而居里温度高达到105℃的铁氧体材料.     

高能球磨法制备Mn-Zn铁氧体材料的研究

以Fe2O3、Mn3O4和ZnO为原料,采用高能球磨法成功制备了Mn-Zn铁氧体,并利用XRD、SEM以及VSM等测试技术对样品进行了表征.研究了预烧温度对铁氧体相的形成过程以及烧结铁氧体材料的显微结构和磁性能的影响.结果表明,随着预烧温度的升高,预烧粉体的颗粒尺寸逐渐增大,起始磁导率和饱和磁化强度均呈现先增大后减小的趋势.适宜的预烧温度为850℃,高于或低于此温度,烧结铁氧体材料的显微结构和磁性能都会恶化.     

退火温度对NiZn铁氧体薄膜性能的影响

采用射频磁控溅射法在Si(100)基片上制备了NiZn铁氧体薄膜,研究了退火温度对薄膜性能的影响.采用XRD分析仪分析了薄膜的相结构,原子力显微镜分析了薄膜的表面形貌,振动样品磁强计测量了薄膜的磁性能,结果表明,随着退火温度的升高,薄膜的结晶状态越好,晶粒尺寸越大,饱和磁感应强度越高,面内矫顽力越小.     

Ti取代对MnZn功率铁氧体微结构及磁性能的影响

采用氧化物陶瓷工艺制备了MnZn功率铁氧体,研究亮磁性能的影响,由于Ti4 是非磁性离子,它对磁性离子Mn2 的取代,必将对材料的微结构、磁性能以及居里温度产生影响.结果表明,Ti4 取代Mn2 可提高MnZn铁氧体居里温度,适量的Ti4 取代,有利于提高致密度和起始磁导率,并降低磁损耗.为了得到优良的电磁性能,适宜的Ti4 取代量为0.5mol%.     

溶胶直接自蔓燃法制备NiZn铁氧体粉末研究

以柠檬酸铁或硝酸铁、硝酸锌、硝酸镍和柠檬酸为原料,利用溶胶直接自蔓延燃烧反应成功制备了尖晶石结构的NiZn铁氧体粉末.研究结果表明,溶胶直接自蔓延燃烧法形成的NiZn铁氧体粉末的颗粒尺寸总体较小,在含柠檬酸铁体系中晶粒平均尺寸仅为16～23nm,当柠檬酸量与金属盐总量的摩尔比为2时,形成的NiZn铁氧体粉末晶粒尺寸达最大.溶胶直接自蔓延燃烧法得到的NiZn铁氧体粉末的饱和磁化强度相对较小,约为10.54emu/g,矫顽力较大,约为412.5Oe .     

Fe粉含量对燃烧合成制备超细Ni_(0.4)Zn_(0.6)Fe_2O_4粉体相组成、形貌和磁性能影响

以Fe粉、NiO、ZnO为原料,NaClO_4为氧源,NaCl为稀释剂,通过燃烧合成法成功制备了千克级超细NiZn铁氧体。采用XRD、SEM、EDS以及VSM等研究了Fe粉含量对NiZn铁氧体粉体相组成、形貌和磁性能的影响。结果表明,随着Fe粉含量k增加,退火后颗粒尺寸逐渐增大,外形呈现为扁平球形,形成了单相铁氧体,最小粒径为750nm,最大为1 200nm。当k=0.7时退火的产物饱和磁化强度最大为66A·m2/kg,而k=0.5时产物的矫顽力最小可达16.29×79.6A/m。     

Influence of Cu<Superscript>2+</Superscript> ions on structural and magnetic properties of NiZn ferrites

The paper is devoted to the preparation of NiZn ferrite with small substitutions of copper by means of ceramic technology. The influence of small Cu substitution on the microstructural and magnetic properties of NiZn ferrites have been analysed by means of various experimental methods and interpreted from the point of view of preparation technology optimisation and possible applications of such materials. A strong correlation between the substituent content and resulting properties has been observed, thus allowing preparation of material with the properties tailored for any particular application.     

A technique for measuring pole tip saturation of low inductance heads

Increasing the coercive force of a magnetic recording medium normally improves high density digital performance. However, in rigid disk systems, the head is not in intimate contact with the disk. In addition, the ferrites employed as head materials have much lower saturation magnetization than the metals normally used in other types of heads. Under these conditions, the head field may be inadequate to fully saturate recording media of higher than normal coercive force. In the development of the latest disk products, increasing the coercive force has not improved performance but has increased overwrite modulation. This situation has not been improved by increasing write current amplitude. Pole tip and core saturation of the record head has been suspected as the cause of these observations. This paper describes a method of characterizing saturation effects in low inductance heads such as those used with rigid disks. Evidence of the deterioration of performance due to pole tip and core saturation is shown from isolated pulse measurements on a rigid disk with NiZn and MnZn ferrite heads.     

EPR and SQUID studies on magnetic properties of SiO2-doped Ni–Zn ferrite nanocomposites

Effects of the silica content and temperature on the magnetic properties of Ni_0.5Zn_0.5Fe₂O₄/SiO₂ nanocomposites have been studied by electron paramagnetic resonance (EPR) and superconducting quantum interference device (SQUID) technique. The content of TEOS in the starting solution affects the interaction between NiZn ferrite and silica, and then determines the particle size and the EPR properties. In addition, the SQUID properties of the composites were sensitive to particle size. It was observed that the saturation magnetization (M_s), remnant magnetization (M_r) and initial susceptibility (χ_i) decreased with increasing SiO₂ content.     

贫铁MnZn铁氧体磁导率的频散特性解析

采用传统氧化物法制备了MnZn铁氧体材料和NiZn铁氧体材料. 分析了贫铁MnZn铁氧体磁导率的频散特性, 在K. Itoh等人二段型频散特性模型的基础上, 提出了与实际测量数据更相符合的三段型频散特性模型, 并用三段型频散特性模型计算模拟了磁导率的频率特性曲线. 同时通过研究Fe₂O₃、TiO₂含量对贫铁MnZn铁氧体磁导率的影响, 得出三段型频散特性模型各参数对磁导率频率特性的不同贡献.     

Recycling spent zinc manganese dioxide batteries through synthesizing Zn-Mn ferrite magnetic materials

A novel process to reclaim spent zinc manganese dioxide batteries (SDBs) through synthesizing Zn-Mn ferrite magnetic materials is present. Firstly, the dismantling, watering, magnetism, baking and griddling steps were consecutively carried out to obtain iron battery shells, zinc grains and manganese compounds using the collected SDBs, and then these separated substances were dissolved with 4 mol L(-1) H(2)SO(4) to prepare FeSO(4), ZnSO(4) and MnSO(4) reactant solutions. Secondly, Zn-Mn ferrites with stoichiometric ratio of Mn(0.26)Zn(0.24)FeO(2) were synthesized using chemical co precipitation process with ammonium oxalate precipitator. The XRD results showed that the obtained Zn-Mn ferrites had spinel structure and high purity at the calcining temperatures of 850-1250 degrees C. With the increase of calcining temperature, the finer crystalline structure could be formed, and their intensity of saturation magnetization reached the highest value at 1150 degrees C. The magnetization performances of Zn-Mn ferrites prepared from the SDBs were similar to that of from analysis reagents, suggesting the feasibility to synthesize Zn-Mn ferrites with high properties from SDBs.     

The WRITE process in magnetic recording

An extension of an earlier model of the WRITE process in saturation recording that accounts for internal fields due to magnetization divergence in the recording medium is presented. It is shown that the initial condition of the medium determines the internal field distribution during WRITE and may lead to appreciable peak shift and WRITE over modulation. The special case of two successive reversals of magnetization for a dc biased recording medium is considered in detail. System design criteria for optimization of the recording medium parameters, the head pole gap, and the WRITE time constant are presented for a system where the remaining parameters are constrained. Calculation for the initial and quiescent magnetization and internal field and the expected signal trace, in addition to experimental data, are presented for an out-of-contact drum system employing a NiZn ferrite WRITE-READ head and a CoNiP plating.     

Hexagonal ferrite materials for phase shifter applications at millimeter wave frequencies

The effect of anisotropy field and saturation induction on phase shift at millimeter-wave frequencies has been examined for hexagonal ferrite materials. The analysis was done for both uniaxial and planar anisotropy at three particular frequencies of technological interest, 30, 60, and 90 GHz. The work was concerned primarily with materials; a simple thin slab device configuration was used for the analysis. Limitations on materials parameters due to propagation cutoff, phase error degradation over a specified bandwidth, and low field loss were also considered. The results indicate that any improvement in phase shift over conventional cubic ferrites will require a high saturation magnetization, comparable to that of Li-Zn ferrite, and moderate (6-10-kOe) to large (20-30-kOe) anisotropy fields, depending on the frequency.<>