Smart control of nonlinear vibrations of doubly curved functionally graded laminated composite shells under a thermal environment using 1–3 piezoelectric composites

This paper addresses the active control of geometrically nonlinear vibrations of doubly curved functionally graded (FG) laminated composite shells integrated with a patch of active constrained layer damping (ACLD) treatment under the thermal environment. Vertically/obliquely reinforced 1-3 piezoelectric composite (PZC) and active fiber composite (AFC) are used as the materials of the constraining layer of the ACLD treatment. Each layer of the substrate FG laminated composite shell is made of fiber-reinforced composite material in which the fibers are longitudinally aligned in the plane parallel to the top or bottom surface of the layer and the layer is assumed to be graded in the thickness direction by way of varying the fiber orientation angle across its thickness according to a power law. The novelty of the present work is that, unlike the traditional laminated composite shells, the FG laminated composite shells are constructed in such a way that the continuous variation of material properties and stresses across the thickness of the shell is achieved. The Golla-Hughes-McTavish (GHM) method has been implemented to model the constrained viscoelastic layer of the ACLD treatment in time domain. Based on the first-order shear deformation theory (FSDT), a finite element (FE) model has been developed to model the open-loop and closed-loop nonlinear dynamics of the overall FG laminated composite shell under a thermal environment. Both symmetric and asymmetric FG laminated composite doubly curved shells are considered for presenting the numerical results. The analysis suggests that the ACLD patch significantly improves the damping characteristics of the doubly curved FG laminated composite shells for suppressing their geometrically nonlinear transient vibrations. It is found that the performance of the ACLD patch with its constraining layer being made of the AFC material is significantly higher than that of the ACLD patch with vertically/obliquely reinforced 1-3 PZC constraining layer. The effects of variation of piezoelectric fiber orientation in both the obliquely reinforced 1-3 PZC and the AFC constraining layers on the control authority of the ACLD patch have also been investigated.     

Active damping of geometrically nonlinear vibrations of laminated composite plates using vertically reinforced 1-3 piezoelectric composites

This paper addresses the analysis of active constrained layer damping (ACLD) of geometrically nonlinear transient vibrations of laminated composite plates using vertically reinforced 1-3 piezoelectric composite (PZC) as the material of the constraining layer of the ACLD treatment. The Von Kármán type nonlinear strain-displacement relations and the first-order shear deformation theory (FSDT) are used for deriving the coupled electromechanical nonlinear finite element model. The Golla?CHughes?CMcTavish (GHM) method has been used to model the constrained viscoelastic layer of the ACLD treatment in the time domain. The numerical results indicate that the ACLD patches significantly improve the damping characteristics of the cross-ply and antisymmetric angle-ply plates for suppressing the geometrically nonlinear transient vibrations of the plates.     

Active control of geometrically nonlinear transient vibrations of laminated composite cylindrical panels using piezoelectric fiber reinforced composite

This paper addresses the analysis of active constrained layer damping (ACLD) of geometrically nonlinear transient vibrations of laminated thin composite cylindrical panels using piezoelectric-fiber- reinforced composite (PFRC) materials. The constraining layer of the ACLD treatment is considered to be made of the PFRC materials. The Golla–Hughes–McTavish (GHM) method has been implemented to model the constrained viscoelastic layer of the ACLD treatment in time domain. The Von Kármán type-nonlinear strain-displacement relations and a simple first-order shear deformation theory are used for deriving this electromechanical coupled problem. A three-dimensional finite element (FE) model of smart composite panels integrated with the patches of such ACLD treatment has been developed to demonstrate the performance of these patches on enhancing the damping characteristics of thin symmetric and antisymmetric laminated cylindrical panels in controlling the geometrically nonlinear transient vibrations. The numerical results indicate that the ACLD patches significantly improve the damping characteristics of both symmetric and antisymmetric panels for suppressing the geometrically nonlinear transient vibrations of the panels. The effect of the shallowness angle of the panels on the control authority of the patches has also been investigated.     

Analysis of smart damping of laminated composite beams using mesh free method

This paper is concerned with the development of mesh free model for the performance analysis of active constrained layered damping (ACLD) treatments on smart laminated composite beams. The overall structure is composed of a substrate laminated composite beam integrated with a viscoelastic layer and a piezoelectric layer attached partially or fully at the top surface of the substrate beam. The piezoelectric layer acts as the active constraining layer of the smart beam and the viscoelastic layer acts as the constrained layer. A layer wise displacement theory has been used to derive the models. Both symmetric cross-ply and antisymmetric angle-ply laminated beams are considered for the numerical analysis. It is observed that ACLD treatment significantly improves the active damping properties of the substrate beam. The numerical results also reveal that the triangular ACLD treatment is more effective than the rectangular ACLD treatment of same thickness and volume for active damping of smart composite beams.     

Synthesis and characterization of electrochromic poly(amide–imide)s bearing methoxy-substituted triphenylamine units

New poly(amide–imide)s (PAIs) 3a–d and 3′a–d with methoxy-substituted triphenylamine (TPA) units were prepared by the direct polycondensation from various imide ring-preformed dicarboxylic acids 2a–d with 4,4′-diamino-2″,4″-dimethoxytriphenylamine (1) and 4,4′-diamino-4″-methoxytriphenylamine (1′), respectively, using triphenyl phosphite and pyridine as condensing agents. For the comparative study, the referenced PAIs 3″a–d without methoxy substituents on the TPA unit were also prepared from 2a–d with 4,4′-diaminotriphenylamine (1″). All the polymers were readily soluble in many organic solvents and could be solution-cast into tough and flexible polymer films. The glass-transition temperatures (T_gs) of these PAIs ranged from 196 to 298 °C and the 10% weight-loss temperatures were in excess of 445 °C in nitrogen. Cyclic voltammograms of the PAI films cast onto the indium–tin oxide (ITO)-coated glass substrate exhibit one reversible oxidation redox couples at 0.73–0.89 V vs. Ag/AgCl in an electrolyte/acetonitrile solution. The polymer films revealed good electrochemical and electrochromic stability, with coloration change from a pale yellow neutral form to a green oxidized form. After over 100 redox cycles, the polymer films still exhibited good redox and electrochromic reversibility. The 3 and 3′ series PAIs exhibited enhanced redox-stability and electrochromic performance as compared to the parent 3″ analogs without methoxy substituents on the TPA unit.     

Active control of large amplitude vibrations of smart magneto–electro–elastic doubly curved shells

This paper deals with the analysis of active constrained layer damping (ACLD) of large amplitude vibrations of smart magneto–electro–elastic (MEE) doubly curved shells. The constraining layer of the ACLD treatment is composed of the vertically/obliquely reinforced 1–3 piezoelectric composite (PZC). The constrained viscoelastic layer of the ACLD treatment is modeled by using the Golla–Hughes–McTavish method in the time domain. A three-dimensional finite element model of the overall smart MEE doubly curved shells has been developed taking into account the effects of electro–elastic and magneto–elastic couplings, while the von Kármán type nonlinear strain displacement relations are used for incorporating the geometric nonlinearity. Influence of the curvature ratio, the curvature aspect ratio, the thickness aspect ratio on the nonlinear frequency ratios of the MEE doubly curved shells has been investigated. Effects of the location of the ACLD patches and the edge boundary conditions on the control of geometrically nonlinear vibrations of paraboloid and hyperboloid MEE shells have been studied. Particular attention has been paid to investigate the performance of the ACLD treatment due to the variation of the piezoelectric fiber orientation angle in the 1–3 PZC constraining layer of the ACLD treatment.     

Rational design and characterization of high-efficiency planar A–π–D–π–A type electron donors in small molecule organic solar cells: A quantum chemical approach

Taking the reported donor DR3TBDT as reference, a series of A–π–D–π–A type donor molecules involving different planar donor cores were designed and investigated by using density functional theory (DFT)/time-dependent DFT methods. Preliminary calculations on geometries, energy levels and spectrum properties show that four of the designed molecules (4, 5, 12 and 13) could become potential donor replacements of DR3TBDT due to their good planarity, larger light harvesting efficiencies and similar exciton migration capability. Additionally, several factors influencing on short-circuit current density (J_sc) were analyzed by in-depth quantum chemical investigations on the transition density matrix, charge transfer indexes, exciton binding energy and Gibbs free energy loss in charge dissociation process. Comparative analyses demonstrate that 4 with indaceno[1,2-b:5,6-b′]dithiophene donor core has more significant electron transfer character and favorable exciton dissociation capability for enhancing the J_sc, and would be potentially promising donor material in organic solar cells.     

Multilayer films consisted of azulene-based dye molecules and polyelectrolyte: Preparation, characterization and photoluminescent property

Ultrathin multilayer films of two azulene-based (Az-based) dye molecules (Az), 3-methylazulene-1-carboxylic acid hydrazide (Az-1) and 5-(4-phenylamine)-2-(3-methylazulene-1-yl)-1,3,4-oxadiazoles (Az-2), and poly(sodium 4-styrenesulfonate) (PSS) have been prepared by layer-by-layer self-assembly and characterized by UV-vis spectroscopy, fluorescence spectroscopy, small-angle X-ray reflectivity measurements and atomic force microscopy (AFM) imaging. UV-vis spectra show that the characteristic absorbance values of the multilayer films increase almost linearly with the number of PSS/Az bilayers, suggesting that the deposition process is regular and highly reproducible from layer to layer. Average thicknesses for the PSS/Az-1 and PSS/Az-2 bilayers of the multilayer films are ca. 0.9 and 1.4 nm, respectively. AFM images provide the surface morphology of the PSS/Az films, indicating that the film surface is relatively uniform and smooth. The occurrence of photoluminescent activity conforms the potential for creating luminescent multilayer films with Az-based dye molecules.     

New diketopyrrolopyrrole based D–A–D π-conjugated molecules: Synthesis,optical, electrochemical,morphological and photovoltaic properties

Two solution processable donor–acceptor, π-conjugated molecules that consist of diketopyrrolopyrrole (DPP) central acceptor unit with dibenzofuran (DPP-DBF) or acenaphtene (DPP-ACN) donor substituents, were prepared by Suzuki coupling reaction. The optical, electrochemical and film forming properties of these D–A–D molecules were investigated and used as active materials in bulk heterojunction solar cells.     

Crystal structure,nonlinear optical and photophysical properties of a novel chromophore constructed with terpyridine,triphenylamine and ethyl cyanocaetate functional moieties

A novel chromophore (Z)-ethyl-3-(4-((4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl) (phenyl) amino)phenyl)-2-cyanoacrylate(3), constructed with triphenylamine moiety as the electron donor (D), 2, 2: 6, 2-terpyridine moiety as an electron acceptor (A), and ethyl cyanocaetate group as an auxiliary electron acceptor (A′), has been designed and synthesized. The crystal structures of 3 and its mediator 2 (4″-(4′-(4-(Diphenylamino) phenyl) aldehyde)-2,2′:6′,2″-Terpyridine), have been determined by single crystal X-ray diffraction analysis. The linear and nonlinear spectra of these chromophores were investigated on the basis of experimental and calculation methods. The two-photon absorption (TPA) cross-sections of 1–3 were determined by a femtosecond open-aperture Z-scan technique. The maximum value of the TPA cross-section (σ) for 3 is 7938.3 GM in DMF solution. However, much weaker two-photon absorption responses were observed at the same condition for chromophore 1 and 2, respectively. The results of the work indicate that, the photophysical properties of the D–A configuration group are influenced largely by the auxiliary moiety (A′) attached.     

Road accident involvement per miles travelled—V

This paper concludes a series reporting on the methods and results of the Queensland Vehicle-Mile Performance Survey. The earlier parts of the series appeared in Accident Analysis and Prevention7, 191–205; 8, 97–127; 9, 21–54; 10, 143–176. The variable treated in this part is sex of driver. The entire series will be published in book form by Pergamon Press.     

Smart damping of geometrically nonlinear vibrations of composite shells using fractional order derivative viscoelastic constitutive relations

In this article, a three-dimensional fractional order derivative model has been developed for the constrained viscoelastic layer of the active constrained layer damping (ACLD) treatment of laminated composite shells undergoing geometrically nonlinear vibrations. The constraining layer of the ACLD treatment is made of vertically/obliquely reinforced 1–3 piezoelectric composites and acts as the distributed actuator. A three-dimensional smart nonlinear finite element model has been developed. Several numerical results are presented to check the accuracy of the present three-dimensional fractional derivative model of the constrained viscoelastic layer for smart damping of geometrically nonlinear vibrations of laminated composite shells.     

Synthesis of diketopyrrolopyrrole (DPP)-based small molecule donors containing thiophene or furan for photovoltaic applications

Two π-conjugated small molecules based on diketopyrrolopyrrole (DPP), DPP4T and DPP2F2T, were synthesized using the Suzuki coupling reaction. DPP4T and DPP2F2T contained furan and thiophene, respectively, next to a DPP core. Organic photovoltaic cells (OPVs) were fabricated using two DPP-based oligothiophenes as donors. DPP4T showed higher power conversion efficiency (PCE) (1.44%) than DPP2F2T (0.85%). The short-circuit current (J_SC) of DPP4T (4.38 mA cm⁻²) was nearly twice that of DPP2F2T (2.49 mA cm⁻²). The improved photovoltaic properties of DPP4T could be explained by the optical properties and the film morphology.     

Carbohydrate derived copoly(lactide) as the compatibilizer for bacterial cellulose reinforced polylactide nanocomposites

A novel, entirely bio-derived polylactide carbohydrate copolymer (RP1) is used as a compatibilizer, to produce bacterial cellulose (BC) poly(l-lactide) (PLLA) nanocomposites with improved mechanical properties. Contact angle measurements of RP1 droplets on single BC nanofibres proved that it has a higher affinity towards BC than PLLA. RP1 has a comparable Young’s modulus, but lower tensile strength, than PLLA. When RP1 was blended with PLLA at a concentration of 5 wt%, the tensile modulus and strength of the resulting polymer blend decreased from 4.08 GPa and 63.1, respectively, for PLLA to 3.75 GPa and 56.1 MPa. A composite of BC and PLLA (with 5 wt% RP1 and 5 wt% BC) has a higher Young’s modulus and tensile strength, compared to either pure PLLA or PLLA–BC nanocomposites.     

Towards understanding the nanomaterials characteristics of vapor transported CdS in an open end tube

In this study, the evaporation condensation of CdS was carried out in a quartz tube with an open end. The synthesis was carried out on Au coated Si(100) and quartz substrates. The Au coated Si and quartz substrates were put approximately 1 cm and up to 25 cm away from the alumina boat. It was observed that the materials deposited on the substrates in the reactor tube formed with different colors in different regions. The regions were found to be 6–14 cm, 14–18 cm and 18–24 cm away from the center of the alumina boat and were labeled B, C and D, respectively. The morphology, structural and chemical composition of the obtained materials at different regions were investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive analysis of X-ray (EDAX), respectively. EDAX analysis revealed the presence of Cd and S with nearly stoichiometric CdS at region B. At region C a pronounced peak of oxygen was observed together with the peaks of Cd and S. At region D the S peak was diminished. XRD examinations revealed the formation of single crystalline phase of hexagonal CdS in region B. Mixed crystalline phases of hexagonal CdS, monoclinic cadmium sulfite, CdSO₃, and cubic CdO were formed in region C. Cubic CdO was formed in region D. The SEM examinations showed that the morphology of CdS was nanowires (NWs) in shape. The morphology of the mixed oxysulfide phase was a mixture between NWs and nanoparticles (NPs). The morphology of CdO was NPs in shape. The optical constants, the thickness and the surface roughness of the prepared nanostructured films were determined by spectroscopic ellipsometry measurements. A model consisted of two layers was used to fit the calculated data to the experimental ellipsometric spectra. The obtained optical constants were compared with those of CdS and CdO obtained by other preparation methods.     

Thermally and electrochemically stable amorphous hole-transporting materials based on carbazole dendrimers for electroluminescent devices

Amorphous hole-transporting carbazole dendrimers, 1,4-bis[3,6-di(carbazol-9-yl)carbazol-9-yl]-2,6-di(2-ethylhexyloxy)benzene (G2CB) and 1,4-bis[3,6-di(carbazol-9-yl)carbazol-9-yl]-9-(2-ethylhexyl)carbazole (G2CC), were synthesized by a divergent approach involving bromination and Ullmann coupling reactions. Compounds G2CB and G2CC showed high thermal stability (T_g = 206 to 245 °C) and excellent electrochemical reversibility. Double-layer organic light-emitting diodes were fabricated by using G2CB and G2CC as hole-transporting layers (HTLs) and tris(8-quinolinato)aluminum (Alq₃) as light-emissive layer with the device configuration of indium tin oxide/HTL/Alq₃/LiF:Al. Both devices exhibited bright green emission from Alq₃. The device using G2CC as HTL has the best performance with a maximum brightness of 8900 cd/m² at 14 V and a low turn-on voltage of 3.5 V.     

Electro-optical properties of poly[di(2-thiophenyl)carborane] and its opto-electronic application

Electrochemical and optical properties of a hybrid carborane based polymer called poly(di(2-thiophenyl)carborane) (P1) obtained electrochemically were reported as well as its electrochromic device application. Thiophene donor units and m-carborane acceptor unit were combined under the same umbrella via donor–acceptor–donor approach to obtain di(2-thiophenyl)carborane (1). Contrary to the literature, extreme conditions like highly dried solvent or inert atmosphere were not used for polymerization and characterization. Polymer P1 has an ambipolar character since it exhibited a reversible oxidation peak at a half wave potential (E_1/2) of 1.08 V and a quasi reversible reduction peak at E_1/2 = −1.82 V vs. Ag/AgCl. The polymer film has an optical band gap of 1.95 eV with a maximum absorption band centered at 488 nm. Also, it exhibited multicolor electrochromic behavior between its reduced and oxidized states changing from dark orange to light blue. Furthermore, the electrochromic device prepared based on P1 film was stable and robust.     

Preparation and magnetic properties of SrFe12O19/Ni0.5Zn0.5Fe2O4 nanocomposite ferrite microfibers via sol–gel process

SrFe₁₂O₁₉/Ni_0.5Zn_0.5Fe₂O₄ nanocomposite ferrite microfibers with diameters of 1–2 μm have been prepared by the sol–gel process. The SrFe₁₂O₁₉/Ni_0.5Zn_0.5Fe₂O₄ nanocomposite ferrites are formed after the precursor calcined at 850 °C for 2 h, fabricating from nanosized particles with a uniform phase distribution. The ferrite grain size increases with the calcination temperature. The magnetic properties for the nanocomposite ferrite microfibers are mainly influenced by the chemical composition and grain size. The nanocomposite ferrite microfibers obtained at 900 °C show the enhanced specific saturation magnetization (M_sh) of 64.8 Am² kg⁻¹, coercivity (H_c) of 146.5 kA m⁻¹ and remanence (M_r) of 33.6 Am² kg⁻¹ owing to the exchange–coupling interaction. This exchange–coupling interaction in the SrFe₁₂O₁₉/Ni_0.5Zn_0.5Fe₂O₄ nanocomposite ferrite microfibers has been discussed.     

The effect of solution chemistry on the preparation of MgAl2O4 by hydrothermal-assisted sol-gel processing

Preparation of magnesium aluminate spinel powder by hydrothermal-assisted sol-gel processing from MgAl₂(OCH₂CH₂OR)₈, RCH₃ (1), CH₂CH₂OCH₃ (2), MgAl₂[OCH(CH₃)₂]₈ (3) and MgAl₂(O-^sBu)₈ (4) in toluene and parent alcohol has been investigated. Coordination status of aluminum atom in precursors was determined by ²⁷Al NMR and correlation between coordination number of aluminum and development of spinel phase in hydrothermal-assisted sol-gel processing has been studied. The gels obtained from hydrothermal-assisted hydrolysis of magnesium-aluminum alkoxides that contain six-coordinated aluminum atoms in solution (1 and 2) after calcination at 700 °C resulted in the formation of pure spinel phase, whereas in similar hydrolysis and calcination processes of precursors that contain four-coordinated aluminum (3 and 4) spinel phase forms along with some Al₂O₃ and MgO. Selected powders obtained from hydrothermal-assisted sol-gel processing were characterized by thermal analysis (TGA/DSC), X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). Results indicate that the coordination status of aluminum in the precursor is very crucial for the formation of pure phase spinel. The morphology of prepared spinels was studied by SEM and the results showed that the solvent in hydrothermal-assisted sol-gel processing has a marked effect on the morphology of the resulting MgAl₂O₄. In hydrothermal-assisted sol-gel processing of aluminum-magnesium alkoxides in hydrophobic solvent, spherical particles are formed, while in the parent alcohol, non-spherical powders are formed.     

Role of chain length and spacers in the organization of long chain Schiff base compounds at air/water and solid/liquid interfaces

Langmuir films of long chain Schiff base compounds: N-(4-fluorobenzylidene)hexadecanamine (compound 1), N-(4-fluorobenzylidene)octadecanamine (compound 2) and 4-{[(4-fluorobenzylidene)amino]methyl}-N-hexadecylaniline (compound 3) have been studied at air/water interface using the characteristic surface pressure-molecular area (π-A) and surface potential-molecular area (ΔV-A) isotherms. Photoelastic modulated Fourier transform infrared spectroscopy has been used to analyze the films of the three compounds at air/water interface. The Langmuir-Blodgett films of these compounds have been characterized using X-ray diffraction that shows layered structures, with interlayer distances of up to 4.4 nm for compound 3. The results show that the layer-to-layer distance can be easily and rationally designed by choosing alkyl chains of different lengths and spacer. Compound 3 packs in an interdigitated bilayer structure with longer lamellar spacing whereas compounds 1 and 2 show a noninterdigitated monolayer structure. Atomistic model calculations have been carried out on the three compounds and the dipole moment values obtained agreed well with the experimental results of surface potential in Langmuir films. Among the three compounds, compound 3 forms stable vesicles spontaneously at room temperature.