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1.
In recent years, the recycling and composting of municipal solid wastes has gained acceptance as an alternative to landfilling and incineration. Compost materials have been used as soil amendments in landscaping, erosion control, expansive soil treatment, and turf management. Compost amended soils are enriched with decomposed organic matter and hence usually exhibit different strength and compressibility in soil behaviors. An experimental investigation was carried out on compost amended soils to understand the effects of decomposed organic matter on strength and volume change properties. Two types of composts, a biosolids compost and a dairy manure compost, and a control cohesive soil were chosen as test materials. Tests conducted on these materials showed that the presence of organic matter enhanced shrinkage resistance and shear strength at low compost proportions (20–30%). At high proportions (beyond 30%), the shear strength reached plateau conditions. One-dimensional vertical swell and secondary consolidation properties increased with an increase in compost proportions. As low proportions of composts yielded better enhancements to most expansive soil properties, it was concluded that compost materials can provide engineering benefits to control soils when used in moderate proportions.  相似文献   

2.
Classical analyses for volatile flavors (headspace or distillation/extract methods) give information on either the volatiles present in the air above a food before eating or the total volatile composition of the food. When foods are eaten, however, many changes take place (such as hydration/dilution with saliva, increase in surface area, etc.) that affect the release of volatiles from the food and therefore the profile of volatiles that are sensed in the nose. If we wish to study the relationship between flavor volatiles and the sensory properties of a food, it seems logical to measure the volatile profile that exists during eating. Although volatile flavor release during eating has been measured using a variety of sensory and psychophysiological analyses, only recently have instrumental methods been developed to measure the release of volatile compounds in humans as they eat. Whereas the sensory data give an overall measure of flavor perception, instrumental analyses can potentially follow the release of each and every flavor volatile and thus give a full picture of the aroma profiles generated during eating. From these instrumental measurements, a number of key factors have been identified. First, it has been shown that the volatile profile measured during eating is indeed different from the headspace profile of whole foods. Second, it is clear that the volatile profile in-mouth changes with time as the state of the food changes with chewing. Third, the volatile release from low-water foods is affected by the rate and extent of hydration in-mouth. The ability to measure aroma before, during, and after eating may lead to an understanding of the links between aroma release, interaction of volatiles with aroma sensors in the nose, and the overall perception of food flavor.  相似文献   

3.
This study is the first to report the effect of water saturation on the retardation of nonionic organic compounds under dynamic conditions. Three nonaggregated sandy soil samples, that varied in their organic carbon content but had similar grain size distributions, were utilized. Two nonionic organic compounds were used: (1) dimethylphthalate, which served as a nonvolatile compound; and (2) benzene, which was volatile. Results showed that retardation coefficients for unsaturated soils are higher than those determined when the soil is saturated. The extent of deviation in retardation between the saturated and unsaturated soils generally increased as the degree of water saturation was reduced. No functional relationship between the extent of deviation in the retardation coefficient and the amount of organic carbon on the soil was found. When normalized to the saturated solid-to-water ratio, retardation coefficients for dimethylphthalate determined at different degrees of saturation were similar, leading to the conclusion that the distribution coefficient did not increase as the media was desaturated. Volatilization did not significantly affect the retardation of benzene under the employed range of saturation. Theoretical analysis showed that the impact would be significant for volatile compounds with higher Henry's coefficients and in aquifers with low organic matter content. Diffusive transport in the air phase had a significant impact on the spreading of benzene. Previously developed empirical relations reasonably predicted this impact.  相似文献   

4.
Decomposed granite (DG) soils are very erosive and, when disturbed, are difficult to revegetate. Sediment eroding from DG roadcuts can severely impact nearby drainage basins. Two ways of reducing surface erosion are to increase the surface saturated hydraulic conductivity (Ksat) of the soil and to stabilize the surface with vegetation. This study examined the ability of unscreened yard waste compost to increase the Ksat of these soils and facilitate revegetation. A compost application rate of 24% by volume increased postconstruction Ksat of a DG roadcut to levels comparable to a revegetated reference site. The establishment of vegetation was important to maintain the initial increase in Ksat associated with tillage and compost amendment. By the second year, above-ground biomass significantly increased with increasing compost amendment rate. There was also a significant increase in soil Ksat in the 12 and 24% compost treatments in the second year compared to the first year, indicating the strong influence of plant growth on soil surface hydrology.  相似文献   

5.
Nitric oxide (NO) emissions from soil amended with municipal wastewater biosolids or mineral fertilizer can adversely impact ozone levels in the lower troposphere and are studied here. A comprehensive laboratory protocol was developed and conducted to consider the influence of biosolids-amended (BSA) soil and mineral-fertilizer-amended (MFA) soil, as compared with unamended soil, on NO emissions with varying temperature, moisture content, and pH. NO plays an important role in the formation of tropospheric ozone. Minimization of NO flux from soil is advantageous, protecting air quality as well as conserving valued nitrogen fertilizers. BSA and MFA soils were found to produce NO emissions over five times greater than unamended soils. Distinctions between NO flux from MFA and BSA soil cannot be made. NO flux from soils at pH 6.25 and 6.75 were not found to be statistically different. Soils with higher water-filled pore space (WFPS) and temperature are generally shown to produce greater quantities of NO within the range of temperature (15°–28°C) and WFPS (3–40%) studied.  相似文献   

6.
Poultry litter is composted to reduce odor and pathogens and to improve its quality as a soil amendment. Organic material, e.g., sawdust, is added to increase the C:N ratio to achieve optimum degradation of organic C and retention of N through microbial biomass formation. However, the relative biodegradabilities of the organic material in poultry litter and the amendment are usually not known. Furthermore, it is assumed that as microorganisms metabolize organic compounds and produce CO2, they increase in biomass and, therefore, retain N. In this study, bench-scale compost reactors were used to determine the relative contributions of poultry litter and of the amendment (sawdust) to the biodegradability of a compost mix. Approximately 29% of the volatiles lost from the poultry litter mix came from the sawdust. Fiber analyses revealed that only a small portion of cellulose was degraded. Although microbial subpopulations able to degrade selected macromolecules were present at varying levels, the overall level of microorganisms did not change markedly. Populations capable of degrading bacterial cell walls were present throughout the composting period, and microbiological assays indicated that inorganic nutrients were available to support limited microbial growth. These results suggest that N compounds and inorganic nutrients are recycled, rather than fixed during composting.  相似文献   

7.
1. In glass-house trials the influence of residues of clover, grass, and mixtures (1:1) of them added to natural and partially sterilized loam soil upon the parasitic activity of Rhizoctonia solani and the soil micro-organisms and their activity was analyzed. 2. Burying of plant residues (1%) increased the content of organic substance in soil for 8 weeks and longer. 3. The soil reaction (pH) was not noteworthy affected by application of clover or grass residues. 4. However, the populations of bacteria and actinomycetes were increased, especially by adding clover dried. In natural soil, the maximum of stimulation was reached later than in soil sterilized. Adding of grass and roots of grass enlarged the spectrum of fungi observed in the soil amended. Roots of grass stimulated the cellulose-decomposing organisms remarkably. 5. The activity of dehydrogenase (AD) was influenced in different manner: in natural soil fresh clover, grass, mixtures of them, and clover dried increased, and fresh roots of clover, grass, and mixtures of them diminished AD; in soil sterilized the most variants stimulated this activity. 6. All plants residues increased the cellulolytic activity of soil for a long time, but in sterilized soil this effect reached its maximum earlier than in natural soil amended and did not last so long, too. 7. The possible explanations for the inhibition of parasitic activity of Rhizoctonia solani caused by burying plant residues are discussed.  相似文献   

8.
In this study, microcosm experiments were conducted to evaluate the effectiveness of (1) nutrients, hydrogen peroxide (H2O2), and cane molasses addition; (2) soil washing by biodegradable surfactant [Simple Green (SG)]; and (3) soil pretreatment by Fenton-like oxidation on the bioremediation of fuel-oil contaminated soils. The dominant native microorganisms in the fuel-oil contaminated soils after each treatment process were determined via polymerase chain reaction, denaturing gradient gel electrophoresis, and nucleotide sequence analysis. Results show that approximately 32 and 56% of total petroleum hydrocarbon (TPH) removal (initial concentration of 5,000?mg?kg?1) were observed in microcosms with the addition of nutrient and cane molasses (1,000?mg?L?1), respectively, compared to only 9% of TPH removal in live control microcosms under intrinsic conditions (without amendment) after 120 days of incubation. Addition of cane molasses would cause the increase in microbial population and thus enhance the TPH degradation rate. Results also show that approximately 61% of TPH removal was observed in microcosms with the addition of H2O2(100?mg?L?1) and nutrient after 120 days of incubation. This indicates that the addition of low concentration of H2O2(100?mg?L?1) would cause the desorption of TPH from soil particles and increase the dissolved oxygen and subsequent bioremediation efficiency in microcosms. Approximately 95 and 69% of TPH removal were observed in microcosms with SG (100?mg?L?1) and higher dose of H2O2(900?mg?L?1) addition, respectively. Moreover, significant increases in microbial populations were observed and two TPH biodegraders (Pseudomonas sp. and Shewanella sp.) might exist in microcosms with SG or H2O2 addition. This indicates that the commonly used soil remedial techniques, biodegradable surfactant flushing, and Fenton-like oxidation would improve the TPH removal efficiency and would not cause adverse effects on the following bioremediation process.  相似文献   

9.
Juvenile Eisenia fetida (Savigny) were exposed for 20 weeks to an uncontaminated soil and to soils contaminated with cadmium, copper, lead, and zinc collected from seven sites at different distances from a smelting works at Avonmouth, southwest England. The survival, growth (= weight after 5 weeks exposure), time to sexual maturation (= percentages of adults present after 8 weeks), and reproduction (= number of cocoons produced by the worms) were compared with soil metal concentrations. Of the parameters measured, growth and sexual maturation time had the lowest EC50 values. The effects of metal-contaminated soils could be attributed both to the direct toxicity of the metals and to changes in the "scope for growth" of the exposed worms. A comparison of the results with those of an earlier toxicity test conducted with adult worms indicated that juveniles are more sensitive to metals than adults. Significant toxic effects on the growth and sexual maturation times of juveniles were detected in soils from sites for which no significant effects on the cocoon production of adults could be detected. The greater sensitivity of juvenile worms indicates the importance of considering effects on a variety of life history stages when conducting a risk assessment of the effects of pollutants in soils. Although E. fetida does not occur naturally in soils at Avonmouth, the present study provides evidence to support the suggestion that pollution from the smelter is responsible for the absence of worms within 2 km of the factory. Results presented in this paper, and from previous studies, suggest the observed absence is due to the effects of zinc on the growth and maturation of juveniles and the cocoon production rate of adult worms.  相似文献   

10.
The potential for the use of kiln ash as an additive to Lateritic soils to improve their engineering characteristics as road construction material was experimentally investigated. The results of laboratory tests indicate that no significant improvement of the soil properties occurred until after several weeks of curing time. In general, as the content of kiln ash in the soil was increased, the soil pH increased from 5.5 to 11.8; the maximum unconfined shear strength increased from 340 to 423 kPa (corresponding to 0–8% kiln ash content), the soil liquid limit reduced from 59 to 49% (corresponding to 0–20% kiln ash as content). No significant change in the plasticity limits of the lateritic soil was observed, in the range of 0 to 8% kiln ash content. Relative to the compressibility of the natural soil (measured in terms of the total strain), a decrease of about 3% occurred for kiln ash contents of 5, 10, and 20% within 1 to 7 days; and that this decrease reached about 19% for 20% kiln ash content as time progressed (to more than 177 days). These results imply that significant and desirable changes in soil compressibility can be achieved after a few months if the soils are admixed with kiln ash. Soil solution pH changes cause a time-dependent increase in soil strength, where calcium cations combine with silica and aluminum of the soil to form insoluble cementitious materials.  相似文献   

11.
Infiltration of Water into Soil with Cracks   总被引:2,自引:0,他引:2  
This paper presents the physical basis of the FRACTURE submodel for simulating infiltration of precipitation∕irrigation water into relatively dry, cracked, fine-textured soils. The FRACTURE submodel forms part of the HYDRUS-ET variably saturated flow∕transport model. Infiltration into the soil matrix is formally divided into two components: (1) Vertical infiltration through the soil surface; and (2) lateral infiltration via soil cracks. The first component is described and solved using the 1D Richards' equation. Excess water that does not infiltrate through the soil surface is either considered to be runoff, if no soil cracks are present, or routed into soil cracks from where it may laterally infiltrate into the soil matrix. Horizontal infiltration from soil cracks into the soil matrix is calculated using the Green-Ampt approach and incorporated as a positive source∕sink term Sf in the Richards' equation describing flow in the matrix. In addition to the hydraulic properties of the soil matrix, the FRACTURE submodel requires parameters characterizing the soil cracks, notably the specific crack length per surface area lc and the relationship between crack porosity Pc and the gravimetric soil water content w. An example problem shows that infiltration from soil cracks can be an important process affecting the soil water regime of cracked soils. A comparison with the more traditional approach, involving surface infiltration only, indicates important differences in the soil water content distribution during a rainfall∕irrigation event. This extension of the classical approach to include crack infiltration significantly improves the identification and prediction of the soil water regime.  相似文献   

12.
The degradation of deethylatrazine (DEA), a major metabolite of atrazine, was studied by using radiotracers in soils with two different atrazine histories. DEA degradation was enhanced in soils which had received long-term exposure to atrazine (atrazine-history soil) compared with soils that had not received long-term atrazine exposure (no-history soil). After 60 days of incubation, mineralization of DEA to 14CO2 in the atrazine-history surface soil was twice that in the no-history surface soils, with 34% and 17% of the applied 14C-DEA as CO2, respectively. In surface soils, 25% of the applied 14C remained as DEA in the atrazine-history soil, compared with 35% in the no-history soil. Microbial plate counts indicated an increase in numbers of bacteria and fungi in soils incubated with DEA compared to control soils. No significant difference in total microbial respiration was seen among atrazine-history and no-history soils incubated with DEA, but DEA-treated soils had greater microbial respiration than untreated control soils after 6 days. A 14C-most-probable-number procedure was used to enumerate specific DEA degraders. A greater number of DEA degraders were indicated in atrazine-history subsurface soil compared with all other soils in this study (p < 0.05). From this study, it appears that an increase in microbial activity contributes to decreased persistence and increased degradation of DEA in soils that have had long-term exposure to atrazine at field application rates, compared to soils with no long-term exposure. Decreased persistence of this major metabolite of atrazine in atrazine-history soils is important in that there will be less available for movement in surface runoffs.  相似文献   

13.
Axenic cultures of the ammonia-oxidizing bacterium Nitrosomonas europaea were starved of ammonia (energy source) for up to 342 d. During this time the bacteria retained the ability to respond instantly to ammonia (1 mM) or hydroxylamine (0.1 mM) amendment by oxidizing it to nitrite without initial protein synthesis. In vivo, the ability to oxidize amended ammonia stayed almost constant during the starvation period, but a drop in the hydroxylamine oxidation rate (to 33%) was observed after 4 wk of starvation when exogenous hydroxylamine was supplied as sole energy source. In contrast, it has been shown that the level and in vitro activity of hydroxylamine oxidoreductase were not significantly affected during the starvation period. Only minor changes were detected between the protein patterns on one-dimensional SDS-PAGE of growing and starved cells. Thus, it is concluded that the activities of the energy-generating enzymes in N. europaea were not affected during long-term ammonia starvation.  相似文献   

14.
Human neutrophils (PMN) demonstrated potent fungistatic activity against Histoplasma capsulatum (Hc) yeasts in a sensitive microassay that quantifies the growth of yeasts by the incorporation of [3H]leucine. At a PMN:yeast ratio of 1:2, PMN inhibited the growth of yeasts by 37%. Maximum inhibition of 85% to 95% was achieved at a PMN/yeast ratio of 10:1 to 50:1. Opsonization of the yeasts in fresh or heat-inactivated serum was required for PMN-mediated fungistasis, but ingestion of the yeasts was not required. Recognition and phagocytosis of opsonized yeasts was via PMN complement receptor (CR) type 1 (CR1), CR3, and FcRIII (CD16). PMN fungistatic activity was evident by 2 h, was maximum at 24 h, and persisted up to 5 d. In contrast, yeasts multiplied within monocytes to a greater extent than in culture medium alone. PMN from three patients with chronic granulomatous disease (CGD) inhibited the growth of Hc yeasts by an average of 97%, compared with 86% in three normal controls. Furthermore, preincubation of PMN with the lysosomotropic agent NH4Cl inhibited fungistatic activity in a concentration-dependent manner. Finally, experiments with subcellular fractions of PMN demonstrated that the principal component of the fungistatic activity of PMN was localized in the azurophil granules. These data demonstrate that human PMN possess potent fungistatic activity against Hc yeasts and further show that fungistasis is mediated by antimicrobial agents contained in the azurophil granules.  相似文献   

15.
A simulation study was conducted with five soil amendments, viz., goat manure, coir pith, phosphogypsum, polyacrylamide, and a control at two rainfall intensities of 60 and 120?mm?h?1 under dry and wet soil conditions in a clay loam vertisol with the objective of identifying a superior soil amendment for maximum infiltration and suitable soil aggregate stability. The F-test based on analysis of variance of infiltration data indicated that soil amendments, rainfall intensities, and soil conditions were significantly different from each other. Based on least significant difference test, polyacrylamide was found to be superior with a significantly higher infiltration, compared to all other amendments. An exponential model of infiltration over a time interval was calibrated for each soil amendment under dry and wet soil conditions. Based on the model, polyacrylamide and phosphogypsum were found to have a better soil aggregate stability compared to other soil amendments. The exponential model gave a significant predictability of instantaneous infiltration ranging from 0.75 to 0.99 under different situations. A grouping of treatments based on mean and coefficient of variation of infiltration in comparison with soil aggregate stability values indicated that polyacrylamide was superior under different situations in the study. Phosphogypsum was found to be the second best soil amendment with a relatively lower infiltration compared to polyacrylamide, but with a better soil aggregate stability compared to other soil amendments. Coir pith, goat manure, and control gave a significantly lower infiltration with a relatively higher variation compared to polyacrylamide and phosphogypsum, and also had a relatively lower soil aggregate stability under different situations examined in the study.  相似文献   

16.
For reduction of iron oxides by volatiles from coal, the major reductant was found to be H2, and it can affect the overall reduction of iron oxides. In this study, the reduction by actual volatiles of composite pellets at 1000 °C was studied. The volatile reduction of the hand-packed Fe2O3/coal composite pellet as it is devolatilizing out of the pellet was found to be negligible. However, the reduction of iron oxide pellets at the top layer by volatiles from the bottom layers of a three-layer pellet geometry was observed to be about 15 pct. From the morphological observations of partially reduced pellets and the computed rates of bulk mass transfer, volatile reduction appears to be controlled by a mixed-controlled mechanism of bulk gas mass transfer and the limited-mixed control reduction kinetics. Using the reduction rate obtained from the single pellet experiments with pure hydrogen and extrapolating this rate to an H2 partial pressure corresponding to the H2 from the volatiles, an empirical relationship was obtained to approximately predict the amount of volatile reduction up to 20 pct.  相似文献   

17.
Volume changes due to wetting may occur in naturally deposited soils as well as earthen construction (e.g., compacted fills or embankments). Depending on the stress level, some soils exhibit increase in volume upon wetting (swell) while others may exhibit decrease in volume upon wetting (collapse). The work described in this paper focused on wetting-induced volume changes in compacted soils. Motivation for this work stemmed from observations of earthen structures that exhibit problematic behavior under wetting conditions, even though soils were compacted to engineering specifications (i.e., at or above minimum density and within moisture content ranges). Not only is this problematic behavior a concern but also the laboratory tests used to predict settlement of constructed facilities may not properly model the actual behavior of soil compacted under field conditions. For example, settlements experienced by compacted fills may be different from settlement predictions based on one-dimensional oedometer tests. These differences are partly related to the variations in the soil structure in tested specimens that arise because soil clods compacted in the laboratory are smaller than soil clods compacted in the field. The term “soil structure” includes the combined effects of soil fabric and interparticle forces. “Fabric” generally refers to the geometric arrangement of particles, whereas interparticle forces include physical and physicochemical interactions between particles. The soil structure in this case is associated with specimen preparation methods and is influenced by several factors including soil composition (including pore water chemistry), compaction method, clod sizes, initial moisture condition of clods, dry density or void ratio, and compaction moisture content. A laboratory research study was conducted to investigate the influence of variations in clod-size and structure on one-dimensional volume change, with emphasis on wetting-induced volume change, for nine different fine-grained soils. The results of the study suggest that the influence of structure in one-dimensional oedometer tests depends on soil type and nature of the clods in the compacted soil. Clayey soils appear to be influenced more by differences in structure, whereas silts or clayey sands of low plasticity (PI<10) do not appear to suffer as much from structure effects in one-dimensional oedometer tests. This is attributed to more extensive clod development in clayey soils. Furthermore, the moisture condition of clods appears to have an important influence on volume change behavior.  相似文献   

18.
The evaluation of pesticide-mineralising microorganisms to clean-up contaminated soils was studied with the widely applied and easily detectable compound atrazine, which is rapidly mineralised by several microorganisms including the Pseudomonas sp. strain Yaya 6. The rate of atrazine removal was proportional to the water content of the soil and the amount of bacteria added to the soil. In soil slurry, 6 mg atrazine kg soil-1 was eliminated within 1 day after application of 0.3 g dry weight inoculant biomass kg soil-1 and within 5 days when 0.003 g kg soil-1 was used. In partially saturated soil (60% of the maximal water-holding capacity) 15 mg atrazine kg soil-1 was used. In unsaturated soil, about 60% [U-ring-14C] atrazine was converted to 14CO2 within 14 days. Atrazine was very efficiently removed by the inoculant biomass, not only in soil that was freshly contaminated but also in soil aged with atrazine for up to 260 days. The bacteria exposed to atrazine in unsaturated sterile soil were still active after starvation period of 240 days: 15 mg newly added atrazine kg soil-1 was eliminated within 5 days.  相似文献   

19.
土壤改良剂是一种修复土壤退化的颗粒状物料。以我国年产1.3亿t的来计,制备完成后的土壤改良剂显热折合每年3.5×1013 kgce。目前,这部分显热几乎白白放散掉,基于此,本文构建、分析了一种土壤改良剂余热回收利用工艺流程及关键设备,建立了土壤改良剂余热回收竖罐气固传热解析模型,藉此确定了竖罐的结构和操作参数,为我国土壤改良剂余热回收探索了一条技术路径。研究结果表明:该工艺及装备可有效回收改良剂的显热;处理量为6 t/h时,罐体适宜的高度为2.2 m,气固水当量比为1.2;回收到的余热用于改良剂制备的回转窑中,可节约燃料22.86%。  相似文献   

20.
Sand compaction pile (SCP) is a ground improvement technique extensively used to ameliorate liquefaction resistance of loose sand deposits. This paper discusses results of laboratory tests on high-quality undisturbed samples obtained by the in situ freezing method at six sites where foundation soils had been improved with SCP. Inspection of samples revealed that the improved ground was desaturated during the ground improvement. Degree of saturation (Sr) was lower than 77% for the sand piles and 91% for the improved sand layers, while Sr was approximately 100% for improved clayey and silty soils. A good correlation was found between Sr and 5% diameter of the soil; the larger 5% diameter of soils (D5), the lower the degree of saturation. It appeared that the variation of Sr with D5 for soils within a month after the ground improvement work was quite similar in trend to that after more than several years. Degree of saturation of soils after several years was noticeably, but not significantly, higher as compared with that shortly after ground improvement, indicating longevity of air bubbles injected in the improved soil. Undrained cyclic shear tests were also carried out on saturated and unsaturated specimens and effects of desaturation on undrained cyclic shear strength were studied. The test results were summarized in a form of liquefaction resistance with reference to normalized standard penetration test N-value.  相似文献   

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