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纳米零价铁的强化改性及其对水污染治理最新研究进展 总被引:1,自引:0,他引:1
《化学世界》2015,56(1)
近年来,纳米零价铁的强化改性技术及其在水处理领域的应用成为研究热点。特别是针对卤代污染物、硝酸盐、重金属及废水中染料去除方面。介绍了纳米零价铁强化改性、负载功能化、工程实际应用及其对水污染治理研究进展,并对纳米零价铁改性的未来发展趋势进行展望。 相似文献
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介绍纳米氧化锌的制备方法以及表面改性技术进展。沉淀法是纳米氧化锌工业化生产方法,产品粒子小,粒径分布窄,分散性好。纳米氧化锌表面改性方法主要有表面包覆改性法、表面化学改性法、机械化学改性法和外膜层改性法等。 相似文献
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《Ceramics International》2015,41(6):7751-7758
Up to 5 wt% of nano-alumina or nano-iron oxide was added to magnesia refractory matrix. The crystalline phases and microstructure characteristics of specimens sintered at 1600 °C for 4 h in an electric furnace were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The physical properties are reported in terms of density and porosity. The mechanical behavior was studied by a cold crushing strength (CCS) test. In addition, the chemical behavior with regard to slag attack was studied by the SEM technique. As a result, it was found that the presence of nano-iron oxide in the magnesia matrix induced magnesioferrite spinel formation, which improved the sintering process. Nano-iron oxide also influenced the bonding structure through a direct bonding enhancement. On the other hand, the presence of nano-alumina in the magnesia matrix induced magnesium-aluminate spinel formation, resulting in lower properties in comparison with those obtained by nano-iron oxide addition. 相似文献
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Uniform pseudocube nano-iron oxide red (hematite)particles was prepared in the liquid phase by using δ-FeOOH as seed and iron as raw material at low temperature. The effects of such factors as initial pH of reaction, concentration of catalyst, reaction time on the preparation of these hematite particles were investigated. The product was characterized by XRD, IR, FESEM. The results showed that pure pseudocube hematite particles could be prepared under the experimental conditions of solution initial pH 7, β=0.09(β=[Fe2+]/[δ-FeOOH]), air oxidation temperature and time of 100℃ and 48 h respectively. The product crystallized integrally with particle diameter 90—100 nm, and its color was brightly red. This is a new method to prepare high-purity nano-iron oxide red with the characteristics of simple operation, non-pollution and low cost. 相似文献
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Nano-sized iron particle/carbon composites have been synthesized from a petroleum residue by heating at 420 °C with ferrocene under pressure. The morphologies and structural features of the composites were investigated using TEM, HREM and XRD measurements. The effect of ferrocene addition on the development of turbostratic carbon from the petroleum residue was discussed. It was found that, by increasing the amount of ferrocene added from 3% to 20%, the size of the nano-iron particles tended to increase from 20–80 nm to 30–180 nm. The iron particles pyrolyzed from ferrocene mainly exist in the forms Fe–O and Fe1−xS when the ferrocene content was low (3% and 6%), and α-Fe when ferrocene contents were high (10% and 20%). Upon further heat treatment in the range 500 to 900 °C, the iron particles tended to aggregate and Fe–O and Fe1−xS were transformed into α-Fe and austenite. In comparison with the carbon formed without ferrocene addition, the resulting carbon exhibited a turbostratic structure as shown by HREM, in which the d002 spacing decreased with the increase of ferrocene loading and increasing temperature, suggesting the carbonization was promoted by the catalysis of the nano-iron particles. 相似文献
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纳米铁在污染土壤和地下水的修复中受到广泛关注。为进一步探究其在多孔介质的迁移行为,本研究采用羧甲基淀粉钠(CMS)对纳米零价铁(nZVI)进行包覆,进行了改性纳米零价铁的沉降试验,测量zeta电位与粒径分布探究其分散性;进行了不同pH条件下改性纳米零价铁在酸洗砂与水洗砂的柱实验,分析了化学异质性与pH对纳米铁在多孔介质迁移的影响。结果表明,CMS包覆纳米铁不仅使纳米颗粒本身稳定,而且还减少其在多孔介质表面沉积,大大提高了迁移性。pH=6~8时,nZVI的zeta电位由18.3mV减小到2.9mV,有效粒径由685nm增大到880nm,稳定性变差;而CMS-nZVI的zeta电位值由-19.7mV增大到-53.5mV,颗粒间静电排斥力增强稳定性变好。经能量色散X射线光谱(EDS)分析,水洗砂表面存在碳、铝、铁等氧化物杂质,这些杂质带有正电荷,会增强与带负电的CMS-nZVI的吸附作用,不利于其迁移;而经过酸洗后的石英砂,其表面杂质大大减少,在pH=8时,CMS-nZVI在酸洗砂最大迁移率为77.0%要好于水洗砂的63.0%。此外较高pH环境有助于增加石英砂介质的表面负电荷,减少颗粒与介质的吸附,促进纳米颗粒的迁移。 相似文献
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《Diamond and Related Materials》2004,13(2):362-370
We present the single step preparation of nano-iron cores embedded in carbon layers and their preliminary application to the growth of carbon nanotubes. CO2 laser pyrolysis of volatile iron and carbon precursors in a gas flow reactor was used in order to obtain the Fe–C nanocomposites. The structure and composition of the obtained nanopowders were analysed by transmission electron microscopy, high-resolution transmission electron microscopy, electron energy loss spectroscopy and Raman spectroscopy. The results indicate that the synthesized carbon embedded iron nanoparticles (∼3–7 nm mean diameter) present sharp particle distributions. The degree of agglomeration and the number of surrounding carbon layers depend on the relative concentration of reactive donors. Silicon substrates seeded with a dilution of Fe–C nanocomposites were further used to catalyze nanotubes/nanofibres growth by the laser-induced CVD method. A deeper insight in the inception and growth mechanism of these structures is needed in order to achieve different levels of encapsulation and subsequent nanotube growth. 相似文献
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Analysis of the many studies of carbon nanotube formation in high-temperature ovens clearly indicates the key requirements of nanotube formation are an ‘atomic’ carbon source and a source of nanometal particles. We adapted this formulation to the high temperature (>3000 K) environment found in a low-power (<1000 W) atmospheric pressure, microwave plasma torch, by simultaneously feeding carbon monoxide (carbon source), and (presumably) iron carbonyl (source of metal catalyst particles) through an argon stabilized plasma flame. This technique led to the relatively rapid (25 mg/h) formation of carbon nanotubes of a unique form: macro-sized ‘woven’ threads. Scanning electron microscopy and high-resolution transmission electron microscopy studies revealed that the woven threads consist entirely of carbon nanotubes (primarily carbon single-wall nanotube) and associated nano-iron particles. The structures appear ‘fractal’ in that each woven thread appears to be constructed of smaller threads that in turn are formed of yet smaller woven threads. Simple mechanical tests show the threads can be bent without breaking, and the thread will spring to its original shape when the force holding it is released. Threads of the size produced can be woven together to form actual cloth or ropes and thus this result represents a step toward the ultimate application of carbon nanotubes for super strong/light structures. 相似文献
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以磷铁废渣为原料提供磷源和铁源,用硝酸和硫酸混合溶液浸出磷铁渣中的铁和磷元素,并通过沉淀法制备电池级纳米磷酸铁。探究了硝酸浓度、反应时间、反应温度对磷铁渣溶解率的影响,并研究了反应过程中铁磷比、温度和pH对制备的磷酸铁性能影响。利用X衍射分析仪、扫描电子显微镜、热重分析仪、红外光谱仪和电感耦合等离子体发射光谱仪等分析手段对磷酸铁的形貌、晶体结构与化学成分进行了表征。实验结果表明,磷铁渣浸出最佳的实验条件为:硝酸浓度1.5mol/L,反应时间4h,反应温度90℃,此条件下磷铁的溶解率为95.11%;磷酸铁制备过程中的最佳实验条件为:铁磷比1∶1,反应温度60℃,反应pH=1.0,所制备的FePO4结晶度高,颗粒形貌规整,分散均匀,一次颗粒粒径为100~200nm,铁磷摩尔比为0.97,杂质元素含量符合电池级磷酸铁的要求。 相似文献
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A mixed solution of ferrous and ferric sulfate leached from blast furnace (BF) flue dust was used to prepare nanometer-sized iron oxide black pigment (Fe3O4, magnetite) by the co-precipitation method. The pH value played a very important role in affecting the color and particle size of Fe3O4 and the evolution of green rust in to Fe3O4 or FeOOH. The experimental conditions including the solution pH, the way of adding precipitant, volume of air and reaction time for the formation of nano-iron oxide black pigment were investigated carefully in order to determine the optimal ones. The color, morphology and particle size of as-prepared Fe3O4 pigment were characterized by means of a color measurement instrument, X-ray diffraction (XRD) and transmission electron microscopy (TEM) respectively. The results showed that the obtained pigment had low average spectral reflectance (<4%), good oil absorption (~23%), high black intensity and narrow size distribution of 60–70 nm. Furthermore, the formation mechanism of Fe3O4 from the mixed solution of ferrous and ferric sulfate was discussed. 相似文献
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以阿莫西林为研究对象,探讨了其经不同程度磁性纳米铁(Fe3O4 NPs)多相类芬顿预处理后对活性污泥理化特性及其微生物群落结构的影响。结果表明,随着预处理程度(未经预处理、经40% H2O2预处理和经60% H2O2预处理)的升高,活性污泥对废水COD平均去除率由81.5%升高到89.1%,氨氮平均去除率由86.2%升高到95.6%,同时活性污泥中蛋白酶的含量由0.13 mg·g-1升高到0.19 mg·g-1。且随着阿莫西林预处理程度的升高,活性污泥溶性微生物产物(SMP)的三维荧光光谱(EEM)中可见光区类腐殖酸与类富里酸的吸收峰强度逐渐减小,表明活性污泥活性良好。对于微生物群落分布而言,在未经预处理、经40% H2O2、经60% H2O2预处理的条件下,变形菌门所占比例分别为73..81%、84.08%和77.08%,同时厚壁菌门所占比例为0.6%、0.82%与0.78%。变形菌门为优势菌种,诸多固氮细菌与聚磷菌属于变形菌门;而厚壁菌门可利用水解酶来分解蛋白质与糖类,两者所占比例的升高,为废水中污染物的高效去除提供了保障。 相似文献