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文章研究采用琥珀酰酐对废蚕丝丝素蛋白进行化学改性,研究丝素蛋白浓度、琥珀酰酐用量、反应温度、反应时间对丝素蛋白琥珀酰化程度的影响。通过正交实验确定丝素蛋白琥珀酰化的适宜条件为:丝素蛋白浓度2%、琥珀酰酐用量15%、温度40℃、反应时间30 min。丝素蛋白经琥珀酰化修饰后,起泡特性与乳化特性与原来相比均有不同程度的改善。 相似文献
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以质量分数28%再生蚕丝素蛋白水溶液进行静电纺丝,结合拉曼光谱和广角X射线分析测试纤维的构象和晶体结构,探讨了纺丝过程中射流发生情况。结果表明,静电纺丝所得纤维中,仅部分丝素蛋白分子转变为β折叠构象,丝素Ⅱ晶型含量少,纤维只经历了有限的拉伸,说明静电纺丝中射流不是单一细化,而是发生了分裂。 相似文献
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蚕丝是一种天然的高分子材料,由60%~80%的丝素、15%~35%的丝胶及约5%的石蜡、色素、糖类等杂质组成。丝素具有良好的生物相容性和降解性,在药物缓释、促进伤口愈合、组织工程支架等生物医药领域及降血糖、抑菌等医疗保健方面均具有广泛应用;丝胶包裹在丝素纤维外层,对丝素起保护作用,其不仅是非常有用的生物材料,还具有许多生物活性和药理作用,如抗氧化性、抗肿瘤活性、物理胃肠功能等作用。近年,蚕丝蛋白在生物样本保存领域的应用备受研究者关注,本文对蚕丝蛋白在生物样本低温保存和常温保存方面的应用和成果、存在的问题及未来的研究方向作一综述,以期为蚕丝蛋白在生物样本保存领域的应用提供参考。 相似文献
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根据蚕体内丝素蛋白浓度的变化,研究了相应条件下再生丝素蛋白浓溶液的流动曲线,探讨了流变行 为中丝素蛋白分子的构象变化,并用拉曼光谱对应力作用下再生丝素蛋白分子的构象变化进一步作了讨论。 相似文献
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天然丝素在化妆品中的护肤特性及应用 总被引:1,自引:0,他引:1
贾艳梅 《精细与专用化学品》1999,7(14):13-14
天然丝素是世界上最受欢迎的天然型营养化妆品添加剂之一。蚕丝经处理、加工可制成丝素粉、丝肽液、丝胶冻及丝素氨基酸等,本文详细阐述了这几种产品的加工、性能及作用机理,并提供了详细的应用配方。 相似文献
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[Halloysite nanotubes (HNT)]‐filled and kaolin filled composite films based on poly(vinyl alcohol) (PVA)/chitosan (CS) blend were prepared via solution casting method. Tensile properties, fracture morphology, FTIR spectra, thermal stability, swelling properties, moisture absorption, and oxidative degradation of the composite films were investigated. Addition of 0.5 wt% of filler led to the optimum tensile properties of the films. Increased roughness and tearing in the fracture surface morphology supported the tensile results. The FTIR results indicated there were physical interactions present in the composite films. Thermal stability of the composite films differed slightly where PVA/CS/HNT composite films showed better thermal stability than PVA/CS/kaolin composite films. Moreover, the presence of HNT and kaolin fillers in the blend reduced the swelling and moisture absorption properties of the films. Finally, the composite films were degraded by using Fenton's reagent. Degradation percentage of the composite films decreased with increasing filler loading. J. VINYL ADDIT. TECHNOL., 19:55–64, 2013. © 2013 Society of Plastics Engineers 相似文献
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PVAc乳液的共聚共混改性研究 总被引:1,自引:0,他引:1
采用乳液种子聚合法合成甲基丙烯酸甲酯(MMA)、醋酸乙烯酯(VAc)的共聚乳液,再与酚醛树脂(PF)形成共混乳液。分析了甲基丙烯酸甲脂用量对乳液性能的影响,酚醛树脂对共聚乳液性能的影响。该共聚共混乳液的粘度及固含量都符合要求,稳定性好,具有良好的机械性能和耐水性。 相似文献
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Polyvinyl chloride paste blending resins were prepared by a suspension polymerization process, and the optimum ingredients and technological conditions were studied experimentally. The effect of dispersant, surfactant, and agitator design on the particle morphology was discussed. In order to improve the thermal stability of the blending resin, stabilizer was added to the polymerization system, and a special after-treatment was adopted. The effect of blending resins on the rheological and gelation characteristics of the plastisols formed and on mechanical properties, thermal stability, and foamability of the finished articles is demonstrated. 相似文献
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D. A. Kourtides 《Polymer Composites》1988,9(3):172-183
Flammability, thermal properties, and selected mechanical properties of composites fabricated with epoxy and other thermally stable resin matrices are described. Properties measured included limiting-oxygen index, smoke evolution, thermal degradation products, total-heat release, heat-release rates, mass loss, flame spread, ignition resistance, thermogravimetric analysis, and selected mechanical properties. This paper describes the properties of eight different graphite composite panels fabricated using four different resin matrices and two types of graphite reinforcement. The resin matrices included: XU71775/H795, a blend of vinyl poly(styrylpyridine) and bismaleimide; H795, a bismaleimide; Cycom 6162, a phenolic; and PSP 6022M, a poly(styrylpyridine). The graphite fiber used was AS-4 in the form of either tape or fabric. The properties of these composites were compared with those of epoxy composites. It was determined that the blend of vinyl poly(styrylpyridine) and bismaleimide (XU71775/H795) with the graphite tape was the optimum design giving the lowest heat release rate. 相似文献
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本文重点研究了钙锌复合稳定剂和有机锡稳定剂及辅助稳定剂对氯化聚氯乙烯(CPVC)树脂的动态热稳定效果,确定合理的稳定体系及配比;研究了内外润滑剂对CPVC树脂加工流动性能的影响;此外还提出CPVC管材参考配方及相应的性能指标并与国外同类产品做对比。 相似文献
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本文以四官能环氧树脂基体作参比物、选择两种典型的双马来酰亚胺树脂基体(环氧改性双马基体、烯丙基双酚A/双马共聚基体)作为对象,研究其吸湿特性以及吸湿对树脂基体性能的影响,结果表明,树脂基体的化学结构和交联密度对吸湿特性有较大的影响,吸湿量对树脂基体性能的影响也与基体材料的类型,交联密度有关,不能简单地用给定时间下的吸湿率来评定树脂基体的湿热性能优劣。 相似文献
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Plastisols, which are a blend of poly(vinyl chloride) resin and a plasticizer (DEHP), were used as a toughening agent of a resol resin in order to improve the mechanical properties. It was not possible to formulate resol blends by adding more than 10 % of plastisol owing to a lack of apparent homogeneity in the systems, which also showed many air bubbles. The relationship between dynamic mechanical, mechanical and thermal properties and the amount of plastisol added was studied. It was determined from the infrared spectroscopy and dynamic mechanical results that the resol–plastisol blends seem to be formed by a reaction between the phenol and PVC giving a higher crosslinked structure. An improvement in the thermal resistance of the blends at lower temperatures was observed with an increase in the percentage of plastisol. Flexural analysis showed the elastic behaviour of the systems. However, it was not possible to observe the effect of the plasticizer (DEHP) owing to the low quantity of plastisol that was added to the resol. Copyright © 2004 Society of Chemical Industry 相似文献
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《国际聚合物材料杂志》2012,61(1):11-19
An intercrosslinked network of varying percentages of N,N′-bismaleimido-4,4′-disphenyl methane (BMI), vinyl ester oligomer (VEO) modified unsaturated polyester (UP) matrices have been developed. Vinyl ester oligomer was prepared by reacting commercially available epoxy resin GY 250 (Ciba-Geigy) and acrylic acid was used as toughening agent for unsaturated polyester resin. BMI-VEO-UP matrices were characterized for their mechanical properties, viz tensile strength, flexural strength and unntoched Izod impact test as per ASTM standards. The dielectric strength and water absorption measurements were also performed according to ASTM standards. Data obtained from mechanical studies, dielectric strength and water absorption indicate that the introduction of VEO into unsaturated polyester resin improves mechanical properties and affects the moisture resistance according to its percentage concentration. The incorporation of BMI into the VEO modified unsaturated polyester system improves mechanical properties, dielectric strength and resistance to moisture absorption according to its percentage concentration. 相似文献
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采用原位悬浮聚合制备了丙烯酸酯共聚物(ACR)接枝氯乙烯(VC)(ACR-g-VC)树脂和ACR-g-VC/纳米水滑石复合材料,并研究了复合材料的形态、加工塑化性能、力学和热性能。采用原位聚合/熔融加工得到的ACR-g-VC/纳米水滑石复合材料中,纳米水滑石基本以初级粒子形式存在,分散性明显优于由ACR-g-VC与纳米水滑石直接熔融共混制备的复合材料。水滑石含量对原位聚合/熔融加工得到的ACR-g-VC/纳米水滑石复合材料的简支梁缺口冲击强度和储能模量影响较小,而ACR-g-VC的热稳定和加工塑化性能随纳米水滑石的引入而提高。水滑石质量分数为2%的复合材料质量损失10%的温度比聚氯乙烯提高近20℃,而塑化时间缩短至22 s。 相似文献