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无机柱撑蒙脱石的微波制备及吸附作用研究 总被引:2,自引:0,他引:2
用微波加热方法制备无机柱撑蒙脱石,并用X射线衍射分析法对其结构进行表征;研究了未改性蒙脱石和无机柱撑蒙脱石吸附水溶液中F^-离子的适宜条件及吸附模式。结果表明,无机柱撑蒙脱石的层间距增加为1.7395nm;室温条件下,F^-离子初始质量浓度50mg/L,吸附剂投加量20g/L,吸附振荡时间为40min时,无机柱撑蒙脱石对F^-的去除率达74.6%,较相同条件下未改性柱撑蒙脱石对F^-离子的去除率提高了19.5%;吸附等温线符合Freundlich吸附等温方程。 相似文献
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二氧化钛柱撑膨润土对染料甲基橙的吸附行为 总被引:8,自引:0,他引:8
以sol-gel法制备TiO2溶胶和钇掺杂TiO2溶胶为柱化剂,制备出了TiO2柱撑膨润土和钇掺杂TiO2柱撑膨润土.X射线衍射分析表明经柱撑后的膨润土层间距明显增大,达1.9 nm以上,经500℃煅烧后其层间距稳定在1.8 nm以上.研究了甲基橙在4种TiO2柱撑膨润土上的吸附行为,结果表明4种TiO2柱撑膨润土吸附染料甲基橙的速率和吸附量均较大,其吸附动力学行为均遵循Bangham方程和Langmuir方程所描述的规律.平衡吸附量qe与平衡浓度ρe之间的关系符合Freundlich和Langmuir等温吸附方程.其吸附均为吸热过程,吸附热值在12~17kJ/mol,吸附表现为表面物理吸附和离子交换作用. 相似文献
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以钠基膨润土为原料,制备了4种二氧化钛(TiO2)改性柱撑膨润土,并探讨了膨润土的改性方法、投土量、溶液的振荡时间、温度、pH值等因素对膨润土吸附副品红实验的影响.结果表明,4种TiO2改性柱撑膨润土对副品红的吸附效果明显好于原土;未经煅烧的TiO2改性柱撑膨润土的吸附效果要明显优于经高温(500 ℃)煅烧过的柱撑膨润土;掺杂钇的TiO2改性柱撑膨润土的吸附性能略好于未经掺杂的柱撑膨润土;膨润土投土量、溶液的振荡时间、温度和pH值均会对柱撑膨润土的吸附效果产生影响;20 ℃时,4种柱撑膨润土对溶液中副品红的吸附等温线均符合Langmuir吸附等温方程. 相似文献
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铝柱撑改性膨润土处理电镀废水中Cr6+的实验研究 总被引:1,自引:0,他引:1
以膨润土为原料制备了铝柱撑改性膨润土,并研究了不同影响因素对铝柱撑改性膨润土去除电镀废水中Cr6+的影响.结果表明:铝柱撑改性膨润土对Cr6+的去除率明显优于膨润土原土;废水的pH、吸附时间和膨润土投加量对Cr6+的去除率影响较大;pH=4,吸附时间为40 min,投加质量浓度为40 g/L,铝柱撑改性膨润土对Cr6+的去除率达到最大86.1%;铝柱撑改性膨润土对电镀废水中Cr6+的吸附符合Langmuir吸附等温方程. 相似文献
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《硅酸盐学报》2016,(2)
以蒙脱石K10为原料,制备出OH/Fe摩尔比分别为0.6、0.8、1.0、1.5和2.0的系列羟基铁柱撑蒙脱石吸附剂(OH/Fe蒙脱石),比较它们对庆大霉素的吸附能力,研究pH值和时间等因素对OH/Fe蒙脱石吸附庆大霉素的影响规律,并分析吸附机理。结果表明:柱撑OH/Fe蒙脱石对庆大霉素吸附量从低到高依次为K10(33.3 mg/g)、0.6 OH/Fe(43.4 mg/g)、0.8 OH/Fe(44.8 mg/g)、1.0 OH/Fe(56.0 mg/g)、2.0 OH/Fe(64.8 mg/g)、1.5 OH/Fe(71.9 mg/g),OH/Fe摩尔比为1.5时吸附量最大,达到K10的2倍以上,符合Freundlich吸附等温线。柱撑蒙脱石对庆大霉素的吸附在3 h内接近吸附平衡,并且吸附量随pH值的增加而显著增加,吸附可用伪二阶动力学方程描述。吸附量增大主要归功于柱撑后蒙脱石层间距增大,阳离子交换是庆大霉素进入蒙脱石的主导机制,表面配位的化学吸附也是另一种辅助机制,同时羟基铁柱撑蒙脱石吸附庆大霉素后柱撑结构易坍塌。 相似文献
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以Sol—Gel法制备TiO_2溶胶和钇掺杂TiO_2溶胶为柱化剂,制备出了TiO_2柱撑膨润土和钇掺杂TiO_2柱撑膨润土;X射线衍射分析表明,经柱撑后的膨润土层问距明显增大,达1.9nm以上,经500℃煅烧后其层间距稳定在1.8nm以上。研究了茜素黄在4种TiO_2柱撑膨润土上的吸附行为,结果表明:4种TiO_2柱撑膨润土吸附染料茜素黄的速率和吸附量均较大,其吸附动力学行为均遵循Bangham方程和Langmuir方程所描述的规律。平衡吸附量q_e与平衡浓度p_e之间的关系符合Freundich和Langmuir等温吸附方程。其吸附均为吸热过程,吸附热值在13kJ.mol~(-1)~16kJ.mol~(-1)范围,吸附表现为表面物理吸附和离子交换作用。 相似文献
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以氧氯化锆为锆源,将聚合羟基阳离子Zr^(4+)柱撑插入提纯钠化蒙脱石(Na-mt)层间制备锆柱撑蒙脱石(Zr-Pmtn)材料。用X射线衍射、Fourier变换红外光谱和热重-差热分析对样品进行表征,并测定了Zr-Pmtn材料对废水中黄药的吸附效果。结果表明:Zr-Pmtn材料的晶面间距为1.99 nm,热稳定性较好,具有良好的吸附性能;吸附时间为90 min时,吸附动力学达到平衡,溶液最佳pH=3,Zr-Pmtn材料对黄药的饱和吸附量为5.75 mg/g,且Zr-Pmtn材料对黄药的吸附动力学符合拟二级动力学方程,吸附平衡数据符合Langmuir等温线模型。Zr-Pmtn材料吸附黄药属于自发过程和吸热反应。 相似文献
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Debasish Mohapatra Debaraj Mishra Gautam Roy Chaudhury Radhanath Prasad Das 《Korean Journal of Chemical Engineering》2007,24(3):426-430
In the present study, the As(V) removal efficiency of different clay minerals was investigated as a function of solution pH,
time, As(V) concentration, and temperature. Arsenic mobility was also investigated by determining the As(V) released from
the loaded samples by leaching with various aqueous solutions. The kinetics of adsorption was observed to be fast and reached
equilibrium within 3 h. As(V) adsorption on studied clays was pH dependent and maximum adsorption was achieved at pH 5.0.
The maximum adsorption capacity was calculated by fitting the Langmuir equation to the adsorption isotherms and found to be
0.86, 0.64, and 0.52 mg As(V)/g of kaolinite, montmorillonite, and illite, respectively. The negative effect of temperature
on As(V) adsorption showed the interactions to be exothermic. Based on the results, it was found that among the studied clay
minerals, kaolinite was the best As(V) adsorbent and montmorillonite had strong retention capacity. The electrokinetic behavior
of kaolinite and montmorillonite was modified in the presence of As(V), indicating that adsorption involves inner sphere surface
complexation and strong specific ion adsorption. 相似文献
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《分离科学与技术》2012,47(4):656-663
The effects of contact time, reaction temperature, and ionic strength on crystal violet adsorption onto Cu(II)-loaded montmorillonite were studied. The kinetic experimental data were analyzed using pseudo-first-order, pseudo-second-order, and Elovich equations to examine the adsorption mechanism. The result suggested that the adsorption was best represented by the pseudo-second-order equation. The suitability of the Langmuir, Freundich, and Temkin isotherms to equilibrium data was also investigated at 25°C. The maximum adsorption capacity was 114.3 mg dye/g Cu(II)-loaded montmorillonite at adsorbent concentration 1 g/L. The differential heat of adsorption was evaluated and the result showed that adsorption of crystal violet onto the Cu-loaded sample was chemical in nature. The ionic strength and reaction temperature exhibited an insignificant impact on the crystal violet adsorption. The Cu(II)-loaded montmorillonite could serve as low-cost adsorbents for removing crystal violet from aqueous solution compared to the data reported in the literature. 相似文献
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Ping Na Xiumin Jia Bin Yuan Yuan Li Jiyu Na Yuchen Chen Linshuang Wang 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2010,85(5):708-714
BACKGROUND: Arsenic pollution in drinking water has been found in most countries. Arsenate (As(V)) and arsenite (As(III)) are two major forms of inorganic arsenic species, and the latter is the more toxic. The removal of arsenic ions from water has attracted increased attention, and therefore further understanding and development of techniques for removal of arsenic ions are required. RESULTS: Adsorption of arsenate and arsenite from aqueous solutions using Ti‐pillared montmorillonite (Ti‐MMT) was investigated as a function of contact time, pH, temperature, coexisting ions, and ionic strength. The adsorption of both arsenate and arsenite were temperature and pH dependent, indicating different adsorption mechanisms. The effect of coexisting ions on the adsorption was also studied and, among the ions investigated, only phosphate had a noticeable influence on the adsorption of arsenate, while the effect of other ions was negligible. A pseudo‐second‐order chemical reaction model was obtained for both arsenate and arsenite; adsorption isotherms of arsenate and arsenite fitted the Langmuir and Freundlich isotherm models well. X‐ray diffraction (XRD) and X‐ray photoelectron spectroscopy (XPS) were used to study the nature of surface elements before and after adsorption. CONCLUSIONS: This work demonstrates that Ti‐pillared montmorillonite is an efficient material for the removal of arsenate and arsenite from aqueous solutions. Experimental parameters such as contact time, solution pH, temperature, initial concentration, coexisting ions, and ionic strength have been optimized. Copyright © 2010 Society of Chemical Industry 相似文献
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Katrina C.M. Kwok Gordon McKay 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2010,85(12):1561-1568
BACKGROUND: The sorption of arsenate, a poison of acute toxicity found in natural waters, onto chitosan, a biosorbent derived from waste seafood shells has been studied. A batch adsorber design model was developed to determine how much chitosan adsorbent is required to reduce the arsenate concentration in solutions to the WHO standard of 10 µg L?1. RESULTS: A series of batch kinetic experiments has been carried out at different initial pH values. The initial arsenate sorption appears to be completed after 30 min, however, a steady reversible reaction takes place resulting in the desorption of arsenate over 48 h. These phenomena in the batch kinetic data have been correlated simultaneously using the newly developed pseudo‐first order reversible model. Two batch reactor design models have been developed and compared. The first model is a conventional approach based on the equilibrium isotherm capacity equation. A second batch adsorption reactor design is based on the principle of contacting time required, tmax, for the chitosan to achieve its maximum adsorption capacity, qmax. The practical outcome from the second batch adsorber model results in a saving in adsorbent mass per batch of approximately 39.4%, 96.2% and 92.3% chitosan adsorbent at pH conditions of 3.5, 4.0 and 5.0, respectively. CONCLUSION: The adsorbent cost and handling costs are reduced in the second batch adsorber model. There is also a significant savings in the batch turnaround time required in the batch adsorber design when the design is based on the maximum adsorption capacity rather than the equilibrium adsorption capacity. Copyright © 2010 Society of Chemical Industry 相似文献
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《分离科学与技术》2012,47(13):2047-2058
In this work multiwalled carbon nanotubes (MWCNTs) modified by oxidation (o-MWCNTs) and by aminofunctionalization (e-MWCNTs) were examined as potential adsorbents for arsenate removal from water. Adsorption characteristics of raw and modified MWCNTs were investigated in batch adsorption experiments. The influence of solution pH (pH range 3–10), contact time, and temperature (25, 35, and 45°C) were studied. Ethylenediamine-functionalized MWCNTs have the greatest affinity for arsenate ions, followed by o-MWCNTs and raw-MWCNTs. The obtained experimental data for raw- and o-MWCNTs fitted Sips isotherm model, while for the e-MWCNTs, the Freundlich model provided the best fit to the experimental points. The maximum adsorption capacity for arsenate ions was achieved using e-MWCNTs, 12.18 mg g?1. The presence of the arsenate on the adsorbent is confirmed by FTIR spectroscopy. Thermodynamic studies indicated the spontaneity and endothermic nature of the adsorption. Sodium hydroxide solution (0.1 M) was found to desorb about 70% of arsenate from e-MWCNTs. The results with spiked drinking water samples demonstrated that e-MWCNTs, due to the present basic and acidic groups, were very efficient for the removal of arsenate ions, as well as of some cations, at pH 4. 相似文献
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