Boiling time effect on CHF enhancement in pool boiling of nanofluids

Using TiO₂–water nanofluids as the test liquid, pool boiling experiments were carried out to investigate the dependence of the nucleate boiling heat transfer, surface wettability and critical heat flux (CHF) on the boiling time in nanofluids. In the experiments performed at sufficiently high nanoparticle concentrations, the boiling heat transfer first degraded, then improved, and finally reached an equilibrium state. It was hence supposed that the present nanofluids had competing effects to deteriorate and enhance the nucleate boiling heat transfer. As for the surface wettability and CHF, the static contact angle asymptotically decreased whilst the CHF asymptotically increased with an increase in the boiling time. The maximum CHF enhancement measured in the present experiments was 91%, and strong correlation was found between the contact angle and the CHF. Although the boiling time needed to achieve the maximum CHF enhancement was less than a minute at high particle concentrations, a longer time of the order of 1 h was necessary at the lowest particle concentration tested in this work. This experimental result indicated that sufficient attention should be paid to the boiling time effect particularly in industrial applications of nanofluids to emergency cooling.     

Experimental investigation of the effect of particle deposition on pool boiling of nanofluids

Research on pool boiling of nanofluids has shown contradicting trends in the heat transfer coefficient (HTC). Such trends have been attributed, in part, to nanoparticle deposition on the heater surface. An experimental investigation of the transient nature of nanoparticle deposition and its effect on the HTC of pool boiling of nanofluids at various concentrations has been carried out. Pool boiling experiments have been conducted on a horizontal flat copper surface for alumina (40–50 nm) water based nanofluids at concentrations of 0.01, 0.1 and 0.5 vol.%. Nanofluids boiling experiments have been followed by pure water boiling experiments on the same nanoparticle-deposited (NPD) surfaces. This technique has been employed in order to separate the effect of nanoparticle deposition from the effect of nanofluids properties on the HTC. Contrary to what was expected, boiling of pure water on the NPD surface produced using the highest concentration nanofluid resulted in the highest HTC. A closer look at the nature of the NPD surfaces explained such trend. A new approach using a transient surface factor in Rohsenow correlation has been proposed to account for the transient nature of nanoparticle deposition. The applicability of such approach at different concentrations has been investigated.     

Pool boiling characteristics of nanofluid on flat plate based on heater surface analysis

Nucleate pool boiling of Al₂O₃ based aqueous nanofluid on flat plate heater has been studied experimentally. For boiling of nanofluid (< 0.1 vol.%) on heating surface with ratio of average surface roughness to average diameter of particles much less than unity when boiling continue to CHF, the heat transfer coefficient of nanofluid boiling reduces while critical heat flux (CHF) increases. CHF enhancement increased with volume fraction of nanoparticles. Atomic force microscope (AFM) images from boiling surface showed that after boiling of nanofluid the surface roughness increases or decreases depending on initial condition of heater surface. Changes in boiling surface topology during different regions of boiling, wettability and thermal resistance of heater surface owing to nanoparticles deposition cause to variations in nanofluids boiling performance.     

Boiling enhancement by TiO2 nanoparticle deposition

TiO₂ nanoparticle-coated nickel wires were produced by electrical heating in various nanofluid concentrations ranging from 0.01 to 1 wt.% with various processing heat fluxes from 0 to 1000 kW/m². The experimental results demonstrated up to 82.7% enhancement on critical heat flux (CHF) in condition of coated nickel wire (processed in 1 wt.% with 1000 kW/m²) boiling in pure water. The contact angle measurement revealed that the hydrophilic porous coating formed by vigorous vaporization of TiO₂ nanofluid in nucleate boiling regime enormously modified the wettability of heating surface consequently improving the CHF. Besides, it is evident that the coverage of nanoparticle deposition tended to become more complete as concentration and processing heat flux increased based on SEM and EDS analysis. The nanoparticles dispersed in base fluid exhibited little effect on CHF enhancement and could even hinder the percentage of CHF augmentation from boosting, which demonstrated that one could enhance CHF by using only small amount of nanoparticles just adequate to form surface coatings instead of preparing working fluid with great bulk. However, according to the boiling curves in all cases of coated nickel wires, it is supposed that the nucleate boiling heat transfer coefficient deteriorates as a result of thermal resistance resulted from the occurrence of nanoparticle deposition. In summary, the coated porous structure of nanoparticles leads to enhance CHF and to decrease boiling heat transfer coefficient.     

Pool boiling characteristics of low concentration nanofluids

The pool boiling behavior of low concentration nanofluids (?1 g/l) was experimentally studied over a flat heater at 1 atm. Boiling of nanofluids produces a thin nanoparticle film, on the heater surface, which in turn is believed to increase the critical heat flux. The present study also indicates that the nanoparticle deposition results in transient characteristics in the nucleate boiling heat transfer. Finally, this study investigates possible causes responsible for the deposition of nanoparticle on the heater surface. Experimental evidence shows that microlayer evaporation, during nanofluid boiling, is responsible for the nanoparticle coating formed on the heater surfaces.     

Surface effects of ribbon heaters on critical heat flux in nanofluid pool boiling

This paper deals with a study of enhanced critical heat flux (CHF) and burnout heat flux (BHF) in pool boiling of water with suspended silica nanoparticles using Nichrome wires and ribbons. Previously the current authors and other researchers have reported three-digit percentage increase in critical heat flux in silica nanofluids. This study investigates the effect of various heater surface dimensions, cross-sectional shapes as well as surface modifications on pool boiling heat transfer characteristics of water and water-based nanofluids. Our data suggest that the CHF and BHF decrease as heater surface area increases. For concentrations from 0.1 vol% to 2 vol%, the deposition of the particles on the wire allows high heat transfer through inter-agglomerate pores, resulting in a nearly 3-fold increase in burnout heat flux at very low concentrations. The nanoparticle deposition plays a major role through variation in porosity. The CHF enhancement is non-monotonic with respect to concentration. As the concentration is increased, the CHF and BHF decrease prior to increasing again at higher concentrations. Results show a maximum of 270% CHF enhancement for ribbon-type heaters. The surface morphology of the heater was investigated using SEM and EDS analyses, and it was inferred that the 2 vol% concentration deposition coating had higher porosity and rate of deposition compared with 0.2 vol% case.     

Nucleate boiling heat transfer enhancement for water and FC-72 on titanium oxide and silicon oxide surfaces

An experimental study was performed to investigate the nucleate boiling and critical heat flux (CHF) of water and FC-72 dielectric liquid on hydrophilic titanium oxide (TiO₂) nanoparticle modified surface. A 1 cm² copper heater with 1 μm thick TiO₂ coating was utilized in saturated pool boiling tests with water and highly-wetting FC-72, and its performance was compared to that of a smooth surface. Results showed that TiO₂ coated surface increased CHF by 50.4% and 38.2% for water and FC-72, respectively, and therefore indicated that boiling performance enhancement depends on the level of wettability improvement. A silicon oxide (SiO₂) coated surface, exhibiting similar surface topology, was tested to isolate the roughness related enhancement from the overall enhancement. Data confirmed that hydrophilicity of TiO₂ coated surface provides an additional mechanism for boiling enhancement.     

Boiling heat transfer and critical heat flux of ethanol–water mixtures flowing through a diverging microchannel with artificial cavities

This paper presents an experimental study on the convective boiling heat transfer and the critical heat flux (CHF) of ethanol–water mixtures in a diverging microchannel with artificial cavities. The results show that the boiling heat transfer and the CHF are significantly influenced by the molar fraction (x_m) as well as the mass flux. For the single-phase convection region except for the region near the onset of nucleate boiling with temperature overshoot, the single-phase heat transfer coefficient is independent of the wall superheat and increases with a decrease in the molar fraction. After boiling incipience, the two-phase heat transfer coefficient is much higher than that of single-phase convection. The two-phase heat transfer coefficient shows a maximum in the region of bubbly-elongated slug flow and deceases with a further increase in the wall superheat until approaching a condition of CHF, indicating that the heat transfer is mainly dominated by convective boiling. A flow-pattern-based empirical correlation for the two-phase heat transfer coefficient of the flow boiling of ethanol–water mixtures is developed. The overall mean absolute error of the proposed correlation is 15.5%, and more than 82.5% of the experimental data were predicted within a ±25% error band. The CHF increases from x_m = 0–0.1, and then decreases rapidly from x_m = 0.1–1 at a given mass flux of 175 kg/m² s. The maximum CHF is reached at x_m = 0.1 due to the Marangoni effect, indicating that small additions of ethanol into water could significantly increase the CHF. On the other hand, the CHF increases with increasing the mass flux at a given molar fraction of 0.1. Moreover, the experimental CHF results are compared with existing CHF correlations of flow boiling of the mixtures in a microchannel.     

Sorption and agglutination phenomenon of nanofluids on a plain heating surface during pool boiling

The pool nucleate boiling heat transfer experiments of water (H₂O) based and alcohol (C₂H₅OH) based nanofluids and nanoparticles-suspensions on the plain heated copper surface were carried out. The study was focused on the sorption and agglutination phenomenon of nanofluids on a heated surface. The nanofluids consisted of the base liquid, the nanoparticles and the surfactant. The nanoparticles-suspensions consisted of the base liquid and nanoparticles. The both liquids of water and alcohol and both nanoparticles of CuO and SiO₂ were used. The surfactant was sodium dodecyl benzene sulphate (SDBS). The experimental results show that for nanofluids, the agglutination phenomenon occurred on the heated surface when the wall temperature was over 112 °C and steady nucleated boiling experiment could not be carried out. The reason was that an unsteady porous agglutination layer was formed on the heated surface. However, for nanoparticles-suspensions, no agglutination phenomenon occurred on the heating surface and the steady boiling could be carried out in the whole nucleate boiling region. For the both of alcohol based nanofluids and nano-suspensions, no agglutination phenomenon occurred on the heating surface and steady nucleate boiling experiment could be carried out in the whole nucleate boiling region whose wall temperature did not exceed 112 °C. The boiling heat transfer characteristics of the nanofluids and nanoparticles-suspensions are somewhat poor compared with that of the base fluids, since the decrease of the active nucleate cavities on the heating surface with a very thin nanoparticles sorption layer. The very thin nanoparticles sorption layer also caused a decrease in the solid–liquid contact angle on the heating surface which leaded to an increase of the critical heat flux (CHF).     

Critical heat flux on flow boiling of methanol–water mixtures in a diverging microchannel with artificial cavities

This study constitutes an experimental investigation into the convective boiling heat transfer and critical heat flux (CHF) of methanol–water mixtures in a diverging microchannel with artificial cavities. Flow visualization shows that bubbles are generally nucleated at both the artificial cavities and side walls of the channel. This confirms the proper functioning of such artificial cavities. Consequently, the wall superheat of the onset nucleate boiling is significantly reduced. Experimental results show that the boiling heat transfer and CHF are significantly influenced by the molar fraction (x_m) as well as the mass flux. The CHF increases with an increase in mass flux at the same molar fraction. On the other hand, the CHF increases slightly from x_m = 0 to 0.3, and then decreases rapidly from x_m = 0.3 to 1 at the same mass flux. The maximum CHF is reached at x_m = 0.3, particularly for a mass flux of 175 kg/m² s, due to the Marangoni effect. Flow visualization confirms that the Marangoni effect helps a region with a liquid film breakup persist to a higher heat flux, and therefore a higher CHF. Moreover, a new empirical correlation involving the Marangoni effect for the CHF on the flow boiling of methanol–water mixtures is developed. The present correlation prediction shows excellent agreement with the experimental data, and further confirms that the present correlation may predict the Marangoni effect on the CHF for the convective boiling heat transfer of binary mixtures.     

Thermal conductivity measurement and characterization of binary nanofluids

Binary nanofluids, nanoparticle suspensions in binary mixture, are developed to enhance the heat and mass transfer performance of absorption refrigeration cycles. To stabilize the nanoparticles in a strong electrolyte, polymer is used as a steric stabilizer. The effective thermal conductivities of the binary nanofluids with the concentrations of nanoparticle up to 0.1 vol% are measured using the transient hot wire method. Comparing the thermal conductivity change with time, it is found that the dispersion stability of nanofluids is a dominant factor for enhancing the thermal conductivity of binary nanofluids. It is also found that the thermal conductivity of the binary nanofluids (H₂O/LiBr binary mixture with Al₂O₃ nanoparticles) increases with the particle volume concentration and enhances by 2.2% at 0.1 vol% concentration condition. Also a modified dimensionless group is proposed to find the maximum radius of nanoparticles to maintain stable nanofluids. In this study, it was estimated ～1.3 μm.     

Comparison study of liquid replenishing impacts on critical heat flux and heat transfer coefficient of nucleate pool boiling on multiscale modulated porous structures

The critical heat flux (CHF) and heat transfer coefficient of de-ionized (DI) water pool boiling have been experimentally studied on a plain surface, one uniform thick porous structure, two modulated porous structures and two hybrid modulated porous structures. The modulated porous structure design has a porous base of 0.55 mm thick with four 3 mm diameter porous pillars of 3.6 mm high on the top of the base. The microparticle size combinations of porous base and porous pillars are uniform 250 μm, uniform 400 μm, 250 μm for base and 400 μm for pillars, and 400 μm for base and 250 μm for pillars. Both the CHF and heat transfer coefficient are significantly improved by the modulated porous. The boiling curves for different kinds of porous structures and a plain surface are compared and analyzed. Hydrodynamic instability for the two-phase change heat transfer has been delayed by the porous pillars which dramatically enhances the CHF. The highest pool boiling heat flux occurring on the modulated porous structures has a value of 450 W/cm², over three times of the CHF on a plain surface. Additionally, the highest heat transfer coefficient also reaches a value of 20 W/cm² K, three times of that on a plain copper surface. The study also demonstrates that the horizontal liquid replenishing is equally important as the vertical liquid replenishing for the enhancement of heat transfer coefficient and CHF improvement in nucleate pool boiling.     

An experimental study on CHF enhancement in flow boiling using Al2O3 nano-fluid

The critical heat flux (CHF) is one of the most important thermal hydraulic parameters in heat transfer system design and safety analyses. CHF enhancement allows higher limits of operation conditions such that heat transfer equipment can be operated safely with greater margins and better economy. The application of nano-fluids is thought to have strong potential for enhancing the CHF. In this study, zeta potentials of Al₂O₃ nano-fluids were measured and flow boiling CHF enhancement experiments using Al₂O₃ nano-fluids were conducted under atmospheric pressure. The CHFs of Al₂O₃ nano-fluids were enhanced up to ～70% in flow boiling for all experimental conditions. Maximum CHF enhancement (70.24%) was shown at 0.01 vol% concentration, 50 °C inlet subcooling, and a mass flux of 100 kg/m² s. Inner surfaces of the test section tube were observed by FE–SEM and the zeta potentials of Al₂O₃ nano-fluids were measured before and after the CHF experiments.     

Enhanced boiling of HFE-7100 dielectric liquid on porous graphite

Enhanced boiling of HFE-7100 dielectric liquid on porous graphite measuring 10 mm × 10 mm is investigated, and results are compared with those for smooth copper (Cu) of the same dimensions. Although liquid is out-gassed for hours before performing the pool boiling experiments, air entrapped in re-entrant type cavities, ranging in size from tens to hundreds of microns, not only enhanced the nucleate boiling heat transfer and the critical heat flux (CHF), but also, the mixing by the released tiny air bubbles from the porous graphite prior to boiling incipience enhanced the natural convection heat transfer by ∼19%. No temperature excursion is associated with the nucleate boiling on porous graphite, which ensues at very low surface superheat of 0.5–0.8 K. Conversely, the temperature overshoot at incipient boiling on Cu is as much as 39.2, 36.6, 34.1 and 32.8 K in 0 (saturation), 10, 20 and 30 K subcooled boiling, respectively. Nucleate boiling ensues on Cu at a surface superheat of 11.9, 10.9, 9.5 and 7.5 K in 0 (saturation), 10, 20 and 30 K subcooled boiling, respectively. The saturation nucleate boiling heat flux on porous graphite is 1700% higher than that on Cu at a surface superheat of ∼10 K and decreases exponentially with increased superheat to ∼60% higher near CHF. The CHF values of HFE-7100 on porous graphite of 31.8, 45.1, 55.9 and 66.4 W/cm² in 0 (saturation), 10, 20 and 30 K subcooled boiling, are 60% higher and the corresponding superheats are 25% lower than those on Cu. In addition, the rate of increase in CHF with increased liquid subcooling is 50% higher than that on Cu.     

Correlation of critical heat flux and two-phase friction factor for subcooled convective boiling in structured surface microchannels

Critical heat flux (CHF) and pressure drop of subcooled flow boiling are measured for a microchannel heat sink containing 75 parallel 100 μm × 200 μm structured surface channels. The heated surface is made of a Cu metal sheet with/without 2 μm thickness diamond film. Tests and measurements are conducted with de-ionized water, de-ionized water +1 vol.% MCNT additive solution, and FC-72 fluids over a mass velocity range of 820–1600 kg/m² s, with inlet temperatures of 15(8.6)°C, 25(13.6)°C, 44(24.6)°C, and 64(36.6)°C for DI water (FC-72), and heat fluxes up to 600 W/cm². The CHF of subcooled flow boiling of the test fluids in the microchannels is measured parametrically. The two-phase pressure drop is also measured. Both CHF and the two-phase friction factor correlation for one-side heating with two other side-structured surface microchannels are proposed and developed in terms of the relevant parameters.     

Experimental investigation and model development for thermal conductivity of α-Al2O3-glycerol nanofluids

In order to investigate the effect of nanoparticle volume fraction, nanoparticle size and temperature on the thermal conductivity of glycerol based alumina (α-Al₂O₃) nanofluids, a set of experiments were carried out for temperature ranging from 20 °C to 45 °C. The nanofluids contained α-Al₂O₃ nanoparticles of three different sizes (31 nm, 55 nm and 134 nm) were prepared by two-step method at volume fractions ranging from 0.5% to 4%. The experimental results show that α-Al₂O₃-glycerol nanofluids have substantially higher thermal conductivity than the base fluid and the maximum enhancement of the relative thermal conductivity was 19.5% for the case of 31 nm at 4% volume fraction. The data analyses indicated that the volume fraction and size of the nanoparticles have significant effects on the thermal conductivity ratio (TCR) of Al₂O₃-glycerol nanofluids, while the temperature has almost no significant effect on the data for range of this study. At room temperature, the effective thermal conductivity remains almost constant for 50 h at 4% volume fractions. The comparison of the obtained experimental data and predictions from some existing theoretical and empirical models reveals that the thermal conductivity ratio and its trend could not be accurately explained by the models in open literature. Consequently, a new empirical correlation based on the experimental data has been developed in this study.     

A new mechanistic model for pool boiling CHF on horizontal surfaces

This work proposes a new mechanistic model for predicting the critical heat flux (CHF) in horizontal pool boiling systems. It is postulated that when the vapor momentum flux is sufficient to lift the liquid macrolayer from the heating surface, wetting is no longer feasible, and a transition from nucleate to film boiling occurs. This is the same mechanism that has found success in predicting CHF in flow boiling systems. An experimental investigation of CHF with pentane, hexane, and FC-72 in saturated horizontal pool boiling with chamber pressures of 150, 300, and 450 kPa provides evidence that the new model captures the variation of CHF with pressure reasonably well compared with other well known models. The new model is also compared with existing data from the literature over a reduced pressure range of 2 × 10^?5–2 × 10^?1. The mean deviation between the predicted and measured CHF is typically within 20% over the parameter space covered.     

Pool boiling of perfluorocarbon mixtures on silicon surfaces

The need for higher pool boiling critical heat flux (CHF) in electronic cooling applications has turned attention to the use of binary mixtures of dielectric liquids. The available literature demonstrates that the addition of a liquid with higher saturation temperature, higher molecular weight, higher viscosity and higher surface tension can lead to significant enhancement of CHF, beyond what can be achieved through changes in pressure, liquid subcooling, and the product of surface effusivity and heater thickness. The current study focuses on extending the available data on mixture CHF enhancement, as well as pool boiling, on polished silicon surfaces to FC-72/FC-40 mixture ratios of 10%, 15%, and 20% of FC-40 by weight, a pressure range of between 1 and 3 atm, and fluid temperature from 22 to 45 °C, leading to high subcooling conditions. It is found that peak heat flux can be increased to as high as 56.8 W/cm² compared to 25.2 W/cm² for pure FC-72 at 3 atm and 22 °C. It is believed that the increase in the mixture latent heat of evaporation and surface tension, accompanying the depletion of the lower boiling point fluid in the wall region plays the major role in enhancing the critical heat flux for binary mixtures.     

Effects of high subcooling on two-phase spray cooling and critical heat flux

Experiments were performed with FC-77 using three full-cone spray nozzles to assess the influence of subcooling on spray performance and critical heat flux (CHF) from a 1.0 × 1.0 cm² test surface. The relatively high boiling point of FC-77 (97 °C at one atmosphere) enabled testing at relatively high levels of subcooling. Increasing the subcooling delayed the onset of boiling but decreased the slope of the nucleate boiling region of the spray boiling curve. The enhancement in CHF was relatively mild at low subcooling and more appreciable at high subcooling. CHF was enhanced by about a 100% when subcooling was increased from 22 to 70 °C, reaching values as high as 349 W/cm². The FC-77 data were combined with prior spray CHF data from several studies into a broad CHF database encompassing different nozzles, fluids, flow rates, spray orientations, and subcoolings. The entire CHF database was used to modify the effect of subcooling in a previous CHF correlation that was developed for relatively low subcoolings. The modified correlation shows excellent predictive capability.     

Unconfined laminar nanofluid flow and heat transfer around a square cylinder

The momentum and forced convection heat transfer for a laminar and steady free stream flow of nanofluids past an isolated square cylinder have been studied numerically. Different nanofluids consisting of Al₂O₃ and CuO with base fluids of water and a 60:40 (by mass) ethylene glycol and water mixture were selected to evaluate their superiority over conventional fluids. Recent correlations for the thermal conductivity and viscosity of nanofluids, which are functions of particle volumetric concentration as well as temperature, have been employed in this paper. The simulations have been conducted for Pe = 25, 50, 100 and 200, with nanoparticle diameters of 30 and 100 nm and particle volumetric concentrations ranging from 0% to 4%. The results of heat transfer characteristics of nanofluid flow over a square cylinder showed marked improvement comparing with the base fluids. This improvement is more evident in flows with higher Peclet numbers and higher particle volume concentration, while the particle diameter imposes an adverse effect on the heat transfer characteristics. In addition, it was shown that for any given particle diameter there is an optimum value of particle concentration that results in the highest heat transfer coefficient.