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木粉对PVC发泡木塑复合材料性能的影响 总被引:1,自引:0,他引:1
采用PVC树脂和木粉加入发泡剂制得PVC/木粉发泡复合材料。本文对木粉进行了热重分析,考察木粉粒径及含量对PVC/木塑发泡材料性能的影响,考察了木粉含量对发泡、熔融指数、转矩加工流变性以及耐候性的影响。结果表明:TG分析表明PVC/木塑复合材料加工的最佳温度200℃左右。随着木粉粒径的减小,PVC/木粉复合材料的冲击强度和弯曲强度出现先上升后下降的趋势,100目木粉,力学性能最好。随着木粉用量的增加,体系的拉伸强度、冲击强度和弯曲强度均呈降低的趋势,材料的发泡效果变差,流动性、稳定性、耐候性变差,因此PVC木塑复合材料应该控制其木粉含量。 相似文献
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PVC/木塑发泡复合材料性能研究 总被引:1,自引:0,他引:1
实验采用PVC树脂与木粉,加入发泡剂及各种添加剂制得了PVC木塑发泡复合材料,主要研究了木粉粒径、放热型发泡剂偶氮二甲酰胺和吸热型发泡剂碳酸氢钠用量、泡孔调节剂ACR以及加工改性剂MBR用量对复合材料力学性能及材料密度的影响,并通过SEM电镜照片分析对比了单纯使用AC和采用AC与NaHCO3复合发泡时制品的发泡性能及泡孔结构,同时分析了泡孔调节剂ACR用量对PVC木塑发泡复合材料中泡孔大小,泡孔结构及其在基体中分布状态的影响.结果表明:当木粉粒径为20目,AC与NaHCO3用量均为1份,ACR用量为8份时所得材料的综合性能最佳,泡孔结构最理想. 相似文献
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考察了高钙固硫灰粒径对PVC发泡木塑材料弯曲性能、握钉力和落锤冲击性能的影响。结果表明:当高钙固硫灰粒径为18μm时,PVC发泡木塑材料具有最佳的弯曲性能;当高钙固硫灰粒径为11μm时,PVC发泡木塑材料具有最佳的握钉力;高钙固硫灰的粒径对PVC发泡木塑材料的落锤冲击性能几乎没有影响。 相似文献
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PVC/木粉复合材料挤出发泡成型的研究 总被引:1,自引:0,他引:1
介绍木塑复合材料挤出发泡成型的发展和加工难点,并针对聚氯乙烯(PVC)/木粉复合材料挤出发泡的成型方法,从原料、配方、工艺、设备等方面作了详细分析。最后简述了PVC/木粉复合材料挤出发泡制品的性能及影响制品性能的主要因紊。 相似文献
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木粉粒径对PVC/木塑复合材料力学性能的影响 总被引:2,自引:0,他引:2
采用木粉填充聚氯乙烯(PVC)基木塑复合材料,研究了木粉粒径对复合体系力学性能的影响。结果表明:随着填充PVC木粉粒径的变化,PVC/木塑复合材料的冲击强度和弯曲强度出现先上升后下降的趋势,这种趋势被PVC/木塑复合材料电镜照片所证实。100目木粉,粒径适中,PVC树脂和木粉界面相容性好,冲击强度和弯曲强度出现最大值。 相似文献
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PVC木塑复合材料成型技术 总被引:3,自引:0,他引:3
介绍了废旧塑料再利用技术,探讨了PVC木塑复合材料的配方、工艺、制备及木粉的处理方法。结果表明:经处理的木粉,在PVC和木粉之间形成了较高强度的界面层,使木粉与基体树脂粘接力强,改善了材料的力学性能。 相似文献
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将木粉和PVC共混,同时加入相容剂POE—MAH,三者经挤出机挤出形成化学反应相容。生成PVC塑化木粉。研究了该塑化木粉的吸水性。研究表明:体系中PVC比例增加、木粉比例减小时。临界含水量变小,即吸水性变小。 相似文献
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Poly(vinyl chloride)/wood fiber (flour) composites are currently experiencing a dramatic increase in use. Most of them are used to produce window/door profiles, decking, railing, and siding by using conical counterrotating intermeshing twin‐screw extruders. Heat stabilizers, processing aids, impact modifiers, lubricants, and pigments are still important for PVC/wood composite formulations. Poly[methylene(polyphenyl isocyanate)] (PMPPIC), γ‐aminopropyltriethoxysilane, maleated polypropylene (MAPP), and copper metallic complex have proved to be effective coupling agents for this composite system. Mechanical properties of PVC/wood composites can be enhanced by combining wood with mica or glass fibers to form hybrid reinforcements. Ultraviolet light resistance and weathering dimensional stabilities of PVC/wood composites are superior to those of natural wood. Density reduction can be achieved through the microcellular foaming technique by using chemical blowing agents, such as azodicarbonamide and sodium bicarbonate, or physical blowing agents, such as carbon dioxide. J. Vinyl Addit. Technol. 10:59–69, 2004. © 2004 Society of Plastics Engineers. 相似文献
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Relatioships between the density of foamed rigid PVC/wood‐flour composites and the moisture content of the wood flour, the chemical foaming agent (CFA) content, the content of all‐acrylic foam modifier, and the extruder die temperature were determined by using a response surface model based on a four‐factor central composite design. The experimental results indicated that there is no synergistic effect between teh CFA content and the moisture content of the wood flour. Wood flour moisture could be used effectively as foaming agent in the production of rigid PVC/wood‐flour composite foams. Foam density as low as 0.4 g/cm3 was produced without the use of chemical foaming agents. However, successful foaming of rigid PVC/wood‐flour composite with moisture contained in wood flour strongly depends upon the presence of all‐acrylic foam modifier in the formulation and the extrusion die temperature. The lowest densities were achieved when the all‐acrylic foam modifier concentration was between 7 phr and 10 phr and extruder die temperature was as low as 170°C. 相似文献
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In this study, PVC/(wood flour) (WF) composites were prepared by using a counterrotating twin‐screw extruder, and the effects on the mechanical properties of concentration and particle size of the WF, type and amount of coupling agent, K value of PVC, feed rate of extruder, and die temperature were investigated. Optimization of various formulation parameters based on the Taguchi method demonstrated that the wood content and wood particle size were the most important parameters. Flexural modulus increased upon increasing WF loading up to 50 wt%. Also, flexural strength and modulus increased with particle size because of the higher aspect ratio and better quality of mixing. Use of coupling agents had a minor effect that was attributed to the moderately high polarity of PVC causing relatively good compatibility between WF particles and the PVC matrix. The optimum level of WF calculated by considering the contribution factor was 50 wt%. J. VINYL ADDIT. TECHNOL., 2011. © 2011 Society of Plastics Engineers 相似文献
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The effects of chemical foaming agent (CFA) types (endothermic versus exothermic) and concentrations as well as the influence of all‐acrylic processing aid on the density and cell morphology of extrusion‐foamed neat rigid PVC and rigid PVC/wood‐flour composites were studied. Regardless of the CFA type, the density reduction of foamed rigid PVC/wood‐flour composites was not influenced by the CFA content. The cell size, however, was affected by the CFA type, independent of CFA content. Exothermic foaming agent produced foamed samples with smaller average cell sizes compared to those of endothermic counterparts. The experimental results indicate that the addition of an all‐acrylic processing aid in the formulation of rigid PVC/wood‐flour composite foams provides not only the ability to achieve density comparable to that achieved in the neat rigid PVC foams, but also the potential of producing rigid PVC/wood‐flour composite foams without using any chemical foaming agents. 相似文献
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采用化学发泡一步法模压成型制备了软质PVC发泡材料,研究了发泡剂、泡孔成核剂、改性剂等主要助剂用量对软质PVC发泡材料密度、泡孔结构以及力学性能的影响,并进行了软质PVC发泡材料的配方筛选.结果表明加入吸热发泡剂N能提高发泡体系的发泡效果,降低材料的密度,改善材料的力学性能,当发泡剂AC用量为2份,用量为0.6份时,材料的综合性能优异;当成核剂用量为1份时,体系发泡效果较好;加入粉末NBR不仅能提高发泡材料的断裂伸长率和柔韧性,还可降低发泡材料密度,改善泡孔结构;当NBR用量为20份时,发泡材料密度达到0.44 g/cm3,力学性能优异. 相似文献