Crop production,nitrogen recovery and water use efficiency in rice–wheat rotation as affected by non-flooded mulching cultivation (NFMC)

Non-flooded mulching cultivation (NFMC) for lowland rice, as a novel water-saving technique, has been practiced in many areas of China since the 1990s. However, the information on NFMC effects on crop production, nitrogen and water use in rice–wheat rotations is still limited. A field experiment using ¹⁵N-labeled urea was conducted to evaluate the impacts of NFMC on crop yield, fertilizer N recovery and water use efficiency in rice–wheat rotations. Plastic film mulching (PM), and wheat straw and plastic film double mulching (SPM) resulted in the same rice grain yield (7.2 t ha^–1) while wheat straw mulching (SM) and no mulching (NM) led to 5 and 10% yield reduction, compared with rice under traditional flooding (TF). In the rice–wheat rotation, crop productivity in PM, SM or SPM was comparable to that in TF but greater than in NM. Weed growth and its competition with rice for nitrogen were considered the main reason that led to yield decline in NM. Compared with TF, NFMC treatments did not obviously affect fertilizer N recoveries in plant and soil in both rice and wheat seasons. The total fertilizer N recoveries in crop, weed and soil in all treatments were only 39–44% in R–W rotations, suggesting that large N losses occurred following one basal N application for each growing season. Water use efficiency, however, was 56–75% greater in NFMC treatments than in TF treatment in the R–W rotation. The results revealed that NFMC (except NM) can produce comparable rice and wheat yields and obtain similar fertilizer N recovery as TF with much less water consumption.     

Comparative study of reactivity and agronomic effectiveness of Indian,US, African and Middle East rock phosphates for growing rice

Comparative reactivity and efficiency of eight Indian, six US, two African and one Middle East sources of rock phosphates for growing rice on laterite, red and alluvial soils under flooded conditions were evaluated in pot and laboratory experiments. When applied to moist aerobic soils, 15 days prior to flooding and transplanting rice, all the Indian sources were as poor as theno phosphate control in the three soil types, in respect of P availability in soil, grain yield response and P uptake by rice. North Carolina rock phosphate used in this study was as good as superphosphate in the laterite and red soils, but was also as poor as control in the black soil.NH₄ -citrate was found to interfere in the colorimetric determination of citrate soluble P by the vanado-molybdate colour method. A modified sulpho-molybdate-Sn Cl₂ blue colour method could successfully be used to determine 2–8µg P in the presence of 0.02 to 0.2 meq NH₄ -citrate, especially in rocks containing small amounts of citrate soluble P. All the Indian, as well as Idaho, Missouri and Tennessee rock phosphates were found to be less reactive as they contained much lower amounts of citrate extractable P in eight successive extracts as compared to North Carolina rock phosphate.The cumulative citrate soluble P of 10 rock phosphates determined experimentally in eight successive extracts was significantly correlated with their reported a₀ (length of a axis of unit apatite crystal), mole ratio of CO₃/PO₄ or weight ratio of F/P₂O₅ of rocks. In the absence of X-ray and computer facilities, these regression equations were used to calculate the a₀, CO₃/PO₄, F/P₂O₅, ACS, empirical formula and the apatite content of the unknown Indian rock samples. The Indian rock phosphates had a lower degree of CO₃ and F substitution for PO₄ in the apatite crystal, giving low ACS values and hence were less reactive. This might explain their lower efficiency for direct application for growing rice, obtained in the present experiment. These Indian rock phosphates had also lower apatite content. The use of the statistical method was limited to francolites alone. Scope for the use of this method for other unknown francolite rock phosphate samples has been discussed.     

Studies on the substitution of inorganic fertilizers with organic manure and their effect on soil fertility in rice—wheat rotation

Field studies on the substitution of N and P fertilizers with farm yard manure (FYM) and their effect on the fertility status of a loamy sand soil in rice—wheat rotation are reported. The treatments consisted of application of 12 t FYM ha^–1 in combination with graded levels of N and P. Application of fertilizer N, FYM and their different combinations increased the rice yield significantly. There was no significant response to P application. The magnitude of response to the application of 12 t FYM and its combined use with each of 40 kg and 80 kg N ha^–1 was 0.7, 2.2 and 3.9 t ha^–1 respectively. Application of 120 kg N ha^–1 alone increased the yield by 3.9 t ha^–1, and was comparable to rice yield obtained with 80 kg N and 12 t FYM ha^–1. This indicated that 12 t FYM ha^–1 could be substituted for 40 kg N as inorganic fertilizer in rice. In addition FYM gave residual effects equivalent to 30 kg N and 13.1 kg P ha^–1 in the succeeding wheat. The effect of single or combined use of inorganic fertilizers and FYM was significantly reflected in the build up of available N, P, K and organic carbon contents of the soil. The relationship for predicting rice yield and nutrients uptake were also computed and are discussed.     

Crop response of aerobic rice and winter wheat to nitrogen,phosphorus and potassium in a double cropping system

In the aerobic rice system, adapted rice cultivars are grown in non-flooded moist soil. Aerobic rice may be suitable for double cropping with winter wheat in the Huai River Basin, northern China plain. Field experiments in 2005 and 2006 were conducted to study the response of aerobic rice and winter wheat to sequential rates of nitrogen (N), phosphorus (P) and potassium (K) in aerobic rice—winter wheat (AR-WW) and winter wheat—aerobic rice (WW-AR) cropping sequences. Fertilizer treatments consisted of a complete NPK dose, a PK dose (N omission), a NK dose (P omission), a NP dose (K omission), and a control with no fertilizer input. Grain yields of crops with a complete NPK dose ranged from 3.7 to 3.8 t ha⁻¹ and from 6.6 to 7.1 for aerobic rice’ and ‘winter wheat’, respectively. N omissions caused yield reductions ranging from 0.5 to 0.8 t ha⁻¹ and from 1.6 to 4.3 t ha⁻¹ for rice and wheat, respectively. A single omission of P or K did not reduce rice and wheat yields, but a cumulative omission of P or K in a double cropping system significantly reduced wheat yields by 1.2–1.6 t ha⁻¹. N, P and K uptake of both crops were significantly influenced by fertilizer applications and indigenous soil nutrient supply. Nutrient omissions in a preceding crop reduced plant N and K contents and uptake additionally to direct effects of the fertilizer treatments in wheat, but not in rice. Apparent nutrient recoveries (ANR) differed strongly between ‘aerobic rice’ and ‘winter wheat’; in rice: for N it ranged from 0.30 to 0.32, for P from 0.01 to 0.06, and for K from 0.03 to 0.19 and in wheat: for N from 0.49 to 0.71, for P from 0.09 to 0.15, and for K from 0.26 to 0.31. Further improvements of crop productivity as well as nutrient-use efficiencies, should be brought about by developing cropping systems, by an appropriate choice of adapted cultivars, by a site- and time-specific fertilizer management and by eliminating other yield-limiting factors. It is concluded that nutrient recommendations should not be based on the yield response of single crops only, but also on the after-effects on nutrient availability for succeeding crops. A whole cropping system approach is needed.     

Evaluation of the fertilizer value of some indigenous rock phosphates and basic slag of India

Summary Field and pot culture experiments were conducted in terai acid soil (Haplaquoll) to evaluate the fertilizer value of one basic slag and two rock phosphates, such as Purulia rock phosphate (Igneous) and Mussoorie rock phosphate (sedimentary). In the field experiments two crop sequences were followed: (i) Rice — wheat — greengram (ii) Greengram — rice — wheat. In terms of crop yield and P uptake Purulia rock phosphate did not show any significant effect, except in case of greengram grown as the third crop after its application. Mussoorie rock phosphate increased the yield and P uptake through its direct and residual effect in all the crops, except in rice. Irrespective of crop species and crop sequences basic slag showed considerable direct and residual effect in increasing the crop yield and P uptake. Its effect was at par with that of superphosphate. By total yield increase of three consecutive crops due to added P the efficiencies of the fertilizers were graded as basic slag > superphosphate = Mussoorie rock phosphate > Purulia rock phosphate for rice — wheat — greengram rotation and superphosphate > basic slag > Mussoorie rock phosphate > Purulia rock phosphate for greengram — rice —wheat rotation. Composting improved the efficiency of all the insoluble phosphatic fertilizers.     

Autointoxication mechanism ofOryza sativa

Ammonium sulfate and potassium nitrate added as a top dressing and rice straw were incorporated into soil to understand their effect on the chemical nature of the paddy soil and on the growth and yield of rice plants during two successive crop seasons. Redox potential (Eh) determination indicated that the paddy soil appeared to be the reduced form in mixture with rice residues. The amounts of ammonium nitrogen (NH₄ ⁺—N) and nitrate nitrogen (NO₃ ^–—N) were significantly higher in the second crop than in the first crop, and the quantity of NH₄ ⁺—N was about 10 times greater than that of NO₃ ^–—N. The incorporation of rice straw decreased both the available nitrogen and the soil cations, Zn²⁺, Cu²⁺, Ca²⁺, Mn²⁺, and Na⁺. The quantity of Zn²⁺, Cu²⁺, Mg²⁺, and Na⁺ was significantly lower in the second crop that that in the first. The growth and yield of rice plants were significantly affected by cultural treatment; thus the ammonium sulfate dressing treatment resulted in higher yields than the potassium nitrate treatment. The NH₄ ⁺—N treatment had an antagonistic effect on the phytotoxic nature of rice straw decomposed in soil. The phytotoxicity (primarily phenolic type compounds) of aqueous extracts of soil varied between treatments and was significantly higher in the soil which had been mixed with rice straw. This finding correlated well with the higher amounts of phytotoxic plant phenolics produced by the decomposing rice residues in the soil.This study was supported by the National Science Council of the Republic of China.Paper No. 215 of the Scientific Journal Series, Institute of Botany, Academia Sinica.     

Nitrous oxide emissions from paddy soil in three rice-based cropping systems in China

Rice-flooding fallow, rice-wheat, and double rice-wheat systems were adopted in pot experiment in an annual rotation to investigate the effects of cropping system on N₂O emission from rice-based cropping systems. The annual N₂O emission from the rice-wheat and the double rice-wheat cropping systems were 4.3 kg N ha^–1 and 3.9 kg N ha^–1, respectively, higher than that from rice-flooding fallow cropping system, 1.4 kg N ha^–1. The average N₂O flux was 115 and 118 g N m^–2 h^–1 for rice season in rice-wheat system and early rice season in double rice-wheat system, respectively, 68.6 and 35.3 g N m^–2 h^–1 for the late rice season in double rice-wheat system and rice season in rice-flooding fallow, respectively, and only 3.1–5.3 g N m^–2 h^–1 for winter wheat or flooding fallow season. Temporal variations of N₂O emission during rice growing seasons differed and high N₂O emission occurred when soil conditions changed from upland crop to flooded rice.     

N2O emission from cropland in China

Based on the regionalization of uplands and paddy fields in China, the crop intensity in each region and the available field measurements, N₂O emission from cropland in China in 1995 was estimated to be 398 Gg N, in which, 310 Gg N was from uplands, accounting for 78% of the total. 88 Gg N–N₂O was emitted from paddy fields with 35 Gg N emitted during the rice growing season and 53 Gg N emitted during upland crop season. N₂O emission from upland and from paddy field during upland land crop season accounted for 91% of the total emission.     

Preparation,forms and properties of controlled-release phosphate fertilizers

Controlled-release phosphate fertilizers include phosphate rocks (PRs) for direct application, partially acidulated phosphate rocks (PAPRs) and thermal phosphates. Phosphate rocks contain apatite as the main P containing mineral, the composition and the chemical nature of which vary between PRs. Based on the solubility in chemical extractants PRs are broadly grouped into ‘reactive’ and ‘unreactive’. The ‘reactivity’ of PRs is influenced strongly by the extent of carbonate substitution for phosphate in the apatite minerals. Under certain soil and climatic conditions reactive PRs (RPRs) can be used as a source of P for direct application. Partially acidulated phosphate rocks (PAPRs) are produced either by direct partial acidulation of PRs with mineral acids or by mixing PRs with fully acidulated superphosphate reaction mixtures. Partial acidulation of PRs with H₃PO₄ generally results in higher water soluble P contents than those acidulated with H₂SO₄. Mixing of RPRs with superphosphate reaction mixtures sometimes results in the preferential consumption of free acid and thereby increases the amounts of residual unreacted PRs. Thermal phosphates are produced by either heating PRs below melting point both in the presence and the absence of silica (calcined phosphates) or heating PRs with silica above melting point (fused phosphate). These phosphates are alkaline in nature and hence suitable for acidic soils.     

Nitrogen input, <Superscript>15</Superscript>N balance and mineral N dynamics in a rice–wheat rotation in southwest China

A field experiment and farm survey were conducted to test nitrogen (N) inputs, ¹⁵N-labelled fertilizer balance and mineral N dynamics of a rice–wheat rotation in southwest China. Total N input in one rice–wheat cycle averaged about 448 kg N ha⁻¹, of which inorganic fertilizer accounted for 63% of the total. The effects of good N management strategies on N cycling were clear: an optimized N treatment with a 27% reduction in total N fertilizer input over the rotation decreased apparent N loss by 52% and increased production (sum of grain yield of rice and wheat) compared with farmers’ traditional practice. In the ¹⁵N-labelled fertilizer experiment, an optimized N treatment led to significantly lower ¹⁵N losses than farmers’ traditional practice; N loss mainly occurred in the rice growing season, which accounted for 82% and 67% of the total loss from the rotation in farmers’ fields and the optimized N treatment, respectively. After the wheat harvest, accumulated soil mineral N ranged from 42 to 115 kg ha⁻¹ in farmers’ fields, of which the extractable soil NO₃ ⁻–N accounted for 63%. However, flooding soil for rice production significantly reduced accumulated mineral N after the wheat harvest: in the ¹⁵N experiment, farmers’ practice led to considerable accumulation of mineral N after the wheat harvest (125 kg ha⁻¹), of which 69% was subsequently lost after 13 days of flooding. Results from this study indicate the importance of N management in the wheat-growing season, which affects N dynamics and N losses significantly in the following rice season. Integrated N management should be adopted for rice–wheat rotations in order to achieve a better N recovery efficiency and lower N loss.     

Methane production from anaerobic soil amended with rice straw and nitrogen fertilizers

Laboratory experiments were conducted on the effects of rice straw application and N fertilization on methane (CH₄) production from a flooded Louisiana, USA, rice soil incubated under anaerobic conditions. Rice straw application significantly increased CH₄ production; CH₄ production increased in proportion to the application rate. Urea fertilization also enhanced CH₄ production. The maximum production rate was 17% higher, and occurred 1 week earlier, than that of soil samples which did not receive urea, possibly due to the increase in soil pH following urea hydrolysis. The increase in soil pH following urea hydrolysis may have stimulated CH₄-generating bacteria by providing more optimal soil pH conditions or contributed to the drop in redox potential (Eh). The significant decrease in both the production rate and the total amount of CH₄ by application of NH₄NO₃ was associated with increases in soil Eh after addition of this oxidant. Addition of 300 mg. kg^–1 NO ₃ ^- -N increased soil Eh by 220 mV and almost completely inhibited CH₄ production. However, this inhibitory effect was short-termed. Soon after the applied NO ₃ ^- -N was reduced through denitrification, CH₄ production increased. When (NH₄)₂SO₄ was applied, the inhibition of CH₄ production was not associated with an increase in soil Eh which did not change significantly. A direct inhibitory effect of sulphate on methanogenesis might have been more important.     

Effect of crop residue management on nitrogen dynamics and balance in a lowland rice cropping system

Two field experiments were conducted in a rice–fallow–rice cropping sequence during consecutive dry and wet seasons of 1997 on a Fluvic Tropaquept to determine the fate and efficiency of broadcast urea in combination with three residue management practices (no residue, burned residue and untreated rice crop residue). Ammonia volatilization losses from urea (70 kg N ha^–1) broadcast into floodwater shortly after transplanting for 11 d were 7, 12 and 8% of the applied N from no residue, burned residue and residue treated plots, respectively. During that time, the cumulative percent of N₂ + N₂O emission due to urea addition corresponded to 10, 4.3 and nil, respectively. The ¹⁵N balance study showed that at maturity of the dry season crop, fertilizer N recovery by the grain was low, only 9 to 11% of the N applied. Fifty to 53% of the applied ¹⁵N remained in the soil after rice harvest, mainly in the upper 0–5 cm layer. The unaccounted for ¹⁵N ranged from 27 to 33% of the applied N and was unaffected by residue treatments. Only 4 to 5% of the initial ¹⁵N-labeled urea applied to the dry season rice crop was taken up by the succeeding rice crop, to which no additional N fertilizer was applied. Grain yield and N uptake were significantly increased (P=0.05) by N application in the dry season, but not significantly affected by residue treatments in either season.     

Impact of organic residue management on nitrogen use efficiency in an annual rice cropping sequence of lowland Central Thailand

Field experiments were conducted in Central Thailand under a rice–fallow–rice cropping sequence during consecutive dry and wet seasons of 1998 to determine the impact of residue management on fertilizer nitrogen (N) use. Treatments consisted of a combination of broadcast urea (70 kg N ha^–1) with rice straw (C/N 67) and rice hull ash (C/N 76), which were incorporated into the puddled soil 1 week before transplanting at a rate of 5 Mg ha^–1. Nitrogen-15 balance data showed that the dry season rice recovered 10 to 20% of fertilizer N at maturity. Of the applied N, 27 to 36% remained in the soil. Loss of N (unaccounted for) from the soil–plant system ranged from 47 to 54% of applied N. The availability of the residue fertilizer N to a subsequent rice crop was only less than 3% of the initial applied N. During both season fallows NO₃-N remained the dominant form of mineral-N (NO₃+NH₄) in the aerobic soil. In the dry season grain yield response to N application was significant (P=0.05). Organic material sources did not significantly change grain yield and N accumulation in rice. In terms of grain yields and N uptake at maturity, there was no significant residual effect of fertilizer N on the subsequent rice crop. The combined use of organic residues with urea did not improve N use efficiency, reduced N losses nor produced higher yields compared to urea alone. These results suggested that mechanisms such as N loss through gaseous N emissions may account for the low fertilizer N use efficiency from this rice cropping system. Splitting fertilizer N application should be considered on the fertilizer N use from the organic residue amendment.     

Detectability of15N-depleted fertilizer N in soil and plant tissue during a corn-rye crop rotation

Use of¹⁵N-depleted fertilizer materials have been primarily limited to fertilizer recovery studies of short duration. The objective of this study was to determine if¹⁵N-depleted fertilizer N could be satisfactorily used as a tracer of residual fertilizer N in plant tissue and various soil N fractions through a corn (Zea mays L.) -winter rye (Secale cereale L.) crop rotation. Nitrogen as¹⁵N-depleted (NH₄)₂SO₄ was applied at five rates (0, 84, 168, 252, and 336 kg N ha^–1) to corn. Immediately following corn harvest a winter rye cover crop treatment was initiated. Residual fertilizer N was easily detected in the soil NO ₃ ^- -N fraction following corn harvest (140-d after application). Low levels of exchangeable NH ₄ ⁺ -N (<2.5 mg kg^–1) did not permit accurate isotope-ratio analysis. Fertilizer-derived N recovered in the soil total N fraction following corn harvest was detectable in the 0 to 30-cm depth at each N rate and in the 30 to 60 and 60 to 90-cm depths at the 336 kg ha^–1 N rate. Atom %¹⁵N concentrations in the nonexchangeable NH ₄ ⁺ -N fraction did not differ from the control at each N rate. Nitrogen recovery by the winter rye cover crop reduced residual soil NO ₃ ^- -N levels below the 10 kg ha^–1 level needed for accurate isotope-ratio analysis. Atom %¹⁵N concentrations in the soil total N fraction (approximately one yr after application) were indistinguishable from the control plots below the 168, 252, and 336 kg ha^–1 N rate at the 0 to 30, 30 to 60, and 60 to 90-cm depths, respectively. Recovery of residual fertilizer N by the winter rye cover crop was verified by measuring significant decreases in atom %¹⁵N concentrations in rye tissue with increasing N rates. The greatest limitation to the use of¹⁵N-depleted fertilizer N as a tracer of residual fertilizer N in a corn-rye crop rotation appears to be its detectibility from native soil N in the total N pool.Research partially supported by grants from the National Fertilizer and Environmental Research Center/TVA and the Virginia Division of Soil and Water Conservation.     

Influence of passivation pretreatment in common acid and alkali on oxidation behaviour of Ti3SiC2 at 500°C

Passivation treatments in NaOH, H₂SO₄ and HCl were conducted in order to improve the oxidation resistance of Ti₃SiC₂ at 500°C. The oxidation resistance of Ti₃SiC₂ passivated in NaOH was the greatest of any treatments due to the formation of an amorphous film during passivation treatment, which became dense, crystalline and seemingly highly protective during oxidation. The detrimental phase transformation of TiO₂ was limited by doping with SiO2. Different levels of corrosion happened during passivation treatment in H₂SO₄ and HCl, which is harmful to oxidation resistance.     

Effect of soil clay mineralogy on the efficiency of ammonium sulfate in flooded rice

The effect of soil clay mineralogy on the efficiency of (NH₄)₂SO₄ in flooded rice was investigated in a greenhouse pot trial with four clayey soils of diverse clay mineralogies (x-ray amorphous, montmorillonite, vermiculite, beidellite). KCl (75 kg K ha^–1) and triple superphosphate (25 kg P ha^–1) were incorporated in the soil with and without (NH₄)₂SO₄ (100 kg N ha^–1) before transplanting 1-week-old IR-36 rice seedlings which were then grown to maturity under flooded conditions. Efficiency of (NH₄)₂SO₄ was inferred from the response of agronomic characteristics such as tiller number, height, grain and straw yields to NH₄ fertilization.The results showed greatest efficiency of (NH₄)₂SO₄ on the x-ray amorphous soil, followed by montmorillonitic soil; efficiency was much lower on the vermiculitic and negligible on the beidellitic soil.Soil clay mineralogy may be an important factor in the reduced efficiency of NH₄ (or NH₄-forming) fertilizers in certain rice soils.     

Phosphorus availability from partial acidulation of two phosphate rocks

Two phosphate rocks, one from Pesca (Colombia) and the other from Togo, were acidulated to various degrees with H₂SO₄ and H₃PO₄ for evaluation in varying granule size ranges. Products acidulated with H₂SO₄ were also prepared using different drying temperatures. Phosphorus availability was measured by dry-matter yield and P uptake in greenhouse experiments with maize.It was observed that partial acidulation with H₂SO₄ was effective in increasing the water-soluble P level of phosphate rock when the drying temperature of the product was not excessive. Crop response and P uptake were both highly correlated to the water solubility of the product. The relative agronomic effectiveness (RAE) of Togo rock increased from 3% when unacidulated to 33%, 47%, and 52% when 20%, 30%, and 40%, respectively, of the H₂SO₄ required to make SSP was added. Similar results were obtained with Pesca rock. No consistent effect due to granule size was observed.Twenty percent acidulation of Pesca rock with H₃PO₄ was 53–76% as effective as TSP with a single crop and 79–90% as effective over three cropping periods, showing a potential for high residual value.     

Effect of soil water contents in the non-rice growth season on CH4 emission during the following rice-growing period

A pot experiment was carried out to investigate the effect of soil water content in the non-rice growth season (winter season) on CH₄ emission during the following rice-growing period. The results showed that CH₄ fluxes increased significantly with the increase of soil water content in the winter season, except air-dry water condition. The mean CH₄ fluxes of treatments with soil water contents in the winter of 3.89–5.37% (air-dry), 25–35%, 50–60%, 75–85% and 107% (flooded) of field water capacity (FWC) were 13.04, 4.04, 8.61, 13.26 and 20.47 mg m^–2 h^–1, respectively. Antecedent soil water contents also markedly affected temporal variation patterns of CH₄ fluxes and soil redox potential (E_h) during the rice-growing period. The higher soil water contents in the winter season were, the quicker soil E_h decreased, and the earlier CH₄ emission occurred after rice transplanting, except air-dry water condition. Though the seasonal mean CH₄ flux was significantly correlated with the seasonal mean soil E_h, the seasonal variation of CH₄ fluxes was not always significantly correlated with soil E_h. For the treatment flooded in the fallow season, there was no significant correlation between CH₄ flux and soil E_h, but there was significant correlation between CH₄ flux and soil temperature during rice growth season. In contrast, for the other four treatments, it was soil E_h, not soil temperature that significantly affected the temporal variation of CH₄ emissions. Soil water contents in the fallow season significantly influenced concentrations of soil labile organic carbon (including undecomposed plant debris), active Fe and Mn immediately before rice transplanting. The mean CH₄ fluxes during rice-growing period were significantly correlated with soil labile organic carbon contents (positively) and contents of soil active Fe and Mn (negatively).     

Effect of phosphorus and potassium fertilizer on crop response and soil fertility in a long-term experiment

Data from 32 years of a rotation-fertility experiment were analyzed to determine the average P and K application rates required for maximum yield and for optimum yield. A four-year rotation of corn, soybean, wheat, hay was used for the first 10 years and then changed to corn-1, soybean, wheat, corn-2. Rates of P application per 4-year rotation ranged from 0 to 196 kg ha^–1 and for K from 0 to 558 kg ha^–1. Multiple regression equations were fitted to the mean yields per 4-year rotation for the response of each crop to P and K applications. The range in P application rates in kg of P per 4-year rotation required to get maximum yields of corn was 118 to 172, for soybeans was 134 to 150, and for wheat was 116 to 138. The range in K application rates in kg K per 4-year rotation to get maximum yields of corn was 378 to 411, for soybeans was 324 and 476, and for wheat was 11 to 323. For rates of application where P and K added exceeded crop removals, soil test P and K increased linearly with the cumulative positive balance of P and K. Where crop removal exceeded application rate, no relation was found between crop removal and soil test.Journal paper No. 10, 915 Purdue University Agric. Exp. Stn., West Lafayette, IN 47907. Contribution from the Department of Agronomy.     

Transformations of residual fertilizer P in a semi-arid tropical soil under eight-year peanut-wheat rotation

Long-term transformations of residual phosphorus (P) governs the availability of phosphorus to crops. Very limited information is available on the transformations of residual fertilizer P in semi-arid tropical soils under long-term crop rotations. Therefore, using sequential phosphorus fractionation procedure, we studied changes in labile and stable forms of inorganic and organic P in a semi-arid alluvial soil (Typic Ustisamments) after eight years of annual fertilizer P application either to one crop (alternate) or to both crops (cumulative) in a peanut (Arachis hypogaea) — wheat (Triticum aestivum) rotation.Total residual fertilizer P in soil (P recovered from P-fertilized minus control plots) ranged from 62 to 176 mg P kg^–1. In the alternate P treatments (P applied to peanut or wheat only), on an average of 3 rates of applied P (13, 26 and 39 kg P ha^–1), in surface (0–15 cm) and subsurface (15 to 30 cm) soil, respectively, residual fertilizer P consisted of 14.8 and 2.2% resin-P, 8.6 and 2.8% NaHCO₃-P, 6.3 and 0% microbial-P, 31.4 and 4.2% NaOH-P, 7.8 and 3.0% aggregate protected-P, 12.5 and 3.0% HCl-P, 3.4 and 0% H₂SO₄-P. The corresponding values for surface and subsurface soils of cumulative P treatments (P applied to both peanut and wheat) were: 12.8 and 1.6% resin-P, 6.9 and 2.3% NaHCO₃-P, 4.7 and 0% microbial-P, 32.5 and 4.2% NaOH-P, 5.6 and 2.0% aggregate protected-P, 14.8 and 3.8% HCl-P, 6.7 and 2.1% H₂SO₄-P. Considerable lower values for the 15–30 cm depth indicate only a very small movement of residual P to the subsoil.Significantly lower amount of fertilizer P (28% and 44%) found in labile (resin, NaHCO₃ and microbial P) and semi-labile (NaOH and sonicated NaOH P) fractions for the cumulative P treatment than alternate P treatment (35 and 46%, respectively) suggests that increased rates and frequency of applied P tend to enhance the conversion of residual P to stable forms which are less available to plants. About 12 to 19% of residual fertilizer P found as organic P in labile and semi-labile forms confirmed that organic P increased with long-term fertilizer management. In conclusion, the results of our study suggest that the alternate application of fertilizer P to a crop, as is shown for wheat, helps reduce the transformations of residual P to stable P forms.