Thermal and radiative characteristics of oxyfluoride glass singly doped with lanthanide ions

Rare earths-doped oxyfluoride glasses based on germanium oxide and lead fluoride were prepared from commercial raw materials. The glasses with general composition of 50GeO2-(50-x-y)PbO-yPbF2-xLnF3 (Ln=Pr3+-Yb3+), contained different concentrations of optically active dopants (x=0.2 mol.% and 2 mol.%) and PbF2 (y≤15 mol.%). The differential thermal analysis (DTA) was used to determine both thermal characteristic and thermal stability properties of the glasses in the function of the kind of dopant, its concentration, and a glass composition. Characteristic glass temperatures such as glass transition temperature (Tg), glass crystallization temperature (Tc) and temperature corresponding to the maximum of the crystallization rate (Tpc) were evaluated. On the basis of obtained results, the thermal stabilities of glasses under study were evaluated using various thermal stability criteria (Dietzel factor ?T, Saad-Poulain factors H' and S). It was found that the increase in rare earth fluoride contents influenced thermal characteristics when the characteristic temperatures of the individual glass was shifted towards higher values. The effect of the PbF2 content and the kind of rare earth impurity on the glass stability was observed. Absorption spectra of lanthanide-doped glasses were measured at room temperature and used to determine the phenomenological intensity parameters Ωt and next, to estimate radiative properties of lanthanide ions in this matrix. Radiative transition probabilities of luminescent states of Ln3+, branching ratios and radiative lifetimes were determined. The variation of the Ωt along the lanthanide series was presented and discussed.     

Process optimization of electroless copper plating and its influence on electrochemical properties of AB5-type hydrogen storage alloy

The amount of Cu coating by chemical plating was investigated based on quadratic regression orthogonal experimental design being adapted to the variation law of temperature,pH value and Ni2+concentration,and the relevant regression equation was expressed as y=2.1609+0.5295×10-3T2-0.0342P2-0.0265N2+0.0023TP+0.0020TH+0.0199PN-0.0959T+0.3814P-0.2073N.The results showed that the deposition rate augmented with the increasing in temperature,pH value and Ni2+concentration.The experimental parameters of the optimal coating were temperature 75 ℃,pH value 8.5 and Ni2+concentration 1.2 g/L.The electrochemical tests indicated that the cycle stability increased from 60.66% to 75.58%,indicating that the treated alloy exhibited better corrosion resistance.     

天铁热力风机升级改造方案设计

通过对天铁集团高炉现状、风机现状的分析,提出了对热力厂风机升级改造的规划,确定了实施方案.该方案实施后将彻底改变风机渐进式改造的现象,使新高炉的备用机组发挥更大的作用,可增加现有高炉的风压、风量,使现有高炉的产量、冶炼强度进一步提高.     

Recent progress report on DNA B-Z transition modulated by rare earth-amino acid complex and Alzheimer's disease amyloid beta

Rare earth dements have unique physical, magnetic, luminescent and catalytic properties. They have been successfully used as medicine and probes in luminescent resonance energy transfer (LRET) for bioassays, as well as reagents for diagnosis in magnetic resonance imaging (MRI). In this progress report, we will focus on recent progress on how rare earth amino complexes bind to DNA and change DNA structure, especially on DNA B-Z transition induced by rare earth amino acid complex and its potential impact on Alzheimer's disease (AD).     

Numerical Simulation on Inclusion and Bubble Entrapment in Solidified Shell in Model Experiment and in Mold of Continuous Caster With DC Magnetic Field

A model experiment investigating entrapment of inclusions and bubbles on the solidified shell was performed using molten steel,and the conditions for inclusion and bubble entrapment and mechanism of entrapment were studied.The results were applied to the flow behavior in the casting mold of a continuous caster.At the solid-liquid interface,entrapment of inclusions is greatly reduced by the existence of a low velocity flow,e.g.,0.05m/s.The above-mentioned interfacial flow velocity dependency of inclusion entrapment is considered to be largely influenced by changes in the thickness of the concentration boundary layer,which depend on the interfacial flow velocity.Specifically,bubbles and inclusions which enter the concentration boundary layer are drawn to the solid-liquid interface by a suction force which is several orders larger than the Saffman’s force.In addition to the above-mentioned suction force,the so-called cleaning effect is determined by fluid-dynamic forces such as drag force,etc.which act on particles,and furthermore,by resident time of particles at the solid-liquid interface,which depends on the solidification rate.In a FC mold with a 2-stage electromagnetic brake,flotation of bubbles entrained in the jet flow from the nozzle is accelerated with the large DC magnetic field.This is attributed to the braking effect of the DC field on the nozzle jet and the upward flow by the buoyancy of the bubbles.As a result,the interfacial flow velocity can be normalized by increasing the strength of the magnetic field,and entrapment of large bubbles and inclusions can be reduced.     

Influence of Controlled Rolling and Cooling Process on the Mechanical Properties of Low Carbon Cold Forging Steel

In the present paper,controlled rolling and cooling processing was conducted by using a laboratory hot rolling mill.The influence of different processing parameters on the mechanical properties of low carbon cold forging steel was investigated.The results show that the faster cooling after the deformation (especially in low temperature rolling conditions) leads to the refinement of the ferrite grain.The specimen exhibits very good mechanical properties owing to the finer ferrite grains.The pearlite morphologies can also affect the mechanical properties of low carbon cold forging steel.The mechanical properties increase with decreasing final cooling temperature within the range from 650℃ to 570 ℃ due to the finer interlamellar spacing of pearlite colony.The mechanical properties of the specimens with fast cooling after the conventional rolling are not only better than those of the specimens with slow cooling after low temperature rolling,but also almost similar to those of the specimens with fast cooling after low temperature rolling.It is suggested that fast cooling after high temperature rolling (the conventional rolling) process would be of important industrial value.     

The LIMMCAST Program at HZDR:Modelling of Fluid Flow and Transport Phenomena in the Continuous Casting Process

Model experiments with low melting point liquid metals are an important tool to investigate the flow structure and related transport processes in melt flows relevant for metallurgical applications.We present the new experimental facility LIMMCAST for modelling the continuous casting process of steel using the alloy SnBi at temperatures of200-400℃.The parameters of the facility and the dimensions of the test sections will be given,and the possibilities for flow investigations in tundish,submerged entry nozzle and mould will be discussed.In addition,the smaller set-up Mini-LIMMCAST will be presented,which works with the room-temperature liquid alloy GaInSn.The main value of cold metal laboratory experiments consists in the capabilities to obtain quantitative flow measurements with a reasonable spatial and temporal resolution.New ultrasonic and electromagnetic techniques for measuring the velocity in liquid metal flows came up during the last decade allowing for a satisfying characterisation of flow quantities in the considered temperature range up to 400℃.First results from LIMMCAST and Mini-LIMMCAST will be presented covering the following phenomena:fully contacfless electromagnetic tomography of the flow in the mould,flow monitoring by a multitude of ultrasonic sensors,and analysis of the flow in the mould under the influence of an electromagnetic brake:intensification of the flow turbulence contrary to the expected flow damping,injection of argon bubbles through the stopper rod:occurrence of pressure oscillations.     

汽车零件强度、寿命与可靠性分析与模型

The elasto-plastic stress/strain behavior of an automobile rear axle was analyzed by three-dimension finite element method.Based on the stress in critical area where fatigue crack appears,the fatigue life of the welded structure was predicted using the critical shear stress plane criterion.To improve the fatigue property of the rear-axle,the welding-seam was strengthened by both pellet spraying and plasma melting,and evident improvement was experimentally illustrated.Based on the viewpoint that a complex component is also a system in the respect of reliability assessment and statistical dependence among component failures(i.e.the so call"common cause failure")is inherent for system under stochastic load environment,a system-level load-strength interference model was presented and the reliability of the rear axle was estimated as a system,instead of a component.     

铝土矿、氧化铝和电解铝产业链市场及利润流向

本文主要介绍近几年铝土矿、氧化铝和电解铝产业链的市场和利润流向演变以及未来发展形势.     

提高轧制重轨BS75A成材率的措施

介绍了武钢大型厂生产重轨BS75A时,利用现有设备,通过不断研究,找到了一条提高重轨(BS75A)生产成材率的方法,并取得了较好的经济效益.     

Computational Analysis of Masonry Structures with a Funicular Model

This paper presents a computational approach for the assessment of masonry structures based on the well known analogy between the equilibrium of arches and that of hanging strings or cables working in tension. According to the analogy, the hanging strings model the inverted shape of the equilibrium lines (or thrust lines) describing the locus of the equilibrium forces acting across the sections of the arch. The approach proposed combines two developments. First, a new cable element is proposed to numerically model the strings used to describe the equilibrium lines. The formulation proposed, obtained as a modification of the conventional equations for inextensible cables, is based on an exact analytical derivation. Compared to other available numerical approaches, it has the advantage of ensuring the exact equilibrium of the cable net after deformation. Second, complementary algorithms are proposed for the assessment of the strength of masonry structures by the application of the limit theorems of plasticity (static approach). These algorithms are intended to find optimized solutions complying with the so-called safe (or lower-bound) and uniqueness theorems. Two examples of application are described to illustrate the accuracy of the method and its ability to handle masonry structural systems.     

Failure Resistance of Historic Stone Bridge Structure of Charles Bridge. II: Susceptibility to Floods

The paper is a follow-up to the first part devoted to an analogical problem investigated with a view to the degradation of the stone structure due to the effects of nonstress load, and it deals with the probability problem of the bridge structure collapse under the effect of an extreme flood wave. The paper presents the results of the numerical analysis of the response of the historic stone bridge structure of Charles Bridge of the 14th century to the flood wave effect simulated by angular rotation, subsidence, and shifting in the footing bottom of a bridge pier. Special focus is on the effect of interventions into the stone bridge structure dating back to the last major overhaul of 1967–1975, particularly, on the effect of the reinforced concrete slab (tie plate) connecting the opposite bridge breast walls increasing the rigidity of the breast walls and their structurally efficient connection to the vaults of the bridge arches. The numerical analyses performed point out the prevailing negative effects of the implemented interventions in terms of structural rigidity of the stone bridge structure exposed to the effect of a flood wave.     

Nanotopography Impact in Shallow Trench Isolation Chemical Mechanical Polishing-Dependence on Slurry Characteristics

The nanotopography of the surface of silicon wafers has become an important issue in ULSI device manufacturing since it affects the post-chemical mechanical polishing (post-CMP) uniformity of the thickness deviation of dielectric films. In this study, the nanotopography impact was investigated in terms of its dependence on the characteristics of ceriabased slurries, such as the abrasive size, the grain size of the polycrystalline abrasive and the surfactant added to the slurry. It was found that the magnitude of the post-CMP oxide thickness deviation due to nanotopography increased with the surfactant concentration in the case of smaller abrasives but was almost independent of the concentration in the case of larger abrasives. The grain size of the polycrystalline abrasive did not affect the nanotopography impact.     

Failure Analysis of a Bridge Embankment with Cracked Approach Slabs and Leaking Sand

This paper describes a successful failure analysis to determine the causes of loss of backfill sand from a mechanically stabilized earth (MSE) wall, and cracks on the concrete approach slabs on top of it. The Texas Department of Transportation was concerned that the cracks on the approach slabs may be related to the excessive loss of backfill from behind the MSE walls, and that the embankment structure may be unsafe due to potential voids under the concrete slab. Several cubic meters of sugar sand had washed out of the wall and deposited adjacent to the paneled walls. A series of destructive and nondestructive tests were carried out to determine the causes of the problems. It was found that the cracking of the approach slab and the loss of backfill were unrelated. Suggestions for resolving both problems were made based on this study.     

Formation of Secondary Containment Systems Using Permeation of Colloidal Silica

U.S. Environmental Protection Agency (USEPA) regulations require the capture of spills from liquid tanks containing hazardous chemicals by using a secondary containment system. Compacted clay or geomembrane liners are commonly used in secondary containment systems, but they are cumbersome when used in conjunction with existing liquid tanks because of pipeline networks surrounding the tanks. This study evaluates the formation of hydraulic barriers for secondary containment through the permeation of colloidal silica grout. A simplified infiltration model is presented to predict the downward movement of the colloidal silica grout into a soil layer, considering the time-dependent increase in dynamic viscosity of the colloidal silica for different concentrations of an electrolyte accelerator. Because the simplified infiltration model cannot predict the soil-grout interaction or the permeation of the colloidal silica by fingering, its results were calibrated by using the observations from a large-scale column test involving the permeation of colloidal silica into sand. The predicted position of the wetting front was found to match that of the experiment when the parameter governing the change in viscosity of the colloidal silica was increased by a factor of 30. The infiltration model calibrated with observations from column infiltration experiments provides a simple approach to the design of the secondary containment systems using permeation of colloidal silica.     

不同市场条件下金属露天矿分期方案动态优化

不同市场条件下金属露天矿分期方案动态优化有关于金属露天矿分期方案动态优化的整体方案的设计与实施,是结合采选联合优化的一部分内容,针对地下采选一体化实现的露天金属矿采选联合优化,露天金属矿采选联合优化也是与金属露天矿分期方案动态优化相关,对于采选联合优化的选矿过程都是存有金属露天矿分期方案动态优化的内容,这就需要施工人员和设计者在涉及到井下的内部转化以及其他金属露天矿分期方案动态优化部分的过程中能够对于一些采选联合优化的内涵做出详尽的了解和分析。比如地下采矿中通常采用一体化设计,但是这种设计的缺点就是难以进行露天金属矿采选联合优化,但是对于矿山开展的试验性研究工作还是有利的,能够实现按空间位置的一体化是采选联合优化的内涵及发展历程的关键。     

New Orleans Levee System Performance during Hurricane Katrina: London Avenue and Orleans Canal South

Hurricane Katrina was one of the worst natural disasters in U.S. history. The effects of the hurricane were particularly devastating in the city of New Orleans. Most of the damage was due to the failure of the levee system that surrounds the city to protect it from flooding. This paper presents the results of centrifuge models conducted at Rensselaer Polytechnic Institute and the U.S. Army Corps of Engineers simulating the behavior of the levees at London Avenue North and South that failed during Hurricane Katrina. Those levees failed without being overtopped by the storm surge. Also included are the results of a centrifuge model of one levee section at Orleans Canal South, which did not fail during the hurricane. The key factor of the failure mechanism of the London Avenue levees was the formation of a gap between the flooded side of the levee and the sheetpile. This gap triggered a reduction of the strength at the foundation of the protected side of the levee. The results are fully consistent with field observations.     

延长碳化时间对焦炭性能的影响

为了研究延长碳化时间对焦炭质量的影响，通过对焦炭块度、冷热强度和气孔率等指标进行宏观分析，并且从焦炭显微结构微观角度分析延长碳化时间对焦炭内部结构的改变。结果表明，随着碳化时间的延长，焦炭中的镶嵌组织逐渐增多，光学组织之间有很好的结合性，减少了裂纹的发生，阻止了裂纹的延展;焦炭的块度大幅提高，冷热性能均有所改善，孔径和气孔率都有所降低，焦炭的反应性降低。     

Discrete Particle Model for Analyzing Bedform Development

A discrete element model is used to simulate the emergence and evolution in time of wind ripples with the use of simple rules for the motion of individual sediment particles. It is shown, by analyzing the probabilities for the particles to be entrained and deposited over the bed implied by the selected rules, that the same model can be used to simulate the development of underwater bedforms. The results of the model show that the particle-transport processes implied by the simple rules used in the model can represent many different complex aspects of the physics of bedforms. The results of the model are compared with experimental results on underwater ripples obtained by the authors, and a surprisingly good agreement is found in terms of the main dynamical properties of the bedforms, such as growth rate of the amplitude, evolution of the steepness, growth saturation, and bedform celerity. Even though the simulated bedforms do not reproduce the exact geometry of their physical counterparts, the richness of the strongly nonlinear processes that this simple model is able to simulate makes this kind of approach useful to explain many of the observed features of underwater bedforms, which are otherwise very difficult to address theoretically.     

水冷模铸造技术的研究现状

大型扁钢锭主要用于生产特厚钢板,随着钢锭吨位增加,钢锭上部缩孔较深,影响成材率,疏松等级高,偏析严重,大型扁钢锭的质量成为特厚板轧机能力的瓶颈。在查阅大量外文文献的基础上,结合国内水冷模铸造技术的研究现状,总结了水冷模铸造技术的相关专利,详细阐述了水冷模铸造技术对钢锭凝固速度、凝固坯壳均匀程度、凝固组织和疏松缩孔、钢锭内部偏析的影响。介绍了水冷模铸造技术生产钢锭和轧制的工业试验,同时介绍了轧制后钢板的性能情况。大型扁钢锭水冷模铸造技术具备为高品质特厚钢板提供坯料的能力。