Cr对纳米晶复合Nd2Fe14 B/α-Fe永磁材料磁性能的影响

采用快淬和晶化退火法制备了成分为Nd8.5Fe75-xCo5Cu1Nb1Zr3CrxB6.5(x=0.5,1,2)的纳米晶复合永磁合金.研究了Cr的添加对合金晶粒尺寸及磁性能的影响,结果表明适量Cr的添加能有效抑制磁性相晶粒长大,提高了合金的矫顽力.Cr含量为1%(at%),快淬速度为15.0m/s的合金经690℃/4min的晶化处理,由晶化磁粉粘结所得到的磁体最佳磁性能为:Br=0.62T,jHc=806.4kA/m,(BH)max=69.0kJ/m3.     

Nd2Fe14B/α-Fe纳米复相永磁合金微结构的形成

研究了使用不同快淬速度制备的Nd3 6Pr5 4Fe83Co3B5合金中Nd2Fe14B/α-Fe复合纳米晶结构的形成.采用X射线(XRD)、透射显微(TEM)分析技术和振动样品磁强计(VSM)观测和测量了材料的微结构和磁性.结果表明,使用最佳淬速(20m/s)形成的Nd2Fe14B/α-Fe复合纳米晶结构晶粒细小,晶粒尺寸均匀Nd2Fe14B相和α-Fe相的平均晶粒尺寸分别为14nm、16nm.合金中α-Fe相的体积分数为48.6%.纳米晶合金的磁性能为Jr=1.108T,Hc=446.5kA/m,(BH)max=193.6kJ/m3,剩磁比Jr/Js=0.736.     

脉冲磁场退火对纳米晶复合Nd8.5Fe77Co5Zr2.7Ga0.6B6.2永磁合金磁性能的影响

对快淬Nd8.5Fe77Co5Zr2.7Ga0.6B6.2合金,采用脉冲磁场下热处理的方法制备纳米晶复合永磁材料,研究脉冲磁退火对合金的晶化过程、相组成、交换耦合作用以及磁性能的影响,结果表明,同常规退火相比,脉冲磁退火降低了合金的最佳退火温度,改善了合金的微结构,从而增强了软、硬磁性晶粒间的交换耦合作用,明显提高了合金的磁性能,经670℃脉冲磁退火后合金具有最佳的磁性能,即iHc=586kA/m,Jr=1.01T,(BH)max=138kJ/m3,最大磁能积比常规退火工艺条件下提高了15%。     

Nd2Fe14B／a—Fe纳米复相永磁合金微结构的形成

研究了使用不同快淬速度制备的Nd3.6Pr5.4Fe83Co3B5合金中Nd2Fe14B/a-Fe复合纳米晶结构的形成。采用X射线（XRD）、透射显微（TEM）分析技术和振动样品磁强计（VSM）观测和测量了材料的微结构和磁性。结果表明,使用最佳淬速（20m/s）形成的Nd2Fe14B/a-Fe复合纳米晶结构晶粒细小,晶粒尺寸均匀。Nd2Fe14B相和a-Fe相的平均晶粒尺寸分别为14nm、16nm。合金中a-Fe相的体积分数为48.6%。纳米晶合金的磁性能为Jr=1.108T,Hc=446.5kA/m,(BH)max=193.6kJ/m^3,剩磁比Jr/Js=0.736。     

快淬速度对(Nd,Pr)10.5(FeCoZr)83.5B6显微结构和磁性能的影响

采用部分过快淬加后续晶化退火处理工艺,研究了快淬速度对低稀土含量双相复合(Nd,Pr)10.5(FeCoZr)83.5B6合金显微结构和粘结磁体磁性能的影响.合金快淬转轮线速度为24,26,28和30 m·s-1,退火温度655～715℃,退火时间5～20min.快淬速度直接影响条带的显微结构和磁体磁性能.以26m·s-1速度快淬出的条带,快淬态由非晶和微晶混合组成,在700℃经10min晶化处理,可获得平均晶粒尺寸约30nm的均匀、细小显微组织,磁性能也最佳.用3.25wt%环氧树脂粘结的磁体磁性能为Br=0.703T,Hci=544 kA·m-1,Hcb=351 kA·m-1,(BH)m=70 KJ·m-3.     

高性能快淬Nd10.5(FeCoZr)83.4B6.1粘结磁体的制备

采用快淬和动态晶化法制备了成分为Nd10.5(FeCoZr)83.4B6.1的纳米晶交换耦合永磁合金.系统研究了制备过程中快淬速度和动态晶化工艺(包括晶化温度和炉管转速)对合金磁性能和显微组织的影响.经28m/s快淬及700℃/21Hz动态晶化处理后,制成的粘结磁体性能最佳,为Br=0.6849T,Hcj=732kA/m,Hcb=429kA/m,(BH)m=75kJ/m3.     

纳米晶复合Nd8.5Fe76.6-xGaxCo5Zr2.7B6.2(x=0～0.5) 粘结磁体磁性能的研究

采用快淬和晶化退火法制备了成分为Nd8.5Fe76.6-xGaxCo5Zr2.7B6.2(x=0～0.5)的纳米晶复合永磁粘结磁体,研究了其磁性能的变化.结果表明,适量Ga元素的添加能有效提高磁体退磁曲线的方形度,进而提高磁体的最大磁能积.Ga含量0.2%(原子分数),快淬速度为16.0m/s的合金经670℃/4min的晶化处理后,制得的粘结磁体具有较佳的磁性能:Br=0.745T,jHc=730.1kA/m,(BH)max=80.1kJ/m3.适量的Ga元素的添加可以提高磁体的温度稳定性.Ga含量为0.2%(原子分数)的合金具有较好的温度系数,在25～150℃温度区间内剩磁温度系数α=-0.091%/℃,内禀矫顽力温度系数β=-0.353%/℃.     

纳米晶复合Nd10Fe76B10Nb4-xZrx（x=0～4）永磁合金的磁性能研究

采用熔体快淬法制备了成分为Nd10Fe76B10Nb4-xZrx(x=0～4)的合金条带,退火处理后得到了纳米晶复合永磁合金。利用振动样品磁强计(VSM)分析了该合金体系的退磁曲线、磁交互作用曲线(δM-H曲线)、磁化率χ随外加磁场变化曲线,研究了其磁性能及软、硬磁性相间的交换耦合作用的变化。结果表明,添加适量的Zr元素可细化晶粒,从而有效地增强合金中软、硬磁性相间的交换耦合作用,进而提高合金的综合磁性能。当Zr含量为2%(原子分数)时,制得的合金具有最佳的综合磁性能:jHc=1059.16kA/m,Br=1.08T,(BH)max=185.72kJ/m3。     

Nd8.5Dy0.5Fe84.5Co0.5B6合金的晶化工艺

本文采用熔体快淬法制备了纳米微晶Nd8.5Dy0.5Fe84.5Co0.5B6合金,对不同晶化工艺条件下的合金进行了显微组织分析、X射线衍射物相分析和磁性能分析,通过研究该合金的非晶晶化法制备纳米微晶的工艺参数,确定了该材料的最佳晶化工艺:750℃下保温0.5小时,获得平均晶粒尺寸为50nm左右,磁性能优良.     

纳米晶双相Nd3.6Pr5.4Fe83-xGaxCo3B5合金磁性能的研究

用熔体快淬法制备Nd3.6Pr5.4Fe83-xGaxCo3B5(%(原子分数),x=0～1.0)纳米晶双相永磁材料,研究其磁性能的变化.结果表明适量的添加Ga(x=0.25)可以细化晶粒,使快淬薄带中的Nd2Fe14B硬磁相和α-Fe软磁相发生较充分的交换耦合作用,获得较优异的磁性能,Ga含量过多或过少的快淬薄带的磁滞回线出现缩颈现象,低温退火使得该现象得以改善.     

Low cobalt Fe-Co-W semihard magnetic alloys for remanent reed switch applications

Semihard magnetic alloys of Fe-Co-W have been developed for application in remanent reed switches. These alloys are very ductile and can be processed into fine wires. The 78%Fe-12%Co- 10%W alloy shows the magnetic properties: Br= 19.2 kG, Br/B200= 0.95, and Hc= 25 Oe. These magnetic properties are superior to those of the commercially used Remendur (49%Co-48%Fe-3%V) or Nibcolloy (85%Co-12%Fe-3%Nb), and the alloy itself consists of a much less expensive cobalt content than those alloys. This 78%Fe-12%Co-10%W alloy is flattenable into reeds, plateable with contact materials, and sealable in glass vials without losing its magnetic properties. Fe-Co-W alloys are adequate for use in remanent reed switches and present distinct advantages from the aspects of their inexpensiveness and superior characteristics.     

Low-cobalt Cr-Co-Fe magnet alloys obtained by slow cooling under magnetic field

The permanent magnet properties of magnetic field aged Cr-Co-Fe alloys containing 5-9 weight percent (wt %) Co were investigated. By slow cooling from above the spinodal temperature under applied magnetic field, energy products of (BH)max= 4-6 MG . Oe were obtained. The effects of cobalt content, cooling rate, and applied magnetic field strength were studied.     

Effect of the Partial Substitution of V for Nb on the Magnetic Properties of Fe-based Nanocrystalline Alloy

1. IntroductionYoshizawa et al.[1] prepared Fe-Cu-Nb--St-B system nanocrystalline soft magnetic alloys, which wereformed by added Cu and Nb in Fe-St-B alloys. Theaddition of Cu and Nb does not distu-rb the atom arrangement and can remove magnetic anisotropy. Thenanocrystalline alloys have higher permeability, lowcoercivity and higher saturation magnetic induction.But their brittleness makes the application very difficult. Some reports[2] showed that the partial substitution of V for Nb e…     

Magnetic Properties and Thermal Stability of Pr_(1-x)La_xCo_(5-y)Alloys

Pr1-xLaxCo5-y (x=0, 0.15. 0.25, 0.35,1.0, y=0.5, 0.7, 0.9, 1.0) alloys were investigated. The effect of the variation of x and y on magnetic properties and thermal stability of the alloys were studied. The magnetic properties for the Pr0.85La0.15Co4.3 and Pr0.75La0.25Co4.1 magnets are iHc=368 kA/m, Br=0.91 T, (BH)max=145.6 kJ/m3, αBr=-0.03%/℃ and iHc=568 kA/m,Br=0.8 T, (BH)max=127.2 kJ/m3,αBr,=-0.06%/℃, respectively The phase structures of as-cast alloys and magnets were investigated     

Si含量对纳米晶Fe_(87-x)Cu_1Nb_3Si_xB_9合金磁性能的影响

研究了Si含量对Fe87-xCu1Nb3SixB9合金经不同方式退火后磁性能的影响。结果表明:随Si含量的增加,Fe87-xCu1Nb3SixB9合金经普通退火后软磁性能逐渐得到优化;经磁退火后可感生出单轴磁各向异性,且磁退火特征随Si含量的增加而逐渐明显。根据横磁退火实验结果计算出的感生磁各向异性值Ku,则由26.7J/m3(Si=9.5at%)降低至14.1J/m3(Si=13.5at%)。由实验数据的分析认为Fe87-xCu1Nb3SixB9合金在高Si含量时经普通退火或纵磁退火后呈现优异的软磁特性,归因于析出的α-Fe(Si)相晶粒具有小的磁晶各向异性K1,从而导致合金具有更低的有效磁各向异性常数K所至。     

Hard magnetic phase in rapidly quenched Zr-Co-B alloys

In order to identify a hard magnetic phase in rapidly quenched Zr-Co-B alloys and clarify its magnetic properties, Zr-Co-B ribbons, Zr-Co ribbons, and Zr-Co ingots were studied. The hard magnetic phase is interpreted as a Zr₂Co₁₁ intermetallic compound. This compound has a Curie temperature of 500°C and uniaxial magnetic anisotropy with an anisotropy field of 34 kOe. The magnetization of this compound was estimated to be 67 emu/g at 15 kOe. In addition to the hard magnetic phase, the low and high T_c phases appear in both binary and ternary alloys. The low T_c phase is FCC Zr₆Co₂₃ with T_c=180°C. The magnetization of Zr₆Co₂₃ was estimated to be 44 emu/g at 15 kOe. The high T_c phase is cobalt including a small amount of zirconium. In Zr-Co-B alloys, suitable boron addition is shown to enhance the coercive force. On the other hand, the addition increases the magnetization. While the boron addition produces cobalt, it reduces Zr₆Co₂₃ or quenches its ferromagnetism     

Further studies of the miscibility gap in an Fe-Cr-Co permanent magnet system

The miscibility gap of an Fe-Cr-Co system is further examined by monitoring the microstructures and the magnetic properties of the alloys. It is shown that the shape of the miscibility gap is not parabolic but of a peculiar shape, protruding to the Fe side along the Curie temperature. The part of the protrusion of the miscibility gap is called the "ridge" because of its shape resemblance. It is demonstrated that the alloys in the ridge region can exhibit very good magnetic properties. An Fe-25%Cr-12%Co alloy gives the magnetic properties asBr = 1.45T(14.5 kG),bHc = 50.1kA/m (630 Oe) and (BH)max = 61.3 kJ/m³(7.7 MG . Oe), which are almost comparable to those of the columnar Alnico 5 magnets.     

Microstructure and magnetic properties of the permanent magnet material FeAIC

The relationship between microstructure and magnetic properties of a series of permanent magnets based on the composition Fe₉₀Al₈C₂ (wt%) has been studied using X-ray diffractometry and transmission electron microscopy. We have used various fabrication methods, heat treatments and alloying elements in order to optimize the magnetic properties of these alloys and the properties obtained were found to compare favourably with commercially available cobalt steels.     

The effect of force fitting on the magnetic properties of iron-cobalt alloy ring samples

Ring samples of annealed iron-27% cobalt (Fe-27 Co) and iron-cobalt-2% vanadium (FeCo-2V) alloys were subjected to a number of force fitted conditions where the maximum tensile and compressive hoop stresses were varied from 0 to 50 MPa. Various dc and 400 Hz ac magnetic characteristics were determined at each stress level. The dc and 400 Hz ac characteristics of both alloys changed in the force fitted condition, with the compressive hoop stress having more of an effect than the tensile hoop stress on most of the magnetic properties. The most drastic changes were observed in the 400 Hz exciting characteristics at 2.0 T in the FeCo-2V alloy, where the unstressed value of 111 VA/kg was increased to 1700 VA/kg at a calculated maximum compressive hoop stress of -49 MPa. The Fe-27 Co alloy, although having poorer exciting characteristics at the same induction level, changed from 880 VA/kg to 1500 VA/kg at -50 MPa, the conclusion being that the Fe-27 Co alloy is less stress sensitive than the magnetically superior FeCo-2V.     

Sonochemical preparation of bimetallic Co/Cu nanoparticles in aqueous solution

Co/Cu bimetallic nanocrystallites, with average diameter of 50 nm, were prepared by a sonochemical method in the hydrazine solution of copper chloride and cobalt chloride. Cobalt was face-centered cubic phase when synthesized and remained fcc phase throughout the annealing process. X-ray diffractometer (XRD), transmission electron microscope (TEM), differential scanning calorimetry (DSC), vibrating sample magnetometry (VSM), inductively coupled plasma-atomic emission spectrometer (ICP-AES) measurements were carried out to investigate their structural and magnetic properties. It was found that the magnetic properties of bimetallic nanocrystallites were close to that of the sputtered alloys.