共查询到18条相似文献,搜索用时 62 毫秒
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固液相变蓄热技术的研究进展 总被引:4,自引:1,他引:4
综述了相变蓄热材料、相变传热问题求解方法、典型相变传热过程以及相变潜热蓄热系统(LHTES)优化设计及强化传热等诸多固液相变蓄热技术相关问题的研究进展情况 相似文献
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总结近年来国内外相变储能材料的研究状况,包括相变储能材料的制备、传热性能、相变过程数值模拟和应用等,并对复合相变储能材料的传热性能研究方法的前景作了展望。 相似文献
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相变潜热随温度变化对固-液相变过程的影响 总被引:15,自引:1,他引:15
对相变潜热随温度变化的变温固液相变过程进行了数值分析计算,重点分析了相变潜热随温度变化对相变过程的影响。结果表明,对于相变潜热随温度变化的相变过程,其主要影响因素仍然是Stefan数、相对导热系数、相对热扩散系数、相变温度宽度等基本无量纲数。尽管相变潜热随温度的变化会对相变过程造成一定的影响,但如果用相变温度范围内的平均潜热代替实际相变且视为常数,则可以较好地近似实际相变过程:由此不会给预测融化所需要的总时间带来明显的误差,而对温度分布的影响也很小,主要集中在液固过渡区内。 相似文献
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熔融盐是一种非常有前景的高温液体传热蓄热工质,在太阳能热发电、余热回收及工业热利用方面有显著的优势,但是熔融盐本身存在导热性能不高等问题。本文对纳米复合相变材料固液相变储能过程的若干最新研究进行了回顾,综述了熔融盐纳米固液相变复合材料国内外研究现状及发展趋势,最后对纳米复合相变材料固液相变储能过程的未来发展和重点研究方向进行了展望,认为主要解决纳米复合材料内熔化相变传热双温度模型的建立及求解、NC-PCM的制备工艺、金属纳米粒子的团聚性及NC-PCM蓄热器的热循环实验等方面的问题是未来研究的重点。 相似文献
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二元固液相变过程的三维非稳态数值研究 总被引:5,自引:1,他引:4
对二元固液相变进行了传统热理论分析。建立了相变换热及两相流动过程的物理模型和数学模型,并进行了相应的数值求解。由模拟结果可见不同组分在固相和液相中的百分含量以及整场的温度、速度和压力分布等。 相似文献
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Thermal energy can be converted into mechanical energy through the melting process of a phase change material (PCM). A PCM mixed with an insoluble liquid has higher energy converting efficiency during the whole melting process, where the massive microvacuum formed during the freezing process is filled by the insoluble liquid, which increases utilization of the volume change. The traditional theoretical model of the phase change process is unable to sufficiently describe the mixed PCM; therefore, a new model aimed at analyzing the characteristics of the volumetric change rate, as well as the freezing and melting times of the mixed PCM, is theoretically constructed. In this paper, the effective heat capacity method is used, and the effects of porosity are considered when the PCM is in the solid state. Comparisons of this model with the traditional model are carried out using both simulations and experiments for different pressures and geometric structures. Our results indicate that the introduced model has better accuracy when describing the phase change process of the pure PCM mixed with an insoluble liquid. 相似文献
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Adipic acid-silica composite phase change materials for thermal energy storage:Preparation and characterization 下载免费PDF全文
以己二酸为相变材料,二氧化硅溶胶为基体,采用水热法制备己二酸/二氧化硅复合相变储热材料.应用X射线衍射仪(XRD),红外光谱分析(FT-IR),场发射扫描电子显微镜(FE-SEM),同步热分析仪(TG)和差示扫描量热仪(DSC)测试所制备复合材料的显微结构,相变温度和相变焓.结果表明:当反应条件为pH=5,反应温度为150 ℃,反应时间为4 h时,己二酸与二氧化硅之间是简单的物理嵌合关系,复合材料粒径较均匀,平均粒径在1~2 μm;当己二酸的质量分数为30%时,复合材料相变温度峰值为139.0 ℃,相变焓为48.82 J/g;当己二酸的质量分数为50%时,复合材料相变温度峰值为140.5 ℃,相变焓为71.89 J/g. 相似文献
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Form-stable phase change materials for thermal energy storage 总被引:1,自引:0,他引:1
Murat M. Kenisarin Kamola M. Kenisarina 《Renewable & Sustainable Energy Reviews》2012,16(4):1999-2040
The present paper considers the state of investigations and developments in form-stable phase change materials for thermal energy storage. Paraffins, fatty acids and their blends, polyethylene glycol are widely used as latent heat storage component in developing form-stable materials while high-density polyethylene (HDPE), styrene-butadiene-styrene (SBS) triblock copolymer, Eudragit S, Eudragit E, poly (vynil chloride) (PVC), poly (vynil alcohol) (PVA) and polyurethane block copolymer serve as structure supporting component. A set of organic and metallo-organic materials with high transition heat in solid-solid state is considered as perspective for-stable materials to store thermal energy. Another perspective class of form-stable materials are the materials on the basis of such porous materials as expanded perlite and vermiculite impregnated with phase change heat storage materials. The technology of producing new form-stable ultrafine heat storage fibers is developed. It opens availability to produce the clothers with improved heat storage ability for extremely cold regions. The perspective fields of application of form-stable materials are discussed. The further directions of investigations and developments are considered. 相似文献
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Synthetic and physical characterization of phase change materials microencapsulated by complex coacervation for thermal energy storage applications 下载免费PDF全文
This paper presents a comprehensive study of encapsulated phase change materials (PCMs). In order to investigate some synthesis parameters, microencapsulated paraffin with gelatin/gum Arabic wall system was prepared by the complex coacervation method and the performance of these microcapsules was evaluated by optical microscopy and differential scanning calorimetry. Further investigations were carried out on the impact of physical parameters on the melting time by studying the constrained melting transformation of an encapsulated PCM in a spherical shell subjected to a constant temperature media. Results indicate successful production of PCM microcapsules with high melting enthalpy (116 kJ/kg), and the effects of diameter and thermal conductivity on melting time of PCMs were demonstrated. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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物质在物相变化过程中由环境吸收热量或冷量,也可以向环境放出热量或冷量,以实现能量储存和释放.固-液相变储能过程具有较大的承压能力.利用海洋温差能驱动的水下滑翔机工作在几百米深的海水中,承受巨大的外界海水压力,选用固-液相变材料作为感温工质-储能材料,可以保证相变储能动力系统稳定可靠地工作.利用固-液相变储能机理运行的水下机器人即水下滑翔机,不需要自带能源而吸取海洋温差能获得驱动力.本文阐述相变储能机理,回顾相变储能研究的发展.以赤道附近海域为例,以水下热滑翔机相变换热管为分析对象,说明了固-液相变储能过程在水下运载器驱动上的应用. 相似文献
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Recent progress in diatomite based composite phase change materials for thermal energy storage 下载免费PDF全文
硅藻土是一种含量丰富的非金属矿,具有较高的孔隙率,良好的表面结构和热物理性能,因而可作为复合储热材料的载体.本文综述了复合储热材料的种类和制备工艺,并介绍了硅藻土的结构,性能和以硅藻土为载体的复合相变储热材料的研究及应用现状. 相似文献
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Heat transfer behaviour of thermal energy storage components using composite phase change materials 下载免费PDF全文
对基于复合相变材料储热单元的储热性能进行了研究。建立了复合材料和储热单元体内部的二维传热模型,考察了复合材料物性和结构尺寸及传热流体操作条件(流体流速)对单元体储热性能的影响,对比了两种不同结构单元体的储热性能,并搭建实验平台进行了实验对比研究。对比结果表明,模型结果与实验结果趋于一致,验证了模型的准确性。复合材料物性和结构尺寸及传热流体操作条件对单元体储热性能有较大的影响。相比较单管储热单元体,同心管储热单元体有着更优的储热特性,在相同的操作条件下,同心管储热单元体的储热、放热时间较单管储热单元体分别减少10%和15%。 相似文献