Mould heat transfer and continuously cast billet quality with mould flux lubrication Part 2 Quality issues

Abstract

With many billet producers adopting mould powder lubrication, there is a need to clarify the gains in quality that can be achieved with this practice. Over the past three decades considerable research has been conducted to establish the relationship between mould behaviour and defect formation for billets continuously cast with oil lubrication, but little has been done to compare oil cast billets with powder cast billets. In this study, conducted at a Canadian minimill, four faces of a copper mould were instrumented with thermocouples and mould temperatures and billet quality were monitored with mould powder lubrication during casting of 208 × 208 mm billets. In the first part of this two part series (in Ironmaking & Steelmaking No. 1 2000), the results of the mould heat transfer analysis and the influence of variables were presented, together with a comparison between oil and powder lubrication. In the present paper, Part 2, billet quality is examined in detail. The difference in turbulence at the meniscus between oil and powder lubrication is established, and the need to tune mould level sensors when switching to mould powders is demonstrated. Previous work has shown that mould level fluctuations have a strong influence on defects such as offsquareness and transverse depressions, both of which are markedly reduced when casting with mould powders. The inherent stability of the meniscus is improved when employing mould powder lubrication and a submerged entry nozzle. Furthermore, the significant reduction in mould heat transfer at the meniscus, when mould powders are employed, particularly for medium carbon steels has been shown to correlate well with the observed reduction in offsquareness. The paper also elucidates the reasons for the reduction, and in most cases, elimination of transverse depressions in B–Ti grades when casting with mould powders. The mechanism of longitudinal depression formation and subsurface cracking observed in many of the powder cast, medium carbon billets has also been established.     

Simulation of heat transfer and strain behaviour in bloom casting mould

Abstract

An optimum casting model was developed to simulate the effect of mould flux on bloom heat transfer and strain behaviour based on a 3D MiLE method, and the influence of casting speed and superheat on bloom heat transfer and lubrication were also investigated. The simulation results showed that solidified shell thickness growth conforms to a Square Root Law, and that the model predicted results are basically in agreement with previous data in the literature, and provide confidence in model. The bloom temperature distribution range in the corner area is smaller than that in the mid-face, and the corner regions form a high cracking risk zone. The hot tearing indicator and effective stress in the corner area are significantly greater than that in the mid-face, so the corner area is the dangerous zone of cracking; The mould flux lubrication in the bloom mid-face is better than for the bloom corner region, due to a higher shell temperature and a fluid slag; The increasing of casting speed can delay air gap formation of the bloom corner area, improving the lubrication conditions, but when the casting speed is changed, it is also necessary for the mould flux viscosity and crystallization temperature be changed also. Increasing the superheat has little influence on the completely solidified distance of liquid flux in the bloom corner area.     

Challenge to control mould heat transfer during thin slab casting

Abstract

At the thin slab caster of Tata Steel, IJmuiden, mild cooling mould powders were introduced with the aim to control the mould heat transfer during casting. These mild cooling mould powders are characterised by specific values of basicity, solidification point and chemical composition. Application of these mould powders resulted in a redistribution of mould heat transfer during casting, i.e. a reduced and more stable mould heat transfer in the critical upper part of the mould and an increased mould heat transfer in the lower part of the mould. The average mould heat transfer and hence the shell thickness at mould exit are comparable to the standard powder. The application of mild cooling mould powders also resulted in improved solidification behaviour of the steel shell. A thinner chill zone with smaller thickness variations was observed. Furthermore, it was found that the mould taper required optimisation to match the changes in shrinkage behaviour to ensure uniform solidification. The use of mild cooling powders was observed to give an increase in mould friction. Mould thermal monitoring indicated that the solid slag films fractured (sheeting) in the upper part of the mould. However, no operational problems were reported, which indicate that the first 200 mm under the steel meniscus is essential for initial solidification and for the formation of a homogeneous steel shell. All these findings can be understood by considering the crystallisation properties of the mould slag, which include the cooling rate. Mild cooling has been shown to provide uniform heat transfer and adequate lubrication for high speed thin slab casting.     

Numerical simulation of fluid flow and solidification in continuous slab casting mould based on inverse heat transfer calculation

Abstract

A mathematical model based on an inverse heat transfer calculation was built to determine the heat flux between the mould and slab based on the measured mould temperatures. With K–? turbulence model, a mathematical model of three-dimensional heat transfer and solidification of molten steel in continuous slab casting mould is developed. Solidification has been taken into consideration, and flow in the mushy zone is modelled according to Darcy’s law as is the case of flow in the porous media. The heat flux prescribed on the boundaries is obtained in the inverse heat conduction calculation; thus, the effect of heat transfer in the mould has been taken into consideration. Results show that the calculated values of mould temperature coincide with the measured ones. Results also reveal that the temperature distribution and shell thickness are affected by the fluid flow and heat transfer of slab which is governed by the heat flux on the mould/slab interface.     

High speed continuous casting of steel billets: Part 2: Mould heat transfer and mould design

Abstract

A high speed instrumented mould trial was conducted under industrial conditions to study the heat transfer at the midfaces and corners of the mould and to clarify mould taper requirements in high speed continuous casting. The predicted peak heat transfer in this high speed system was found to be up to 2·5 times that reported for conventional speeds, and up to 1·5 times that for other reported high speed systems. The average heat transfer was found to be up to 45% greater than in conventional systems, and comparable with other high speed systems. The effect of casting speed was analysed in detail and was found to be dependent on carbon content. Increased casting speed was also found to increase the metal level standard deviation but to have less of an impact on the heat transfer than similar changes at conventional speeds. A mathematical billet thermal and solidification model was applied to these heat transfer results to determine the response of the current mould to high speed casting conditions. Using this assessment of the mould distortion and billet dimensions, new mould tapers were designed on the basis of minimising any mould-strand interaction and/or binding. New mould taper designs for high and low carbon grades were recommended for casting speeds of 3·0, 3·5, 4·0, and 4·5 m min ^-1. The design sensitivity to changes in casting speed is discussed.     

ASP连铸结晶器铜板热流和温度的研究

根据在线实测的铜板温度以及ASP(Angang Strip Production)板坯连铸机冷却参数,建立了ASP板坯结晶器(高1 000 mm,铸坯断口面170 mm×2 000 mm)铜板传热模型以计算结晶器热流密度的分布函数和得出结晶器热流密度与结晶器高度的关系式。结果表明,铜板温度和热流密度的分布具有相似的规律性,结晶器内、外弧铜板宽度方向上中心和角部的热流波动分别约为400 kW/m²和200 kW/m²,其温度差分别约为30℃和20℃。     

Heat Transfer and Its Effect on Solidification in Combined Mould

SymbolList cp,cps,cpl———Specificheat,specificheatofsolidsteel andmoltensteel,(J·kg-1·K-1);C2———EmpiricalcoefficientoflowReynoldsκεturbu lencemodel;Dl———Darcyconstant;fl,fs———Fractionofmoltensteelandsolidsteel;f2———Empiricalcoefficientre     

Effect of solidus temperature and crystalline phase of mould flux on heat transfer in continuous casting mould

Abstract

Pieces of mould flux film obtained from a commercial continuous casting machine and measurements of the mould temperature have been used in an investigation to explain the mechanism of heat transfer in the mould. Comparison with the results of numerical calculations, indicates that the main factor responsible for the reduction of heat transfer with a high basicity flux is the contact resistance at the interface of the mould wall and solid flux film. The results show that a relatively high contact resistance is introduced when using a crystalline, high solidus mould flux because of the stability of the contact resistance.     

Analysis of variability and non-uniformity of mould heat extraction for round billet continuous casting in plant trials

Abstract

Maintaining a stable and uniform heat transfer from steel shell to mould is important to produce high quality casting billet. In the present paper, a large amount of measured data of heat flux and temperature for round billet continuous casting mould from a plant trial has been analysed to shed light on the variability and non-uniformity of mould heat transfer around the perimeter. The results show that the variability and non-uniformity of heat extraction from the steel through the mould is affected slightly by operational parameters, such as pouring temperature, casting speed, meniscus, electromagnetic stirring current, but strongly by the steel carbon content and mould powder type. The installation of the mould in caster machine determines the magnitude of non-uniformity of heat transfer to a great extent. The relative root mean square (rRMS) of mould heat flux, presenting the variability and non-uniformity of mould heat transfer around the perimeter in transverse section, has wider range of variation and higher mean value compared with that of temperature. When the abnormality of heat transfer happens, such as deposit, the non-uniformity of mould heat transfer is also studied.     

Development of Mould Flux for High Speed Thin Slab Casting

Mould powders impact the stability of the continuous casting process for steel at all casting speeds. The main functions of mould powder are to provide sufficient lubrication and to control the mould heat transfer between the solidifying steel shell and the copper mould. At higher casting speeds associated with thin slab casting, the role of the mould powder is even more important. Actual casting speeds for the thin slab caster at Corus IJmuiden are between 5.4 and 6 m/min; the production level is around 1.3 Mt/year (coils). It has been decided to increase the production of this caster to a level of 1.8 Mt/year (coils). In order to meet this demand, the steel in mould time has to be increased to approximately 85% and the maximum casting speed will be increased to 8 m/min. A collaborative project between Sumitomo Metal Industries (SMI) and Corus IJmuiden was initiated to develop mould powders which facilitate casting speeds up to 8 m/min at the thin slab caster. Main subjects of this project are: mould powder design, characterisation of mould powder and mould slag, trials at the pilot caster of Sumitomo and finally plant trials at the thin slab caster of Corus. A special point of attention is the condition to use mould powder as a granulated material at the thin slab caster. As a consequence, the characterisation work focussed on the choice of raw materials and on the corresponding phase relations at elevated temperatures. Typical of the developed mould powders are so‐called mild cooling properties which will result in a controlled mould heat transfer during casting. In this paper, several aspects of this joint project between Sumitomo and Corus will be described.     

Mould Powder Development for Continuous Casting of Steel

Mould powders significantly determine the stability of the continuous casting process of steel at all casting speeds. The main functions of mould powders are to provide strand lubrication and to control the mould heat transfer in the horizontal direction between the steel shell and the copper mould. The composition, properties and operational performance of mould powders were investigated in detail with a focus on high-speed thin slab casting and conventional slab casting. Various advanced characterisation methods were applied, completed with experiments at laboratory scale and full-scale plant trials. It was found that melting of mould powder at the meniscus and crystallisation of the slag film are key processes during continuous casting. Both powder melting and slag crystallisation are primarily based on the composition of the mould powder and the mould slag. Additionally, the operational parameters during continuous casting will affect these processes as well. Results of the work are used for a further and more fundamental understanding of the mould powder functions and to guide mould powder design for various steel grades.     

Development of an experimental system for the study of the effects of electromagnetic stirring on mold heat transfer

This article focuses on the influence of mold-electromagnetic stirring (M-EMS) on mold heat transfer, for the purpose of developing a general approach to study mold heat-transfer characteristics in continuous casting of small round billets. This study was based on an experimental system with simultaneous, on-line monitoring of mold heat flux and temperature. Several phenomena are discussed including the local mold heat flux/temperatures and their responses to the variation of M-EMS current.     

Mould Powder Requirements for High‐speed Casting

Mould powders play an important role in the stability of the continuous casting process of steel. The main functions of mould slag (i.e. molten powder) are to provide sufficient lubrication and to control the heat transfer between the developing steel shell and the mould. Sufficient lubrication requires an undisturbed melting of mould powders and uniform infiltration of mould slag. Based on the casting practice in IJmuiden, it is found that these demands become even more important for the applied high casting speeds in thin slab casting at 5 to 6 m/min. At Corus RD&T, mould powders were characterised by X‐ray diffraction and subsequent fully quantitative Rietveld analysis. Additionally, the melting of mould powders has been studied in‐situ using high‐temperature X‐ray diffraction, to gain crucial knowledge about melting relations. Slag rims obtained from the thin slab caster mould were characterised using extended microscopic techniques in order to describe the mechanisms of rim formation and growth. Finally, slag films obtained after casting were characterised. As a result, not only the melting process of mould powder, but also the mechanism of formation and growth of slag rims is much better understood. This knowledge will be applied to define the demands on the composition and properties of mould powder for even higher casting speeds.     

Determination of interface heat transfer coefficient between aluminum casting and graphite mold

To produce castings of titanium, nickel, copper, aluminum, and zinc alloys, graphite molds can be used, which makes it possible to provide a high cooling rate. No die coating and lubricant are required in this case. Computer simulation of casting into graphite molds requires knowledge of the thermal properties of the poured alloy and graphite. In addition, in order to attain adequate simulation results, a series of boundary conditions such as heat transfer coefficients should be determined. The most important ones are the interface heat transfer coefficient between the casting and the mold, the heat transfer coefficient between the mold parts, and the interface heat transfer coefficient into the environment. In this study, the interface heat transfer coefficient h between the cylindrical aluminum (99.99%) casting and the mold made of block graphite of the GMZ (low ash graphite) grade was determined. The mold was produced by milling using a CNC milling machine. The interface heat transfer coefficient was found by minimizing the error function reflecting the difference between the experimental and simulated temperatures in a mold and in a casting during pouring, solidification, and cooling of the casting. The dependences of the interface heat transfer coefficient between aluminum and graphite on the casting surface temperature and time passed from the beginning of pouring are obtained. It is established that, at temperatures of the metal surface contacting with a mold of 1000, 660, 619, and 190°C, the h is 1100, 4700, 700, and 100 W/(m² K), respectively; i.e., when cooling the melt from 1000°C (pouring temperature) to 660°C (aluminum melting point), the h rises from 1100 to 4700 W/(m² K), and after forming the metal solid skin on the mold surface and decreasing its temperature, the h decreases. In our opinion, a decrease in the interface heat transfer coefficient at casting surface temperatures lower than 660°C is associated with the air gap formation between the surfaces of the mold and the casting because of the linear shrinkage of the latter. The heat transfer coefficient between mold parts (graphite–graphite) is constant, being 1000 W/(m² K). The heat transfer coefficient of graphite into air is 12 W/(m² K) at a mold surface temperature up to 600°C.     

Mould lubrication and friction behaviour with hydraulic oscillators in slab continuous casting

Abstract

It is very important to obtain reliable lubrication from casting powder both at the meniscus and in the gap between strand and mould as it affects slab surface quality and caster productivity. With knowledge of mould friction, a quantitative insight into the behaviour of powder during caster operation is possible. In the present research, the friction was studied based on a slab continuous caster equipped with hydraulic oscillators. The effects of mould oscillation and the abrupt change of casting speed on mould friction force were evaluated, and the characteristics of lubrication behaviour in a casting sequence were investigated. In particular, a comparison between the mould friction force between sinusoidal oscillation mode and non-sinusoidal oscillation mode was made. Finally, the characteristics of friction before a breakout are discussed. The experimental and analytical results may contribute to the development of mould friction online measurement and more clearly learn the lubrication behaviour in different conditions.     

Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides

Abstract

Infrared transmittance of glassy and crystalline mould fluxes was measured using a Fourier transform infrared spectrometer at room temperature. Radiation heat transfer from the steel shell to the mould was calculated by a model. The results indicate that transition metal oxides MnO, FeO and TiO₂ have a marked negative effect on infrared transmittance and radiation heat flux of glassy samples. With MnO, FeO and TiO₂ added, the reductions of radiation heat flux in glassy samples are 19–25%, 34–36%, 6–29% respectively. X-ray diffraction results indicated that the crystalline phase in transition oxides free samples was mainly Ca₄Si₂O₇F₂. After transition oxides MnO, FeO and TiO₂ added, Mn₂SiO₄, Fe₂SiO₄, CaTiO₃, Ca₂SiO₄ and other minor phases were also precipitated in mould fluxes. On account of strong refraction and scattering, the negative effect on radiation heat flux in crystalline samples was much larger than that in the glassy ones.     

Influence of oxide scales on heat transfer in secondary cooling zones in the continuous casting process,part 1: heat transfer through hot-oxidized steel surfaces cooled by spray-water

For the cooling of steels in the continuous casting process it is necessary to know the heat transfer from the solidifying strand to the cooling water to enable calculation of the secondary cooling zone. Previous investigations have only determined this variable for non-oxidizing metallic surfaces. For many steels cast in practice, however, the formation of oxide layers prevents a direct transfer of the previous results. In the present research the influence of the oxide layers on the heat transfer has been investigated for spay-water cooling. Results have shown that heat transfer in the range of stable film boiling is determined for a constant spray-water temperature in the same way as for non-oxidizing metals, i.e. using the water mass flux density ·_s only. The changed surface qualities resulting from the oxide formation cause the Leidenfrost temperature, however, to shift considerably to higher values.     

方坯连铸保护渣渣膜润滑行为的理论研究

应用传热学和粘性流体力学原理，用数学模拟的方法描述了方坯连铸结晶器内保护渣的润滑行为，计算不同浇注条件下铸坯所受摩擦力，分析了各种因素对铸坯所受摩擦力的影响。     

Continuous casting mould powder evaluation

Abstract

A continuous casting mould powder must satisfy various requirements including thermal insulation, chemical insulation, inclusion absorption, lubrication, and promotion of uniform heat transfer from the solidifying steel strand to the copper mould. The relative importance of these properties varies according to the type of steel cast, the prevailing casting conditions, and the end steel requirements. Development of mould powders at Corus UK Ltd involves plant based trials of different powders whose properties influence the above characteristics of which heat transfer is a major consideration. Particular use is made of mould thermal monitoring which, although primarily designed for sticker breakout detection, is now finding increasing use as an investigative tool in mould slag assessment. Both static and dynamic plant data are now available relating mould slag heat transfer performance to casting conditions and this paper describes some recent investigative work carried out by the Aluminium & Steel Casting Department of Teesside Technology Centre, Corus UK Ltd. The study shows that using a combination of plant based observation and laboratory analysis, a greater depth in understanding of mould powder performance can be realised, yielding important information for future powder development.     

The thermal and metallurgical state of steel strip during hot rolling: Part I. Characterization of heat transfer

A technique using intrinsic thermocouples was developed to monitor the thermal response of steel samples during hot rolling. A series of hot-rolling tests was conducted with the thermocoupleinstrumented samples on CANME’s pilot mill to simulate individual stands of Stelco’s Lake Erie Works hot-strip mill. A mathematical model of heat transfer in the roll bite has been employed to back calculate the roll/strip interface heat-transfer coefficients for lubricated and unlubricated conditions. The influence of reduction, rolling speed, and prerolling on roll-strip heat transfer has also been examined. For unlubricated rolling tests, the heat-transfer coefficient in the roll bite increased with time, reaching a steady-state value of 57 kW/m² °C. The corresponding number for the lubricated tests was 31 kW/m² °C. The observed variation in the interface heat-transfer coefficient with increasing strain and interface pressure points to a strong dependence on the real area of contact between the strip and rolls. Therefore, it appears that heat transfer between the two surfaces occurs primarily by conduction across asperity contacts. The high heat-transfer coefficients attained at the roll/strip interface promote chilling of the strip to a depth of approximately one-eighth of the thickness. To validate the overall heattransfer model, predicted surface temperatures of the strip have been compared with interstand temperature measurements obtained on the industrial mill using pyrometers. Formerly Graduate Student, The Centre for Metallurgical Process Engineering, The University of British Columbia