共查询到19条相似文献,搜索用时 46 毫秒
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以M5640为萃取剂,在CO2协同作用下,从氨?硫酸铵溶液中萃取锌,考察了萃取剂浓度、总氨浓度、相比、温度、加入CO2等因素对锌萃取率的影响. 结果表明,M5640在氨性溶液中对锌有一定的萃取能力,溶液pH值和总氨浓度对锌的萃取率影响较大,向溶液中加入CO2可明显提高M5640对锌离子的萃取能力. 在温度25℃及M5640加入量35vol%、相比O/A=2、锌离子浓度18.02 g/L、总氨浓度3 mol/L、加入CO2的条件下,锌的单级萃取率由不加CO2时的65.1%提升至97%以上,两级错流萃取锌萃取率达99.9%. 萃取得到的有机相不含氨,表明加入CO2可避免氨的共萃. 相似文献
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醋酸稀溶液的络合萃取 总被引:33,自引:5,他引:33
络合萃取法对于极性有机物稀溶液的分离具有高效性和高选择性。本文以醋酸稀溶液为分离对象,通过系统的相平衡实验筛选出30 wt%三辛胺(或7301)+20 wt%正辛醇+50 wt%煤油混合溶剂。同时,探讨了叔胺类萃取剂对醋酸萃取的过程机理,研究了混合溶剂萃取稀醋酸工艺的可行性。 相似文献
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P507与Cyanex272协同萃取分离溶液中钴镍离子 总被引:2,自引:0,他引:2
采用P507与Cyanex272协同萃取分离回收浸出液中的Ni2+, Co2+,考察了初始pH值、有机相复配比(P/C)和水油相比(A/O)的影响. 结果表明,协萃优化条件为:有机相皂化率50%,皂化时间30 min;有机相组成为10%复配萃取剂[P507:Cyanex272为3:2(j)]+85%磺化煤油+5% TBP;相比为3:1,水相pH值为2.5. 在此条件下,Co2+的一级萃取率为92.96%. 利用200 g/L硫酸反萃负载有机相,在相比2:3、振荡强度225 r/min、时间4 min的条件下,Co2+的反萃率为98.68%,实现了低pH值下Ni2+和Co2+的萃取分离. 相似文献
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离心萃取器用于反胶束溶液萃取牛血清白蛋白 总被引:3,自引:0,他引:3
离心萃取器用于反胶束溶液萃取牛血清白蛋白陆强,李宽宏,施亚钧(华东理工大学化学工程研究所,上海200237)关键词离心萃取器,反胶束溶液,牛血清白蛋白1前言以表面活性剂溶于非极性有机溶剂所形成的反胶束溶液为萃取剂,提取与分离水溶液中的蛋白质,是一种有... 相似文献
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硫酸盐镀铜溶液分析方法的选择和探讨 总被引:1,自引:1,他引:0
硫酸盐镀铜溶液由于酸性较强,在生产过程中容易溶入各种杂质,其中铁杂质对镀液分析常用的络合滴定法、碘量法和中和法均有较大干扰,使分析结果不能正确指导生产。根据化学反应的原理指出了误差的来源及相应的解决方法。 相似文献
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1 INTRODUCTIONMacrolide antibiotics are an important group of an-tibiotics.Except for a few antibiotics which containneutral carbohydrate,almost all the macrolide antibi-otics show basicity since they contain the group ofamine carbohydrate. 相似文献
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A novel extractant mixture, di-2-ethylhexyl phosphate (DEHPA) plus HX, was proposed and tested for recovering gallium from sulfate solution. It was found that the extraction capacity of DEPHA for gallium from sulfate solution could be enhanced significantly due to the synergistic effect of acidic extractant HX. Gallium extraction is negligible below pH 0 and highly sensitive to pH of aqueous phase in the range from 0 to 1, and satisfactory extraction can be gained at pH>1. More than 96% Ga extraction was obtained using 15% DEHPA plus 2% HX. Although Fe (Ⅲ) was found to be extracted preferentially to Ga (Ⅲ), effective extraction of Ga (Ⅲ) was possible by reducing ferric to the ferrous state prior to extraction. A loaded organic phase containing 0.48g L-1 Ga could be produced from solution of 0.12g L-1 Ga at A/O ratio of 4 : 1 via three mixer-settler operation stages. Gallium was stripped quantitatively from the loaded organic phase with l,5mol L-1 of sulfuric acid. 相似文献
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《分离科学与技术》2012,47(12):1936-1940
Gallium was separated from aluminum in hydrochloric acid medium by a steady microemulsion. In the cetyltrimethylammonium bromide (CTAB)/n-pentanol/n-heptane/HCl/tributyl phosphate (TBP) system, TBP was introduced as the modifier to avoid emulsification of the microemulsion. The extraction efficiency on gallium was also improved by adding TBP. The factors that influenced the separation efficiency were explored. The results of the experiments showed that the gallium and aluminum were effectively separated within a very short time, and the extraction efficiencies of gallium and aluminum were 92% and 5%, respectively. The maximum back-extraction efficiency of gallium was 92% in HCl solution (4 M). 相似文献
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以自制的硅胶固载硫酸镓为催化剂,正丁酸和异戊醇为原料合成了丁酸异戊酯。考察了催化剂用量、醇酸物质的量比、反应时间及催化剂重复使用次数等因素对收率的影响。结果表明硅胶固载硫酸镓是高效、经济且环境友好的酯化催化剂。适宜反应条件下收率为87.3%。 相似文献
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硅胶固载硫酸镓催化合成尼泊金丁酯 总被引:1,自引:0,他引:1
采用自制的硅胶固载硫酸镓为非均相催化剂合成了食品防腐剂尼泊金丁酯,考察了催化剂用量、醇酸物质的量比、回流反应时间、催化剂重复使用性及带水剂种类等因素对目标产物收率的影响。结果表明该催化剂具有催化活性高,反应时间短,出水速率快,价廉易得,稳定性好,合成工艺流程简单,操作方便,不易腐蚀设备,不需加带水剂即可获得较为理想的收率等诸多优势,基本革除了浓硫酸为酯化催化剂存在的设备腐蚀严重、后处理工艺复杂、主反应选择性低、废液排放量多等弊端。适宜反应条件为:对羟基苯甲酸0.05mol,醇酸物质的量比3,催化剂1.0g,反应时间5h,收率达91.3%。 相似文献
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采用凹凸棒石黏土负载硫酸镓(Ga2(SO4)3)制备了Ga2(SO4)3/凹凸棒石黏土固体酸催化剂,采用红外光谱及X衍射光谱等对催化剂结构进行了表征。通过乳酸丁酯的合成考察了催化剂的较优制备条件和催化性能,并对相应催化反应进行了动力学研究。结果表明催化剂的较优制备条件是:凹凸棒石黏土经1.2mol/L硫酸溶液酸化处理,Ga2(SO4)3负载量为5.7%,焙烧温度350℃,焙烧时间2.5h。在较优酯化反应条件下,平均酯化率为95.5%。动力学研究表明反应为准一级反应,表观活化能为45.072kJ/mol,378K时反应速率常数为2.35×10--2 min--1。 相似文献
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