Carbon dioxide as a working fluid in drying heat pumpsLe dioxyde de carbone comme fluide actif dans des séchoirs à pompe à chaleur

Carbon dioxide as a working fluid in refrigeration and heat pump systems is increasingly important in view of the CFC substitution problem. It is both under ecological and economical aspects an attractive alternative to the HFC working fluids at present in practical use. The thermophysical properties and characteristics of carbon dioxide are quite different from those of refrigerants used in conventional vapour compression cycles. Its application in conventional vapour compression refrigerating systems is limited by its critical parameters (t_c=31.1°C and p_c=73.8 bar). The possibility to use carbon dioxide also beyond these limits in high temperature processes, e.g. heat pumps, is given by the application of a trans-critical process. The design and construction of a commercial drying heat pump system (batch type cabinet dryer with 12 kW heating capacity and closed air circuit) using the natural working fluid carbon dioxide is shown and experimental results of investigations carried out are presented. Energy savings are given compared to manufacturer's data of energy consumption.     

Development of a vapor compression cycle with a solution circuit and desorber/absorber heat exchange

A vapor compression cycle with a solution circuit and desorber/absorber heat exchange (DAHX) has been investigated experimentally using the ammonia/water mixture. A breadboard heat pump was designed and built to measure the cycle performance. COPs in the range of 1.2–1.8 were obtained experimentally for a temperature lift between 60 and 80°C. The cooling capacities were between 7 and 12 kW, which increased with an increase of the ammonia concentration. The pressure ratios encountered were in the range of 2–6. A COP of 1.44 at the temperature lift of 79°C was recorded with a cooling capacity at 10.25 kW. The experimental results are compared to that of the single-stage and two-stage cycle. The two-stage system had the highest temperature lift (110–120°C) and the lowest COP (0.69–1.04). The single-stage system has the highest COP (2.2–3.5) but the lowest temperature lift (40°C). Also, a solution bypass between the Absorber I outlet and Desorber II inlet was proposed to improve the cycle performance. The experimental results showed that the COP varied in the range of 1–2%, while the temperature lift increased by the range between 0 and 6°C. In addition, the analysis of the test result uncertainties was made.     

Nucleate boiling heat transfer coefficients of HCFC22, HFC134a, HFC125, and HFC32 on various enhanced tubes

In this study, nucleate boiling heat transfer coefficients (HTCs) of HCFC22, HFC134a, HFC125, HFC32 were measured on a low fin, Turbo-B, and Thermoexcel-E tubes. All data were taken at the liquid pool temperature of 7 °C on horizontal tubes of 152 mm length and 18.6–18.8 mm outside diameter at heat fluxes of 10–80 kW m⁻² with an interval of 10 kW m⁻² in the decreasing order of heat flux. For a plain and low fin tubes, refrigerants with higher vapor pressures showed higher nucleate boiling HTCs consistently. This was due to the fact that the wall superheat required to activate given size cavities became smaller as pressure increased. For Turbo-B and Thermoexcel-E tubes, HFC125 showed a peculiar behavior exhibiting much reduced HTCs due to its high reduced pressure. The heat transfer enhancement ratios of the low fin, Turbo-B, and Thermoexcel-E tubes were 1.09–1.68, 1.77–5.41, 1.64–8.77 respectively in the range of heat fluxes tested.     

Fluids for high temperature heat pumps

The theoretical performances of some 250 potential work fluids in vapour compression heat pumps condensing at 150°C and evaporating at 100°C have been predicted, using expression for coefficient of performance (COP) and minimum superheat that involve only easily accessible physical properties. Expected correlations were found between COP and critical temperature, between specific compressor displacement and normal boiling point, T_bp, and between condensing pressure and T_bp. Correlations were also found between minimum superheat and both molecular weight and critical pressure. From these correlations, the desirable basic properties of a high temperature heat pump fluid are deduced. The principle of corresponding states is invoked to explain the connection between minimum superheat and critical pressure, and hence the reason why perfluorinated compounds tend to make poor work fluids.     

A theoretical study of a novel regenerative ejector refrigeration cycle

There has been a demand for developments of the ejector refrigeration systems using low grade thermal energy, such as solar energy and waste heat. In this paper, a novel regenerative ejector refrigeration cycle was described, which uses an auxiliary jet pump and a conventional regenerator to enhance the performance of the novel cycle. The theoretical analysis on the performance characteristics was carried out for the novel cycle with the refrigerant R141b. Compared with the conventional cycle, the simulation results show that the coefficient of performance (COP) of the novel cycle increases, respectively, by from 9.3 to 12.1% when generating temperature is in a range of 80–160 °C, the condensing temperature is in a range of 35–45 °C and the evaporating temperature is fixed at 10 °C. Especially due to the enhanced regeneration with increasing the pump outlet pressure, the improvement of COP of the novel cycle is approached to 17.8% compared with that in the conventional cycle under the operating condition that generating temperature is 100 °C, condensing temperature is 40 °C and evaporating temperature is 10 °C. Therefore, the characteristics of the novel cycle performance show its promise in using low grade thermal energy for the ejector refrigeration system.     

An equation of state for 1,1-difluroethane (HFC 152a)

An equation of state for 1,1-difluoroethane (HFC 152a, CH₃CHF₂) has been developed on the basis of reliable experimental data including PVT, liquid C_p, and saturated-liquid-density data measured by our group. It is a non-dimensionalized virial equation whose functional form is the same as that originally developed for 1,1,1,2-tetrafluoroethane (HFC 134a) in our group. The effective range is for pressures up to 15 MPa, temperatures from 230 to 450 K, and densities to 1000 kg m⁻³. The equation represents reliable PVT measurements within ± 1% in pressure for the superheated vapour and supercritical fluid, while within ±0.5% in density for the compressed liquid. In addition, it should be noted that the equation represents the other essential thermodynamic properties including vapour pressures, saturated-liquid/ vapour densities, isobaric/isochoric specific heats and sound velocity in both the liquid and gaseous phase of HFC 152a.     

Performance of diffusion absorption refrigeration cycle with organic working fluids

A diffusion absorption refrigeration (DAR) cycle is driven by heat and utilizes a binary solution of refrigerant and absorbent as working fluid, together with an auxiliary inert gas. Commercial DAR systems operate with ammonia–water solution and hydrogen or helium as the inert gas. In this work, the performance of a simplified DAR system working with an organic absorbent (DMAC – dimethylacetamide) and five different refrigerants and helium as inert gas was examined numerically, with the aim of lowering the generator temperature and system pressure along with a non-toxic refrigerant The refrigerants were: chlorodifluoromethane (R22), difluoromethane (R32), 2-chloro-1,1,1,2-tetrafluoroethane (R124), pentafluoroethane (R125) and 1,1,1,2-tetrafluoroethane (R134a). The results were compared with the performance of the same system working with ammonia–water and helium. Similar behavior was found for all systems, regarding the coefficient of performance (COP) and rich and poor solution concentrations as functions of generator temperature. It was found that typical generator temperature with the new substances was 150 °C, yet lower COPs, higher evaporator temperatures and lower condensation temperature of about 40 °C governed these systems.     

Experimental investigation on the thermal stability of some new zero ODP refrigerants

Five zero ODP (ozone depletion potential) hydro-fluorocarbon refrigerants (HFC-23, HFC-143a, HFC-227ea, HFC-236fa, HFC-245fa) were tested to define their maximum usable temperature and their thermal degradation threshold. Pyrolysis is detected (a) as a pressure change at constant temperature and volume; (b) as a departure of the vapour pressure curve of the heated fluid from that of the original substance. Visual inspection of the vessel walls and fluid chemical analysis complement the method. The minimum detectable degradation rate is believed to be less than 1% in 50 h. All the fluids exhibit a variable, but excellent thermal stability up to the following temperatures at which no decomposition was observable in 50–100 h: 425 °C for HFC-227ea, 400 °C for HFC-23 and HFC-236fa, 350 °C for HFC-143a and 300 °C for HFC-245fa. Clear degradation signs were observed at temperatures 25–50 °C higher. Most of the fluids heated up to their thermal stability threshold exhibited an induction period of 5–50 h in which no decomposition was detectable but after which an observable degradation started. For a given fluid such period decreases at increasing temperatures. The use of fluids in a cyclic process in which the working medium permanence at the top temperature is very brief could take advantage of this behaviour with a reduction in degradation rates or with an increase in the limiting temperature. The influence of the decomposition products on the functionality of a thermodynamic power cycle was investigated by means of an appropriate computer code. The working fluid was assumed to be a binary mixture with 1 to 3% concentration of a light decomposition product of the methane series. Chemical species such as CH₄ and CF4 with a critical temperature much lower than that of the base fluid strongly affect the cycle configuration. On the contrary species with critical temperatures closer to that of the base fluid such as CH₃F, CH₂F₂ or CHF₃ influence only marginally the cycle performance. In general a small concentration of decomposition products in the working medium is likely to be acceptable without noticeable drawbacks.

Résumé

Five zero ODP (ozone depletion potential) hydro-fluorocarbon refrigerants (HFC-23, HFC-143a, HFC-227ea, HFC-236fa, HFC-245fa) were tested to define their maximum usable temperature and their thermal degradation threshold. Pyrolysis is detected (a) as a pressure change at constant temperature and volume; (b) as a departure of the vapour pressure curve of the heated fluid from that of the original substance. Visual inspection of the vessel walls and fluid chemical analysis complement the method. The minimum detectable degradation rate is believed to be less than 1% in 50 h. All the fluids exhibit a variable, but excellent thermal stability up to the following temperatures at which no decomposition was observable in 50–100 h: 425 °C for HFC-227ea, 400 °C for HFC-23 and HFC-236fa, 350 °C for HFC-143a and 300 °C for HFC-245fa. Clear degradation signs were observed at temperatures 25–50 °C higher. Most of the fluids heated up to their thermal stability threshold exhibited an induction period of 5–50 h in which no decomposition was detectable but after which an observable degradation started. For a given fluid such period decreases at increasing temperatures. The use of fluids in a cyclic process in which the working medium permanence at the top temperature is very brief could take advantage of this behaviour with a reduction in degradation rates or with an increase in the limiting temperature. The influence of the decomposition products on the functionality of a thermodynamic power cycle was investigated by means of an appropriate computer code. The working fluid was assumed to be a binary mixture with 1 to 3% concentration of a light decomposition product of the methane series. Chemical species such as CH₄ and CF4 with a critical temperature much lower than that of the base fluid strongly affect the cycle configuration. On the contrary species with critical temperatures closer to that of the base fluid such as CH₃F, CH₂F₂ or CHF₃ influence only marginally the cycle performance. In general a small concentration of decomposition products in the working medium is likely to be acceptable without noticeable drawbacks.     

Experimental correlation of falling film condensation on enhanced tubes with HFC134a; low-fin and Turbo-C tubes

The objectives of this paper are to develop experimental correlations of heat transfer for enhanced tubes used in a falling film condenser, and to provide a guideline for optimum design of the falling film condenser with a high condensing temperature of 59.8 °C. Tests are performed for four different enhanced tubes; a low-fin and three Turbo-C tubes. The working fluid is HFC134a, and the system pressure is 16.0 bar. The results show that the heat transfer enhancement of low-fin tube, Turbo-C (1), Turbo-C (2) and Turbo-C (3) ranges 2.8–3.4 times, 3.5–3.8 times, 3.8–4.0 times and 3.6–3.9 times, respectively, compared with the theoretical Nusselt correlation. It was found that the condensation heat transfer coefficient decreased with increasing the falling film Reynolds number and the wall subcooling temperature. It was also found that the enhanced tubes became more effective in the high wall subcooling temperature region than in the low wall subcooling temperature region. This study developed an experimental correlation of the falling film condensation with an error band of ±5%.     

An experimental study on HC290 and a commercial liquefied petroleum gas (LPG) mix as suitable replacements for HCFC22

This paper presents an experimental study on the performance of hydrocarbon refrigerants, namely propane and a liquefied petroleum gas (LPG) mix as suitable replacements for the widely used refrigerant HCFC22 in refrigeration and heat pump applications. A cylinder of commercially available LPG from New Zealand market was obtained for this study. The composition of the specific LPG mix (by mass fraction) was propane (HC290)—98.95%, ethane (HC170)—1.007%, iso-butane (HC600a)—0.0397% and other constituents in small proportions. Experiments were carried out in a laboratory heat pump test facility with maximum condenser capacity of approximately 15 kW. Condensing temperatures were held constant at 35, 45 and 55°C, while evaporating temperatures were varied over a wide range from − 15 to + 15°C. All tests were carried out at constant degree of superheat (about 1 K) and subcooling (about 8 K). All appropriate precautions were observed against any leaks or fire.The analysis revealed that the hydrocarbon refrigerants performed better than HCFC22 but with a small loss of condenser capacity. The mass flow rate and compressor discharge temperature were found to be significantly lower than HCFC22. The performance of the specific LPG mix tested was found to be better than HC290 at higher condensing temperatures but poorer at a lower condensing temperature. No adverse effects were found with the LPG mix despite the presence of little moisture (less than 0.01%) in its composition. The study reveals that LPG of the tested composition (i.e. predominantly a mixture of propane, ethane and iso-butane) can be an excellent refrigerant in heat pump/refrigeration applications.     

Blends of carbon dioxide and HFCs as working fluids for the low-temperature circuit in cascade refrigerating systems

This paper describes an analysis on the performances of a cascade refrigeration cycle operated with blends of carbon dioxide (CO₂, or R744) and hydrofluorocarbons (HFC) as the low-temperature working fluid. The aim of this work was to study the possibility of using carbon dioxide mixtures in those applications where temperatures below CO₂ triple point (216.58 K) are needed. The analysis was carried out by developing a software based on the Carnahan–Starling–De Santis (CSD) equation of state (EoS) using binary interaction parameters derived from our experimental data. The properties of the investigated blends (R744/R125, R744/R41, R744/R32, R744/R23) were used to simulate the behavior of a cascade cycle using ammonia (R717) as the high-temperature-circuit working fluid and operating at evaporating temperatures down to −70 °C. The use of a suction–liquid heat exchanger on the low-temperature side of the circuit was also investigated. Results show that the R744 blends are an attractive option for the low-temperature circuit of cascade systems operating at temperatures approaching 200 K.     

Modelling the performance of a transcritical CO2 heat pump for high temperature heating

A prototype transcritical CO₂ heat pump was constructed for heating water to temperatures greater than 65°C while providing refrigeration at less than 2°C. The heating capacity was 115 kW at an evaporation temperature of +0.3°C and a hot water temperature of 77.5°C, with a heating coefficient of performance (COP) of 3.4. Performance data is presented for each of the compressor, the gas cooler, and the recuperator as well as for the overall heat pump system. Equipment performance data was incorporated into a computer model to enable parametric investigations of heat pump performance. Model predictions showed that the hot water temperature could be increased from 65 to 120°C with a relatively small reduction in heating capacity and heating COP of 33 and 21%, respectively. Model predictions also highlight the potential for significant capacity improvements by eliminating the recuperator in favour of a larger gas cooler.     

Experimental correlation of pool boiling heat transfer for HFC134a on enhanced tubes: Turbo-E

The objectives of this paper are to study the heat transfer characteristics for enhanced surface tubes in the pool boiling and to provide a guideline for the design conditions for the evaporator using HFC134a. The shape of tube surfaces, the wall superheat, and the saturation temperature are considered as the key parameters. Copper tubes (d_o = 19.05 mm) are treated with different helix angles and the saturation temperatures are controlled from 3 to 16 °C. It is found that the pool boiling heat transfer coefficient decreases with increasing the wall superheat. It is also found that boiling heat transfer coefficients for Turbo-II and Turbo-III are 1.5–3.0 times and 1.2–2.0 times higher than that for Turbo-I without the helix angle, respectively. The higher heat transfer performance from Turbo-II and Turbo-III can be explained by the “bubble detention” phenomenon on the surface without the helix angle for the Turbo-I. The experimental correlations for the pool boiling heat transfer on the present enhanced tubes without (Type I) and with the helix angle (Type II and Type III) are developed with the error bands of ±30%, respectively.     

Review of advanced absorption cycles: performance improvement and temperature lift enhancement

The objective of this study is to propose and evaluate advanced absorption cycles for the coefficient of performance (COP) improvement and temperature lift enhancement applications. The characteristics of each cycle are assessed from the viewpoints of the ideal cycle COP and its applications. The advanced cycles for the COP improvement are categorized according to their heat recovery method: condensation heat recovery, absorption heat recovery, and condensation/absorption heat recovery. In H₂O–LiBr systems, the number of effects and the number of stages can be improved by adding a third or a fourth component to the solution pairs. The performance of NH₃–H₂O systems can be improved by internal heat recovery due to their thermal characteristics such as temperature gliding. NH₃–H₂O cycles can be combined with adsorption cycles and power generation cycles for waste heat utilization, performance improvement, panel heating and low temperature applications. The H₂O–LiBr cycle is better from the high COP viewpoints for the evaporation temperature over 0°C while the NH₃–H₂O cycle is better from the viewpoint of low temperature applications. This study suggests that the cycle performance would be significantly improved by combining the advanced H₂O–LiBr and NH₃–H₂O cycles.     

Condensation heat transfer coefficients of flammable refrigerants

In this study, external condensation heat transfer coefficients (HTCs) of six flammable refrigerants of propylene (R1270), propane (R290), isobutane (R600a), butane (R600), dimethylether (RE170), and HFC32 were measured at the vapor temperature of 39 °C on a plain tube of 19.0 mm outside diameter with a wall subcooling of 3–8 °C under a heat flux of 7–23 kW m⁻². Test results showed a typical trend that external condensation HTCs decrease with the wall subcooling. No unusual behavior or phenomenon was observed for these flammable refrigerants during experiments. HFC32 and DME showed 28–44% higher HTCs than those of HCFC22 due to their excellent thermophysical properties. Propylene and butane showed the similar HTCs as those of HCFC22 while propane and isobutane showed 9% lower HTCs than those of HCFC22. Finally, a general correlation was made by modifying Nusselt's equation based upon the measured data of eleven fluids of various vapor pressures including halogenated refrigerants. The general equation showed an excellent agreement with all data exhibiting a deviation of less than 3%.     

Optimal shape of the multi-passage branching system in a single-phase parallel-flow heat exchanger

A numerical simulation is performed to examine the heat and fluid flow characteristics of the branching system in a single-phase parallel-flow heat exchanger (PFHE) and to obtain its optimal shape. The relative importance of the design parameters [injection angle of the working fluid (Θ), inlet shape and location (Y_c), and height of the protruding flat tube (Y_b)] is determined to decide the optimization sequence. The optimal geometric parameters are obtained as follows: Θ=−21°, Type A, Y_c=0 and Y_b=0. The heat transfer rate of the optimum model compared to that of the reference model is increased by about 55%. The optimal values of the parameters can be applicable to the Reynolds number ranging from 5000 to 20,000.     

A study on the performance of multi-stage condensation heat pumpsEtude sur la performance des pompes à chaleur à condensation en plusieurs étages

In this study, computer simulation programs were developed for multi-stage condensation heat pumps and their performance was examined for CFC11, HCFC123, HCFC141b under the same condition. The results showed that the coefficient of performance (COP) of an optimized ‘non-split type’ three-stage condensation heat pump was 25–42% higher than that of a conventional single-stage heat pump. The increase in COP differed among the fluids examined. The improvement in COP was due largely to the decrease in average temperature difference between the refrigerant and water in the condensers, which resulted in a decrease in thermodynamic irreversibility. For the three-stage heat pump, the highest COP was achieved when the total condenser area was evenly distributed to the three condensers. For the two-stage heat pump, however, the optimum distribution of total condenser area varied with working fluids. For the three-stage system, splitting the condenser cooling water for the use of intermediate and high pressure subcoolers helped increase the COP further. When the individual cooling water for the intermediate and high pressure subcoolers was roughly 10% of the total condenser cooling water, the optimum COP was achieved showing an additional 11% increase in COP as compared to that of the ‘non-split type’ for the three-stage heat pump system.     

Split heat pipe type compound adsorption ice making test unit for fishing boats

In order to settle the problem of the corrosion between sea water and the steel adsorber for ammonia system, a split heat pipe type adsorption ice making test unit, which use compound adsorbent of CaCl₂ and activated carbon to improve the adsorption performance, is designed and constructed. For this test unit there is mass recovery function between two beds and the CaCl₂ in compound adsorbent per bed is 1.88 kg, and there is only one pump for the whole heating and cooling phase for adsorbers. Performances of this system are tested; the lowest evaporating temperature is as low as −42 °C. At the evaporating temperature of −35 and −25 °C, the cooling powers are 0.89 and 1.18 kW, respectively. At the evaporating temperature of −15 °C, its average cooling power is 1.37 kW, which corresponds coefficient of performance of refrigeration COP=0.41 and specific cooling power per kilogram CaCl₂ of each adsorber SCP=731 W kg⁻¹. The mass recovery process has improved SCP and COP for the system by 15.5 and 24.1%, respectively. Heat transfer performance is also improved by the split heat pipe construction; the average heat transfer coefficient for a whole cycle is 155.8 W m⁻² °C⁻¹.     

Experimental study on a continuous adsorption water chiller with novel design

A newly developed adsorption water chiller is introduced and tested. In the new adsorption refrigeration system, there are no refrigerant valves, the problem of mass transfer resistance resulting in pressure drop along refrigerant passage in conventional systems when methanol or water is used as refrigerant can be absolutely solved. Silica-gel–water is used as working pair and mass recovery-like process is adopted in order to use low temperature heat source ranging from 70 to 85 °C effectively. The experiment results demonstrate that the chiller (26.4 kg silica-gel in each adsorber) has a cooling capacity of 2–7.3 kW and COP ranging 0.2–0.42 according to different evaporating temperatures. Based on the experimental tests of the first prototype, the second prototype is designed and tested; the experimental data demonstrate that the chiller performance has been greatly improved, with a heat source temperature of 80 °C, a COP over 0.5 and cooling capacity of 9 kW has been achieved at evaporating temperature of 13 °C.     

Performance des mélanges de frigorigènes utilisés pour remplacer le HCFC22

In this study, 14 refrigerant mixtures composed of R32, R125, R134a, R152a, R290 (propane) and R1270 (propylene) were tested in a breadboard heat pump in an attempt to substitute HCFC22 used in residential air-conditioners. The heat pump was of 3.5 kW capacity with water as the heat transfer fluid (HTF) in the evaporator and condenser that are in a counter current flow configuration. All tests were conducted with the HTF temperatures fixed to those found in the ARI test A condition. Test results show that ternary mixtures composed of R32, R125, and R134a have a 4–5% higher coefficient of performance (COP) and capacity than HCFC22. On the other hand, ternary mixtures containing R125, R134a and R152a have both lower COPs and capacities than HCFC22. R32/R134a binary mixtures show a 7% increase in COP with the similar capacity to that of HCFC22 while R290/R134a azeotrope shows a 3–4% increases in both COP and capacity. The compressor discharge temperatures of the mixtures tested are much lower than those of HCFC22, indicating that these mixtures would offer better system reliability and longer life time than HCFC22. Finally, test results with a suction line heat exchanger (SLHX) indicate that SLHX must be used with special care in air-conditioners since its effect is fluid dependent.